Scribd Logo
Upload

Welcome to Scribd!

  • Reaction Mechanism (Redox)

    Uploaded by

    Zul Andri
    17 views8 pages

    Original Title

    Reaction mechanism (redox) (1)

    Copyright

    © © All Rights Reserved

    Available Formats

    PPTX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    17 views8 pages

    Reaction Mechanism (Redox)

    Uploaded by

    Zul Andri

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 8

    ELECTRON-TRANSFER PROCESSES

    INNER-SPHERE MECHANISM
    Bridge formation

    Electron transfer

    Bridge cleavage
    Rate-determining step
    OUTER-SPHERE MECHANISM
    Pairs of low-spin complexes  similar M-L bond length in GS

    t2g6 t2g5

    High-spin and low-spin  difference M-L bond length

    t2g5 eg2 t2g6


    Marcus-Hush theory

    If the calculated value of k12 agrees w/ experimental data


    strong evidence that the cross-reaction proceeds by
    an outer-sphere mechanism

    You might also like