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  • SEMINARIO Hydrogen Carriers

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    ANGELA MARIA VARGAS TABORDA
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    The document discusses liquid organic hydrogen carriers (LOHCs) and a nickel catalyst for hydrogenating LOHCs. It describes how LOHCs like cycloalkanes and N-heterocycles can store hydrogen at relatively high capacities. A nickel catalyst was synthesized using facile co-precipitation and gas phase reduction methods. Characterization showed the catalyst has small, well-dispersed nickel particles. Testing found the catalyst exhibits excellent activity and stability for hydrogenating benzene and other compounds without adding noble metals. The catalyst is highly suitable for hydrogenating LOHCs as an efficient and clean renewable energy storage solution.

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    The document discusses liquid organic hydrogen carriers (LOHCs) and a nickel catalyst for hydrogenating LOHCs. It describes how LOHCs like cycloalkanes and N-heterocycles can store hydrogen at relatively high capacities. A nickel catalyst was synthesized using facile co-precipitation and gas phase reduction methods. Characterization showed the catalyst has small, well-dispersed nickel particles. Testing found the catalyst exhibits excellent activity and stability for hydrogenating benzene and other compounds without adding noble metals. The catalyst is highly suitable for hydrogenating LOHCs as an efficient and clean renewable energy storage solution.

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    9 views23 pages

    SEMINARIO Hydrogen Carriers

    Uploaded by

    ANGELA MARIA VARGAS TABORDA
    The document discusses liquid organic hydrogen carriers (LOHCs) and a nickel catalyst for hydrogenating LOHCs. It describes how LOHCs like cycloalkanes and N-heterocycles can store hydrogen at relatively high capacities. A nickel catalyst was synthesized using facile co-precipitation and gas phase reduction methods. Characterization showed the catalyst has small, well-dispersed nickel particles. Testing found the catalyst exhibits excellent activity and stability for hydrogenating benzene and other compounds without adding noble metals. The catalyst is highly suitable for hydrogenating LOHCs as an efficient and clean renewable energy storage solution.

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    of 23

    LOHCs

    HYDROGEN C
    ARRIERS

    ÁNGELA MARIA VARGAS TABORDA


    CONTENTS

    01 INTRODUCTION 04 PREPARATION OF
    CATALYST
    02 LOHCs
    05 CATALYTIC
    03 Ni CATALYST for ACTIVITY
    LOHCs
    06 CONCLUSIONS
    01 INTRODUCTION
    • HYDROGEN CARRIERS • Metal Hydrides

    • Complex Hydrides

    • Chemical Hydrides

    • Physical
    Absorbents

    • LOHCs
    T. He et al. / Journal of Energy Chemistry 24 (2015) 587–594
    02 LIQUID ORGANIC HYDROGEN CARRIE
    RS

    H
    N TYPES
    • CYCLOALCANES

    • N-HETEROCYCLES
    NH2

    HN
    T. He et al. / Journal of Energy Chemistry 24 (2015) 587–594
    02 LIQUID ORGANIC HYDROGEN CARRIE
    RS
    CYCLOALCANES
    • Adventages
    - Relatively higher hydrogen
    capacity (6– 8 wt%)
    - Liquid state at room temperature
    - High boiling points
    - Production of COx-free hydrogen
    - Low toxicity
    • Disadventages
    - Coking (catalyst
    desativation)
    T. He et al. / Journal of Energy Chemistry 24 (2015) 587–594
    02 LIQUID ORGANIC HYDROGEN CARRIE
    RS
    CYCLOALCANES (B) Doublet mechanism
    • Mechanism
    cat
    + H2
    (A) Sextet mechanism

    cat + H2
    + 3H2

    + H2

    T. He et al. / Journal of Energy Chemistry 24 (2015) 587–594


    02 LIQUID ORGANIC HYDROGEN CARRIE
    RS
    CYCLOALCANES

    second catalyst
    Effective
    + (W, Ir, Re, Rh,
    against coking.
    Pd) or
    promotor (Ca,
    Al2O3 support)
    T. He et al. / Journal of Energy Chemistry 24 (2015) 587–594
    02 LIQUID ORGANIC HYDROGEN CARRIE
    RS
    • N-HETEROCYCLES

    - Favored low
    temperature hydrogen

    - Indoline HC (1.7 wt%)


    -Piperidine-4-
    carboxamide (4.7 wt%)
    -Dodecahydro-N-
    carbazole (5.8 wt%)
    T. He et al. / Journal of Energy Chemistry 24 (2015) 587–594
    03 NICKEL CATALYST FOR LOHCS
    04 NICKEL CATALYST PREPARATION

    Y. Di. et al. / International Journal of Hydrogen Energy 46 (2021) 21026 - 21037


    04 NICKEL CATALYST CARACTERIZATION

    • DRX

    Y. Di. et al. / International Journal of Hydrogen Energy 46 (2021) 21026 - 21037


    04 NICKEL CATALYST CARACTERIZATION

    • TEM

    (a) Ni70/Al2O3
    Y. Di. et al. / International Journal of Hydrogen Energy 46 (2021) 21026 - 21037
    04 NICKEL CATALYST CARACTERIZATION

    • TEM

    (b) Ni70/AlSiO 1:1

    Y. Di. et al. / International Journal of Hydrogen Energy 46 (2021) 21026 - 21037


    04 NICKEL CATALYST CARACTERIZATION

    • TEM

    (c) Ni70/SiO2
    Y. Di. et al. / International Journal of Hydrogen Energy 46 (2021) 21026 - 21037
    04 NICKEL CATALYST CARACTERIZATION

    • TEM

    (d and e) Ni70/AlSiO 1:1 catalyst


    Y. Di. et al. / International Journal of Hydrogen Energy 46 (2021) 21026 - 21037
    04 NICKEL CATALYST CARACTERIZATION
    • H2
    temperature
    programmed
    reduction
    H2-TPR profiles of
    different catalysts:
    (a) Ni70/Al2O3
    (b) Ni70/AlSiO 3:1
    (c) Ni70/AlSiO 1:1
    (d) Ni70/AlSiO 1:3
    (e) Ni70/SiO2
    Y. Di. et al. / International Journal of Hydrogen Energy 46 (2021) 21026 - 21037
    03 NICKEL CATALYST FOR LOHCS
    • The catalyst is synthesized by facile co-
    precipitation and gas phase reduction
    methods.
    • The catalyst is highly adaptive for the
    hydrogenation of benzene and others.
    • The catalyst can be used as a versatile
    catalyst for hydrogenation of LOHCs.
    • Ni has a small particle size andgood
    dispersion under high load.
    • The hydrogenation activity is 5 wt%
    05 EVALUATION OF CATALYTIC ACTIVITY

    BENCENE AND
    OTHERS
    HYDROGENATION

    • DESHYDROGNATIO
    N/HYDROGENATION
    MECHANISM

    • GS-MS

    Y. Di. et al. / International Journal of Hydrogen Energy 46 (2021) 21026 - 21037


    CONCLUTIONS
     In article, synthesized a series of 70 wt% Ni catalysts
    supported on Al2O3, and other silicates by a facile co-
    precipitation method, which can be used for
    hydrogenation of LOHCs. Presented excellent catalytic
    activity and stability without adding noble metals.

     LOHCs as an efficient, clean, and versatile


    renewable energy source, hydrogen energy is
    expected to make a breakthrough in solving energy
    problems.
    PERSONAL OPINION
    REFERENCES
    • Teng, H., Qijun, P., Ping, C. Liquid Organic Hydrogen
    Carriers. Journal of Energy Chemestry. 2015. 24. 587–
    594.http://dx.doi.org/10.1016/j.jechem.2015.08.007

    • Yuhang, D., Yuan, D., Heshun, Z,. A highly adaptable Ni


    catalyst for Liquid Organic Hydrogen Carriers
    Hydrogenation. international journal of hydrogen energy.
    2021. 46. https://doi.org/10.1016/j.ijhydene.2021.05.196

    • G. Sievi, D. Geburtig, T. Skeledzic, A. Bösmann, P. Preuster,


    O. Brummel, ... & J. Libuda (2019). Towards an efficient
    liquid organic hydrogen carrier fuel cell concept. In:
    Energy & Environmental Science, 12(7), 2305-2314.
    REFERENCES
    • Huang, F, Li, W., Yan, S.-i. Orimo, A. Züttel, CM Jensen,
    Energies 4 (2011) 185.

    • Sakintuna, B., Lamari-Darkrim, F., Hirscher, M., Int. J.


    Hydrogen Energy 32 (2007) 1121.

    • Campbell, P., Zakharov, L., Grant, D. J., Dixon, D. A, Liu, J.


    Am. Chem. Soc. 132 (2010) 3289.
    THANKS
    FOR WATCHIN
    G

    QUESTIONS?

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