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Produced Water Treatment Final
Produced Water Treatment Final
TREATMENT
LUISA FERNANDA ORTIZ RAMIREZ - 2143622
Surface facilities
2021-1
Schedule
Introduction
Disposal standards
Kahoot
Design
Introduction
When hydrocarbons are produced, the well stream typically contains
water produced in association with these hydrocarbons.
Produced water
Brine
Brackish
Salty
Disposal Standards
Chloride Magnesium
anions
Sodium
cations Iron
Calcium
Precipitated Solids (Scales)
The more troublesome
ions are those that
react to form
precipitates when
pressure, temperature, • Calcium carbonate
or composition • Calcium sulfate
changes occur. • Iron sulfide
• Barium and strontium
sulfate
Scale Removal
Mechanical
Hydrochloric acid
method
Organic
Inorganic
phosphate Phosphates Polymeres
phosphates
esters
Sand and Other Suspended Solids
When solids are present, the following practices should
Formation sand be applied:
and clays
- Chemical treatment must be used to “break” the
electronic attraction between the solid particle and
the oil droplet.
- Equipment design must incorporate solids removal
miscellaneous ports, jets, and/or plates.
Stimulation - Oil measurement techniques not affected by the
corrosion
proppant solids should be used.
products.
- Water-flood injection for pressure maintenance and
additional recovery often requires filtration.
Oil in Water
Dissolved Gases Emulsions
Most of these gases are removed in An unstable emulsion will break within
primary separators and stock tanks. minutes. A stable emulsion need
The lower the separation pressure and chemicals, heat, settling time, and
higher the separation temperature, electrostatics to break the emulsion.
the lower the quantity of dissolved
gases will be.
• Normal emulsions
• Hydrogen sulfide.
• Reverse emulsions
• Natural gas.
• Carbon dioxide.
Dispersed Oil
Difference in
specific gravity
causes the oil to Buoyant Drag Ley de
float to the surface force force stokes
of the water
Gravity Separation:
Dispersion:
Skim
(clarifier)
tank
Settling tank
• Tanks whose primary purpose is to remove entrained solids.
Wash tank
• Function as a free-water knockout, they are used when the incoming stream contains 10 to
90% oil. The water from wash tanks is generally sent to a skim (clarifier) tank or another unit to
remove the remaining oil.
Skim Tanks and Skim Vessels:
Configurations: Skim vessels can be either vertical or horizontal in configuration.
VERTICAL:
The oil, water, and gases are introduced below the oil–
water interface. Small amounts of gas liberated from the
water help to “float” the oil droplets. In the quiet zone
between the spreader and the water collector, some
coalescence can occur.
HORIZONTAL:
Pressure reduction Degassing water, Influent oil droplet Size and weight are
from a separator is catching oil slugs or sizes are mostly below the primary
required controlling surges 100 microns. considerations.
31
Skimmer Sizing Equations
Horizontal Cylindrical Vessel: Half-Full
The required diameter and length of a horizontal cylinder operating 50% full of water can be determined
from Stokes’ law:
Skimmer Sizing Equations
Horizontal Cylindrical Vessel: Half-Full
The relationship between the Leff and the seam-to-seam length of a skimmer depends on the
physical design of the skimmer internals.
The Leff should be calculated using Eq. (9-9) but must be equal to or
greater than the values calculated using the following equations:
34
Skimmer Sizing Equations
Vertical Cylindrical Skimmer:
One can determine the required diameter of a vertical cylindrical tank by setting
the oil rising velocity equal to the average water velocity.
The height of the water column in a vertical skimmer can be determined for a
selected d from retention time requirements:
The height of the oil pad in both vertical and horizontal skimmers typically ranges from 2 to 6 in.
Coalescers
The Reynolds number for the flow regime cannot exceed 1,600. The minimum H times W
for a given Qw can be determined from
CPI Sizing
Plate packs come in standard sizes with H = 325 ft (1 m), W = 325 ft (1 m), L = 575 ft (1.75 m), h = 0.69 in.,
and θ = 45°. The size of the CPIs is determined by the number of standard plate packs installed.
To ensure that the Reynolds number limitation is met, the flow through each pack should be
limited to 20,000 bwpd. It is possible to specify a 60 angle of inclination to help alleviate the
solids plugging. This requires a 40% increase in the number of packs
Oil/Water/Sediment Coalescing Separators
Is an enhancement of the cross-flow configuration
• The coalescing section is accessible for • Inlet droplet sizes are less than 10
cleaning or replacement. microns.
• The inlet oil droplet size is less than 50 • Inlet droplet sizes are greater than 100
microns and larger droplets are desired. microns.
• Coalescers can also serve as a skimmer • Size and weight are primary
considerations.
Free-Flow Turbulent Coalescers
This type of flotation unit typically has not worked well in the oil field.
These units have been used successfully in refinery operations
Dissolved Gas Units:
Dispersed Gas Units:
As a result, may understate the effluent concentrations for influent oil concentrations less than 200 mg/l.
Performance Considerations
Gas flotation units should be used: Gas flotation units should not be used:
• Equipment size and weight are prime
• The inlet oil concentrations are not too
considerations.
high (250–500 mg/l).
• Chemical companies are available to
• Service support from water treating
formulate an appropriate chemical chemical vendors is limited.
treatment program. • Very low effluent oil concentrations
• Power costs are low or moderate. are required.
• Power costs are high.
Hydrocyclones
- 40 °API
- Qw: 5000 bwpd
- Enclosure size is 2500 ft2
- Discharge criteria of 48 mg/l
- Water gravity feeds the system. P=14.7 psi
- Soluble crude of 6 mg/l
- Crude oil concentration in produced water is 1000 mg/l
- Maximum crude oil particle diameter dmax: 500 microns
- (ΔSG) w: 1.07
- μw: 1 cp
- Retention time: 10 min
- F (factor taking into account turbulence): 1
The required effluent quality is 48 mg/l. The dissolved oil is 6 mg/l. Therefore, the required
effluent quality is 42 mg/l.
dm = 21 micras
2. We have to consider the flotation cell:
Efficiency: 90%.
Output quality: 42 mg/l
𝑑𝑚 420
=
500 1000
dm = 210 micras
The inlet to the water treatment system is at too low a pressure for a hydrocyclone, therefore, a
skimming vessel must be sized upstream of the flotation unit.
3. Skimming vessel design. The pressure vessel is necessary for process considerations.
1000 𝑄𝑤 𝜇𝑤
𝑑𝐿 𝑒𝑓𝑓 =
( 𝛥 𝑆𝐺 ) ( 𝑑𝑚 )2
141,5 141,5
𝑆𝐺𝑜 = = =0,83
131,5+ 𝐴𝑃𝐼 131,5+ 40 1000 ∗ 5000 ∗1
𝑑𝐿𝑒𝑓𝑓 = 2
=472,41
𝛥 𝑆𝐺=𝑆𝐺𝑤 − 𝑆𝐺𝑜 ( 0,24 ) ( 210 )
𝛥 𝑆𝐺=1,07 −0,83=0,24
Assume various diameters (d) and solve for Leff .
To ensure that the proper retention time has been provided, the following equation must also be met.
2 𝑄𝑤 𝜇𝑤
𝑑 = 6691 𝐹
( 𝛥 𝑆𝐺 ) ( 𝑑 𝑚 )2
5000 ∗ 1
𝑑 2= 6691 ( 1 ) 2
=3160,90𝑑=56,22𝑖𝑛
( 0,24 ) ( 210 )
Seam to seam
• Retention time d (in) Heff (ft) Height (ft)
( 𝑡 𝑟 )𝑤 𝑄𝑤 54 12 16
𝐻 = 0,7
𝑑
2 60 9,72 12,96
66 8,03 11,66
10∗ 5000 72 6,75 9
𝐻= 0,7 35000
𝐻= 78 5,75 7,67
𝑑2 𝑑
2