• All living organisms are based on the carbon atom. The Carbon Atom • Carbon compounds can be solid, liquid, or gas under conditions commonly found on the earth's surface. • Because of this, carbon can help form solid minerals (such as limestone), 'squishy' organisms (such as plants and animals), and can be dissolved in water or carried around the world through the atmosphere as carbon dioxide gas. Carbon . . . On the move! • Carbon atoms continually move through living organisms, the oceans, the atmosphere, and the crust of the planet. Carbon Carbon exists in the nonliving environment as:
• Carbon dioxide (CO2)
• Carbonic acid ( HCO3−) • Carbonate rocks (limestone and coral = CaCO3) • Deposits of Fossil fuels • Dead organic matter Organic Carbon
• Hydrocarbons: CH4
• Carbohydrate: CH2O Inorganic carbon • Carbon Dioxide: CO2
• Calcium Carbonate: CaCO3
Mandale Limestone Quarry
Carbon reservoirs Carbon reservoirs
•The atmosphere.
•The biosphere (include fresh water systems and non-living
organic material, such as soil carbon).
•The oceans ( including dissolved inorganic carbon and
living and non-living marine biota).
•The lithosphere (sediments, Earth core including fossil fuels) .
The Carbon Cycle • This movement is known as the carbon cycle. The paths taken by carbon atoms through this cycle are extremely complex, and may take millions of years to come full circle. • Consider, for example, the journey of a "typical" carbon atom that existed in the atmosphere as part of a carbon dioxide molecule some 360 million years ago, during the Carboniferous Period. That molecule drifted into the leaf of a large fern growing in the extensive tropical swamp forests of that time. • The Carboniferous is a geologic period and system that spans 60 million years from the end of the Devonian Period 358.9 million years ago, to the beginning of the Permian Period, 298.9 Mya. Swamp • Soon after, the fern died and the remains sank into the muck at the bottom of the swamp. • Over thousands of years, more plants grew in the swamp and their remains also sank into the swamp, forming a layer of dead plant material many meters thick. Swamp … to … Rock • Gradually, the climate changed, becoming drier and less tropical. • Sand, dust, and other materials slowly covered the ancient swamp and sealed the decaying vegetation under an ever-thickening layer of sediment. • The sediment hardened, turning to sedimentary rock. Coal = Organic Sedimentary Rock • The carbon atom stayed trapped in the remains of the long-vanished swamp while the pressure of the layers above slowly turned the material into coals. • Some 360 million years later, in the 1900s, the coal bed was mined by humans and burned to fuel industrial civilization. Carbon Cycle Carbon is released into the atmosphere in several ways • Respiration by plants and animals.
• Decay of animal and plant matter.
• Combustion of organic material
• Production of cement.
• The ocean releases CO2 into the atmosphere.
• Volcanic eruptions and metamorphism
Carbon is taken from the atmosphere in several ways • Photosynthesis. • The oceans when the seawater becomes cooler, more CO2 dissolve and become carbonic acid. • In the upper ocean areas organisms convert reduced carbon to tissues, or carbonates. Photosynthesis • CO2 + H2O + sunlight CH2O + O2 Release of Energy
• The process of burning
released the energy stored in the carbon compounds in the coal and reunited the carbon atom with oxygen to form again The Journey Continues • The carbon was released to the atmosphere through the smokestack and the journey continues. • Many other paths are possible, some taking only hours or days to trace, others, like the one we just learned about, many millions of years The Carbon Cycle • Carbon may be stored for extended periods (the "sinks") • There are various way it is likely to be released to the atmosphere (the "source") • There are things that trigger these sources to release carbon (the "release agents") • Together they define the carbon cycle. “The Sinks” = Where Carbon is Stored • Carbon sinks include long-lived trees “The Sinks” • All living and non- living organisms “The Sinks” • Limestone (formed from the carbon- containing shells of small sea creatures that settle to the ocean bottoms and build up into thick deposits) “The Sinks” • Plastic (a modern invention, but very long-lived) “The Sinks” And . . .
• Burial of organic matter
(such as those that formed the fossil fuels we use today). “The Sources” = How Carbon is Released into the Atmosphere • Carbon sources include the burning of fossil fuels and other organic matter “The Sources”
• Weathering of limestone rocks
“The Sources” • The breakdown of substances into simpler molecules is called decomposition. • Fungi and bacteria decompose organic matter. • Carbon dioxide and water are returned to the environment. “The Sources” And . . .
• Release agents include volcanic activity, forest fires
“Releasing Agents” • Combustion is the process of burning a substance, such as wood or fossil fuels. • Because of combustion, carbon dioxide is released back into the atmosphere. “Releasing Agents” And . . .
• Many human activities.
Respiration • CH2O + O2 CO2 + H2O + energy Combustion or Oxidization of hydrocarbon
CH4 + 2 O2 CO2 + 2 H2O + energy
Human Impacts on the Carbon Cycle Burning fossil fuels have serious impact on the carbon cycle. Fossil Fuel
86% of global primary energy consumption is
fossil fuels. Fossil Fuels • Petroleum • Natural Gas • Coal CO2 Concentration
Pre-Industrial value: 280 ppm (600 billion tons)
Current value: 380 ppm (800 billion tons) Critical value: 560 ppm (1200 billion tons) • Co2 concentration in the air is 412 parts per million • The concentration of carbon dioxide in Earth's atmosphere is currently at nearly 412 parts per million (ppm) and rising. • This represents a 47 percent increase since the beginning of the Industrial Age, when the concentration was near 280 ppm, and an 11 percent increase since 2000, when it was near 370 ppm.