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Unit Operation Class
Unit Operation Class
Assistant Professor
Dept. of PG Studies & Research in
Industrial Chemistry
Sir. M.V. Govt. Science College
Bommanakatte, Bhadravathi
KARNATAKA
Introduction
• Chemical Engineering is the branch of engineering which is
concerned with the design and operation of industrial chemical
plants.
The steps involving certain physical changes are known as the unit
operations; whereas the step(s) involving chemical changes in the
material under consideration (i.e., chemical reactions) are known as
the unit process(es).
2.Work / Energy : The units of work (energy) in SI, MKS, CGS and
FPS systems are joule (J), m.kgf, erg and ft.lbf respectively.
3.Heat : The units of heat in SI, MKS, CGS and FPS systems are
joule (J), kilocalorie (kcal), calorie (cal) and British thermal unit
(Btu) respectively.
1 cal = 4.187 J,
1 Btu = 1055.056 J
In the SI system, heat flow/heat flux is usually expressed in watts (W).
Solar cookers
Microwave ovens
Microwave cookers
In general, all 3 mechanisms may operate
simultaneously.
• For example…
• In ovens air circulate by fan, so as to transfer heat by
forced convection.
• Simultaneously, heat is transferred by
conduction from the shelf to the material in contact.
• Heat also radiates from hot walls of the oven.
CONDUCTION
Conduction refers to the mode of heat transfer in which the heat
flow through the material medium occurs without actual
migration of particles of the medium from a region of higher
temperature to a region of lower temperature.
Q A [– dT/dn] … (1)
Q = – kA [dT/dn] … (2)
where ,
Q = rate of heat flow/transfer in watts (W),
A = area normal to the direction of heat flow in m2,
T = temperature in K,
n = distance measured normal to the surface,
(i.e., the length of conduction path along the heat flow in m, )
dT/dn = rate of change of temperature with distance
measured in the direction of heat flow (called as temperature
gradient) in K/m.
k = constant of proportionality and is called the thermal
conductivity. It is the characteristic property of a material through
which heat flows.
The negative sign is incorporated in equation (2)
Q = – kA [dT/dx] … (3)
[The heat flux is defined as the amount of heat transfer per unit
area per unit time or the rate of heat transfer per unit area, Q/A.]
Thermal Conductivity
k = a + bT
Steady state heat conduction is a simpler case in the sense that the
temperature does not vary with time. T is independent of time and
is a function of position in the conducting solid.
x=0 x=x
X
Consider that the wall is made of a material of thermal
conductivity k
is of uniform thickness (x) and constant cross-sectional area (A).
The usual use of Fourier's law requires that the differential equation
(3) be integrated over the entire path from x = 0 to x = x (total
thickness of the wall) as we normally know temperatures only at the
faces.
5
7
8
10
R1 R2 R3
T1 T1 > T' > T" > T2
Q T''
Heat flow
T2
k1 k2 k3
x1 x2 x3
….. (6)
….. (7)
Adding Equations (2), (6) and (7), we get
….. (8)
Under steady state conditions of heat flow, all the heat passing
through the layer-1 (first resistance) must pass through the layer-2
(second resistance) and in turn pass through the layer-3 (third
resistance),
….. (10)
….. (11)
….. (12)
….. (14)
….. (15)
….. (16)
R = R 1 + R 2 + R3 ….. (17)
Then, Equation (16) becomes ….. (18)
Equation (18) is the same as the equation for the rate of any
process :
One can calculate the temperatures at the interfaces of layers of
which the wall is made by making use of the following relation
….. (19)
A thin layer with a low thermal conductivity value may cause a much
larger temperature drop and a steeper thermal gradient than a thick
layer having a high thermal conductivity.
Heat flow through a
cylinder :
Consider a thick walled hollow cylinder as shown in Fig. of inside
radius r1, outside radius r2 and length L.
Assume that T1 > T2, therefore heat flows from the inside of the
cylinder to the outside.
….. (1)
….. (2)
the only variables in Equation (2) are r and T (assuming k to be
constant).
Integrating Equation (2) between the limits
when r = r1 , T = T1 and
when r = r2 , T = T2 gives
….. (3)
….. (4)
….. (5)
The rate of heat flow through a thick walled cylinder is
….. (6)
….. (7)
where rm is the logarithmic mean radius and is given by
….. (8)
dr
r1 r
T2 T1 r2
….. (2)
and r = r 2 , T = T2
….. (3)
….. (4)
….. (5)
Rearranging Equation (5), we get
….. (6)
….. (7)
….. (8)
Thermal Insulation
Process equipments such as a reaction vessel, reboiler, distillation
column, evaporator, etc. or a steam pipe will lose heat to the
atmosphere by conduction, convection and radiation.