Trng i Hc Cng Nghip TP.

HCM Khoa Cng Ngh Ha Hc Mn: Phn tch cng nghip

ti:
Xc nh ng thi CaO v MgO trong phn bn v c
GVGD: Th.s Trn Nguyn An Sa SVTH: Nguyn Vn kiu

Lp: DHPT5

Ni dung

Gii thiu chung

Quy trnh phn tch

Ti liu tham kho

Gii thiu chung

Phn bn v c

Hp cht Cao v MgO

1. Phn bn v c
Khi nim
Phn v c cn gi l phn khong, phn ho hc. l cc loi mui khong c cha cc cht dinh dng ca cy. Cung cp cht dinh dng quan trng cho s pht trin ca cy trng, gp phn lm cho cy trng pht trin tt v t nng sut cao.

c im chung
T l cht dinh dng cao. D tan trong nc v cy trng d hp thu. Khng cha cc cht hu c

1. Phn bn v c
phn loi
Gm c 3 loi chnh: Phn v c a lng : Phn m - Phn ln - Phn kali - Vi bn rung - Phn tng hp v phn hn hp. Phn v c trung lng Phn v c vi lng

1. Phn bn v c

Phn v c a lng

Phn v c vi lng Phn v c trung lng

Hp cht CaO v MgO Tnh cht

CaO
L cht rn dng tinh th mu trng, l mt cht n da v c tnh kim. phn t gam bng 56,1 g/mol, nhit

nng chy 2572 C.

C cu trc tinh th la lp phng tm mt.

MgO
MgO l cht bt xp v trng c trng lng ring 3,19 -3,71 v nhit nng chy cao hn 2500oC.

Hp cht CaO v MgO Vai tr ca CaO v MgO i vi cy trng CaO

Cung cp Canxi. Ci to t chua, mn. To iu kin cho vi sinh vt hot ng tt.

MgO
Cung cp Mg cho cy.

L thnh phn ca dip

lc, gip cy quang hp.

Tng kh nng hp thu

cc cht dinh dng ca cy.

Thc y hp th v
vn chuyn ln.

Khi thiu Ca: L v t non d b cong queo v nh, mp l khng u, hay c hin tng chi cht ngn, r nh tr sinh trng v thng b thi.

Khi thiu Mg: dn n bnh a vng phn tht l ch cn cc gn l

la mu xanh, l tr nn nh, l b rng sm, hoa ra t, km pht trin

Hp cht CaO v MgO Cc nguyn liu sn xut phn bn c cha CaO v MgO Qung Dolomit
Dolomit l tn mt loi trm tch cacbonat v l mt khong vt, cng thc ha hc ca tinh th l CaMg(CO3)2 Tinh th trng, xm n hng Cha khong 32% CaO v 16% MgO

Hp cht CaO v MgO Cc qung khc

Qung apatit
Cc loi qung apatit loi 1 loi 2 cng nh loi 3, khong vt apatit u c cu trc Ca5F (PO4)3 thuc loi fluoapatit, trong

c khong 42,26% P2O5; 3,78%F v khong 50% CaO

khong Secpentin khong vt ph lp silicat, Mg6[Si4O10](OH)3. C b ngoi

ging nh da con rn. Theo c trng bin dng mng tinh th

chia ra ba loi. Trong thnh phn ca n cha ti 15-25%MgO.

Quy trnh xc nh hm lng CaO v MgO

1. Quy trnh ly v x l mu

2. Quy trnh phn tch

3. Tnh ton hm lng CaO v MgO

Quy trnh ly v x l mu
Cch ly mu Dng c ly mu
ng thm mu c dng hnh ng lng mng Bao ti ng mu sch, kh, kn lm bng PE

a im ly mu
Ly mu trong kho Ly mu ti a im bn

Quy trnh ly v x l mu
Cch ly mu Tin hnh ly mu
Cc mu ban u c phn b ngu nhin cc v tr pha
trn, gia va di. C th ly mu cc vi tr ty trong bao. Chn ngu nhin 1% s bao cc lp trn, gia va d

Tin hnh ly mu tng bao vi mt lng mu sao cho

tng lng mu ly c khng t hn 7kg. Ly ti thiu 5 ln

Quy trnh ly v x l mu
X l mu
Nghin mu ri ry qua nha 2mm Trn u t 3 -5 ln Ly mu trung bnh cho n khi cn khong 100g.

Bo qun mu
Bo qun mu ni kh mt, sch, nhit khng kh

phng.
Thi gian bo qun lu gi mu 3 thng k t ngy ly mu.

Quy trnh phn tch

Nguyn tc
Xc nh CaO v MgO bng phng php chun

Complexon thng qua vic xc nh Ca v Mg.

Thuc th
Dung dch tiu chun trilonB
Ch th mu eriochrom T en. Dung dch m pH = 10. Dung dch KOH

Dung dch KCN

Quy trnh phn tch

Qui trnh Chun b mu
Cn 1g mu HCl H2O HCl C cn H2O Dung dch mu Ra H2O Lc HCl

Ha tan

Dung dch

Quy trnh phn tch

Qui trnh Xc nh Ca, Mg
nh mc dung dch mu thnh 250ml Chun b 2 mu song song. Ht 25ml dd cho vao erlen, thm 20ml m pH=10 i vi mu th 1. Thm 5ml dd KCN 5%, v cht ch th ETOO. Tin hnh chun bng EDTA cho n khi dd chuyn t mu nho sang xanh chm.(V1) Tin hnh chun mu trng thu c (V2).

Quy trnh phn tch

Qui trnh Xc nh Ca, Mg
i vi mu th 2: Ht 25ml dd mu vo erlen, thm

5ml dd KOH 30% v 5ml dd KCN vi cht ch th murecid

Tin hnh chun bng dd EDTA cho n khi dd chuyn sang mu tm (V3).

Tin hnh chun mu trng.(V4)

Tnh ton hm lng CaO v MgO

Hm lng CaO:

Hm lng MgO:

Ti liu tham kho

1.Tiu chun 10TCN 455-2001, phng php xc nh canxi

tng v magi tng s

2.Tiu chun 10TCN 301-2005, phng php ly mu v chun b mu. 3.Trn Th Bnh-Phng Tin t-L Vit Phng-Phm Vn Thng, Ha Hc Cng Ngh V Mi Trng, NXB Gio Dc, nm 1999.