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Electrochemistry

Electrochemical Series
1. Electrochemical Series based on the Potential Difference (Voltage Difference) - measure the potential difference between two metals in voltaic cells. - negative terminal (anode) in voltaic cell has a higher tendency to release electrons = higher position in the electrochemical series - positive terminal (cathode) in voltaic cell has a lower tendency to release electrons = lower position in the electrochemical series. - the greater the potential difference (voltage) = further part the positions of two metals in electrochemical series.

2. Electrochemical Series from the Displacement Reaction of Metals - to construct an electrochemical series = ability of a metal to displace another metal from its salt solution. - higher position of a metal in the electrochemical series = able to displace a metal below it from its salt solution. Example: Mg(s) + CuSO4(aq)

MgSO4(aq) + Cu(s)

- Mg is more electropositive than Cu (placed higher than copper in electrochemical series) - Mg atom loses electrons to form magnesium ion and dissolves in the solution.

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