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Integrated sensing platform for gases and liquids in the near and mid-infrared range
J. Faist, P. Jouy
ETH Zurich
Sensing needs
gas fluid
Sensitive Selective
Infrared Spectroscopy
Semiconductor System
Nano-Tera annual meeting, 30. 5. 2013
Sources
Interaction system
Liquid
Pilot/focus applications
Gas: CO2 isotope ratios, e.g for plant respiration monitoring environment Liquid: Cocaine in saliva detection (presence yes/no) traffic security Platform: develop tools and techniques Collaboration with industry (EPFL + industrial partner)
IrSens Jerome Faist Nano-Tera annual meeting, 30. 5. 2013
Measurements in Gases
Main isotope. indicator for heliobacter pyroli stomach cancer quantifiy soil exchange processes. tracer for stratospheric air.
B. Tuzson, M. Mangold, H. Looser, A. Manninen, L. Emmenegger, Opt. Lett. 38, 257 (2013).
B. Tuzson, M. Mangold, H. Looser, A. Manninen, L. Emmenegger, Opt. Lett. 38, 257 (2013).
A patent was filed protecting the use of an absorption mask in a gas cell for MIR laser spectroscopy.
M. Mangold, B. Tuzson and L. Emmenegger, "Method for reducing fringes in laser spectroscopy measurements using an absorption mask in combination with multi-pass optical cells". Switzerland Patent 01884/12, 2012. IrSens Jerome Faist Nano-Tera annual meeting, 30. 5. 2013
D. Hofstetter, J. Di Francesco, L. Hvozdarara, H.-P. Herzig, M. Beck, Appl. Phys. B 103, 967 (2011).
D. Hofstetter, J. Di Francesco, L. Hvozdarara, H.-P. Herzig, M. Beck, Appl. Phys. B 103, 967 (2011).
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Measurements in Liquids
Measurements in liquids
QCL Source Waveguide
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Technological blocks:
M M
Integration
IrSens Jerome Faist Nano-Tera annual meeting, 30. 5. 2013
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0.04 Absorbance
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0 1800 1700 1600 1500 1400 1300 1 Wavenumber [cm ] 1200 1100 1000
Comparison between spectra of pure cocaine, TCE phase of an extract from saliva spiked with pure cocaine and of an extract of saliva spiked with street cocaine (from the Forensic Science Institute Zurich)
10 mm
Improvements to integrate:
Parallel Flow
Merging Drainage
Extraction
Droplet Generation
Parallel Flow
outlet inlet
100 g/ml
5 g/ml
Spectroscopy applications:
HF step detection
light source
M M M
Conclusion
M All integrated gas detection demonstrator M First combination of QCL with QCD M State of the art measurements on CO2 isotopes
(13C/12C ratio: 0.6 accuracy in 1s and 0.1 in 250s) sensitivity, optimization of the gas cell) Multi gas detection (IrNOX and IrSens II)
M Improvement of the detection limit (better QCD M M Commercialization/industralization M Integrated microfluidic system for liquid-liquid extraction mounted on a Si/Ge waveguide M ATR measurements down to 5 g/ml concentrations M Preconcentration microfluidic system M Integration of a reference channel and longer waveguide-liquid interaction M Development of wafer-fused VCSELs around 7600 cm-1 M Detection of several species (HF, Ammonia, Methane) M Characterization of APD with extremely good I-V properties M Optimization of VCSELs geometry for industrial production M Characterization of SPADs arrays
IrSens Jerome Faist
IrSens team
ETH K.Hans, Markus Sigrist M. Beck, B. Hinkov, P. Jouy, J. Faist EPFL E. Kapon, A. Sirbu, V. Yakovlev E. Charbon, P. Keijzer, M.Aminian A. Homsy, P. Wagli, N. DeRooij, L. Hvozdara, J. Di Francesco, Yu-Chi Chang, H.P Herzig UNINE A. Wirthmueller, D. Hofstetter FHNWS H. Looser, W. Koch EMPA B. Tuzson, J. Jagerska, M. Mangold, L. Emmenegger