Marla vllLanleml

!"#$%&'(
!oseue Marrero
ur. uonald 8lake
ConLrlbuuons of
varlous Chemlcal Specles Lo
Czone lormauon oLenual
PealLh LecLs (eyes, lungs...)
8educed roducuvlLy of lanLs
ShorL-llved Creenhouse Cas
Smog
1ropospherlc Czone
lacLors aecung
Czone lormauon oLenual
LnvlronmenLal Condluons
1emperaLure
SunllghL
8oundary layer helghL
ALmospherlc Mlxlng
Lmlsslons
naLural
AnLhropogenlc
Czone
Pydroxyl 8adlcal
1he ueLergenL of Lhe ALmosphere
aruclpaLes ln many lmporLanL
processes ln urban envlronmenLs,
many of whlch lead Lo .
Cxldauon of vCCs
roducuon of Czone
naLural vCCs
*+ ,-&.%# !%#%/01"
,2 3 425 6 ,2
7
3 52
7
52
7
3 82 6 425 3 82
7

82
7
3 !" 6 82 3 42
42 3 2
7
6 2
9

vCCs Lo Czone
*+ ,-&.%# !%#%/01"
,2 3 425 6 ,2
7
3 52
7
52
7
3 82 6 425 3 82
7

82
7
3 !" 6 82 3 42
42 3 2
7
6 2
9

7+ :;<-#"'
=5 3 425 6 4= 3 5
7
2
4= 3 2
7
6 4=2
7

4=2
7
3 82 6 4=2 3 82
7

4=2 3 2
7
6 4=2 3 52
7
vCCs Lo Czone
*+ ,-&.%# !%#%/01"
,2 3 425 6 ,2
7
3 52
7
52
7
3 82 6 425 3 82
7

82
7
3 !" 6 82 3 42
42 3 2
7
6 2
9

7+ :;<-#"'
=5 3 425 6 4= 3 5
7
2
4= 3 2
7
6 4=2
7

4=2
7
3 82 6 4=2 3 82
7

4=2 3 2
7
6 4=2 3 52
7
vCCs Lo Czone
Pydroxyl 8adlcal 8eacuons
CP 8eacuvlLy
1ells us Lhe conLrlbuuon
of speclc specles Lo
Czone lormauon oLenual
lndlvldual reacuvlues are
based on llLeraLure
63 compounds were
lncluded
MeLhane (ppm) :>?@8@A BCC$D 5:>2,:=E28A BCC$D :=2!:FG,A BCC$D
CC (ppb) LLhene ClC-11 8enzene
ropene ClC-12 1oluene
:>?:8@A BCC$D cls-2-8uLene ClC-113 LLhylbenzene
LLhane Lrans-2-8uLene MeLhyl Chloroform o-xylene
ropane LLhyne C -1eLrachlorlde n-ropylbenzene
l-8uLane Palon-1211 3-LLhylLoluene
n-8uLane EG2H@8G,A BCC$D Palon-1301 4-LLhylLoluene
l-enLane lsoprene PClC-22
1,3,3-
1rlmeLhylbenzene

n-enLane o-plnene PClC-142b
1,2,4-
1rlmeLhylbenzene

n-Pexane -plnene PClC-141b
1,2,3-
1rlmeLhylbenzene

n-PepLane MeLhyl 8romlde
n-CcLane 2/IJ"#-$"' BCC$D MeLhyl Chlorlde :>?K> 8GF=:F@A BCC$D
n-nonane LLhanol MeLhyl lodlde MeLhyl nlLraLe
n-uecane AceLaldehyde MeLhylene 8romlde LLhyl nlLraLe
2,3-ulmeLhylbuLane MeLhylene Chlorlde l-ropyl nlLraLe
2,4-ulmeLhylpenLane Chloroform n-ropyl nlLraLe
2-MeLhylpenLane AL;M1"' 1rlchloroeLhene 2-8uLyl nlLraLe
3-MeLhylpenLane uMS (MS) 1eLrachloroeLhene 3-enLyl nlLraLe
2,2,4-
1rlmeLhylpenLane

2-enLyl nlLraLe
CyclopenLane
MeLhane (ppm) :>?@8@A BCC$D EG2H@8G,A BCC$D 5:>2,:=E28A BCC$D
LLhene lsoprene ClC-11
CC (ppb) ropene o-plnene ClC-12
cls-2-8uLene -plnene ClC-113
:>?:8@A BCC$D Lrans-2-8uLene MeLhyl Chloroform
LLhane LLhyne 2/IJ"#-$"' BCC$D C -1eLrachlorlde
ropane LLhanol Palon-1211
l-8uLane :=2!:FG,A BCC$D AceLaldehyde Palon-1301
n-8uLane 8enzene PClC-22
l-enLane 1oluene AL;M1"' BCC$D PClC-142b
n-enLane LLhylbenzene uMS (MS) PClC-141b
n-Pexane o-xylene MeLhyl 8romlde
n-PepLane n-ropylbenzene :>?K> 8GF=:F@A BCC$D MeLhyl Chlorlde
n-CcLane 3-LLhylLoluene MeLhyl nlLraLe MeLhyl lodlde
n-nonane 4-LLhylLoluene LLhyl nlLraLe MeLhylene 8romlde
n-uecane 1,3,3-1rlmeLhylbenzene l-ropyl nlLraLe MeLhylene Chlorlde
2,3-ulmeLhylbuLane 1,2,4-1rlmeLhylbenzene n-ropyl nlLraLe Chloroform
2,4-ulmeLhylpenLane 1,2,3-1rlmeLhylbenzene 2-8uLyl nlLraLe 1rlchloroeLhene
2-MeLhylpenLane 3-enLyl nlLraLe 1eLrachloroeLhene
3-MeLhylpenLane 2-enLyl nlLraLe
2,2,4-1rlmeLhylpenLane
CyclopenLane
Samples
A-;$%# A"-
,"#$&-; N-;;"I B,ND
E-<"&'M";1
A-#$- E-&.-&- ,O-##";
>%' :#J";"' E-'0#
A-;$%# A"-
hup://www.gpsvlsuallzer.com/
k
CP
ln SouLhern Callfornla
0.00
0.30
1.00
1.30
2.00
2.30
3.00
3.30
4.00
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CP
4

,"#$&-; N-;;"I B,ND
E-<"&'M";1
A-#$- E-&.-&- ,O-##";
>%' :#J";"' E-'0#
A-;$%# A"-
Samples
Samples
A-#$- E-&.-&- ,O-##";
>%#J E"-PO
>%' :;-S0$%'
2#$-&0%
k
CP
conLrlbuuon by vCCs
0.00
0.20
0.40
0.60
0.80
1.00
1.20
1.40
2
5

=
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P
Q
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>%' :;-S0$%'
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>%#J E"-PO
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2#$-&0%
8oundary Layer PelghL
Mornlng (10am) Aernoon (3pm)
hup://fuelberg.meL.fsu.edu/pub
hup://fuelberg.meL.fsu.edu/pub
k
CP
conLrlbuuon by vCCs
0.00
0.20
0.40
0.60
0.80
1.00
1.20
1.40
2
5

=
"
-
P
Q
R
0
$
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>%' :;-S0$%'
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>%#J E"-PO
M
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2#$-&0%
ercenL ulerence
Mornlng ! Aernoon
Los AlamlLos Long 8each CnLarlo
:;<-#"' -63 -31 -43
:;<"#"' -83 -20 -72
E0%J"#0P' -4 231 -33
:&%S-QP' -89 -3 -71
2/IJ"#-$"' -38 -22 -40

F2F:>
-43 -13 -33
Concluslon
Czone lormauon oLenual and
CP 8eacuvlLy are aecLed by.
ConcenLrauon of Sources
CenLral valley vs AlrporLs
ulurnal Cycles
8oundary Layer PelghL
Source ulerences
! ollcy dlerences for dlerenL areas
vs
AcknowledgemenLs
!oseue Marrero
ur. uon 8lake
8lake Croup
SA8 MenLors
ur. Lmlly Schaller
8lck Sheuer
uC-8 Crew
SA8lans