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Some exams questions and answers

Which of the following does not represent-1


?a chemical change
A)iron rusting B)reaction of sodium
metal with water C)dissolving sugar
in water D) souring of milk
F)leaves changing color

C) dissolving sugar in water


Which of the following does not represent-2
:a physical property
A) boiling point B) odor
C) density D) reaction with
oxygen. F) solubility in water

Indicate the numbers of protons, neutrons


:and electrons in the following atoms

64
30 Zn , 109
47 Ag , 14
6 C , 243
95 Am

-A-1
Am: 95 protons, 95 electrons, 148
neutrons
C : 6 protons 6 electrons 8
neutrons
Ag: 47 protons 47 electrons 62
neutrons
Zn: 30 protons 30 electrons 34
neutrons

• Calculate the molecular mass of each of


the following:
Li2O, C3H7Br, (CH3CH2CH2)2O,
KHSO3, N2O5, KNO2
(a) -Li2O= (7x2) + 16 = 30 g
(b) -C3H7Br = (3x16) + (7x1) + 80= 123 g
(c) -(CH3CH2CH2)2O = 102 g
(d) -KHSO3 = 39 + 1 + 32 + ( 3x16) = 120 g
(e) -N2O5 = ( 2x14) + (sx16) = 108 g
(f) -KNO2= 39 + 14 + (2x16) = 85 g

-Calculate the number of moles of CO


present in a 125 g sample of
(the gas. ) (6 marks
number of moles = mass in grams/molar
mass
number of moles of CO = 125/28 = 4.464 mol

Answer whether each of the following


statement is true or false:
(Answer 5 only) (15 marks)

a. Bases react with many metals to


produce ionic compounds and
hydrogen gas. ( false)
b. The molarity (M) so called molar
concentration.( true )
c. Within a group, electronegativity
increases from bottom to top.( true)
d. Dilution increases the volume of a
solution.( true)
e. Acids turn the color of the indicator
litmus from red to blue.( false)
f. Matter is anything that has mass
and occupies a size of space.( true)

5. The metal indium melts at 156ºC. The


boiling point of the organic
liquid cyclohexanol is 321 ºF. Will
indium melt in boiling
cyclohexanol? ) (6 marks)
F⁰ = ( C⁰ x 1.8 ) + 32
F⁰ = ( 156 x 1.8 ) + 32 = 280.8 F⁰ ⇒ yes
Indium will melt in boiling point of
cyclohexanol

6. Determine which of the following


represent elements and which do not.
C, CO, Cl, CaCl2, Na, KI
C , Cl , Na : are elements , CO , CaCl₂
, KI : are not
7. Which of the following pairs of symbols
represent isotopes?
(marks 4)
186 66 57 186
E E E E
and 74 , 28 and 28 , 74

70
70
E E
33 34
and

44 22 8
22 E and 11 E , 4 E

and 7
3 E

70 70
E E
34 and 33 are isotops
8. What are the names and symbols of the SI
base units for length,
?mass and time
mass = kg , time = second
9. Write: (10 marks)
a) The molecular formula of Phosphorus
Pentachloride
.b) The name of SF6

a) - phosphorus pentachloride PCl₅)


b) – sulphur hexafluoride SF₆)

Which of the following does not .10


?represent a physical property
A) color
B) clarity
C) hardness
D) melting point
E) flammability
E) flammability does not represent a
physical property
In the metric system, the prefix micro .11
represents the multiple
A) 10-1.
B) 10-2.
C) 10-3.
D) 10-6.
E) 10-9.
D)- 10-6.

?How many g in 580.4 mg-4

g 0.5804
Which metric prefix would replace the-5
?power of ten in 3.68x10ˉ³ m

mm 3.68

.Convert 184⁰F to Celsius-6

C⁰ = F⁰ - 32/1.8
C⁰ = 184-32/1.8 = 48.44
During the course of a day, the .12
difference between the highest and
the lowest temperature for the day was
9°C. What was the
?temperature variation in °F
A) 5
B) 9.3
C) 16.6
D) 25.7
E) 34
F) 48.2
°F = (°C x 1.8 ) + 32
°F = ( 9 x 1.8 ) + 32 = 48.2

7-What is the volume in L of 64.0 fluid ounce


bottle? (1L=1.o6qt) and (1qt=32fl.oz).

Number of
Which of the following does not vary .13
?with temperature
A) volume
B) mass
C) density
D) Kelvin
E) °C
B) mass
Aqueous HI is known as .14
.A) hydroiodic acid
.B) hydrogen iodide
.C) helium iodide
.D) hydrogen monoidide
.E) hyperiodous acid
.A) hydroiodic acid

What the PH of 0.001 M solution of -15


?hydrochloric acid
[ ⁺PH= - log [ H
[ PH= - log [ 10ˉ³
PH= 3
Calculate the PH value of a solution of -16
sulphoric acid containing 4.9 g per liter
?of the acid
the molar concentration of the acid-
= 4.9/98=0.05
the molar concentration of hydrogen ions [ H⁺ ]=-
0.05 x 2 = 0.1 mol/lit

[PH = - log [10ˉ¹


PH= 1
Calculate the PH value of 0.004 -17
solution of acetic
acid, where the ionization ratio
.constant (α) is 25%
H⁺ ] = M x α ]
H⁺ ] = 0.004 x 0.25 = 10ˉ³ ]
[ ⁺PH= - log [ H
[ PH = - log [ 10ˉ³
PH = 3
Calculate the PH value of 0.001 M -18
?solution of sodium hydroxide
OHˉ ] = 10ˉ³ ]
[ ˉPOH = - log [ OH
[ POH = - log [ 10ˉ³
POH = 3
We know that : PH + POH = 14
:So we write
PH + 3 = 14
PH = 11

Q1-Answer only 15
1)-Which of the following is the correct
formula of copper(1) oxide?
a)CuO b)Cu₂O c) Cu(OH)₂ d)Cu₂O₃
e) CuO₂

2)-which of the following is not a physical


property?
(a)solid sulphur is yellow
(b)diamond is highly hard
(c)solid iron(Fe) melts at 1533Cº
(d)carbon reacts with oxygen to form carbon
dioxde (CO₂)

What is the right name of the following -(3


:compound
BaCl₂
a)Bromuim Chloride , b)Barium Chloride ,
c)Barium Dichloride
d)Barium(11)Chloride

Which of the following compounds are-(4


: insoluble in water
a) CaCl₂ b) NaCl c)Fe(OH)₃ d)FeCl₃
e)Pb(NO₃)₂
f) Ag₂SO₄
Regarding the following reaction, which-(5
?statement is incorrect
Cu + 2Ag⁺ → Cu²⁺ + 2Ag
a)copper is oxidized b)copper is reduced
c)Ag⁺ is reducing agent d) silver is
oxidized

Which of the following has the highest-(6


:ionization energy value
a) Cu , b) F , c)Na , d) C ,
e)O

:Which of the following orbitals fills first-(7


a) 3d b)3p c)4f d)3s e)4d
Which of the following is the best -(8
:electrical conductor
a) 0.6 M HNO₃ b)0.4 M CH₃COOH , c) 1.0 M
CH₃CH₂OH d)0.14 M HCl e)0.8 M H₂SO₃
f) 0.80 M NH₄OH

Predict which of the following bond is the -(9


:shortest

Which of the following is the correct-(10


:Lewis symbol for an atom of Cl

11)Which of the following bonds is the most


polar bond:
a)C-O b)NaBr c)N-O d)Cl-Cl e)S-O

12)- Indicate the oxidation number of the


underined atom in each of the following:
a)KMnO₄ b)Mg(ClO₄)₂ C)K₂Cr₂O₇
13)- Which of the following diagrams is not
allowed:

14)-Given the following equation:


2H₂(g) + O₂(g) → 2H₂O(l) ΔH⁰ =-
571.6kJ/mol
Which statement is incorrect?
a) ΔH⁰ for the reverse reaction is + 571.6
kJ/mol

b) ΔH⁰ for the forming one mole of liquid


water is -285.8 kJ/mol

c) ΔH⁰ for the reaction of one-half mole of


oxygeb is -285.8kJ/mol

d) The equation forming gaseous water


would have different ΔH⁰

e) The standard heat of formation of liquid


water is -571.6 kJ/mol.
15)-How many protons, electrons and
neutrons are there in the following atoms:

16)- The emperical fornula of dichloro butane


is C₂H₄Cl and its molecular mass is 127 u ,
what is the molecular formula?

17- calculate the formal charge of the


nitrogen atom in the compond:

Q2- Identify if the following statements are


correct or wrong.
1-( ) the chemical property displayed by
the matter as it does not undergo any change
in the composition.
2-( ) kandela is a SI unit
3-( ) electron affinity is the energy
required to remove one electron from an
isolated atom at the gas state and ground
state.
4-( ) work is the transfer of energy
between the system and its serroundings.
5-( ) the isotopes are atoms of
different atoms having the same mass
number and different atomic number.

Q2- Follow the instruction given for each


question and answer the following :
a- Calculate the consumed amount and
the remaining amount of oxygen during
the reaction of 14.4 g of C₅H₁₂ in 100 g of
oxygen :
C₅H₁₂ + O₂ → CO₂ + H₂O

Answer:
1- we have to balance the equation:
C₅H₁₂ + 8O₂ → 5CO₂ + 6H₂O
1- to solve the problem, we write:
C₅H₁₂ + 8O₂ → 5CO₂ + 6H₂O
72 g 8x32g
14.4g x
3- The consumed amount of oxygen=
X= 14.4g x 256 g/72 g = 51.2 g
4- the remainin amount of oxygen=
100 – 51.2 = 48.8 g

b-when 0.20 mol of magnisum Mg is


reacted with excess of nitrogen, how many
moles of nitrogen are consumed?
3Mg + N₂ → Mg₃N₂

c- what mass of NaOH, in grams is


required to prepare 120 ml of 0.20 M of
NaOH solution?

d- Calcium oxide reacts with carbon


dioxide to form calcium carbonate :
CaO(s) + CO₂(g) → CaCO₃(s) ΔH= - 178.4 kJ
What is the heat evolved in the formation
of 500 g of CaCO₃ ?
e-use the following equations:
N₂(g) + 2O₂(g) → N₂O₂(g) ΔH=9.2 kJ
N₂(g) + 2O₂(g) → 2NO₂(g) ΔH=33.2
kJ
to calculate the enthalpy change for the
reaction:
2NO₂(g) → N₂O₄(g) ΔH=?

f-write the electron configuration for copper


Cu (Z=29) using both : spdf notation and
orbital diagram, then the noble gas
abbreviation.

g- use the lewis theory to show the ionic


bond of Ca & Cl .

h- write the resonance structures of SO₂


accourding to Lewis's theory, the show the
formal charge of each atom.

i- how would you prepare 500 ml of an


aqueous solution that is 3.0 % KOH by mass.
j- what is the concentration in ppm of 0.40 g
of NO₃ˉ in one litter of water.
Answer:
1 ppm = 1 mg/liter
The number of ppm ( miligrams ) per liter=
0.40x1000= 400 ppm

k-what is the molality of sodium chloride


NaCl in a solution containing 117 g of this
salt in 360 ml of water.
Answer :
Molality = the number of moles of the
solute/the mass of the solvent in Kg
1- the molar mass of NaCl = 23 + 35.5 =
58.5 g
2- the number of moles ( NaCl) =
117/58.5 =2 mol
3- the mass of the solvent( H₂O)=360g
= 0.360 Kg
4- the molality= 2/0.360=
l-Arrange the following in order of increasing
the first ionization energy:
C, N, F, O, Be

m-Arrange the following in order of


increasing the electronegativity:
O, AS , P

Q4- Define the following terms:(answer only


four)
(a) Nonmetals
(b) Ionic Bond
(c) Molecule
(d) Electron Affinity
(e) Standard Enthalpy of Formation
GOOD LUCK

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