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1. The wavelength of light emitted from a green laser pointer is 5.32 × 102 nm. What is the wavelength in meters?
5.32 × 10-7 m
2. What is the correct answer, with correct significant figures, to the following expression: (18 + 95) × 0.077351?
8.74
3. At 25 ºC, the density of oxygen in air is 0.275 g/L. What volume is occupied by 25 kg of oxygen at 25 °C?
9.1 × 104 L
4. How many protons, neutrons, and electrons are in an oxygen-18 atom?
a) 6 protons, 8 neutrons, 4 electron
b) 6 protons, 10 neutrons, 8 electrons
c) 8 protons, 8 neutrons, 8 electrons
d) 8 protons, 10 neutrons, 8 electrons
e) 8 protons, 10 neutrons, 18 electrons
20. Dinitrogen trioxide, a blue solid, dissociates to form nitrogen monoxide and nitrogen dioxide gases. What mass of
nitrogen dioxide is formed from the decomposition of 13.1 g of N2O3?
7.93 g NO2
21. Magnesium reacts with iodine gas at high temperatures to form magnesium iodide. What mass of MgI2 can be produced
from the reaction of 4.44 g Mg and 13.4 g I2?
7.93 g
22. If 2.891 g MgCl2 is dissolved in enough water to make 500.0 mL of solution, what is the molarity of the magnesium
chloride solution?
6.073 × 10-2 M
23. A 25.00 mL sample of NaOH is titrated with 17.13 mL of 0.3150 M HCl. What is the concentration of the NaOH
solution?
0.2158 M
24. The thermochemical equation for the combustion of hexane is shown below.
C6H14(g) + 19/2 O2(g) → 6 CO2(g) + 7 H2O(g) ΔH° = -4163 kJ
What is the enthalpy change for the combustion of 2.50 g C6H14?
-121 kJ
26. If 46.1 g Zn at 18.0 °C is placed in 80.0 g H2O at 75.0 °C, what is the final temperature of the mixture? The specific heat
capacities of zinc and water are 0.388 J/g·K and 4.184 J/g·K, respectively.
72.1 °C
27. What is the wavelength of radiation that has a frequency of 2.10 × 1014 s −1?
1.43 × 10−6 m
28. The ________ of a photon of light is ________ proportional to its frequency and ________ proportional to its
wavelength.
energy, directly, inversely
29. What is the energy in joules of a mole of photons associated with red light of wavelength 7.00 × 102 nm?
1.71 × 105 J
30. Which of the following types of experiments demonstrate that an electron has the properties of a particle?
a) nuclear fission
b) electron diffraction
c) light emission from atomic gases
d) mass spectroscopy
e) photoelectric effect
32. All of the following sets of quantum numbers are allowed EXCEPT
a) n = 6, l = 0, ml = +1
b) n = 5, l = 4, ml = 0
c) n = 4, l = 1, ml = -1
d) n = 3, l = 2, ml = +2
e) n = 1, l = 0, ml = 0
37. Which of the following ions have the same ground state electron configuration: Sn4+, Pb4+, Sr2+, and Br-?
Sr2+ and Br-
38. Which one of the following statements is INCORRECT?
a) Ionization energy is always a positive value.
b) Ionization energy is the energy required to remove an electron from a gaseous atom.
c) For any element, the second ionization energy is larger than the first ionization energy.
d) Ionization energy decreases across a periodic of the periodic table.
e) Ionization energy decreases down a group of the periodic table
40. Which combination of atoms is most likely to produce a compound with ionic bonds?
a) Al and F b) P and H c) C and O d) Si and O e) S and Br
41. What is the correct Lewis structure for IF3?
.. .
.. F .
..
I F.. ..
.. F..
..
42. Use VSEPR theory to predict the molecular geometry of IF5.
square-pyramidal
H H
C C H
H C C
H H
a) two σ and nine π
b) two σ and seven π
c) seven σ and two π
d) nine σ and two π
46. What is the hybridization of the sulfur atom in SF4?
sp3d
47. How many electrons, protons and neutrons does 87Sr2+ have?
36 electrons, 38 protons, 49 neutrons
48. What is the formula of maganese (VII) oxide?
Mn2O7
49. What is the empirical formula of the ionic compound that forms between calcium and fluorine?
CaF2
50. What is the quantity of Fe2O3 that will be produced if 5.00 g of FeS2 is reacted with 11.0 g of oxygen according to the
following reaction:
4 FeS2(s) + 11 O2(g) --> 2 Fe2O3(s) + 8 SO2(g)
3.33 g Fe2O3
51. The mineral corundum (which is the host structure for sapphires and rubies) has the formula Al2O3. If the density of
corundum is 3.97 g/cm3 how many aluminum atoms are contained in a corundum crystal with a volume of 0.250 cm3?
1.17x1022 Al atoms
55. Which of the following metals will not dissolve in acid to produce hydrogen gas, H2?
• (a) Fe
• (b) Ag
• (c) K
• (d) Both (a) and (c)
• (e) None of the above
• If you drop it into a graduated cylinder containing water, the level of the water raises from 50.0 mL to 58.0 mL.
• Using a digital balance you measure the mass to be 18.56 g.
• Using a calorimeter you determine that 1303 J of heat is required to raise the temperature from 25° C to 125° C.
2.32 g/cm3
0.70 J/g·°C
58. From the following enthalpies of reaction:
-86 kJ
59. Ozone (O3) exothermically decomposes to give oxygen (O2) according to the following reaction:
60. Increasing the intensity of a light source will have which of the following effects.
65. Arrange the following atoms in order of increasing electron affinity: Br, As, Se, Kr.
Br<Se<As<Kr
66. Arrange the following atoms in order of increasing atomic radius: B, Ca, Ga and Cs.
B<Ga<Ca<Cs
67. Predict which molecule will have the shortest C-O bond?
• (a) CO32-
• (b) CO2
• (c) H2CO
• (d) Both (b) and (c)
• (e) All three, (a), (b) and (c)
-24 kJ
71. Which of the following ionic compounds would you expect to have the largest lattice energy?
• (a) KCl
• (b) RbBr
• (c) CsI
• (d) SrSe
• (e) CaO
72. Which of the following molecules does not violate the octet rule?
• (a) NO2
• (b) GeF4
• (c) TeF4
• (d) BCl3
• (e) XeF4
73. Based on the Lewis dot structures, predict the ordering of N–O bond lengths in the following molecules: NO+, NO2- and
NO3-.
shortest NO+ < NO2- < NO3- longest average N-O bond length
74. Using VSEPR theory, predict the electron domain and molecular geometry of SF4.
trigonal bipyramidal, see-saw
75. Using VSEPR theory, predict the electron domain and molecular geometry of IF3.
trigonal bipyramidal, t-shaped
76. What is the hybrid orbital set used by the carbon atom in the molecule H2CO?
sp2
77. Which of the following molecules is not linear.
• (a) KrF2
• (b) HCN
• (c) SO2
• (d) CO2
• (e) both a and c
Na+(aq), SO42-(aq)