Units 1,2 and 3

1.State the following laws. a. Multiple proportion b. Gay-Lussac’s law

2.Define: Mole-fraction, molality, molarity, limiting reagent
3.Write the differences between : molality and molarity.
4.State : Heisenberg’s uncertainty principle, Bohr’s radius,
5.Write the reason for failures of Bohr’s model
6.What are the drawbacks of Bohr’s model
7.100 ml of 0.1M NaCl solution is mixed with 100ml of 0.2M AgNO3 solution. Find the Mass of AgCl
formedb.Limiting agent c.Mass of unreacted substance(At. Mass Na = 23 Ag = 108 Cl = 35.5)
8.A crystalline salt on being rendered anhydrous loses 46% of its mass. Percentage composition of the
anhydrous salt is Al = 10.50%, K = 15.10 %, S=24.80% , O=49.6% Find the simplest formula of: a)
Anhydrous salt b) Crystalline salt (A1 = 27, K=39, S=32, O = 16
9. If the density of methanol is 0.793 kg L–1, what is its volume needed for making 2.5 L of its 0.25 M solution?
10. Differentiate between orbit and orbital
11. a Draw the diagram of dx2-dy2 and dz2 b. How many electrons in an atom may have the
following quantum numbers?(i) n=3 ; l=0 ii) n=4; l = 3
11.500 ml of 0.50M Na2SO4 is mixed with 50 grams of BaCl2 resulting in the formation of BaSO4
precipitate. Which is the limiting reagent? How many moles and how many grams of BaSO 4 formed.
12. Explain the following.
i) Pauli Exclusion Principle ii) Hund’s rule of Maximum multiplicity iii) Aufbau Principle
13.Find the energy required to promote an electron in hydrogen from first energy level to fifth level also
find the wavelength of light emitted when it come back to ground level.
14.A electron is accelerated to a velocity of 2x108 m/s. If the velocity can be measured with a precision of
±0.3%, calculate the uncertainty in position of electron [ h=6.63x10-34Js.Mass of proton is 9.1x 10-33Kg]
15. If ‘g’ is the sub shell to be filled after ‘f’’ a) Where it would appear for the first time?
b) How many orbitals it has? c) How many electrons it can accommodate
16.Calculate the molality of 2M aqueous solution of NaOH. Density is 1.5g/cc ( Na = 23, O =16, H
=1)
17.Give reasons
a.Electron affinity of Be,Mg, N are nearly zero.
b.Electron-gain enthalpy of oxygen is than sulphur
c.Noble gases have the highest Ionisation enthalpy in each period. Justify:
d.Second electron gain enthalpy of chlorine less negative or positive.
eThe radius of cation is smaller than that of the parent atom
b.Explain why second ionization enthalpy of an element is more than its first ionization enthalpy?
18.The atomic number of an element is 32.In which group and period of the periodic table this element is
placed.
19.Arrange the following as stated:
i) N2,O2,F2,Cl2 ( Increasing order of bond dissociation energy )
ii) F,Cl,Br,I ( Increasing order of electron affinity)
20.Arrange the following in increasing order of size. N3-, Na+, F-, O2-, Mg2+
21.3d orbital is filled before 4p orbital. Why?
21.What is Zeeman effect?b) What is the important implication of Heisenberg’s uncertainity principle?
22.What will be the molarity of a solution, which contains 5.85 g of NaCl(s) per 500 mL?
(i) 4 mol L–1 (ii) 20 mol L–1 (iii) 0.2 mol L–1 (iv) 2 mol L–1
23.. If 500 mL of a 5M solution is diluted to 1500 mL, what will be the molarity of the solution
obtained?
(i) 1.5 M (ii) 1.66 M (iii) 0.017 M (iv) 1.59 M
24.. The number of atoms present in one mole of an element is equal to Avogadro number. Which
of the following element contains the greatest number of atoms?
(i) 4g He (ii) 46g Na (iii) 0.40g Ca (iv) 12g He
 25.. If the concentration of glucose (C6H12O6) in blood is 0.9 g L–1, what will be the molarity of glucose
in blood?
(i) 5 M (ii) 50 M (iii) 0.005 M (iv) 0.5 M
26.The empirical formula and molecular mass of a compound are CH2O and 180 g respectively. What
will be the molecular formula of the compound?
(i) C9H18O9 (ii) CH2O (iii) C6H12O6 (iv) C2H4O2
27.Which of the following options does not represent ground state electronic
configuration of an atom?
(i) 1s2 2s2 2p6 3s2 3p6 3d8 4s2 (ii) 1s2 2s2 2p6 3s2 3p6 3d9 4s2
(iii) 1s2 2s2 2p6 3s2 3p6 3d10 4s1 (iv) 1s2 2s2 2p6 3s2 3p6 3d5 4s1
29.Which of the following is responsible to rule out the existence of definite paths or trajectories of
electrons?
a) Pauli’s exclusion principle. b) Heisenberg’s uncertainty principle. c) Hund’s rule of maximum
multiplicity.
d) Aufbau principle
30.The number of radial nodes for 6d orbital is :
a) 3 b) 4 c) 2 d) 1
31.Among halogens, the correct order of amount of energy released in electron gain (electron gain
enthalpy) is:
(i) F > Cl > Br > I (ii) F < Cl < Br < I (iii) Cl >F > Br > I (iv) Br < Cl < F
<I
32.The order of screening effect of electrons of s, p, d and f orbitals of a given shell of an atom on its
outer shell electrons is:
(i) s > p > d > f (ii) f > d > p > s (iii) p < d < s > f (iv) f > p > s > d
33.The period number in the long form of the periodic table is equal to
(i) magnetic quantum number of any element of the period. (ii) atomic number of any element of the
period. (iii) maximum Principal quantum number of any element of the period.
(iv) maximum Azimuthal quantum number of any element of the period.
34.The first ionisation enthalpies of Na, Mg, Al and Si are in the order:
(i) Na < Mg > Al < Si (ii) Na > Mg > Al > Si (iii) Na < Mg < Al < Si (iv) Na > Mg > Al < Si
35.Hydrogen bonds are formed in many compounds e.g., H2O, HF, NH3 . The boiling point of such
compounds depends to a large extent on the strength of hydrogen bond and the number of hydrogen
bonds. The correct decreasing order of the boiling points of above compounds is :
(i) HF > H2O > NH3 (ii) H2O > HF > NH3 iii) NH3 > HF > H2O (iv) NH3 > H2O > HF
36.Which of the following angle corresponds to sp2 hybridisation?
(i) 90° (ii) 120° (iii) 180° (iv) 1
37. The is SI unit of surface tension is------
Which of the following is the correct order of size of the given species:
(i) I > I – > I + (ii) I+ > I– > I (iii) I > I+ > I – (iv) I– > I > I+
38. Orbital angular momentum depends on __________.
(i) l (ii) n and l (iii) n and m (iv) m and s
39. The pair of ions having same electronic configuration is __________.
(i) Cr3+, Fe3+ (ii) Fe3+, Mn2+ (iii) Fe3+, Co3+ (iv) Sc3+, Cr3+
40. Consider the isoelectronic species, Na+, Mg2+, F – and O2–. The correct order of
increasing length of their radii is _________.
(i) F- < O2– < Mg2+ < Na+
(ii) Mg2+ < Na+ < F– < O2–
(iii) O2– < F– < Na+ < Mg2+
(iv) O2– < F– < Mg2+ < Na+
What is critical temperature?
Vegetables cooked with difficulty at hill station. Why?
Draw the structure of 2-hydroxybutan-2-one
What is Biochemical Oxygen Demand?
What is blue bay syndrome?
Write IUPAC names of the following compounds:
a) CH3-CO-CH2(CH3)-CH2-COOH
b) CH3 CH(CH3) CH2 -CH2-CONH2
Draw the resonance structures for benzaldehyde.
Using curved-arrow notation, show the formation of reactive intermediates when the following
covalent bonds undergo fission
(i) CH3O-OCH3 (ii) CH3–Cu
What are electrophiles and nucleophiles? Give one example for each.
Arrange the following carbocations in increasing order of their stability :
CH3CH2CH+CH3, (CH3)3C+ , CH3CH+2 and CH3+
Explain electromeric effect with an example.