General Instructions:

I All questioms are compulsory

I1. Question numbers 1 to 3 are very short answer questions each of I mark

M. Question numbers 4 and 5 are short answer questions each of 2 marks.

IV Question numbers 6 to 8 are short anSWer questions each of3 marks and
question number 9 is of 4 marks.

1) State the Law of definite proportion.

2) Define mole fraction

3) How many atoms are present in 52u of He ?

4) Write the balanced chemical equation for the combustion of methane gas
and calculate the amount of water produced by the combustion of 8 gm. of
methane
5) State Avogadro's Law.
Calculate the number of molecules in 3.4g of H2S.(atomic mass of S-32g/mol)
6) Nitrogen occurs in nature in the form of two isotopes with atomic masses 14 and
15 respectively. If the atomic mass of nitrogen is 14.0067, what is the
percentage
of abundance of the two isotopes?

7) How much magnesium sulphide can be obtained from 2g Mg and 2g'S' by the
reaction Mg+S MgS ? (atomic mass of Mg-24g/mol)
Which is the limiting reagent? Calculate the amount of one of the reactants
which remains unreacted ?

8) An organic compound on analysis give the following percentage composition.

C-54.24 %, H-9.05% and 0 =36.71 %
Find the molecular formula of this compound, if its molecular mass= 88u

9) a) Distinguish between molarity and molality of a solution.

b) 2.8g of KOH is dissolved in water to give 200ml of solution.

What is the molarity of KOH in the solution ? (at. mass of K = 39 0 = 16)
Instructions:
All questions are compulsory
2. Questions 1 to 14 are very short answer questions of 1 mark each.

3. Questions 15 to 18 are short answer questions of 2 marks each.

4 Questions 19 to 24 are short answer questions of3 marks each.

5 Questions 25 and 26 are long answer questions of5 marks each.

6. Calculators are not permitted. Use logarithm table if necessary.

1. What are the two important developments which contributed significantly in the formulation of

Quantum mechanical model of atom ?

2. State Heisenberg's uncertainity principle.
3. Which quantum number defines the three dimensional shape of the orbital ?

4. State Hund's rule of maximum multiplicity.

5. Calculate the radius of the third orbit of hydrogen atom.
6. Which rule helps in calculating the number of electrons to be present in one subshell ?
7. Which orbital is designated by the set of quantum numbers, n =4, 1=1, m -0.
1s
(a) 4p,(b) 4s, (c) 3d, (d)
8. What will be the molality of the solution containing 18.25gof HCl gas in 500 g of water ?

(b) 0.5 (c) 1.5 (d) Im

(a) 0.1 m m m

9. Which of the following will have largest number of atoms ?

1 gN; (d) 1 gOz
(a) 1 gC (b) 1 g H2 (c)
10.State Avogadro's law.
11. What is the mass of one "C atom in grams ?
from 100 g of magnesium sulphate (MgSO,)?
2 . How much magnesium is obtained
(Atomic mass of Mg= 24,S =32)
3 . Define molarity.
Class XI Chem Pagel of 2
 carbonate or copper nitrate
contains
coppe
Copper oxide obtained by heating copper observation
in same ratio mass. Which law is
illustrated by this
aDd oxygem the by
"Cl that accounts
H Calculate the percentage ofnaturally occurring isotopesCl and
for the aveage atomic mass of chlorine taken as 35.5.
16. Calculate the mass ofa photon with wavelength 6.626 A.

17. Caleulate the energy associated with the second orbit of Li' ion.

1 8 8 Ot carbon were heated with 16g of sulphur. How much carbon disulfide (CS2) wi
beformed whenthereaction is complete? (C+2S CS;)
19. Write the electronic
configuration of the following.
i) Chlorine i) Chromium i) Calcium
20. Calculate the uncertainity in position of an object of mass 3.313 g and a speed or

50 ms', if the speed is measured within an accuracy of 2%.

21. ) What are the possible values of magnetic quantum number for a value of 2 for

the azimuthal quantum number ?

1) Write the set of quantum numbers to describe the valence electron in potassium.
ii) How many electrons in copper has (n +1) =4?
22. The density of 3 molal solution of NaOH is 1.11 gmL". Calculate the molarity
of this solution.
23.An organic compound on analysis gave the following percentage composition

C-40.68 %, H=5.08 % and the rest is oxygen. Molecular mass of the compound
is 118 gmol. Find the molecular formula of the compound.
24. i) Calculate the mumber of moles in 3.011 x10 molecules of nitrogen.
ii) Find the number of moles of hydrogen atoms in 2 moles of glucose
ii) What mass of CO contains the same number of molecules as present tin 64 g

ofoxygen?
25. i) What are the postulates of Bohr theory to explain the structure of atom ?
ii) Find the frequency and wavelength of a photon emitted during the transition of
an electron from fourth energy level to second energy level?

26. i) A solution is prepared by mixing 4.6g of ethanol and 6.4 g of methanol. Find the
mole fraction of each component in the solution.

i) If the density of methanol is 0.8 kg L", what is its volume needed for making
2.5 L of 0.25 M solution?
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