Nama : . Kelas: .

JABA TAN PELAJARAN NEGERI JOHOR

PEPERIKSAAN PERCUBAAN SPM 2010 4541/2

CHEMISTRY
Kertas 2
August

2Y2jam
Dua jam tiga puluh minit

JANGAN BUKA KERTAS SOALAN 1Nl SEHINGGA DIBERITAHU

1. Tu/iskan nama dan tingkatan pada

ruang yang disediakan. Markah
10
10
10
20
Untuk
20 Markah
Soalan
Kegunaan Pemeriksa
Diperoleh
C
B
A 48
10
2. Kertas soa/an ini ada/ah Penuh
1 da/am
23
5769
dwibahasa. Jumlah
Bahagian
3. Soa/an da/am bahasa /nggeris
mendahului soa/an yang sepadan
dalam bahasa Melayu.
4. Ca/on dibenarkan menjawab
keseluruhan atau sebahagian
soalan sama ada da/am
bahasa/nggeris atau bahasa
Melayu.
5. Calon dikehendaki membaca
maklumat di halaman be/akang
kertas soalan ini.

Kertas ini mengandungi 28 halaman bercetak

SULIT 2

Section A
BahagianA

[60 marks]
[60 markah]

Answer all questions in this section.

Jawab semua soa/an da/am bahagian ini.

1 Diagram 1 shows three industrial processes involved in manufacturing ammonium

I sulphate.
Rajah 1 menunjukkan tiga proses industri da/am penghasi/an ammonium su/fat.
Process I

Sulphur I
Sulfur

Sulphur dioxide I
Sulfur dioksida

Sulphur trioxide I
Sulfur trioksida
Nitrogen I Hydrogen I
Nitrogen Hidrogen

Oleum I
Oleum 1
l ProcessI 11
Sulphuric Acid I
Ammonia I
Asid su/furik Ammonia

1
Process III

Ammonium sulphate I
Ammonium sulfat

Diagram 1
Rajah 1

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I
~IT 3

From the flow chart shown in Diagram 1. answer the following questions.
Dari carta alir pada Rajah 1, jawab soalan berikut.

(a) For Process I.

Untuk proses I.

(i) Name the industrial process of producing sulphuric acid.

Namakan proses industri untuk membuat asid sulfurik

[ 1 mark]

(ii) State how to produce sulphur dioxide from sulphur.

Nyatakan bag aim ana untuk membuat sulfur dioksida dari sulfur

[ 1 mark]

(iii) Write the chemical formula of sulphur trioxide

Tuliskan formula kimia untuk sulfur dioksida

[ 1 mark]

(iv) Sulphur trioxide dissolves in compound M to produce oleum. What is

compound M?
Sulfur trioksida melarut dalam sebatian M untuk menghasilkan oleum.
Apakah sebatian M ?

[ 1 mark]
(v) State how sulphuric acid is produced from oleum.
Nyatakan bagaimana asid suffurik di hasilkan dari oleum

[ 1 mark]
(vi) Sulphuric acid produced is mixed with water in a beaker. State the
observation if a piece of marble is dropped into the beaker.
Asid sulfurik yang terhasil dilarutkan ke da/am bikar berisi air.
Nyatakan pemerhatian jika sebutir marmar dimasukkan ke dalam bikar
itu.

[ 1 mark]

[Lihat sebelah
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SULIT 4

(b) Name a suitable catalyst for Process 11.

Namakan satu mangkin yang sesuai untuk Proses 1/.

[1 mark]

(c) For Process Ill,

Untuk Proses Ill,

(i) Write the chemical equation for the reaction of ammonia with sulphuric
acid.
Tuliskan persamaan tindak ba/as untuk tindak ba/as ammonia dengan
asid su/furik.

[2 mark]

(ii) State one use of ammonium sulphate in daily life.

Nyatakan satu kegunaan ammonium su/fat da/am kehidupan seharian

[1 mark]

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~ULIT 5

2 Graph 2 shows the temperature against time when solid P is heated.

Graf 2 menunjukkan gmf suhu melawan masa bagi pemanasan pepejal P.
Temperature 1°C
SuhuloC

200 +----------------------------------------------------

136

Time/s
Masa/s
Graph 2
Graf2

(a) Based on Graph 2 • answer the following questions:

Berdasarkan Graf 2, jawab soalan-soalan berikut :

(i) What is meant by melting point?

Apakah yang dimaksudkan dengan takat lebur ?

[1 mark]

(ii) State the melting point of substance P .

Nyatakan takat lebur bahan P.

[1 mark]
(Hi) State the physical state of P from time t1 to h.
Nyatakan keadaan fizik P dari masa t1 hingga t2.

[1 mark]
[Lihat sebelah
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SULIT 6 ~ ..

(iv) Explain why the temperature remains constant from time t1 to t2.
Terangkan kenapa suhu tidak berubah dart masa t1 hingga h.

............., , [2 marks]

(v) Diagram 2 shows the set-up of apparatus used by a student to

determine the melting point of substance P.
Rajah 2 menunjukkan susunan radas yang digunakan o/eh seorang
pe/ajar untuk menentukan takat /ebur bahan P.

Ethanol
Etano/

SolidP
BahanP

Diagram 2
Rajah 2

Identify one mistake in the diagram. Explain why.

Kenalpasti satu kesilapan da/am rajah tersebut. Je/askan mengapa.

[2 marks]

(b) When solid iodine is heated. it changes to purple fume.

Apabila pepeja/ iodin dipanaskan ) la bertukar ke wasap ungu.

(i) Name the process involved.

Namakan proses yang terfibat.

[1 mark]

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~ SULIT 7

(ii) Name one isotope of iodine and state its use.

Namakan satu isotop untuk iodin dan nyatakan kegunaannya .

............................................. .[2 marks]

3 Diagram 3 shows the set up of apparatus to investigate the electrolysis of sodium

chloride solution.
Rajah 3 menunjukkan susunan radas untuk mengkaji elektrolisis larutan natrium
klorida. Gas yang terkumpul pada elektrod Y berwama kuning dan melunturkan
wama kertas litmus biru lembab.

Greenish yellow gas

Gas berwarna kuning
kehijauan

Sodium chloride solution

Larutan natrium klorida

Carbon electrode X Carbon electrode Y

E1ektrod karbon X Karbon e'ektrod Y

Diagram 3
Rajah 3

(a) (i) What is meant by anion?

Apakah yang dimaksudkan dengan anion?

[1 mark]
(ii) Write the formulae for all anions that are present in sodium chloride
solution.
Tuliskan formula bagi semua anion yang hadir dalam larutan natrium
klorida.

[1 mark]

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 --- ---_ ... ~-_ .. _- -----

SULIT 8

(Hi) The gas collected at electrode X decolourises a damp blue litmus

paper. Name the gas.
Gas yang terkumpul pada elektrod X melunturkan kertas litmus biru
lembap. Namakan gas itu.

[1 mark]
(b) By referring to diagram 3 •
Dengan merujuk kepada Rajah 3,
(i) Which electrode is the cathode?
Elektrod yang manakah merupakan katod ?

[1 mark]

(ii) Write the half-equation for the reaction at the cathode.

Tuliskan persamaan setengah bagi tindak balas di katod.

[1 mark]

(iii) Describe a test to identify the gas collected at the cathode.

Huraikan satu ujian untuk mengenalpasti gas yang terkumpul di katod.

[2 marks]

(c) The experiment is repeated by using 0.001 mol dm-3 sodium chloride
solution.
Eksperimen ini diulangi dengan menggunakan larutan natrium klorida
0.001 mol dm'3

(i) Name the ion that is selectively discharged at the anode.

Namakan ion yang didiscas secara pilihan di anod.

[ 1 mark]

(ii) Give a reason for Y9ur answer in (c)(i)

Berl alasan bagi jawapan anda di (c)(i)

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 9

[ 1 mark]

(iii) Name the gas collected at the anode.

Namakan gas yang terkumpu/ di anod.

[1 mark]

4 Table 4 shows the molecular formulae and observations for three compounds when
they react with bromine water.
Jadual4 menunjukkan formula molekul dan pemerhatian bagi tiga sebatian apabila
bertindakbals dengan air bromin.

Brown Molecular
colour is decolourised
I I Brown colour remains
I Compound I Formula
Warna perang Molekul
menjadi Formula
Warna perang
tidak
C2H4 Pemerhatian
Observation
tidak
berwama berubah
C4H10
Q C2Hs ............................................. " .......

Tabie4
Jadua/4

(a) Name the homologous series for these compounds.

Namakan siri hom%g bagi sebatian-sebatian ini.

i) Compound P
Sebatian P

Compound Q
Sebatian Q
[2 marks]

ii) What is the general formula for the homologous series of compound
R?
Apakah formula am bagi siri homolog sebatian R?

...... ~ , , , .
[ 1 mark J

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SULIT 10

iii) Complete the observation for compound R in Table 4.

Lengkapkan pemerhatian untuk sebatian R da/am Jadua/ 4.
[1 mark]

iv) Name a substance that can replace bromine water.

Namakan satu bahan lain yang bo/eh menggantikan air bromin.

[ 1 mark]

v) Explain why compound P is chemically more reactive than compound

Q.
Je/askan mengapa sebatian P /ebih reaktif secara kimia berbanding
sebatian Q.

[ 1 mark]
(b) Compounds P and Q can undergo complete combustion to form gas X and
water.
Sebatian P dan Q bo/eh menga/ami pembakaran /engkap untuk menghasi/kan
gas X dan air.

i) Name gas X.
Namakan gas X.

[ 1 mark]
ii) Write a balanced chemical equation when compound P or Q reacts
with oxygen.
Tu/is persamaan kimia yang seimbang apabila sebatian P atau Q
bertindak ba/as dengan oksigen.

[ 1 mark]

Hi) Compare the sootiness of the flame when compound P and Q are
burnt in the air. Explain why.
Bandingkan keje/agaan nya/aan apabi/a sebatian P dan Q terbakar di
udara. Terangkan mengapa.

[2 marks]

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 ~LIT 11

5 Diagram 5 shows the set-up of apparatus to study the electron transfer at a distance.
Rajah 5 menunjukkan susunan radas eksperimen untuk mengkaji pemindahan
electron pada satu jarak.

'''"
Carbon electrode Y
Elektrod karbon Y
Carbon electrode X
Elektrod karbon X
Acidified potassium manganate
(VII) solution
Iron (H) sulphat Larutan kalium manganat (VII)
Ferum (II) su?fat berasid
.. - - ....

\&~jJ
-::::- -::::-
-::::::~::::::-:--

Diagram 5
Dilute
Sulphuric acid
A.'dd sulfurik

Rajah 5

(a) What is the function of dilute sulphuric acid?

Apakah fungsi asid sulfurik cair?

[1 mark]

(b) (i) State the observation at carbon electrode X.

Nyatakan pemerhatian di elektrod karbon X.

[1 mark]
(ii) Write the half equation for the reaction in (b) (i)
Tuliskan persamaan setengah untuk tindak balas di (b) (i).

[2 marks]

(iii) Describe a confirmatory test for the product formed at carbon electrode
X.
Huraikan satu ujian pengesahan untuk hasil yang terbentuk di elektrod
karbon X.

[2 marks]

[Lihat sebelab
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SULIT 12 ".:...----

(c) (i) State the observation at carbon electrode Y.

Nyatakan pemerhatian di elektrod karbon Y.

[1 mark]

(ii) What is the role of acidified potassium manganate (VII) solution in the
experiment?
Apakah peranan larutan kalium manganat (VII) berasid da/am
eksperimen ini ?

[1 mark]

(iii) Give a reason for your answer in (c) (ii).

Berikan satu penjelasan untukjawapan anda pada (c) (ii).

[1 mark]

(d) Suggest another reagent that can replace acidified potassium manganate (VII)
solution.
Cadangkan satu reagen lain yang baleh menggantikan larutan kalium
manganat (VII) berasid.

[1 mark]

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 ~ULIT 13

6 Natural rubber is obtained from latex secreted by rubber tree. Latex is a white milk-
like fluid. Table 6 shows the results of latex coagulation.
Getah asli dipero/ehi daripada /ateks yang didapati dari pokok getah. Susu getah
merupakan cecair yang berwama putih seakan susu. Jadua/6 menunjukkan
keputusan pembekuan susu getah.

Procedure Latex coagulates

Susu
Observation
Pemerhatian slowly dengan
getah membeku
Latex
Susucoagulates immediately
getah membeku dengan cepat
dur
tambah kepada susu getah per/ahan
dded toterdedah
arkan latex di udara
tex is exposed to the air

Table 6
Jadua/6

(a) Based on the Table 6, answer the following questions.

Berdasarkan Jadua/ 6, jawab soa/an-soa/an berikut.

i} What is solution X ?
Apakah /arutan X?

[ 1 mark]

ii) The coagulation of latex will also occur when it is exposed to air.
Explain why this happens.
Proses pembekuan susu getah juga berlaku apabi/a ia terdedah
kepada udara. Je/askan mengapa ini terjadi.

[1 mark]
iii) Suggest a solution that can be used to prevent latex from coagulating.
Cadangkan satu /arutan yang bo/eh digunakan untuk mengha/ang
pembekuan susu getah.

[1 mark]

b) During the preparation of soap, a concentrated alkali X is added to oil or fat.

The mixture is heated and then sodium chloride is added. The general
equation for this reaction is shown below.
Semasa proses pembuatan sabun, farutan a/kali pekat X di tambah kepada
minyak atau /emak. Campuran kemudian di panaskan bersama dengan
natrium kforida. Persamaan tindak ba/asnya ada/ah seperti di bawah.

[Lihat sebelah
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 SULIT 14

alkaliX0 ~R3 CH-+ OH

Rj-C-O-Na+
-C-O-Na+
Soaps + Rz -C- O-Na+ 00
CH2-0H
CHz-OH
Glycerol 11
1\
11

0fat 0

Based on the equation above. answer the following questions.

Berdasarkan persamaan di atas, jawab soa/an -soa/an berikut.

i} What is the name of the process?

Apakah nama proses tersebut?

[ 1 mark]

ii) What is alkali X ?

Apakah alkali X?

[1 mark]

iii) Why is sodium chloride solution added to the mixture?

Mengapakah larutan natrium k/orida ditambahkan kepada campuran?

[1 mark]

iv) Describe briefly the cleansing action of soap.

Huraikan dengan ringkas tindakan pembersihan oleh sabun

[2 marks]

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 ~LIT 15

c) Diagram 6 shows the structural formulae of two cleansing agents X and Y.

Rajah 6 menunjukkan formula struktur bagi dua agen pembersih X dan Y.

Cleansing agent X:
Agen pembersih X :

Cleansing agent Y:
Agen pembersih Y:

Diagram 6
Rajah 6

Based on Diagram 6, compare the effectiveness of cleansing action of agent

Y to agent X. Explain why.
Berdasarkan Rajah 6, bandingkan keberkesanan tindakan pembersihan agen
pencuci Y berbanding agen X. Terangkan mengapa.

i.

ii.

[2 marks]

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 SULIT 16

Section B
BahagianB

[20 marks]

Answer anyone question from this section.

Jawab mana-mana satu soa/an daripada bahagian ini.

7 Diagram 7 shows parts of the Periodic Table of elements.

Rajah 7 menunjukkan sebahagian unsurda/am Jadua/ Berka/a.

1
r--- 2
0 Cl AI
13 14 15 16 17
-18
C

Diagram 7
Rajah 7

(a) Write the electron arrangements for aluminium ion and oxide ion.
Tuliskan susunan e/ektron bagi ion aluminium dan ion oksida
[2 marks]

(b) Describe the formation of the following chemical bonds and draw the electron
arrangement of compounds formed.
Huraikan pembentukan bagi ikatan kimia berikut dan /ukis susunan e/ektron
bagi sebatian yang terbentuk.

(i) Ionic bond between magnesium atom and chlorine atom.

/katan ionik di antara atom magnesium dengan atom k/orin.
[5 marks]

(ii) Covalent bond between carbon atom and chlorine atom.

/katan kova/en di antara atom karbon dengan atom k/orin.
[5 marks]
(c) Explain each of the following statements.
Terangkan setiap pemyataan berikut.

(i) Compound formed in (b)(i) can conduct electricity in the molten state
while compound formed in (b)(ii) cannot conduct electricity in any
state.
Sebatian yang terbentuk da/am (b)(i) bo/eh mengkonduksikan e/ektrik
da/am keadaan /eburan man aka/a sebatian yang terbentuk da/am
(b)(ii) tidak dapat mengkonduksikan e/ektrik da/am semua keadaan.

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 17

[4 marks]

(ii) The melting and boiling points for compound in (b) (i) is higher than
compound in (b)(ii).
Takal /ebur dan takat didih bagi sebatian da/am (b)(i) lebih tinggi
daripada sebatian da/am (b)(ii).
[4 marks]

8 Table 8 shows the heat of combustion of the first five alcohols.

Jadual 8 menunjukkan haba pembakaran unluk lima a/kohol yang pertama.

Haba
CHsOH
C2HsOH
Heat Pembakaran --2675
2017
Alcohol/
I
I I Molecular
CSH110H Formula mof Combustion
-- mo/ekul
715
1376
Formula / / I
Butanol
Pentanol Propanol Metano/ C4HgOH
CSH70H
I Elano!
kJ mor1 ,
ohol

Table 8
Jadua!8

The chemical equation for the combustion of ethanol is as below.

Persamaan kimia bagi pembakaran etano! ada!ah seperti di bawah.

~H = -715 kJ mol-1

(a) Based on the equation above, state the meaning of heat of combustion of
ethanol.
Berdasarkan persamaan kimia di atas, nyatakan maksud haba pembakaran
bagi elanol.
[2 marks]
(b) Based on Table 8 I
Berdasarkan Jadual 8,

(i) Draw a graph of magnitude of heat of combustion against the number

of carbon atoms.
Lukis graf magnitud haba pembakaran melawan bilangan atom
karbon.
[3 marks]
[Lihat sebelah
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SULIT 18

(ii) State the relationship between the number of carbon atoms per
molecule of alcohol to the magnitude of the heat of combustion.
Nyatakan hubungan di antara bi/angan atom karbon per mo/eku/
alkohol kepada magnitud haba pembakaran.
[ 1 mark]

(Hi) From the graph, predict the heat of combustion of pentanol in kJ mol .,
Daripada graf, rama/kan haba pembakaran pentanol da/am kJ mort
[2 marks]

(c) Compare the heat of combustion between ethanol and butanol.

Explain why there is a difference in the heat of combustion between ethanol
and butanol.
Bandingkan haba pembakaran etanol dengan butanol.
Terangkan mengapa terdapat perbezaan di antara haba pembakaran etanol
dan butanol.
[4 marks]

(d) Diagram 8 shows the energy level diagram of the heat of combustion of
ethanol.
Rajah 8 menunjukkan gambarajah aras tenaga bagi haba pembakaran etanol.

Energy
Tenaga

LiH = -715 kJ mol"

Diagram 8
Rajah 8

(i) Give four information that you can obtain from Diagram 8.
Serikan em pat maklumat yang boleh diperoleh daripada Rajah 8.
[4 marks]
(ii) Calculate the energy released if 6.9 grams of ethanol is burnt
completely in air.
Kira haba yang di bebaskan jika 6.9 gram etanol di bakar dengan
/engkap di da/am udara.
[4 marks]

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 ~ULIT 19

Section C
Bahagian C

l [20 marks]

Answer anyone question from this section.

I

Jawab mana-mana satu soalan daripada bahagian ini.

9 (a) By using suitable example, explain what are meant by empirical formula and
molecular formula.
Dengan menggunakan contoh yang sesuai, terangkan apa yang dimaksudkan
dengan formula empirik dan formula molekul.
[3 marks]

(b) The information below is for compound Q

Maklumat berikut adalah bagi sebatian Q.

• Carbon 40.00%
Karbon
• Hydrogen 6.66%
Hidrogen
• Oxygen 53.33%
Oksigen

• Relative molecular mass 180

Jisim molekul relatif

Based on the information of compound Q, determine:

Berdasarkan maklumat bagi sebatian Q, tentukan:

(i) The empirical formula

Formula empiriknya

(ii) The molecular formula

Formula molekulnya
[ Relative atomic mass: C,12; H,1; 0,16]
[ Jisim atom relatif: C, 12; H,1; 0,16]
[5 marks]

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SULIT 20

(c) Diagram 9 shows the set-up of apparatus to determine the empirical formula of two
different compounds.
Rajah 9 menunjukkan susunan radas bagi menentukan formula empirik dua
sebatian yang berlainan.

Method I Method 11
Kaedah I Kaedah 11

Metal oxide I Oksida logam

Metal
Logam
--+~=~ -=~
gas
Dry Ihydr::·::l.;:··
Gas "--.. paper
Asbestos
Hidrogen Heat I Kertas
kering panaskan asbestos

Table 9
Rajah 9

(i) Explain why method 11is not suitable to determine the empirical formula of
magnesium oxide?
Terangkan mengapa kaedah 11tidak sesuai bagi menentukan formula empirik
bagi magnesium oksida?
[1mark]
(ii) Suggest one metal oxide in method 11.
Cadangkan sa tu oksida logam dalam kaedah 11.
[1 mark]

(iii) Using a suitable example, describe a laboratory experiment to determine the

empirical formula of an oxide of a reactive metal. Your explanation should
include:
Dengan menggunakan contoh yang sesuai, huraikan suatu eksperimen di
makmal untuk menentukan formula empirik bagi suatu oksida logam reaktif..
Penerangan anda mestilah meliputi :

• Procedure of the experiment

Prosedurbagieksperimen

• Tabulation of data
Penjadualan data

[10 marks]

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 ~LIT 21

10 (a) Table 10 shows different concentrations of hydrochloric acid and the

corresponding pH values.
Jadua/ 10 menunjukkan kepekatan berlainan bagi asid hidrokforik dan ni/ai pH
yang sepadan. .

I
I i Hydrochloric Kepekatan30.1
0120.001
1asidImol
Concentration
0.01 dm-3
,
ofhidrok/orik
hydrochloric
pH acid
k I B
AcidC !i

Table 10
Jadua/10

(i) Based on Table 10, state the relationship between the concentration of
hydrochloric acid and the pH value.
Berdasarkan Jaduaf 10, nyatakan hubungan antara kepekatan asid
hidrok/orik dan ni/ai pH.

(ii) Explain your answer in a (i) by referring to the number of hydrogen ions
present in the acid.
Je/askan jawapan anda di a (i) dengan merujuk kepada bilangan ion
hidrogen yang terdapat dafam asid itu.

(iii) Arrange the hydrochloric acids in Table 10 according to increasing order

of acidity.
Susun asid hidrok/orik da/am Jaduaf 10 menurut susunan menaik
keasidan.

[4 marks]

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 SULIT 22

(b) The following information is about two different alkalis.

Maklumat di bawah adalah mengenai dua alkali yang berfainan.

Alkali 13
10
Concentration
Kepekatan Imol
pH pH0.1
Imol 0.1
dm-3
dm-3
idroksida
onia
e solution
Ammonia solution

Explain why the two alkalis have different pH values.

Terangkan mengapa dua alkali tersebut mempunyai nilai pH yang
berlainan.

[6marks]

(c) You are required to prepare dry barium sulphate salt.

Anda dikehendaki menyediakan garam barium sulfat kering.

(i) Suggest two solutions to prepare barium sulphate salt.

Cadangkan dua larutan untuk menyediakan garam barium sulfat.

(ii) Describe a laboratory experiment to prepare the salt. In your

description. include the chemical equation and ionic equation.
Huraikan suatu eksperimen makmal untuk menyediakan garam
tersebuLHuraian anda mest; mengandungi persamaan kimia dan
persamaan ion.

[1 Om arks]

END OF QUESTION PAPER

KERTAS SOALAN TAMA T

4541/2 © 2010 Hakcipta Jabatan Pelajaran Negeri Johor

SULlT
 MARKING SCHEME OF CHEMISTRY TRIAL EXAMINATION
PAPER 2, 2010

H2S04+-72NH3
As
S03
(NH4)zS0421
Dissolve
Ferum
Concentrated
Burn
Bubbles IIDilute
fertilizers
Total
Mark
Contact
sulphur
of Iron inloxygen
water
insulphuric
gas air
are Mark
released Scheme
acidSub 10
11 Beaker 11 Mark
Total I
mark 1
decreases
a of reactants and product
(b)(iii)

~
. to
~

(a) 83°C
(i) Total
21
Mark
1. Temperature
Heat andenergy Mark aScheme
at which
liquid absorbed 11 Mark
solid Subsolid changes to
mark
attraction (H)

4541/2 Answer © HAK CIPTA JPNJ 2010

 1-
II
Ii
I I
1.(b) 21(i) . bath
Sublimation
1Iodine-131
Water
(v)
(i i) 2.
should
To treatbe
Melting
bath.
thyroid
used
IIpoint
2. flammable. Ethanol
thyroid
point ofGlands
and isis10 ethanol
not
patients
of Total
P
ethanol 178°C
higher
11
II Diagnosis
than boilingof
!i
I

I
1'pop'
Total
Insert
A
(a)
Mark (i)
Question 211Hydroxide
1asound
Chlorine
OH-,
I I 2H+ Carbon
Because +CI-
2e
lighted
The is -7electrode
wooden
producel
hydroxide
negatively Mark
ion beisScheme
Y
splinter
can
ion charged
H2 ionlinto
heard
located 1 lower
particle 1 Sub
. mark
I I
1
I

I
I Mark
(c) (i) I

(iii) I Oxygen gas

Total
I 1 I~i
I 10 I

4541/2 Ans\\cr HAK C1PTA JPNJ 2010

 4

II I
I 21 Q:
1IIIln
1" +I-7
CnH
11. Mark
Alkene
Total
Alkane
Carbon
302
2n+2
Compound
alkene +Q
dioxide
2C02 Mark 2Scheme
H2O 11 bonds
produceddouble
carbon-carbon
1
mere I I
soot. are
I I
Sub Mark
k bonds.
11
AcidifiedI )C2H4 2.P: dichromate (VI) solution
potassium II
Brown colour remains )

+
(i) 702 -7 4C02 + 6 H2O
(iii)
(v)

Total 10

e Fe
Fe 3+ 1
Total
2
Mark
+-72+ To allow
Green 2 Mark
colourmovement
solution turn Scheme
of Sub
ions I yellow1 the
11 To complete
to brown Mark

(i)

4541/2 Answer © HAK CIPTA JPNJ 2010

 ~ j-. ..~A...,A,
21
111.
IActIAPurple
asfew
Potassium
Bromine solution
oxidizing
drops ischlorine
ofagent
manganate
wat~r! sodiumdecolourised
(VII) 5solution!
hydroxide
watjZr! turn II I
Mn04-
facidified
solutionl
e solution iso~,\.dj:'.
added into
the the
productproduct formed
formed
hexacyanoferrate around
(11) aroundcarbon
solution carbon
is Y.
added Y. into
potassium dichromate (VI) solution
(ii) 2. Brown
Dark blue
1. A few colourof I potassium
precipitate
drops precipitate
is formed. produced.
) (c) (i)

Total 10

1Mark
Total
Because
Ammonia, bacteria
Saponification
Concentrated from
solution
NH3acid!
Ethanoic Mark
air
( Spelling
potassium
formic Scheme
enter
mustf the
hydroxide,
acid belatex
any correct)
KOHl!
suitable 11
and dilute Mark
Sub
mark coagulation.
(iii)
(ii)

4541/2 Answer © HAK CIPTA JPNJ 2010

 6

To 1Agent a Y
2
1.Max2
(iii)
1.When
precipitate sDetergent
cloth
2. more
with
the soapsgrease
doI tonotreduce
effective is form 10
theinto1 11
scumll
dipped
tension of 3. water.
clean
2. The well in hard
hydrophilic
hydrophobic
Detergent water.
canpart
part dissolve
still dissolves
perform initswater
incleaning
the
(iv)

Total

4541/2 Answer © HAK CIPTA JPNJ 2010

 7

Mark
Question Mark Scheme Sub Total
mark Mark

7(a) Aluminium ion: 2.8 1

Oxide ion: 2.8 1 2

(b)(i) 1. Magnesium atom donates / releases 2 1

electron to form magnesium ion / Mg2+
// Mg _ Mg2+ + 2e

2. Chlorine atom accepts / receives one I 1

electron to form chloride ion / Cl'
// Cl + e - cr

3. Magnesium ion and chloride ion are I 1

attracted to one another by electrostatic
force.

2+

Chloride ion, cr magnesium ion, Mg2+

1. Correct number of shells and number of 1

electron
2. Correct charge 1 5
(ii)

4541/2 Answer © HAK CIPTA JPNJ 2010

 8

I 1. Correct number of shell and electron

2. Correct number of atoms of elements I

1

1
\

3. Carbon atom contribute I needs I requires I 1

4 electrons to share

4. Chlorine atom contribute I needs I requires I 1

1 electron to share

5. One carbon atom share 4 valence 1 5

electrons with 4 chlorine atoms.

I ! 1.
Compound (b)(i) I MgCb is an ionic I 1
(c)(i) 4 1
4.
3. has state,
Compound
2. In molten
CCI4 no(b)(ii) I CCI4
freely
MgClzmoving aions/l
has isfreely only
covalent
moving I

(ii) I
11. Ions in MgClz are held together by strong 1I
Waals 4 1
1
3.
2. AMolecules
lot of heat in
energy
CCl4 are
is held
needed
4. Less heat energy is needed to together
to by
overcome I

Total 20

4541/2 Answer © HAK CIPT A JPNJ 2010

 9

J of
e!ol
is
46
heat produced
burnt
rbutanol released
molecule!/
magnitude mark
The tomore
the 3. More
4.
2. 1.
of
The
TheI
1. 1.
Correct
ethanol
the
Ethanol
Number
1. 1.
energy
relative
Butanol heat
surrounding.
completely
1
2
3
Mark
4
Total
Heat
The
The
higher
[ 3200
Graph
carbon
heat ofaxis
of
burnt
mass
has
heat
-of
heat
dioxide
inand
ofcombustion
energy
the
3300
combustion
mole
of
combustion.
inlevel
20
air oxygen
higher
of
combustion
] level
numberkJ mol
and to
labels
of produced
to
of
iswater
released
reactants
butanol
number
-1
of ethanol
of
Mark
diagramethanol
carbon
-1
are
produced
Sub
715
iscarbon
higher
of715
6.9is=the
of=Scheme
butanol
formed.
higher
than
kJ. kJ
/
0.15
atoms is
shows heat
per 211
22
Mark

0.15 mole will released (i)0.15

(d) (b) (m)
(i) x 715 =
(ii)
Total

4541/2 Answer © HAK CIPT A JPNJ 2010

 \
\
-\
\
\
10

Mark
Question Mark Scheme Sub Total
mark Mark

9. (a) 1. Empirical formula is the formula that 1

shows the simplest ratio of atoms of
each element in the compound.

2. Molecular formula is the formula that I 1

shows the actual number of atoms of
each element in the compound.

3. Example: empirical formula of ethene' is 1 3

CH2 and the molecular formula is C2H4

(b )(i)

Element I Carbon Hydrogen Oxygen

Percentage I 40.00 6.66 53.33

Number ~~=3.331 6.~6 = 6.66

of moles 1

Ratio of 1
1 ! 2 1
moles

Empirical formula is CH20 1 3

(ii)

n(CH20) = 180
12n + 2n + 16n = 180
30n:: 180 1
n=6

1 2

(c)(i)
Because magnesium is more reactive than 1 1
. hydrogen!! because magnesium oxide does
! not react with hydrogen gas.

(ii)
Lead oxide ! Stanum oxide I iron oxide ! 1 1
copper-)i;)xide

4541/2 Answer © HAK CIPTA JPNJ 2010

 11

(Hi) 1. Clean [5 - 15) cm magnesium ribbon 1

with sandpaper and coil it.

2. Weigh an empty crucible with its lid. I 1

3. Place the magnesium in the crucible and I 1

weigh again

4. Record the reading. I 1

5. Heat the crucible very strongly. I 1

6. Open and close the lid very quickly. I 1

7. When burning is complete stop the 1

heating I

8. Let the crucible cool and then weigh it I 1

again

9. The heating, cooling and weighing 1

I process is repeated until a constant
mass is recorded.

Max 10
Description Mass(g)
Crucible + lid

Crucible + lid + Mg I Zn I Al 1

Total 20
lI7~~,'b~le
+ lid+ MgO I ZnO

4541/2 Answer © HAK CIPTA JPNJ 2010

 12

'-'
V , ,... 0i IIncreasing I
1III~
I

i~
Total
Mark
Sub
I
1. The
I
I pH Mark
I 1 The
Scheme
acidity
value
higher the [- a measure
I of hydrochloric
is actually
concentration acid 1 1
I Iis:
ofofhydrochloric I Mark
mark
r the pH value.
,t 4
1
the concentration of H+ ions [and OH- ionsJ !
+ ion per unit(iii)(ii)

1 I
1
II 1. I Pour
11.
(b) Barium [20nitratel
Sodium - hydroxide
100] Barium
cm3 ofis [0.1
chloride molIII
- 1.0]alkali.
a strong 1
0] I
ainbeaker 61 = 13
ammonia
beaker.
NaOH solution.
114 and pH of NH3 = 10 111 I 1
ration
tion
nhatel
trationinto
ofofthe
Any hydroxide ions, I \

5.
3.
4. When
Whereas
The the concentration
ammonia
concentration of
ionises
ef hydroxide
partially
hydroxide ions in
inion is I I
1/2 Answer
I (ii) ~-~~-
© HAK CIPTA JPNJ 2010
n (c) (i)
 13

sol-
1 +correct.
20 ~ IBaS04I 3. Stir the
II mixture. II 11
- 1 10
ater. be I Ionic eguation:
must Ba2+
Na2S04 + Ba(N03h ~ BaS04 + 2NaN03
between
Chemical equation:

4541/2 Answer © HAK CIPTA JPNJ 2010