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Justeq07
Justeq LLC
Justeq07
Patented in most of the strategic countries The most economical among all the available water treatment biocides Bromine releasing biocide The most stable liquid among the liquid halogen biocides in the market Mostly used for cooling water and white water for paper machines Started to market in the US from March, 2008. Over 70 water treatment companies are using this product in the US already. Paper machine application started in 2010 The only effective and economical oxidizing biocide for the systems with high halogen demand.
efficiency
- Frequent boil out of paper machine - Mud and slime build-up by bio-flocculation
Halogen Biocides
- Chlorine (Cl2, NaOCl, Ca(OCl)2)
- Chlorine + NaBr
Effective in C/W above pH8 Effective in C/W contaminated with ammonia
- Stabilized bromine
- Justeq07 In-situ generation of bromine in slime
Stabilized Bromine
- Strength Stable and easy to use Effective above pH8 - Weakness Cost (high consumption) Less effective in high COC, long HTI systems (Over stabilization)
Justeq07
Continuous generation of bromine in C/W Bromine is mainly generated within bio-film, slime mass and algae Requires less than half the amount of stabilized bromine products Non-oxidizer may not be needed Effective in C/W of high pH
P.S.Stewart et al. Center for Biofilm Engineering and Department of Chemical Engineering, Montana State University"Biofilm Penetration and Disinfection Efficacy of Alkaline Hypochlorite and Chlorosulfamates" Journal of Applied Microbiology,2001,(V91),525 -532
HOBr
HOBr
Slime Mass
HOBr
Bacteria
Steady conversion of Stabilized Chlorine and Bromide to free HOBr in process waters Oxidation of bromide only occurs in situ (pH 5-10) Rate increases with temperature Enhanced biofilm penetration
Stabilized Bromine
Justeq07 lasts more than twice as long as stabilized bromine products in uncontaminated cooling water
Total Hal ogen Resi dual , ppm
4
0 0 2 4 6 8 10 12 14hr
Ho u r A ft e r S l u g Do s e
Stabilized Bromine
Justeq07
Recirculation Rate Holding Volume Delta Temperature Cycle of Concentration Corrosion Inhibitor Program Scale Inhibitor Program pH
~40,000gpm ~1,000,000gallon 18oF ~15 Low Zinc Phosphate with Tolyl Triazole Anionic Polymer and Phosphonate 7.7 8.2
TREATMENT SUMMARY
PAST BIOCIDE APPLICATION
1.5% Isothiazolone Slug/2 week (60ppm/each) 900lb/month 12% NaOCl Continuous 22,000lb/month Target Bacteria Count(CFU/ml) <10
4
New Method
New Product Slug/day (23 ppm of H.V) 5,800lb/month Treatment Cost 80% of Past Method
D-1
D+1
D+3
D+4
D+7
D+10
D+14
D+21
D+24
D+29
6 5 4 3 2 1 0
D-1
Bacteria count increases with initial detachment of slime from system surfaces when New Product is applied
Turbidity
TURBIDITY(FAU)
60
50 40 30 20 10 0
D-1
D+1
D+3
D+4
D+7
D+10
D+14
D+21
D+24
D+29
Turbidity increases initially when New Product is applied because of surface cleaning
Before Justeq07
After Justeq07
Cl-
T-Fe
1.0
(ppm)
Cl- 500
400 300 200 D-1 D D+1 D+3 D+4 D+7 D+10 D+14 D+21 D+24 D+29
0.8 T-Fe
0.6 0.4 0.2 (ppm)
MAKE UP C.O.C Calculated (Without NaOCl) Measured 645 (With Conventional Treatment) New Product 633
Ca2+(ppm) 44 15 660
Cl-(ppm) 18 15 270 240 EXTRA 510 12% NaOCl 22,000 lb/month 302 New Product 5,800 lb/month (3,250 lb/month as 12% NaOCl)
Justeq07 lasts much longer than Stabilized Bromine in high halogen demanding water
18 16 14
Justeq07
12 10 8 6 4 2 0 0.0 5.0
Stabilized Bromine
10.0 15.0 20.0 25.0
time (hr)
Justeq07/Stabilized Bromine
Justeq07 Cost Slime Control Algae Control High Halogen Demanding Systems Convenience for Use Metal Corrosion Potential Low Excellent Excellent Excellent Excellent Very Low Stabilized Bromine High Excellent Good Poor Good Medium
Unstabilized Chlorine 1
Justeq07 0.2
2. AOX formation with same halogen concentration (US Patent 5,683,654 Table II)
Unstabilized Chlorine 1
AOX Discharge from Cooling Water Treatment (Combination of above 1. and 2.)
Unstabilized Chlorine 1 Stabilized Bromine 0.2 Justeq07 0.02
Justeq07 discharges much less AOX to environment. Only 2% of chlorine and 10% of stabilized bromine.
Recommended Dosage
Slug dosing:
-25ppm, once/day in holding volume
**Dosage for 1-2ppm total chlorine in C/W is higher during clean-up period
Compatible with Water Treatment Chemicals Azole Copper Corrosion Inhibitors are Decomposed much less by Justeq07 than by Chlorine or Bromine
ECONOMICAL
Effect of various oxidants on vapor phase corrosion of mild steel. (Solutions, March 2003, COMBINED HALOGENS:
NEW PRODUCTS TO COMBAT AN OLD PROBLEM, By Bruce Urtz, Ondeo Nalco Company)
**Justeq07 should be even less corrosive than bromosulfamate because chlorosulfamate is much less reactive
Contact Information
Justeq LLC 2871 Crimson Ct. Northbrook, IL 60062 Tel: 847-656-8626 www.justeq.com
The information contained herein is, to our knowledge, true and accurate. Because conditions of use are beyond our control, we make no warranty or representation, express or implied, except that the product herein conform to the labeling. Nothing contained herein should be construed as permission or recommendation to infringe on any patent. No agent, representative or employee of this company is authorized to vary any terms of this notice. 2007 Justeq LLC.