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General Chemistry 11th Edition Ebbing Solutions Manual
CHAPTER 2
Atoms, Molecules, and Ions
■ SOLUTIONS TO EXERCISES
Note on significant figures: If the final answer to a solution needs to be rounded off, it is given first with
one nonsignificant figure, and the last significant figure is underlined. The final answer is then rounded to
the correct number of significant figures. In multistep problems, intermediate answers are given with at
least one nonsignificant figure; however, only the final answer has been rounded off.
2.1. The element with atomic number 17 (the number of protons in the nucleus) is chlorine, symbol
Cl. The mass number is 17 + 18 = 35. The symbol is 1735 Cl.
2.2. Multiply each isotopic mass by its fractional abundance; then sum:
34.96885 amu 0.75771 = 26.496247
36.96590 amu 0.24229 = 8.956467
35.452714 = 35.453 amu
The atomic weight of chlorine is 35.453 amu.
2.4. Take as many cations as there are units of charge on the anion and as many anions as there are
units of charge on the cation. Two K+ ions have a total charge of 2+, and one CrO42 ion has a
charge of 2, giving a net charge of zero. The simplest ratio of K+ to CrO42 is 2:1, and the
formula is K2CrO4.
2.5. a. CaO: Calcium, a Group 2A metal, is expected to form only a 2+ ion (Ca2+, the calcium ion).
Oxygen (Group 6A) is expected to form an anion of charge equal to the group number
minus 8 (O2−, the oxide ion). The name of the compound is calcium oxide.
b. PbCrO4: Lead has more than one monatomic ion. You can find the charge on the Pb ion if
you know the formula of the anion. From Table 2.5, the CrO4 refers to the anion CrO42 (the
chromate ion). Therefore, the Pb cation must be Pb2+ to give electrical neutrality. The name of
Pb2+ is lead(II) ion, so the name of the compound is lead(II) chromate.
2.6. Thallium(III) nitrate contains the thallium(III) ion, Tl3+, and the nitrate ion, NO3. The formula is
Tl(NO3)3.
34
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2.10. When you remove one H+ ion from HBrO4, you obtain the BrO4 ion. You name the ion from the
acid by replacing -ic with -ate. The anion is called the perbromate ion.
2.12. Sodium thiosulfate is composed of sodium ions (Na+) and thiosulfate ions (S2O32), so the
formula of the anhydrous compound is Na2S2O3. Since the material is a pentahydrate, the formula
of the compound is Na2S2O35H2O.
2.13. Balance O first in parts (a) and (b) because it occurs in only one product. Balance S first in part
(c) because it appears in only one product. Balance H first in part (d) because it appears in just
one reactant as well as in the product.
a. Write a 2 in front of POCl3 for O; this requires a 2 in front of PCl3 for final balance:
O2 + 2PCl3 2POCl3
b. Write a 6 in front of N2O to balance O; this requires a 6 in front of N2 for final balance:
P4 + 6N2O P4O6 + 6N2
c. Write 2As2S3 and 6SO2 to achieve an even number of oxygens on the right to balance what
will always be an even number of oxygens on the left. The 2As2S3 then requires 2As2O3.
Finally, to balance (6 + 12) O's on the right, write 9O2.
2As2S3 + 9O2 2As2O3 + 6SO2
d. Write a 4 in front of H3PO4; this requires a 3 in front of Ca(H2PO4)2 for twelve H's.
Ca3(PO4)2 + 4H3PO4 3Ca(H2PO4)2
2.2. If 7999 out of 8000 alpha particles deflected back at the alpha-particle source, this would imply
that the atom was a solid, impenetrable mass. Keep in mind that this is in direct contrast to what
was observed in the actual experiments, where the majority of the alpha particles passed through
without being deflected.
© 2017 Cengage Learning. All Rights Reserved. May not be scanned, copied or duplicated, or posted to a publicly accessible website, in whole or in part.
36 Chapter 2: Atoms, Molecules, and Ions
2.3. Elements are listed together in groups because they have similar chemical and/or physical
properties.
2.4. Statement (a) is the best statement regarding molecular compounds. Although you may have
wanted to classify Br2 as a molecular compound, it is an element and not a compound. Regarding
statement (b), quite a few molecular compounds exit that don’t contain carbon. Water and the
nitrogen oxides associated with smog are prime examples. Statement (c) is false; ionic
compounds consist of anions and cations. Statement (d) is very close to the right selection but it is
too restrictive. Some molecular compounds containing both metal and nonmetal atoms are known
to exist, e.g., cisplatin, Ni(CO)4, etc. Because numerous molecular compounds are either solids or
liquids at room temperature, statement (e) is false.
2.5. a. This compound is an ether because it has a functional group of an oxygen atom between
two carbon atoms (–O–).
b. This compound is an alcohol because it has an –OH functional group.
c. This compound is a carboxylic acid because it has the –COOH functional group.
d. This compound is a hydrocarbon because it contains only carbon and hydrogen atoms.
2.6. The SO42-, NO2-, and I3- are considered to be polyatomic ions. Statement (a) is true based on the
prefix poly. By definition, any ion must have a negative or positive charge; thus, statement (b) is
true. Bring that the triiodide ion has only iodine atoms bonded together, and no other elements
present, statement (c) is false. There are numerous examples to show that statement (d) is true,
e.g., chromate, dichromate, permanganate to name a few. Oxoanions are polyatomic ions
containing a central characteristic element surrounded by a number of oxygen atoms, e.g., sulfate
and nitrite given in this concept check’s. Statement (e) is true.
2.7. A bottle containing a compound with the formula Al2Q3 would have an anion, Q, with a charge of
2. The total positive charge in the compound due to the Al3+ is 6+ (2 x 3+), so the total negative
charge must be 6; therefore, each Q ion must have a charge of 2. Thus, Q would probably be
an element from Group 6A on the periodic table.
2.2. Divide each amount of chlorine, 1.270 g and 1.904 g, by the lower amount, 1.270 g. This gives
1.000 and 1.499, respectively. Convert these to whole numbers by multiplying by 2, giving 2.000
and 2.998. The ratio of these amounts of chlorine is essentially 2:3. This is consistent with the law
of multiple proportions because, for a fixed mass of iron (1 gram), the masses of chlorine in the
other two compounds are in a ratio of small whole numbers.
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F, but is slightly imperfect at the end. Parchment, ff. 189, 13 × 9¾ in.,
quires of 8 with catchwords. Well written in double column of 46 lines
(corresponding column for column with F throughout), apparently in six
different hands, of which the first wrote quires 1, 2, 6, 8-11, 21, the
second 3 and perhaps 7, the third 4, 5, 16, 17, the fourth 12-15, 19, the
fifth 18, and the sixth 20, 22-24. Latin summaries in the margin
(sometimes omitted). Three leaves are lost in the seventh quire (iii. 1087-
1632), and one at the end, containing the last thirteen lines of the Latin
Carmen de multiplici, &c., with probably the account of the books and
the piece ‘Eneidos, Bucolis.’ A floreated initial to each book, and space
left for miniatures on ff. 1 and 7. Old stamped leather binding.
Former possessors, Thomas Stone ‘of Bromsberrowe in the County
of Glouc.’, Henry Harman, William Mallowes (Q. Elizabeth’s reign?),
John Feynton.
The various hands differ very much from one another in correctness. The first
and the fourth give a text so closely corresponding to that of F, that it is almost
impossible not to believe that it is copied from it. In the case of some of the other
hands this exact correspondence in details of spelling and punctuation disappears,
and a much less correct text is given, but this seems chiefly due to carelessness
(the third hand, for example, is evidently inaccurate and much neglects the metre).
At the same time it must be noted that K has the marginal note at the beginning of
the Prologue, which is wanting in F, ‘Hic in principio,’ &c., and there are some
readings which seem to be derived from another source, as iii. 778, 906, 921,
1732, 1832 (all in the seventh quire), where there is agreement with AM. On the
whole the question of the dependence of K upon F must be left doubtful.
We can trace to this MS. a good many of the mistakes which appear in H₃ and
the Magdalen MS., and found their way sometimes thus into printed editions, e.g.
Prol. 160 bothe, 260 to make manhode, i. 3170 om. his, ii. 78 fader, 101 hem
wolde, 103 all hys cause, 126 he, 135 pore, 138 wich, 162 In (originally The). The
cause of the great increase of error about the beginning of the second book is the
appearance on the scene of the careless third hand, which on f. 40 (for example) in
its last ten lines has at least twenty variations in spelling, &c., from the text of F,
while the first hand resuming has not a single one in its first eighteen lines. Indeed,
whole columns may be found in the parts copied by the first or the fourth hand
which do not differ from F in the smallest particular, either of spelling or
punctuation.
Nine good miniatures cut out of a MS. of the Conf. Amantis are in the
possession of Mr. A. H. Frere, who kindly allowed me to see them. They
are as follows. (1) Tereus, (2) Codrus, (3) Socrates and his wife, (4)
Dives and Lazarus, (5) Roman Triumph, (6) Ulysses and Telegonus, (7)
The Three Questions, (8) Lycurgus taking an oath from the Athenians
(?), (9) King on a quay with bales and gold vessels, apparently landed
from a ship near, perhaps Apollonius landing at Tarsis. Several of the
pictures represent more than one scene of the story, as that of Tereus, in
which we have the king at meat presented with the head of his son, while
there are three birds in the background and the scene of the outrage on
Philomene on the left; and again in (4), where the rich man and his wife
are sitting at table and refusing food to the beggar, while in the
background on the right an angel is receiving the soul of the dying
Lazarus.
These miniatures are supposed to have belonged to Sir John Fenn,
editor of the Paston Letters. The MS. from which they were cut seems to
have been of the middle of the fifteenth cent.
Evidence is afforded of one other large and well written MS. of the
Conf. Amantis by a fragment of parchment in the Shrewsbury School
Library, of which a photograph has most kindly been sent to me by Dr.
Calvert of Shrewsbury. It contains about 70 lines of the Prologue, viz.
189-195 (with the Latin), 224-244, 274-294, 323-343. The leaf to which
it belonged must have measured at least 15½ × 11½ in., and was written
in double column of 50 lines.
Three other MSS. are mentioned in the Catalogue of 1697 (vol. ii. pt.
1), viz. 611 ‘John Gower’s Old English Poems’ with ‘S. Anselmi
Speculum Religiosorum,’ at Naworth Castle, which I strongly suspect is
identical with Harl. 3490 (H₁), 4035, ‘Goweri Confessio Amantis, Fol.
magn.,’ belonging to Ric. Brideoake, Esq., of Ledwell, Oxon., and 6974,
‘Jo. Gower’s Poems, fol.,’ belonging to Sir Henry Langley of the County
of Salop (i.e. of the Abbey, Shrewsbury).
The average excellence of the Gower MSS. stands high, and there is
a surprisingly large proportion of well written and finely decorated
copies, which attain to more than a respectable standard of correctness.
Manuscripts such as L or B₂, which stand in the third rank among copies
of the Confessio Amantis, would take a very different place among the
authorities for any of Chaucer’s works, second only to the Ellesmere
MS. if they were copies of the Canterbury Tales, and easily in the first
place if it were a question of the Legend of Good Women or the Hous of
Fame. It is evident not only that Gower was careful about the text of his
writings, but also that there was some organized system of reproduction,
which was wanting in the case of Chaucer.
The lines are numbered in each book (for the first time), and the
numbers with an asterisk attached are those of the lines in other
recensions than that of the text. In addition to this it should be observed
that as nearly all references to Gower for the last forty years have been
made by Pauli’s edition, it has been thought advisable to place in the
margin of this text indications of the volumes and pages of that edition:
thus P. 1. 153 stands for ‘Pauli, vol. i. p. 153.’
Setting aside matters of spelling, punctuation and grammatical form,
we may note that the material differences of reading between the text of
this edition and that of Pauli are in number about two thousand.
B G .
Passe forth, thou pilgryme, and bridel wel thy beeste;1
Loke not agein for thing that may betyde;2
Thenke what thou wilt, but speke ay with the leeste;
Avyse thee wel who stondeth thee besyde;3
Let not thyne herte beo with thy tonge bewryde;
Trust not to muche in fayre visayginge,
For peynted cheere shapeth efft to stynge.4
Byholde thy selff, or that thou other deme;
Ne beo not glad whane other done amyss;5
10 Sey never al that which wolde the sothe seme,6
Thou maist not wite what thy fortune is:7
For there is no wight on lyve iwyss8
That stondeth sure, ther fore I rede beware,9
And looke aboute for stumbling in the snare.
LINENOTES:
1 1 forþe wele
2 2 ageine
3 4 weele stondeþe
4 7 shapeþe (efft] her R)
5 9 gladde (glad R) amysse
6 10 þee
7 11 wit (witte R)
8 12 ewysse
9 13 stondeþe
10 15 mens (mennys R)
11 16 adradde
12 18 enpeyreþe mans (mannes R)
13 19 wele þowe
14 20 ageyne
15 21 gode (good R) certaine
16 22 (Playe not pecus R)
17 24 hurte bourdeþe (a brere R)
18 25 fareþe doþe
19 26 right ful (full R)
20 27 frome
21 28 þowe shalt kache hareme to pley wt þeos beestis longe
(Thow shalt haue hurt yf þou play with her longe R)
22 34 Remembre doþe amisse
23 35 haste arte
CORRIGENDA ET ADDENDA
p. 2, note on 24-92, for Λ, read ΛP₂, and for Of these H₃ Magd. have
read Of these Magd. has
p. 13, note on 331, for RSnDAr read RSnDAr, Δ
p. 14, l. 349, for new read newe
p. 19, note on 543, read scholde A, B, K schold S, F
p. 23, note on 668, for hol] hole AC read hol B, F hole AC note on 683,
for A read AM
p. 25, l. 747, for for read forto
p. 29, l. 871, for form read forme
p. 33, l. 1024, for wist read wiste
p. 57, l. 782, for There read Ther
p. 60, l. 914, for She read Sche so also p. 244, l. 679
p. 64, l. 1052, for righte read rihte
p. 70, l. 1275, for Commandeth read Comandeth
p. 72, note on 1338, for SΔ read SAdΔ, H₃
p. 88, l. 1946, for wenyinge read wenynge
p. 96, l. 2248, for well read wel
p. 100, l. 2365, for myght read myht so also p. 117, l. 2990
p. 107, l. 2630, for discoevered read descoevered
p. 109, l. 2710, for all read al so also p. 156, l. 966, p. 238, l. 447, p. 346,
l. 1668
p. 112, l. 2822, for bare read bar
p. 113, l. 2838, for But read Bot
p. 133, below l. 96, a small space should be left
p. 138, l. 274, for greveth read grieveth
p. 150, l. 750, for her read hire
p. 170, l. 1498, for Till read Til
p. 182, note on 1916, for RCLB₂, H₃ read RCLB₂, Δ, H₃
p. 200, note on 2592, for AdB read SAdBΔ
p. 234, note on 313, for H₁ ... B₂ read H₁ ... B₂, Δ
p. 252, note on 983, add pater Δ
p. 257, note on 1164, for XRCLB₂ read H₁XRCLB₂
p. 260, note on 1258, for AdT read AdTΔ
p. 262, note on 1336 (margin), add om. Δ
p. 265, note on 1448, for X ... B₂, WH₃ read X ... B₂, Δ, WH₃
p. 266, note on 1473, for AdBT read SAdBTΔ
p. 269, note on 1605, for SBΛ read BΛ and for AdTΔ read SAdTΔ
p. 280, note on 2023, for Phoreus T read Phoreus TΔ
p. 282, l. 2077, for hounde read hound
p. 284, note on 2166, for W read Δ, W
p. 289, l. 2357, for pouere read povere
p. 292, note on 2444, for H₁ ... B₂ read H₁ ... B₂, SΔ
p. 307, l. 225, for distruid read destruid
p. 314, l. 498, for accordant read acordant
p. 334, l. 1224 (margin), add Confessor
p. 346, l. 1653, for accompte read acompte
p. 351, note on 1872, for AC read AC, S
p. 387, l. 3188, for By read Be
p. 396, l. 3507, for thinge read thing
p. 421, l. 716, for harme read harm
p. 464, note on 745 ff., add The authority here followed is the Trésor of
Brunetto Latini, pp. 84-88 (ed. 1863).
p. 468, note on 463 ff., add The authority for this is perhaps the Trésor,
p. 191.
p. 473, l. 11, for 7101), Spertachus for Cyrus (vii. 3418), &c. read 7101).
p. 489, note on 2459 ff., for I am unable [to say where Gower found this
version of the story. The name Geta is quite unknown in the
classical] form of it. read The name Geta was taken by Gower from
the Geta of Vitalis Blesensis, a dramatic piece in Latin elegiacs
founded on Plautus, in which Geta takes the place of Sosia: see
Wright’s Early Mysteries, &c., pp. 79-90.
p. 509, note on 2606, for on the ferst, read on the ferste,
AN ADDITIONAL MS. OF THE ‘CONFESSIO
AMANTIS’
On June 12, 1902, a very valuable manuscript of the Confessio
Amantis, which had not hitherto been described, was offered for sale by
Messrs. Sotheby. By the kind assistance of Dr. Furnivall, who was
allowed by the auctioneers to examine the book before the sale, I am able
to give the following description of it.
F MS. Contains Confessio Amantis with ‘Explicit’ (six
lines), ‘Quam cinxere,’ and ‘Quia vnusquisque,’ after which ‘Deo
gracias.’ Then at the end an alphabetical index to the contents of the
poem. Parchment, ff. 213 (originally), 17½ × 12¼ in., neatly written in
double column of 46 lines to the column, Latin summaries in the text,
red: middle of the fifteenth century. Illustrated throughout with well-
painted miniatures, of which there were originally 108, including
pictures of the signs of the Zodiac and of the positions of the principal
stars. Of these miniatures nine are missing from the book, but these have
now been identified with the series of nine miniatures in the possession
of Mr. A. H. Frere, which are described on p. clxvi of my Introduction.
At the end of the text (f. 203) is written ‘Andw. Fountaine, 1791. Æ. 20.’
This is a very large folio, giving a fair text of the first recension. The interest of
it depends upon the miniatures. In describing the illustrated New College MS. 266
I remarked that other similar copies must once have existed. In saying this I was
referring to the Frere miniatures, and it is a matter of some interest to me to have
been able to identify these with the nine which are missing from the Fountaine
MS. The subjects of the Frere miniatures correspond duly with the places from
which pictures have been cut out, and the words which in some cases have been
cut away with the pictures fit in with those that remain in the MS. For example, on
f. 26 a miniature has been cut out before i. 3067 (the tale of the Three Questions),
the text of the Latin summary above the missing picture being cut off after the
words ‘tocius perdicionis.’ The Frere miniature which relates to this tale continues
the sentence, supplying the words ‘causam sua culpa ministrat’; and so also with
some of the others. In some respects we can now correct our account of the Frere
miniatures. The subjects of seven are correctly given in the description, but the last
two represent, as we can now see, (8) Alexander and the Pirate, iii. 2363 ff., (9)
Lycurgus departing with his goods from Athens, vii. 2917 ff. The book was bought
by Mr. Quaritch for £1550, certainly the highest price ever paid for a Gower
manuscript.
G. C. M.
CONFESSIO AMANTIS[24a]
Incipit Prologus
Of hem that writen ous tofore
The bokes duelle, and we therfore
Ben tawht of that was write tho:
Forthi good is that we also
In oure tyme among ous hiere24
Do wryte of newe som matiere,25
Essampled of these olde wyse26
So that it myhte in such a wyse,27