CNG HA X HI CH NGHA VIT NAM

QCVN 40:2011/BTNMT QUY CHU N K THU T QU C GIA V N C TH I CNG NGHI P

H N I - 2011

National Technical Regulation on Industrial Wastewater

L i ni u QCVN 40:2011/BTNMT do Ban son tho quy chun k thut quc gia v cht lng nc bin son thay th QCVN 24:2009/BTNMT, Tng cc Mi trng, V Khoa hc v Cng ngh, V Php ch trnh duyt v c ban hnh theo Thng t s 47/2011/TT-BTNMT ngy 28 thng 12 nm 2011 ca B trng B Ti nguyn v Mi trng.

National Technical Regulation on Industrial Wastewater

QUY CHU N K THU T QU C GIA V N C TH I CNG NGHI P

1. QUY NH CHUNG
1.1. Ph m vi i u ch nh Quy chun ny quy nh gi tr ti a cho php ca cc thng s nhim trong nc thi cng nghip khi x ra ngun tip nhn nc thi. 1.2. i t ng p d ng 1.2.1. Quy chu n ny p d ng i v i t ch c, c nhn lin quan n ho t ng x n c thi cng nghi p ra ngu n tip nhn nc thi. 1.2.2. Nc thi cng nghip ca mt s ngnh c th c p dng theo quy chun k thut quc gia ring. 1.2.3. Nc thi cng nghip x vo h thng thu gom ca nh my x l nc thi tp trung tun th theo quy nh ca n v qun l v vn hnh nh my x l nc thi tp trung. 1.3. Gi i thch thu t ng Trong Quy chun ny, cc thut ng di y c hiu nh sau: 1.3.1. Nc thi cng nghip l nc thi pht sinh t qu trnh cng ngh ca c s sn xut, dch v cng nghip (sau y gi chung l c s cng nghip), t nh my x l nc thi tp trung c u ni nc thi ca c s cng nghip. 1.3.2. Ngun tip nhn nc thi l: h thng thot nc th, khu dn c; sng, sui, khe, rch; knh, mng; h, ao, m; vng nc bin ven b c mc ch s dng xc nh.

2. QUY NH K THU T 2.1. Gi tr t i a cho php c a cc thng s nhi m trong n c th i

cng nghi p khi x vo ngu n ti p nh n n c th i 2.1.1. Gi tr ti a cho php ca cc thng s nhim trong nc thi cng nghip khi x vo ngun tip nhn nc thi c tnh ton nh sau: Cmax = C x Kq x Kf Trong : - Cmax l gi tr ti a cho php ca thng s nhim trong nc thi cng nghip khi x vo ngun tip nhn nc thi. - Cl gi tr ca thng s nhim trong nc thi cng nghip quy nh ti Bng 1; - Kq l h s ngun tip nhn nc thi quy nh ti mc 2.3 ng vi lu lng dng chy ca sng, sui, khe, rch; knh, mng; dung tch ca h, ao, m; mc ch s dng ca vng nc bin ven b;
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- Kf l h s lu lng ngun thi quy nh ti mc 2.4 ng vi tng lu lng nc thi ca cc c s cng nghip khi x vo ngun tip nhn nc thi; 2.1.2. p dng gi tr ti a cho php Cmax = C (khng p dng h s Kq v Kf) i vi cc thng s: nhit , mu, pH, coliform, Tng hot phng x , Tng hot phng x . 2.1.3. Nc thi cng nghip x vo h thng thot nc th, khu dn c cha c nh my x l nc thi tp trung th p dng gi tr Cmax = C quy nh ti ct B Bng 1. 2.2. Gi tr C c a cc thng s nhi m trong n c th i cng nghi p c quy nh t i B ng 1 B ng 1: Gi tr C c a cc thng s nhi m trong n c th i cng nghi p TT 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 Thng s Nhit Mu pH BOD5 (20oC) COD Cht rn l lng Asen Thu ngn Ch Cadimi Crom (VI) Crom (III) ng Km Niken Mangan St Tng xianua Tng phenol Tng du m khong Sunfua Florua Amoni (tnh theo N) Tng nit Tng pht pho (tnh theo P) Clorua (khng p dng khi x vo ngun nc mn, nc l) n v o C Pt/Co mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l A 40 50 6 n 9 30 75 50 0,05 0,005 0,1 0,05 0,05 0,2 2 3 0,2 0,5 1 0,07 0,1 5 0,2 5 5 20 4 500 Gi tr C B 40 150 5,5 n 9 50 150 100 0,1 0,01 0,5 0,1 0,1 1 2 3 0,5 1 5 0,1 0,5 10 0,5 10 10 40 6 1000

27 Clo d Tng ho cht bo v thc vt 28 clo hu c Tng ho cht bo v thc vt 29 pht pho hu c 30 Tng PCB 31 Coliform

mg/l mg/l mg/l mg/l vi khun/

1 0,05 0,3 0,003 3000

2 0,1 1 0,01 5000

100ml 32 Tng hot phng x Bq/l 0,1 0,1 33 Tng hot phng x Bq/l 1,0 1,0 Ct A Bng 1 quy nh gi tr C c a cc thng s nhi m trong nc thi cng nghip khi x vo ngun nc c dng cho mc ch cp nc sinh hot; Ct B Bng 1 quy nh gi tr C c a cc thng s nhi m trong nc thi cng nghip khi x vo ngun nc khng dng cho mc ch cp nc sinh hot; Mc ch s dng ca ngun tip nhn nc thi c xc nh ti khu vc tip nhn nc thi. 2.3. H s ngu n ti p nh n n c th i Kq 2.3.1.H s Kq ng vi lu lng dng chy ca sng, sui, khe, rch; knh, mng c quy nh ti Bng 2 di y:
B ng 2: H s Kq ng v i l u l ng dng ch y c a ngu n ti p nh n n c th i Lu lng dng chy ca ngun tip nhn nc thi (Q)

H s Kq n v tnh: mt khi/giy (m /s) Q 50 50 < Q 200 200 < Q 500 Q > 500 Q c tnh theo gi tr trung bnh lu lng dng chy ca Thu vn).
2.3.2. H s Kq ng vi dung tch ca ngun tip nhn nc thi l h, ao, m c quy nh ti Bng 3 di y: B ng 3: H s Kq ng v idung tch c a ngu n ti p nh n n c th i Dung tch ngun tip nhn nc thi (V) n v tnh: mt khi (m3) V 10 x 106 10 x 106 < V 100 x 106 V > 100 x 106 H s Kq 0,6 0,8 1,0
4
3

0,9 1 1,1 1,2 ngun tipnhn

nc thi 03 thng kh kit nht trong 03 nm lin tip (s liu ca c quan Kh tng

V c tnh theo gi tr trung bnh dung tch ca h, ao, m tip nhn nc thi 03 thng kh kit nht trong 03 nm lin tip (s liu ca c quan Kh tng Thu vn).

2.3.3. Khi ngun tipnhn nc thi khng c s liu v lu lng dng chy ca sng, sui, khe, rch, knh, mng th p dng Kq = 0,9; h, ao, m khng c s liu v dung tch th p dng Kq = 0,6.
2.3.4. H s Kqi vi ngun tip nhn nc thi l vng nc bin ven b, m ph nc mn v nc l ven bin. Vng nc bin ven b dng cho mc ch bo v thu sinh, th thao v gii tr di nc, m ph nc mn v nc l ven bin p dng Kq = 1. Vng nc bin ven b khng dng cho mc ch bo v thu sinh, th thao hoc gii tr di nc p dng Kq = 1,3. 2.4. H s l u l ng ngu n th i Kf Hs lu lng ngun thiKf c quy nh ti Bng 4 di y: B ng 4: H s l u l ng ngu n th i Kf H s Kf Lu lng ngun thi (F) n v tnh: mt khi/ngy m (m3/24h) F 50 1,2 50 < F 500 1,1 500 < F 5.000 1,0 F > 5.000 0,9 Lu lng ngun thi F c tnh theo lu lng thi ln nht nu trong Bo

co nh gi tc ng mi trng, Cam kt bo v mi trng hoc n bo v mi trng.

3. PH NG PHP XC NH
3.1. L y m u xc nh ch t l ng n c th i p d ng theo h ng d n c a cc tiu chu n qu c gia sau y: - TCVN 6663-1:2011 (ISO 5667-1:2006) Cht lng nc Phn 1: Hng dn lp chng trnh ly mu v k thut ly mu; - TCVN 6663-3:2008 (ISO 5667-3: 2003) - Cht lng nc - Ly mu. Hng dn bo qun v x l mu; - TCVN 5999:1995 (ISO 5667-10: 1992) - Cht lng nc - Ly mu. Hng dn ly mu nc thi. 3.2. Ph ng php xc nh gi tr cc thng s ki m sot nhi m trong n c th i cng nghi p th c hi n theo cc tiu chu n qu c gia v qu c t sau y: - TCVN 4557:1988 Cht lng nc - Phng php xc nh nhit ;
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- TCVN 6492:2011 (ISO 10523:2008) Ch t l ng n c - Xc nh pH; - TCVN 6185:2008 - Cht lng nc - Kim tra v xc nh mu sc; - TCVN 6001-1:2008 (ISO 5815-1:2003), Cht lng nc Xc nh nhu cu oxy sinh ha sau n ngy (BODn) Phn 1: Phng php pha long v cy c b sung allylthiourea; - TCVN 6001-2:2008 (ISO 5815-2:2003), Cht lng nc Xc nh nhu cu oxy sinh ha sau n ngy (BODn) Phn 2: Phng php dng cho mu khng pha long; - TCVN 6491:1999 (ISO 6060:1989) Cht lng nc - Xc nh nhu cu oxy ho hc (COD); - TCVN 6625:2000 (ISO 11923:1997) Cht lng nc - Xc nh cht rn l lng bng cch lc qua ci lc si thu tinh; - TCVN 6626:2000 Cht lng nc - Xc nh asen - Phng php o ph hp th nguyn t (k thut hydro); - TCVN 7877:2008 (ISO 5666:1999) Cht lng nc - Xc nh thu ngn; - TCVN 6193:1996 Cht lng nc - Xc nh coban, niken, ng, km, cadimi v ch. Phng php trc ph hp th nguyn t ngn la; - TCVN 6222:2008 Cht lng nc - Xc nh crom - Phng php o ph hp th nguyn t;
- TCVN 6658:2000 Cht lng nc Xc nh crom ha tr su Phng php trc quang dng 1,5 diphenylcacbazid; - TCVN 6002:1995 Cht lng nc Xc nh mangan Phng php trc quang dng formaldoxim; - TCVN 6177:1996 Cht lng nc Xc nh st bng phng php trc ph dng thuc th 1,10-phenantrolin;

- TCVN 6665:2011 (ISO 11885:2007) Ch t l ng n c- Xc nh nguyn t ch n l c b ng ph pht x quang Plasma c p c m ng (ICP-OES); - TCVN 6181:1996 (ISO 6703-1:1984) Cht lng nc - Xc nh xianua tng; - TCVN 6494-1:2011 (ISO 10304-1:2007) Cht lng nc Xc nh cc anion ha tan bng phng php sc k lng ion Phn 1: Xc nh bromua, clorua, florua, nitrat, nitrit, phosphat v sunphat ha tan; - TCVN 6216:1996 (ISO 6439:1990) Cht lng nc - Xc nh ch s phenol Phng php trc ph dng 4-aminoantipyrin sau khi chng ct; - TCVN 6199-1:1995 (ISO 8165/1:1992) Cht lng nc- Xc nh cc phenol n ho tr la chn. Phn 1: Phng php sc k kh sau khi lm giu bng chit;

- TCVN 5070:1995 Cht lng nc - Phng php khi lng xc nh du m v sn phm du m; - TCVN 7875:2008 Nc Xc nh du v m Phng php chiu hng ngoi; - TCVN 6637:2000 (ISO 10530:1992) Cht lng nc-Xc nh sunfua ho tanPhng php o quang dng metylen xanh; - TCVN 5988:1995 (ISO 5664:1984) Cht lng nc - Xc nh amoni - Phng php chng ct v chun ; - TCVN 6620:2000 Cht lng nc - Xc nh amoni - Phng php in th; - TCVN 6638:2000 Cht lng nc - Xc nh nit - V c ha xc tc sau khi kh bng hp kim Devarda; - TCVN 6202:2008 (ISO 6878:2004) Cht lng nc - Xc nh pht pho Phng php o ph dng amoni molipdat; - TCVN 8775:2011 Cht lng nc - Xc nh coliform tng s - K thut mng lc; - TCVN 6187-1:2009 (ISO 9308-1: 2000) Cht lng nc - Pht hin v m escherichia coli v vi khun coliform. Phn 1: Phng php lc mng; - TCVN 6187-2:1996 (ISO 9308-2:1990(E)) Cht lng nc - Pht hin v m vi khun coliform, vi khun coliform chu nhit v escherichia coli gi nh. Phn 2: Phng php nhiu ng (s c xc sut cao nht); - TCVN 6225-3:2011 (ISO 7393-3:1990) Cht lng nc - Xc nh clo t do v clo tng s. Phn 3 Phng php chun iot xc nh clo tng s; - TCVN 7876:2008 Nc Xc nh hm lng thuc tr su clo hu c Phng php sc k kh chit lng-lng; - TCVN 8062:2009 Xc nh hp cht phospho hu c bng sc k kh - K thut ct mao qun; - TCVN 6053:2011 Cht lng nc - o tng hot phng x anpha trong nc khng mn - Phng php ngun dy; - TCVN 6219:2011 Cht lng nc - o tng hot phng x beta trong nc khng mn. 3.3. Chp nhn cc phng php phn tch hng dn trong cc tiu chun quc gia v quc t c chnh xc tng ng hoc cao hn cc tiu chun vin dn mc 3.2. v cc tiu chun quc gia, quc t mi ban hnh nhng cha c vin dn trong quy chun ny.

4. T CH C TH C HI N
4.1. Quy chun ny p dng thay th QCVN 24:2009/BTNMT - Quy chun k thut quc gia v nc thi cng nghip ban hnh km theo Thng t s 25/2009/TT-BTNMT
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ngy 16 thng 11 nm 2009 ca B trng B Ti nguyn v Mi trng quy nh Quy chun k thut quc gia v mi trng.

4.2. UBND cc tnh, thnh ph trc thuc trung ng cng b mc ch s dng ngun nc v H s Kq trong quy hoch s dng ngun nc v phn vng tip nhn nc thi. 4.3. C quan qun l nh nc v mi trng cn c vo c im, tnh cht ca nc thi cng nghip v mc ch s dng ca ngun tip nhn la chn cc thng s nhim c trng v gi tr c bn (gi tr C) quy nh ti Bng 1 trong vic kim sot nhim mi trng. 4.4. Trng hp cc tiu chun quc gia vin dn trong Quy chun ny sa i, b sung hoc thay th th p dng theo tiu chun mi.