1

V ) I2 (aq ) I (aq

)S2 O32 (aq

). S4 O 62 (aq
I 2 (aq) + 2S2 O 32 (aq)
2I (aq) + S4 O 62 (aq) :

[ I2 ]0 = 0, 20mol /
I = 0,50mol /
0
1
2
2
2

S2 O32 = 0,30mol /

0
S4 O62 = 0, 020mol /

.

1

2 t
I
=
0,15mol
/

[ 2 ]t

:2

) CH 3 COOH(aq) / CH 3 COO (aq ) HCOOH(aq) / HCOO (aq

)CH 3 COO (aq) + HCOOH(aq)
CH 3 COOH(aq) + HCOO (aq

K A1 (HCOOH / HCOO ) = 1, 6.104

K A2 (CH3COOH / CH3COO ) = 1, 6.105
K A1
25C = 10
K A2

=K

A B C
C = 1, 0.101 mol / :
:
1

HCOO
CH COO

i 3
i

HCOOH
CH
COOH

i
[
]i 3

. Qr,i

)V1(ml
)V2(ml
)V3 (m

)V4 (m

10,0

pH
HCOO

i
[ HCOOH]i

4,2

:
V = V1 + V2 + V3 + V4
2
HCOO
CH COO

eq 3
eq

[ HCOOH ]eq CH3COOH eq

C
1,0
1,0
10,0

A
10,0
10.0
10,0

B
5,0
10,0
20,0
1,0

1,0

3,7

3,8

CH3 COO

i
CH3 COOH i

H3O+ . KA

3 .
4 Qr,i

Qr,i

HCOO

eq
[ HCOOH ]eq

K
4

V1 = 15, 0m

CH 3COO

eq
CH 3COOH eq
Qr,eq

) HCOO (aq C1 = 0,15mol /

V2 = 15, 0m HNO 2 C2 = 0, 20mol /
V3 = 10, 0m HCOOH C3 = 0,10mol /

V4 = 10, 0m NO2 C4 = 0,10mol /

HCOO (aq) + HNO 2 (aq)
HCOOH(aq) + NO 2 (aq) :

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 1 .
2 . :
2 1

2 2 HCOO = 0, 020mol /

2 3
5
pH .
pH pH
) . ( 7, 2 7, 6
1 pH pH = 8, 50 .
. HCO / CO
2 CO / HCO i .
i
3 pH 0,10mol . :
) . CO (aq) + H 3 O + (aq)
HC O(aq) + H 2 O( .
4 :
V = 1, 0.105
0,10mol H 3 O +

CO / HCO i 2

i
4 1
4 2 .
4 3 K A CO / HCO i pH

i
.
6
: pK A1 (HCOOH / HCOO ) = 3,8 : 25C pK A 2 (HF / F ) = 3, 2 pK e = 14
I S
V0 = 15m S HCOOH C 0
. C B = 5.102 mol / . VBE = 9m
1 . .
2 VB = 6m pH . pH=4
HO . .
3 C 0 .
4 pH
II
A VA = 10m HF CA = 0,10mol / VA = 40m
) ( Na + + F . CA = 0, 20mol /
B VB = 25m CB = 0, 20mol / VB = 25m
) (Na + + HCOO . CB = 0,10mol /
pH 25C pH A = 4,1 : A . pH B = 3,5 : B

)
F(aq
A B + HCOOH(aq) :

)(aq

HF(aq) + HCOO

1 .
2 Q r,i .
3 . xf

4 x max

5 .
2

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