.

.
1
pH pH 6,35
pH 0,05
1 pH
2
+
3 . H 3 O
4 :
5 H 3 O +
2
C3 H 6 O3 . HA
S0 p = 85% = 1, 20 103 g / L

. S0 S C . V = 1, 00L

V0 = 5, 0mL S0 1, 00L 200mL

.
1 C .
2 .
3 V1 pH . pH = 2,57

3 1 V1
3 2 .
3
V ) CH3COOH(aq . C = 0,10mol / L
1 .
2 = 4,9mS.m 1 . :
CH COO = 4,1mS.m 2 .mol 1 , H O+ = 35mS.m 2 .mol 1
3

3 .

4 pH .
3
SA CA = 2, 0 103 mol / L
SB . CB = 1, 2.103 mol / L VA = 100mL
SA VB = 150mL . SB
.
pH . pH = 4,1 :
1 pH .
2

SA . SB

3 .
4 1 ) n 0 (H3O+ ) n 0 (HO .

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4 2 . x
5 [ H3O+] f .
6 .
) 4 (
:
: S1 HA1 C1
: S2 HA 2 C 2
pH 3, 0

1 HA1 HA 2 .
2 C1 . S1

3 pH S2 C 2
4 C 2 S2 C1
5 S1 S2 S1 S2 . pH S2 . 3, 7

5 1 C1 pH S1
5 2 2 HA 2 14% 2

1 .
-2

S . C=1,0.10 mol/l

-1

. = 0, 43S.m

1 .
2 .
3 .
4
H O+ = 35, 0mS.m 2 .mol 1 , C = 7, 63mS.m 2 .mol1 : . 25C
3

2
) (S=1,0cm2 ;L=1,0cm C=5,0.10-
4mol/l . G=2,03.10-4S :
1 .
2 .
3 .
4 K .
H O+ = 35, 0mS.m 2 .mol1 , C H COO = 3, 23mS.m 2 .mol1 :
5

3
1 .
2 K .
3 V=100ml C=0,010mol/l :
K=1,6.10-4 . 1,2.10-4mol :
4 pH .
4
-2
S HCOOH C=1,0.10 mol/l
d=1,22 . p=80% S
k=1,0.10-2m-1 . G=5,4.10-3S
-1
1 V0 V=1,0l S0 . C0=1,0.10 mol/l
2 V=100ml S . S0
3 .
4 : S

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x max

4 1 x V max = V xVmax

4 2 .
5 pH . S
6 .
: eau = 1g / cm 3
M(HCOOH) = 46g / mol : : 25C
H O+ = 35, 0mS.m 2 .mol1 , HCOO = 5, 46mS.m 2 .mol 1
3

5
) (S V 1, 0mmol :
) C6 H5 COOH(aq )) (CH3COO (aq) + Na + (aq ) . CH3COOH(aq

1 .
2
3 K x eq

4 K = 4 x eq
5 ) (

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