Kha hc LTH m bo mn Ha hc Thy Ngc

thi th i hc s 02

THI TH I HC S 02 MN: HA HC
Thi gian lm bi: 90 pht I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Cho cc nguyn t 6C, 14Si, 16S, 15P. Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l: A. C, S, P, Si. B. S, P, Si, C. C. Si, P, S, C. D. C, Si, P, S. Cu 2: t chy hon ton mt th tch hn hp kh gm metan, etan, propan bng oxi khng kh (oxi chim 20% th tch), thu c 7,84 lt kh CO2 (ktc) v 9,9 gam H2O. Th tch khng kh (ktc) cn dng t chy hon ton lng hn hp kh trn l A. 70 lt. B. 78,4 lt. C. 84 lt. D. 56 lt. Cu 3: Tnh cht no sau y khng bin i tun hon theo chiu tng ca in tch ht nhn ca cc nguyn t trong bng tun hon? A. Nguyn t khi. B. m in. C. Nng lng ion ha. D. Bn knh nguyn t. Cu 4: Ha tan hon ton 22,4 gam mt kim loi M cha bit vo dung dch H2SO4 c, nng d thu c dung dch A v mt kh B c kh nng lm phai mu cnh hoa hng. Hp th hon ton B vo 800 ml dung dch NaOH 1M, ch cho cc phn ng xy ra hon ton ri c cn dung dch, thu c 48,1 gam cht rn. Kim loi M cho ban u l A. Fe. B. Ca. C. Mg. D. Cu. Cu 5: Cho cc cht: NaOH, Fe2O3, K2SO4, CuCl2, CO2, Al v NH4Cl. S cp cht c phn ng vi nhau l A. 5. B. 6. C. 7. D. 8. Cu 6: Tin hnh phn ng cracking m gam isobutan mt thi gian thu c hn hp X gm cc hirocacbon. Cho X qua bnh cha 6,4 gam Br2 th thy dung dch trong bnh b mt mu hon ton v thot ra 2,24 lt hn hp kh Y c t khi hi so vi H2 l 16. Gi tr ca m l A. 3,20 gam. B. 4,88 gam. C. 9,60 gam. D. 7,32 gam. Cu 7: em t chy hon ton ancol X thu c CO2 v nc theo t l mol l 3:4. S ancol tho mn iu kin trn l A. 3. B. 4. C. 5. D. 6. Cu 8: Cho s phn ng: (X) (A) (B) (C) Cng thc cu to ph hp ca X l A. CH3 C CH. C. CH3 CH2 C C CH3. Cu 9: Cho cc phn ng:

(D)

P.V.A (polivinylaxetat)

B. CH3 C C CH3. D. C A, B, C u c th ng.

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Al4C 3 + H 2O NaH + H 2O NaNH 2 + H 2O Zn3P2 + H 2O F2 + H 2O

Al(OH)3 NaOH + H 2

+ CH 4

NaOH + NH3 Zn(OH)2 HF + O2

Hg 2

+ PH3

C 2H 2 + H 2O Al + NaOH + H2O

CH3CHO Na[Al(OH)4 ] + H2 Na[Al(OH)4 ] + NH3

Al + NaNO3 + NaOH + H2O

S phn ng m trong H2O ng vai tr l cht oxi ha v cht kh ln lt l: A. 3 v 2. B. 3 v 1. C. 2 v 1. D. 2 v 2. Cu 10: Cho isopren v isopentan tc dng vi Br2 theo t l 1:1 trong nhng iu kin thch hp th s sn phm c th thu c (khng k cc ng phn hnh hc) ti a ln lt l: A. 3 v 4. B. 6 v 4. C. 4 v 3. D. 5 v 3. Cu 11: ng dng no di y khng phi ca glucoz? A. Trng gng, trng rut phch. B. Lm thc phm dinh dng v thuc tng lc. C. Nguyn liu sn xut ancol etylic. D. Nguyn liu sn xut PVC. Cu 12: Mnh no di y l khng ng? A. Hn hp Fe3O4 v Cu c th tan ht trong dung dch HCl. B. Hn hp Al2O3 v K2O c th tan ht trong nc. C. Hn hp CuS v FeS c th tan ht trong dung dch HCl. D. Hn hp Al v BaO c th tan ht trong nc. Cu 13: Cho x mol Mg vo dung dch cha a mol Cu(NO3)2 v b mol AgNO3. Mun dung dch thu c ch cha mt mui duy nht th gi tr ca x ti thiu l: A. b +
a 2.

B. 2b + a .

C. a +

b 2.

D. b + 2 a .

Cu 14: Cho hirocacbon X phn ng vi HBr th thu c hai sn phm hu c khc nhau, trong tng phn trm khi lng ca Br trong hn hp l 58,39%. Tn gi ca X l A. 3-metylbut-1-en. B. pent-2-en. C. but-2-en. D. isobutilen. Cu 15: Cho 6,76 gam oleum H2SO4.nSO3 vo nc thnh 200 ml dung dch. Bit 10 ml dung dch ny trung ho va vi 16 ml dung dch NaOH 0,5 M. Gi tr ca n l A. 1. B. 2. C. 3. D. 4. Cu 16: Cho cc cht sau: etyl amin, imetyl amin, anilin v amoniac. Th t ng vi tnh baz tng

dn l: A. Etyl amin < imetyl amin < anilin < amoniac. B. Amoniac < anilin < etyl amin < imetyl amin. C. Anilin < etyl amin < imetyl amin < amoniac. D. Anilin < amoniac < etyl amin < imetyl amin. Cu 17: Cho 4,86 gam Al tan va trong 660 ml dung dch HNO3 1M thu c dung dch X ch cha 1 cht tan v V lt hn hp kh Y (ktc) gm N2 v N2O. Gi tr ca V l A. 2,688 lt. B. 0,448 lt. C. 1,344 lt. D. 1,568 lt.

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Cu 18: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l A. 6. B. 4. C. 5. D. 3. Cu 19: Mt mui X c CTPT C3H10O3N2. Ly 19,52 gam X cho phn ng vi 200 ml dung dch KOH 1M. C cn dung dch sau phn ng thu c cht rn v phn hi. Trong phn hi c cht hu c Y n chc bc I v phn rn ch l hn hp cc cht v c c khi lng m gam. Gi tr ca m l A. 18,4 gam. B. 13,28 gam. C. 21,8 gam. D. 19,8 gam. Cu 20: Cho 8,42 gam hn hp A gm Na2CO3, NaOH, CaCO3 v Ca(OH)2 tc dng vi dung dch HCl d thu c 0,672 lt CO2 (ktc) v dung dch B. C cn dung dch B thu c 4,68 gam mui ca natri v m gam mui ca canxi. Gi tr ca m l A. 2,22 gam. B. 4,44 gam. C. 6,66 gam. D. 8,88 gam. Cu 21: iu no sau y l khng ng? A. Nc Gia-ven c dng ph bin hn clorua vi. B. iu ch nc Gia-ven trong cng nghip bng cch in phn dung dch NaCl, khng c mng ngn xp. C. Ozn c nhiu ng dng nh: ty trng tinh bt, du n, cha su rng, st trng nc, D. Axit H2SO4 c s dng nhiu nht trong cc axit v c. Cu 22: Trong cng nghip, ngi ta iu ch HNO3 theo s sau:
NH3 NO NO 2 HNO 3

Bit hiu sut chung ca ton b qu trnh l 70%. T 22,4 lt NH3 (ktc) iu ch c khi lng HNO3 l A. 22,05 gam. B. 44,1 gam . C. 63,0 gam. D. 31,5 gam. Cu 23: Cho 20,15 gam hn hp X gm CH2NH2COOH v CH3CHNH2COOH tc dng vi 200 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va vi 450 ml dung dch NaOH. Phn trm khi lng ca mi cht trong X l: A. 55,83% v 44,17% . B. 58,53% v 41,47%. C. 53,58% v 46,42%. D. 52,59% v 47,41%. Cu 24: Mt ancol A mch nhnh, bc nht c cng thc phn t l CxH10O. Ly hn hp gm 0,01 mol C2H5OH v 0,01 mol A em trn vi 0,1 mol O2 ri t chy hon ton, sau phn ng thy c O2 d. Cng thc cu to ca A l: A. (CH3)2CH-CH2OH. B. CH2=CH-CH(CH3)-CH2OH. C. (CH3)2C=CH-CH2OH. D. CH3-CH=C(CH3)-CH2OH. Cu 25: Phng trnh ha hc no di y khng xy ra? A. Na 2SO4 + BaCl 2 B. FeS + ZnCl 2 C. 2HCl + Mg(OH) 2 D. FeS + 2HCl
H 2S BaSO 4 ZnS + 2NaCl

Cl 2

Fe 2H2O + MgCl 2 + FeCl 2

Cu 26: Cho 5,1 gam hn hp Mg v Fe vo dung dch CuSO4. Sau khi cc phn ng xy ra hon ton, lc kt ta, thu c 6,9 gam cht rn Y v dung dch Z cha 2 mui. Cho Z vo dung dch NaOH d, lc kt ta ri nung trong khng kh n khi lng khng i thu c 4,5 gam cht rn E. S mol CuSO4 tham gia vo phn ng l A. 0,0375 mol. B. 0,075 mol. C. 0,05 mol. D. 0,1125 mol.

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Cu 27: Xenluloz tc dng vi anhirit axetic (H2SO4 c xc tc) to ra 9,84 gam este axetat v 4,8 gam CH3COOH. Cng thc ca este axetat c dng A. [C6H7O2(OOC-CH3)3]n . B. [C6H7O2(OOC-CH3)(OH)3]n . C. [C6H7O2(OOC-CH3)3]n v [C6H7O2(OOC-CH3)2OH]n . D. [C6H7O2(OOC-CH3)2OH]n . Cu 28: Khi ni v qu trnh iu ch Al trong cng nghip, mnh no di y l khng ng? A. Trong qung boxit, ngoi Al2O3 cn c tp cht l SiO2 v Fe2O3. B. C 2 in cc ca thng in phn Al2O3 u lm bng than ch. C. Trong qu trnh in phn, cc m s b mn dn v c h thp dn xung. D. S dng khong cht criolit s gip tit kim nng lng cho qu trnh sn xut. Cu 29: Th tch nc cn thm vo 1 lt dung dch NaOH c pH = 12,5 thu c dung dch c pH = 11 l A. 30,623 lt. B. 30 lt . C. 15 lt. D. 31,623 lt. Cu 30: Cng thc no di y khng th l ipeptit (khng cha nhm chc no khc ngoi lin kt peptit CONH, nhm NH2 v COOH)? A. C5H10N2O3. B. C8H14N2O5. C. C7H16N2O3. D. C6H13N3O3. Cu 31: Ngm mt vt bng Cu c khi lng 5 gam trong 250 gam dung dch AgNO3 4%. Khi ly vt ra th lng AgNO3 trong dung dch gim 17%. Khi lng ca vt sau phn ng l A. 5,76 gam. B. 6,08 gam. C. 5,44 gam. D. 6,52 gam. Cu 32: Ho tan hon ton 7,74 gam mt hn hp gm Mg, Al bng 500 ml dung dch gm H2SO4 0,28M v HCl 1M thu c 8,736 lt H2 (ktc) v dung dch X. Thm V lt dung dch cha ng thi NaOH 1M v Ba(OH)2 0,5M vo dung dch X th thu c lng kt ta ln nht. Khi lng kt ta l A. 54,02 gam. B. 53,98 gam. C. 53,62 gam. D. 53,94 gam. Cu 33: Cho mt lung CO i qua ng s ng 0,04 mol hn hp A gm FeO v Fe2O3 nung nng. Sau khi kt thc th nghim thu c B gm 4 cht nng 4,784 gam. Kh i ra khi ng s cho hp th vo dung dch Ba(OH)2 d th thu c 9,062 gam kt ta. Phn trm khi lng Fe2O3 trong hn hp A l A. 86,96%. B. 16,04%. C. 28,99%. D. 71,01%. Cu 34: Trong mt bnh kn c dung tch khng i xy ra phn ng sau:
Cl2(k ) + H 2(k ) 2HCl (k )

t0C, hng s cn bng ca phn ng l 0,8 v nng HCl ti thi im cn bng l 0,2 mol. Nu lng H2 ban u c ly nhiu gp 3 ln lng Cl2 th s mol ca H2 ly l A. 0,30 mol. B. 0,45 mol. C. 0,60 mol. D. 0,75 mol. Cu 35: Cho mt dung dch cha 0,23 gam Na+; 0,48 gam Mg2+; 0,96 gam SO24 v x gam NO3 . Mnh no di y khng ng? A. Gi tr ca x l 1,86 gam. B. Khi dung dch tc dng vi BaCl2 d th thu c 2,33 gam kt ta. C. C cn dung dch s thu c 3,53 gam cht rn khan. D. Dung dch c iu ch t hai mui Na2SO4 v Mg(NO3)2.

Cu 36: Cht hu c X n chc c mch h, phn nhnh c CTPT l C5H8O2. X tc dng vi NaOH un nng thu c mui Y c phn t khi nh hn phn t khi ca X v ancol Z. CTCT ca X l A. CH2=C(CH3)-COOCH3. B. CH2=CH-CH(CH3)-COOH. C. HCOO-CH2-C(CH3)=CH2. D. HCOO-CH=C(CH3)-CH3.

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Cu 37: Ngi ta iu ch etilen bng cch un nng ancol etylic 920 vi dung dch H2SO4 c ti 1700C. Bit hiu sut phn ng t 80% v khi lng ring ca ancol etylic l 0,8 gam/ml. Th tch ru 920 cn a vo phn ng thu c 2,24 lt C2H4 (ktc) l A. 6,2500 lt. B. 7,3125 lt. C. 7,8125 lt. D. 7,1875 lt. Cu 38: t chy hon ton mt hirocacbon X ri hp th ton b sn phm vo bnh cha 0,15mol Ca(OH)2 tan trong nc. Sau lc c 10 gam kt ta v thy khi lng dung dch tng thm 6 gam so vi dung dch trc phn ng. Cng thc phn t ca X l A. CH4. B. C2H4. C. C2H6. D. C3H6. Cu 39: Ha tan 86 gam hn hp BaCl2 v CaCl2 vo nc c 400 gam dung dch A. Cho A tc dng vi 500 ml dung dch Na2CO3 1,4M, sau phn ng thu c dung dch B v 79,4 gam kt ta. Nng phn trm ca cc mui trong dung dch A ln lt l A. 4,45% v 17,05%. B. 20,8% v 5,55%. C. 2,37% v 31,95%. D. 10,4% v 11,1%. Cu 40: Gi s trong iu kin thch hp, ngi ta thc hin c phn ng este ha va gia 12,4 gam etylenglicol vi m gam hn hp hai axit hu c n chc no mch h ng ng k tip, thu c 32 gam hn hp ba este a chc. Cng thc hai axit hu c dng l: A. HCOOH, CH3COOH. B. CH3COOH, CH3CH2COOH. C. C2H5COOH, C3H7COOH. D. C3H7COOH, C4H9COOH. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Trong pin in ha Cu-Ag ti in cc ng xy ra qu trnh: B. Kh Cu2+. D. Oxi ha Cu. A. Oxi ha H2O. C. Kh H2O. Cu 42: nhn bit cc cht rn: Mg, Al v Al2O3 ch cn dng thuc th no di y? B. NaOH c. A. H2SO4 c, nng. C. HCl long. D. HNO3 c, nng. Cu 43: Cht no sau y khng c kh nng lm mt mu dung dch thuc tm? A. HCl. B. H2S. C. SO3. D. SO2. Cu 44: S tripeptit ti a to ra c c glyxin, alanin v valin l A. 5. B. 6. C. 4.

D. 3.

Cu 45: Cho m gam hp kim Pb Fe phn ng vi dung dch CuSO4, kt thc phn ng thu c (m 3) gam cht rn X. Trong X c cha: A. Cu, Pb, Fe. B. Cu, Fe. C. Cu, Pb. D. Pb, Fe. Cu 46: t chy hon ton 3,24 gam hn hp X gm hai cht hu c A, B trong B hn A mt nguyn t C thu c H2O v 9,24 gam CO2. Bit t khi hi ca X so vi H2 l 13,5. Cng thc phn t ca A v B ln lt l: A. CH4, C2H4. B. CH2O, C2H2. C. CH4O, C2H2. D. CH4, C2H4O.

Cu 47: 160 ml dung dch HNO3 1,25M thu NO. Kim loi M l A. Zn. B. Ca. C. Mg. D. Ca hoc Mg.

Cu 48: Oxi ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 8) gam hn hp Y gm hai axit. em t chy ht hn hp Y cn va 12,32 lt O2 ( ktc). Gi tr ca m l
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A. 17,81.

B. 15,48.

C. 15,47.

D. 17,80.

Cu 49: Khi clo ha PVC thu c t clorin cha 66,78% clo. S mt xch trung bnh tc dng vi 1 phn t clo l A. 1,5. B. 3. C. 2. D. 2,5. Cu 50: Hirocacbon X c cng thc phn t C6H10. X tc dng vi dung dch AgNO3/NH3 to ra kt ta vng. Khi hiro ha hon ton X thu c neo-hexan. X l A. 2,2-imetylbut-3-in. B. 2,2-imetylbut-2-in. C. 3,3-imetylbut-1-in. D. 3,3-imetylpent-1-in. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Khi in phn dung dch hn hp gm AgNO3, Cu(NO3)2 v Fe(NO3)3 th cc kim loi s c to thnh catot ln lt theo th t: A. Ag Fe Cu. B. Cu Ag Fe. C. Ag Cu Fe. D. Ag Cu Fe . Cu 52: Mt hn hp X gm mt axit no n chc v mt axit hu c khng no, n chc cha mt lin kt i C=C. Cho 16,8 gam hn hp X tc dng vi NaOH va thu c 22,3 gam hn hp mui. Mt khc, em t chy hon ton 16,8 gam hn hp X thu c 14,56 lt CO2 (ktc). CTCT ca hai axit trong hn hp X l: A. HCOOH v C2H3COOH. B. CH3COOH v C2H3COOH. C. C2H5COOH v C3H5COOH. D. HCOOH v C3H5COOH. Cu 53: C 5,668 gam cao su Buna-S phn ng va ht vi 3,462 gam Br2 trong CCl4. T l mt xch butaien v stiren trong loi cao su Buna-S ny l A. 2/3. B. 1/2. C. 1/3. D. 3/5. Cu 54: Trong qu trnh sn xut Ag t qung Ag2S bng phng php thy luyn ngi ta phi dng cc ha cht: B. Dung dch HCl long, Mg. A. Dung dch H2SO4, Zn. D. Dung dch HCl c, Mg. C. Dung dch NaCN, Zn. Cu 55: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. CH3CHO, C2H5OH, CH3COOC2H5, C2H5COOCH3. B. CH3OH, C4H10, C2H5Cl, CH3CHO. C. CH3CHO, C6H12O6, C2H5OH, CH3COOC2H5. D. CH3OH, C4H10, C2H5OH, CH3CHO. Cu 56: Cho m gam hn hp X gm axit glutamic v alanin tc dng vi dung dch HCl d. Sau phn ng lm bay hi cn thn dung dch thu c (m + 11,68) gam mui khan. Nu cho m gam hn hp X tc dng vi dung dch KOH va , sau phn ng lm bay hi cn thn dung dch thu c (m + 19) gam mui khan. Gi tr ca m l: A. 36,6 gam. B. 38,92 gam. C. 38,61 gam. D. 35,4 gam. Cu 57: Th nghim no sau y khng thu c kt ta sau khi phn ng kt thc? A. Cho dung dch CH3NH3 n d vo dung dch Al(NO3)3. B. Nh dung dch NH3 n d vo dung dch ZnCl2. C. Cho kh CO2 li vo dung dch Na[Al(OH)4] (hoc NaAlO2) cho n d.

D. Nh dung dch NH3 n d vo dung dch AlCl3. Cu 58: Trn 0,5 lt dung dch Na2CrO4 0,5M vi 1 lt dung dch BaCl2 0,3M c kt ta X v dung dch Y. Khi lng mui c trong dung dch Y l: A. 39,65 gam. B. 75,9 gam. C. 63,25 gam. D. 52 gam. Cu 59: Cho phng trnh ha hc: FeO + HNO3 Fe(NO3)3 + NxOy + H2O

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Kha hc LTH m bo mn Ha hc Thy Ngc

thi th i hc s 02

Sau khi cn bng phng trnh ha hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca HNO3 l A. 16x 6y. B. 8x 3y. C. 16x 5y. D. 10x 4y. Cu 60: t chy hon ton 7,6 gam mt ru no 2 chc cn 8,96 lt O2 ( ktc). Cng thc phn t ca ru l A. C2H4(OH)2. B. C5H10(OH)2. C. C3H6(OH)2. D. C4H8(OH)2.

Mi kin thc mc xin phn hi v a ch duyhien2110@yahoo.com.vn hoc http://boxmath.vn Xin chn thnh cm n.

Gio vin: V Khc Ngc Ngun: Hocmai.vn

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