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Este qua cc nm thi i hc

Nm 2007 Khi A Cu 1: Mnh khng ng l: A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3. B. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui. C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2. D. CH3CH2COOCH=CH2 c th trng hp to polime. Cu 2: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo. Hai loi axit bo l (cho H = 1, C = 12, O = 16) A. C15H31COOH v C17H35COOH. B. C17H33COOH v C15H31COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C17H35COOH Cu 3: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23) A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam. Cu 4: Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l A. CH2=CH-COO-CH3. B. HCOO-C(CH3)=CH2. C. HCOO-CH=CH-CH3. D. CH3COO-CH=CH2 Nm 2007 Khi B Cu 5: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l A. 2. B. 3. C. 5. D. 4. Cu 6: X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l (cho H = 1, C =12, O = 16, Na = 23) A. HCOOCH2CH2CH3. B. HCOOCH(CH3)2. C. C2H5COOCH3. D. CH3COOC2H5 Cu 7: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l (cho H = 1, C = 12, N = 14, O = 16) A. C2H5COOCH3 v HCOOCH(CH3)2. B. HCOOC2H5 v CH3COOCH3. C. C2H3COOC2H5 v C2H5COOC2H3. D. HCOOCH2CH2CH3 v CH3COOC2H5 Cu 8: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 6. B. 4. C. 5. D. 3. Cu 9: Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic. B. etyl axetat. C. axit fomic. D. ru etylic. Nm 2008 Khi A Cu 10: Este X c cc c im sau: - t chy hon ton X to thnh CO2 v H2O c s mol bng nhau; - Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X). Pht biu khng ng l: A. Cht X thuc loi este no, n chc. B. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O.
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C. Cht Y tan v hn trong nc. D. un Z vi dung dch H2SO4 c 170oC thu c anken. Cu 11: S ng phn este ng vi cng thc phn t C4H8O2 l A. 6. B. 5. C. 2. D. 4. Cu 12: Pht biu ng l: A. Phn ng thy phn este trong mi trng axit l phn ng thun nghch. B. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu. C. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ru (ancol). D. Khi thy phn cht bo lun thu c C2H4(OH)2. Cu 13: Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH)2, CH3OH, dung dch Br2, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l A. 4. B. 2. C. 3. D. 5. Nm 2008 Khi B Cu 14: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. etyl axetat. B. metyl axetat. C. metyl fomiat. D. n-propyl axetat. Cu 15: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l A. CH3COO(CH2)2OOCC2H5. B. CH3OOC(CH2)2COOC2H5. C. CH3OOCCH2COOC3H7. D. CH3COO(CH2)2COOC2H5. Cu 16: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 17,80 gam. B. 18,24 gam. C. 16,68 gam. D. 18,38 gam. Nm 2009 Khi A Cu 17: X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l A. CH3COOCH3 v CH3COOC2H5. B. C2H5COOCH3 v C2H5COOC2H5. C. CH3COOC2H5 v CH3COOC3H7. D. HCOOCH3 v HCOOC2H5 Cu 18: X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H 2SO4 c 140 oC, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 4,05. B. 8,10. C. 18,00. D. 16,20. Cu 19: X phng ho mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l: A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa. B. HCOONa, CHC-COONa v CH3-CH2-COONa. C. CH2=CH-COONa, HCOONa v CHC-COONa. D. CH3-COONa, HCOONa v CH3-CH=CH-COONa. Cu 20: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3 to ra kt ta l A. 3. B. 4. C. 5. D. 2. Cu 21: Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l A. HCOOC(CH3)=CHCH3. B. CH3COOC(CH3)=CH2.
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C. HCOOCH2CH=CHCH3. D. HCOOCH=CHCH2CH3 Nm 2009 Khi B Cu 22: Cho cc hp cht hu c: (1) ankan; (2) ancol no, n chc, mch h; (3) xicloankan; (4) ete no, n chc, mch h; (5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (2), (3), (5), (7), (9). B. (1), (3), (5), (6), (8). C. (3), (4), (6), (7), (10). D. (3), (5), (6), (8), (9). Cu 23: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l A. C3H6O2 v C4H8O2. B. C2H4O2 v C5H10O2. C. C2H4O2 v C3H6O2. D. C3H4O2 v C4H6O2. Cu 24: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O 2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l A. HCOOC2H5. B. OCH-CH2-CH2OH. C. CH3COOCH3. D. HOOC-CHO. Cu 25: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. CH3COOH v CH3COOC2H5 B. C2H5COOH v C2H5COOCH3. C. HCOOH v HCOOC3H7. D. HCOOH v HCOOC2H5. Cu 26: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 26,25. B. 27,75. C. 24,25. D. 29,75 Nm 2010 Khi A Cu 27: Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. C2H5COOH v C3H7COOH. B. HCOOH v C2H5COOH. C. HCOOH v CH3COOH. D. CH3COOH v C2H5COOH Cu 28: Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l A. 4. B. 1. C. 2. D. 3. Cu 29: Cho s chuyn ho: HCl + H 2 du ( Ni, t0 ) + NaOH du, t0 Z. Tn ca Z l X Y + Triolein A. axit stearic. B. axit panmitic. C. axit oleic. D. axit linoleic Cu 30: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l
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A. 8,88.

B. 10,56.

C. 6,66.

D. 7,20.

Nm 2010 Khi B Cu 31: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C 5H10O2, phn ng c vi dung dch NaOH nhng khng c phn ng trng bc l A. 4. B. 5. C. 8. D. 9. Cu 32: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l A. metyl propionat. B. metyl axetat. C. etyl axetat. D. vinyl axetat. Cu 33: Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh nng lm mt mu nc brom l A. 3. B. 5. C. 4. D. 6. Cu 34: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. C2H5OCO-COO CH3. B. CH3OCO- CH2- CH2-COO C2H5. C. CH3OCO- CH2-COO C2H5. D. CH3OCO-COO C3H7 Cu 35: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra 16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l A. CH3COOH v C2H5OH. B. CH3COOH v CH3OH. C. HCOOH v C3H7OH. D. HCOOH v CH3OH. Cu 36: Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na, tho mn s chuyn ho sau: + CH3 COOH + H2 X Y Este c mi mui chn. Tn ca X l H 2 SOa Ni , t 0 4, c A. 2,2-imetylpropanal. C. pentanal. B. 3-metylbutanal. D. 2-metylbutanal.

Nm 2011 Khi A Cu 37: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 14,5. B. 17,5. C. 15,5. D. 16,5. Cu 38: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Gim 7,74 gam. B. Gim 7,38 gam. C. Tng 2,70 gam. D. Tng 7,92 gam. Cu 39: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l A. 5. B. 4. C. 6. D. 2. Nm 2011 Khi B Cu 40: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tho mn cc tnh cht trn l A. 5. B. 2. C. 6. D. 4.
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Cu 41: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l A. 32,36 gam. B. 31,45 gam. C. 30 gam. D. 31 gam Cu 42: Triolein khng tc dng vi cht (hoc dung dch) no sau y? A. H2 (xc tc Ni, un nng). B. Dung dch NaOH (un nng). C. H2O (xc tc H2SO4 long, un nng). D. Cu(OH)2 ( iu kin thng). Cu 43: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l A. 3. B. 5. C. 4. D. 2. Cu 44: Pht biu no sau y ng? A. Trong phn ng este ho gia CH3COOH vi CH3OH, H2O to nn t trong nhm OH ca axit COOH v H trong nhm ca ancol -OH B. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip thc phm, m phm. C. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ho hc, ch cn dng thuc th l nc brom. D. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi thm ca chui chn. Cu 45: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l A. 25%. B. 72,08%. C. 27,92%. D. 75%. Nm 2012 Khi A Cu 46: Cho cc pht biu sau: (a) Cht bo c gi chung l triglixerit hay triaxylglixerol. (b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c. (c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch. (d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5. S pht biu ng l A. 3. B. 2. C. 4. D. 1. Cu 47: Kh este no, n chc, mch h X bng LiAlH4, thu c ancol duy nht Y. t chy hon ton Y thu c 0,2 mol CO2 v 0,3 mol H2O. t chy hon ton 0,1 mol X thu c tng khi lng CO2 v H2O l A. 24,8 gam. B. 28,4 gam. C. 16,8 gam. D. 18,6 gam. Nm 2012 Khi B Cu 48: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (MY < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l A. 3 : 5. B. 3 : 2. C. 2 : 3. D. 4 : 3. Cu 49: Thy phn este X mch h c cng thc phn t C4H6 O2, sn phm thu c c kh nng trng bc. S este X tha mn tnh cht trn l A. 6. B. 4. C. 5. D. 3. Cu 50: S trieste khi thy phn u thu c sn phm gm glixerol, axit CH3COOH v axit C2H5COOH l A. 2. B. 6. C. 4. D. 9.
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Cu 51: Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc dng vi dung dch NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l A. HCOOC6H4C2H5. B. C2H5COOC6H5. C. CH3COOCH2C6H5. D. C6H5COOC2H5.

Chuyn ho hu c n thi i hc 2007 - 2012