S GD & T H NI

TRNG THPT A PHC

THI OLYMPIC HA HC LP 10
(Thi gian lm bi 90 pht)

Nm hc 2012-2013

Cho bit nguyn t khi ca cc nguyn t: H=1, Li= 7, F=9, N=14, O=16, Na=23, Al=27, S=32, Cl=35,5, K=39, Mn=55, Br=80, I=127, Cs=133 Cu 1: (6 im) 1) Cn bng cc phn ng sau bng phng php thng bng electron: (4 im) t a) K2Cr2O7 + KI + H2SO4 () K2SO4 + Cr2(SO4)3 + I2 + H2O b) Cu2S + HNO3 Cu(NO3)2 + CuSO4 + NO + H2O c) Fe + HNO3 Fe(NO3)3 + NO + N2O + H2O Bit t l s mol NO : N2O = 1 : 1 d) Mg + HNO3 Mg(NO3)2 + NO + N2O + N2 + H2O Bit hn hp kh thu c c M = 36,5 . Nu cho hn hp kh phn ng va vi O 2 iu kin thng
o

thu c hn hp kh c M = 40,5 . 2) Nu ni dung phng php sunfat iu ch HCl? Ti sao khng dng phng php ny iu ch HBr, HI? (2 im) Cu 2: (5 im) 1) Cho hp cht X c dng A2B, c tng s proton trong X bng 18 v c cc tnh cht sau: t0 X + O2 Y + Z X + Y B+Z X + Cl2 B + HCl a) Xc nh X v hon thnh cc PTHH trn. b) Vit cc PTHH ca cc phn ng xy ra (nu c) khi cho X ln lt tc dng vi: dung dch nc clo; dung dch FeCl3; dung dch Cu(NO3)2; dung dch Fe(NO3)2 (3 im) 2) X v Y l cc nguyn t thuc nhm A, u to hp cht vi hiro c dng RH (R l k hiu ca nguyn t X hoc Y). Gi A v B ln lt l hiroxit ng vi ha tr cao nht ca X v Y. Trong B, Y chim 35,323% khi lng. Trung ha hon ton 50 gam dung dch A 16,8% cn 150 ml dung dch B 1M. Xc nh cc nguyn t X v Y. (2 im) Cu 3: (5 im) 1) Hp th hon ton 1,344 lt SO2 (ktc) vo 13,95 ml dung dch KOH 28%, c khi lng ring l 1,147g/ml. Hy tnh nng phn trm cc cht c trong dung dch sau phn ng. (2 im) 2) Cho 10,8 gam kim loi ho tr 3 tc dng vi kh clo to thnh 53,4g clorua kim loi. a) Xc nh tn kim loi? b) Tnh lng MnO2 v th tch dung dch HCl 37% (d = 1,19g/ml) cn iu ch lng clo dng cho phn ng trn. Bit hiu sut phn ng iu ch bng 80%. (3 im) Cu 4: ( 4 im) Ha tan hon ton 1,62 gam nhm trong 280 ml dung dch HNO 3 1M c dung dch A v kh NO (sn phm kh duy nht). Mt khc, cho 7,35 gam hai kim loi kim thuc hai chu k lin tip vo 500ml dung dch HCl, c dung dch B v 2,8 lt kh H 2 (ktc). Khi trn dung dch A vo dung dch B thy to thnh 1,56 gam kt ta. a) Xc nh tn 2 kim loi kim. b) Tnh nng mol/lt ca dung dch HCl dng.

------------ HT -----------Ghi ch: - Hc sinh khng c s dng bt k ti liu no (k c Bng tun hon cc nguyn t ha hc) - Gim th coi thi khng cn gii thch g thm.