Cu 1: Nung mt hp cht hu c X vi lng d cht oxi ha CuO ngi ta thy thot ra kh CO2, hi H2O v kh N2.

Chn kt lun chnh xc nht trong cc kt lun sau : A. X chc chn cha C, H, N v c th c hoc khng c oxi. B. X l hp cht ca 3 nguyn t C, H, N. C. Cht X chc chn c cha C, H, c th c N. D. X l hp cht ca 4 nguyn t C, H, N, O. Cu 2: t chy hon ton 0,4524 gam hp cht A sinh ra 0,3318 gam CO2 v 0,2714 gam H2O. un nng 0,3682 gam cht A vi vi ti xt chuyn tt c nit trong A thnh amoniac, ri dn kh NH3 vo 20 ml dung dch H2SO4 0,5 M. trung ho axit cn d sau khi tc dng vi NH3 cn dng 7,7 ml dung dch NaOH 1M. Bit MA= 60. Cng thc phn t ca A l A. CH4ON2. B. C2H7N. C. C3H9N. D. CH4ON. Cu 3: t chy hon ton 0,01 mol cht hu c X cn va 0,616 lt O2. Sau th nghim thu c hn hp sn phm Y gm : CO2, N2 v hi H2O. Lm lnh ngng t hi H2O ch cn 0,56 lt hn hp kh Z (c t khi hi vi H2 l 20,4). Bit th tch cc kh u o ktc. Cng thc phn t X l A. C2H5ON. B. C2H5O2N. C. C2H7O2N. D. A hoc C. Cu 4: Metol C10H20O v menton C10H18O chng u c trong tinh du bc h. Bit phn t metol khng c ni i, cn phn t menton c 1 ni i. Vy kt lun no sau y l ng ? A. Metol v menton u c cu to vng. B. Metol c cu to vng, menton c cu to mch h. C. Metol v menton u c cu to mch h. D. Metol c cu to mch h, menton c cu to vng. Cu 5: t chy 200 ml hi mt hp cht hu c X cha C, H, O trong 900 ml O2, th tch hn hp kh thu c l 1,3 lt. Sau khi ngng t hi nc ch cn 700 ml. Tip theo cho qua dung dch KOH d ch cn 100 ml kh bay ra. Cc th tch kh o cng iu kin nhit , p sut. CTPT ca Y l A. C3H6O. B. C3H8O2. C. C3H8O. D. C3H6O2. Cu 6: Khi brom ha ankan X ch c mt dn xut monobrom duy nht c t khi hi so vi hiro l 75,5. X c tn l A. 3,3-imetylhexan. B. isopentan. C. 2,2-imetylpropan. D. 2,2,3,3- tetraetylbutan. Cu 7: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO 2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 3. B. 4. C. 2. D. 5. Cu 8: Hn hp A gm hiro v cc hirocacbon no, cha no. Cho A vo bnh c niken xc tc, un nng bnh mt thi gian ta thu c hn hp B. Pht biu no sau y khng ng ? A. t chy hon ton hn hp A cho s mol CO2 v s mol nc lun bng s mol CO2 v s mol nc khi t chy hon ton hn hp B. B. S mol oxi tiu tn t hon ton hn hp A lun bng s mol oxi tiu tn khi t hon ton hn hp B. C. S mol A - S mol B = S mol H2 tham gia phn ng. D. Khi lng phn t trung bnh ca hn hp A bng khi lng phn t trung bnh ca hn hp B. Cu 9: Trong cc h hirocacbon : ankan, anken, ankaien, ankin, xicloankan, xicloanken, h hirocacbon no khi t chy cho ra s mol nc nh hn s mol CO2 ? A. Ankaien, ankin. B. Ankin, xicloanken. C. Ankin, xicloankan. D. Ankin, ankaien, xicloanken. Cu 10: Vitamin A cng thc phn t C20H30O, c cha 1 vng 6 cnh v khng c cha lin kt ba. S lin kt i trong phn t vitamin A l A. 7. B. 6. C. 5. D. 4. Cu 11: Dy gm cc cht u c kh nng tham gia phn ng trng hp l A. stiren ; clobenzen ; isopren ; but-1-en. B. 1,2-iclopropan ; vinylaxetilen ; vinylbenzen ; toluen. C. buta-1,3-ien ; cumen ; etilen ; trans-but-2-en. D. 1,1,2,2-tetrafloeten ; propilen ; stiren ; vinyl clorua Cu 12: t chy hon ton hirocacbon X cho CO2 v H2O theo t l mol 1,75 : 1 v th tch. Cho bay hi hon ton 5,06 gam X thu c mt th tch hi ng bng th tch ca 1,76 gam oxi trong cng iu kin. Nhn xt no sau y l

ng i vi X ? A. X khng lm mt mu dung dch Br2 nhng lm mt mu dung dch KMnO4 un nng. B. X tc dng vi dung dch Br2 to kt ta trng. C. X c th trng hp thnh PS. D. X tan tt trong nc. Cu 13: Cho 224,00 lt metan (ktc) qua h quang c V lt hn hp A (ktc) cha 12% C2H2 ; 10% CH4 ; 78% H2 (v th tch). Gi s ch xy ra 2 phn ng : 2CH4 C2H2 + 3H2 (1) v CH4 C + 2H2 (2). Gi tr ca V l A. 407,27. B. 448,00. C. 520,18 D. 472,64. o Cu 14: Nhit phn 3,36 lt metan 1500 C trong 0,1 giy. Dn ton b hn hp kh sau phn ng qua dung dch AgNO3/NH3 (d) thy th tch hn hp gim 20% so vi ban u (cc kh o cng iu kin nhit v p sut). Hiu sut phn ng nhit phn metan l A. 40%. B. 66,66%. C. 60%. D. 80%. Cu 15: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom ; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH3CH=CHCH3. B. CH2=CHCH2CH3. C. CH2=C(CH3)2. D. CH2=CH2. Cu 16: Hin nay PVC c iu ch theo s sau : C2H4 CH2ClCH2Cl C2H3Cl PVC. Nu hiu sut ton b qu trnh t 80% th lng C2H4 cn dng sn xut 5000 kg PVC l A. 280 kg. B. 1792 kg. C. 2800 kg. D. 179,2 kg. Cu 17: Cho 4,96 gam gm CaC2 v Ca tc dng ht vi nc c 2,24 lt (ktc) hn hp kh X. Dn X qua bt Ni nung nng mt thi gian c hn hp Y. Cho Y qua bnh ng brom d thy thot ra 0,896 lt (ktc) hn hp Z. Cho t khi ca Z so vi hiro l 4,5. tng khi lng bnh nc brom l A. 0,4 gam. B. 0,8 gam. C. 1,2 gam. D. 0,86 gam. Cu 18: Dn m gam hn hp X gm C2H2 v H2 qua ng ng Ni nung nng c kh Y. Dn Y vo dung dch AgNO3/NH3 d c 12 gam kt ta, kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy ht Z c 4,4 gam CO2 v 4,5 gam nc. Gi tr ca m l A. 5,6 gam. B. 5,4gam. C. 5,8 gam. D. 6,2 gam. Cu 19: Hn hp X gm C2H2 v H2 ly cng s mol. Ly mt lng hn hp X cho i qua cht xc tc thch hp, un nng c hn hp Y gm 4 cht. Dn Y qua bnh ng nc brom thy khi lung bnh tng 10,8 gam v thot ra 4,48 lt kh Z (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 33,6 lt. B. 22,4 lt. C. 16,8 lt. D. 44,8 lt. Cu 20: t chy mt hirocacbon A thu c s mol nc bng 4/5 s mol CO2. Xc nh dy ng ng ca A bit A ch c th l ankan, ankaien, ankin v A c mch h. C bao nhiu ng phn ca A cng nc c xc tc cho ra 1 xeton v bao nhiu ng phn cho kt ta vi dung dch AgNO3/NH3. Cho kt qu theo th t A. Ankin, ankaien, C5H8 ; 3 v 2 ng phn. B. Ankin, C4H6 ; 1 v 1 ng phn. C. Ankin, C5H8 ; 2 v 1 ng phn. D. Anken, C4H10 ; 0 v 0 ng phn Cu 21: A l hn hp gm C2H6, C2H4 v C3H4. Cho 6,12 gam A tc dng vi lng d dung dch AgNO3/NH3 c 7,35 gam kt ta. Mt khc 2,128 lt A (ktc) phn ng va vi 70 ml dung dch Br2 1M. % C2H6 ( theo khi lng) trong 6,12 gam A l A. 49,01%. B. 52,63%. C. 18,3%. D. 65,35%. Cu 22: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 trong dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z c 2,24 lt kh CO2 (ktc) v 4,5 gam H2O. Gi tr ca V l A. 11,2. B. 13,44. C. 5,60. D. 8,96. Cu 23: Nh dung dch AgNO3 vo ng nghim cha mt t dn xut halogen CH2=CHCH2Cl, lc nh. Hin tng xy ra l A. Thot ra kh mu vng lc. B. xut hin kt ta trng. C. khng c hin tng. D. xut hin kt ta vng. Cu 24: Cho cc cht sau: C6H5CH2Cl ; CH3CHClCH3 ; Br2CHCH3 ; CH2=CHCH2Cl. Tn gi ca cc cht trn ln lt l A. benzyl clorua ; isopropyl clorua ; 1,1-ibrometan ; anlyl clorua. B. benzyl clorua ; 2-clopropan ; 1,2-ibrometan ;1-cloprop-2-en. C. phenyl clorua ; isopropylclorua ; 1,1-ibrometan ; 1-cloprop-2-en.

D. benzyl clorua ; n-propyl clorua ; 1,1-ibrometan ; 1-cloprop-2-en. Cu 25: a. un si dn xut halogen X vi nc mt thi gian, sau thm dung dch AgNO3 vo thy xut hin kt ta. X l A. CH2=CHCH2Cl. B. CH3CH2CH2Cl. C. C6H5CH2Br. D. A hoc C. b. un si dn xut halogen X vi dung dch NaOH long mt thi gian, sau thm dung dch AgNO3 vo thy xut hin kt ta. X khng th l A. CH2=CHCH2Cl. B. CH3CH2CH2Cl. C. C6H5CH2Cl. D. C6H5Cl. Cu 26: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c o (t cao, p cao) thu c cht Y c CTPT l C7H7O2Na. Hy cho bit X c bao nhiu CTCT ? A. 3. B. 5. C. 4. D. 2. Cu 27: Cho 5 cht : CH3CH2CH2Cl (1) ; CH2=CHCH2Cl (2) ; C6H5Cl (3) ; CH2=CHCl (4) ; C6H5CH2Cl (5). un tng cht vi dung dch NaOH long, d, sau gn ly lp nc v axit ho bng dung dch HNO3, sau nh vo dung dch AgNO3 th cc cht c xut hin kt ta trng l A. (1), (3), (5). B. (2), (3), (5). C. (1), (2), (3), (5). D. (1), (2), (5). Cu 28: Hirat ha 2 anken c hn hp Z gm 2 ancol lin tip trong dy ng ng. t chy hon ton 0,53 gam Z ri hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,05M c dung dch T trong nng ca NaOH l 0,025M (Gi s th tch dung dch thay i khng ng k). Cng thc cu to ca 2 anken l A. CH2=CH2 v CH2=CHCH3. B. CH2=CHCH3 v CH2=CHCH2CH3. C. CH2=CHCH3 v CH3CH=CHCH3. D. CH2=CHCH3 v CH2=C(CH3)2. Cu 29: a. Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng) : Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l A. CH3COOH, CH3OH. B. C2H4, CH3COOH. C. C2H5OH, CH3COOH. D. CH3COOH, C2H5OH. b. Cho s chuyn ho : Glucoz X Y CH3COOH. Hai cht X, Y ln lt l A. CH3CH2OH v CH=CH. B. CH3CH2OH v CH3CHO. C. CH3CHO v CH3CH2OH. D. CH3CH(OH)COOH v CH3CHO. Cu 30: Dy gm cc cht u tc dng vi ancol etylic l o o A. HBr (t ), Na, CuO (t ), CH3COOH (xc tc). o B. Ca, CuO (t ), C6H5OH (phenol), HOCH2CH2OH. C. NaOH, K, MgO, HCOOH (xc tc). o D. Na2CO3, CuO (t ), CH3COOH (xc tc), (CHCO)2O. Cu 31: Hp cht hu c X c cng thc phn t l C5H12O, khi tch nc to hn hp 3 anken ng phn (k c ng phn hnh hc). X c cu to thu gn l A. CH3CH2CHOHCH2CH3. B. (CH3)3CCH2OH. C. (CH3)2CHCH2CH2OH. D. CH3CH2CH2CHOHCH3. Cu 32: t chy ancol ch cha mt loi nhm chc A bng O2 va nhn thy : nCO2 : nO2 : nH2O = 6: 7: 8. A c c im l A. Tc dng vi Na d cho nH2 = 1,5nA. B. Tc dng vi CuO un nng cho ra hp cht a chc. C. Tch nc to thnh mt anken duy nht. D. Khng c kh nng ha tan Cu(OH)2. Cu 33: Cho m gam tinh bt ln men thnh C2H5OH vi hiu sut 81%, hp th ht lng CO2 sinh ra vo dung dch Ca(OH)2 c 55 gam kt ta v dung dch X. un nng dung dch X li c 10 gam kt ta na. Gi tr m l A. 75 gam. B. 125 gam. C. 150 gam. D. 225 gam. Cu 34: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l A. 20,0. B. 30,0. C. 13,5. D. 15,0. Cu 35: Khi t chy 0,05 mol X (dn xut benzen) thu c di 17,6 gam CO2. Bit 1 mol X phn ng va vi 1 mol NaOH hoc vi 2 mol Na. X c cng thc cu to thu gn l A. CH3C6H4OH. B. CH3OC6H4OH. C. HOC6H4CH2OH. D.C6H4(OH)2. Cu 36: A l cht hu c c cng thc phn t CxHyO. t chy hon ton 0,1 mol A ri hp th ton b sn phm chy vo nc vi trong thy c 30 gam kt ta. Lc b kt ta em un nng phn nc lc thy c 20 gam kt ta na. Bit A va tc dng Na, va tc dng NaOH. Ch ra cng thc phn t ca A. A. C6H6O. B. C7H8O. C. C7H8O2. D. C8H10O.

Cu 37: Ch ra th t tng dn mc linh ca nguyn t H trong nhm -OH ca cc hp cht sau: phenol, etanol, nc. A. Etanol < nc < phenol. C. Nc < phenol < etanol. B. Etanol < phenol < nc. D. Phenol < nc < etanol. Cu 38: Ha cht no di y c th dng phn bit cc l mt nhn cha cc dung dch : C6H5ONa, NaCl, BaCl2, Na2S, Na2CO3 l A. dd NaOH. B. dd HCl. C. Na. D dd KCl. Cu 39: So vi etanol, nguyn t H trong nhm -OH ca phenol linh ng hn v : A. Mt electron vng benzen tng ln, nht l cc v tr o v p. B. Lin kt C-O ca phenol bn vng. C. Trong phenol, cp electron cha tham gia lin kt ca nguyn t oxi tham gia lin hp vo vng benzen lm lin kt -OH phn cc hn. D. Phenol tc dng d dng vi nc brom to kt ta trng 2, 4, 6-tri brom phenol. Cu 40: C bao nhiu phn ng xy ra khi cho cc cht C6H5OH ; NaHCO3 ; NaOH ; HCl tc dng vi nhau tng i mt ? A. 3. B. 4. C. 5. D. 6. Cu 42: Dy gm cc cht u phn ng vi phenol l A. dung dch NaCl, dung dch NaOH, kim loi Na. B. nc brom, axit axetic, dung dch NaOH. C. nc brom, anhirit axetic, dung dch NaOH. D. nc brom, anehit axetic, dung dch NaOH. Cu 43: Hin tng ln lt xy ra khi nh vi git dung dch HCl c vo ng nghim cha mt t dung dch HCOONa v mt t dung dch C6H5ONa ri lc mnh l A. C s phn lp ; dung dch trong sut ha c. B. Dung dch trong sut ha c. C. C phn lp ; dung dch trong sut. D. Xut hin s phn lp c 2 ng nghim. Cu 44: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 3. B. 6. C. 4. D. 5. Cu 45: Cho X l hp cht thm ; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HOC6H4COOCH3. B. CH3C6H3(OH)2. C. HOC6H4COOH. D. HOCH2C6H4OH. Cu 46: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X tc dng c vi NaOH theo t l s mol 1 : 2. Cng thc cu to thu gn ca X l A. C6H5CH(OH)2. B. CH3C6H3(OH)2. C. CH3OC6H4OH. D. C. HOCH2C6H4OH Cu 47: Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l A. 1,15 gam. B. 4,60 gam. C. 2,30 gam. D. 5,75 gam. Cu 48: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu : Tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l A. 3. B. 4. C. 2. D. 1. Cu 49: Mt hp cht hu c A gm C, H, O c 50% oxi v khi lng. Ngi ta cho A qua ng ng 10,4 gam CuO nung nng thu c 2 cht hu c v 8,48 gam cht rn. Mt khc cho hn hp 2 cht hu c trn tc dng vi dung dch AgNO3(d) trong NH3 to ra hn hp 2 mui v 38,88 gam Ag. Khi lng ca A cn dng l A. 1,28 gam. B. 4,8 gam. C. 2,56 gam. D. 3,2 gam. Cu 50: un nng ancol A vi hn hp NaBr v H2SO4 c thu c cht hu c B, 12,3 gam hi cht B chim mt o th tch bng th tch ca 2,8 gam N2 cng nhit 560 C ; p sut 1 atm. Oxi ho A bng CuO nung nng thu c hp cht hu c c kh nng lm mt mu dung dch nc brom. CTCT ca A l A. CH3OH. B. C2H5OH. C. CH3CHOHCH3. D. CH3CH2CH2OH. Cu 51: Thc hin cc th nghim sau: TN 1 : Trn 0,015 mol ru no X vi 0,02 mol ru no Y ri cho tc dng ht vi Na c 1,008 lt H2. TN 2 : Trn 0,02 mol ru X vi 0,015 mol ru Y ri cho hp tc dng ht vi Na c 0,952 lt H2. Th nghim 3 :

t chy hon ton mt lng hn hp ru nh trong th nghim 1 ri cho tt c sn phm chy i qua bnh ng CaO mi nung, d thy khi lng bnh tng thm 6,21 gam. Bit th tch cc khi o ktc. Cng thc 2 ru l A. C2H4(OH)2 v C3H6(OH)2. B. C2H4(OH)2 v C3H5(OH)3. C. CH3OH v C2H5OH. D. Khng xc nh c. Cu 52: Cho ln lt cc cht C2H5Cl, C2H5OH, C6H5OH, C6H5Cl vo dung dch NaOH long un nng. Hi my cht c phn ng ? A. C bn cht. B. Mt cht. C. Hai cht. D. Ba cht. Cu 53: Cho s : C6H6 X Y Z m-HOC6H4NH2. X, Y, Z tng ng l A. C6H5Cl, C6H5OH, m-HOC6H4NO2. B. C6H5NO2, C6H5NH2, m-HOC6H4NO2. C. C6H5Cl, m-ClC6H4NO2, m-HOC6H4NO2. D. C6H5NO2, m-ClC6H4NO2, m-HOC6H4NO2. o Cu 54: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c, t cao, p cao thu c cht Y c CTPT l C7H6O. Hy cho bit X c bao nhiu CTCT ? A. 3. B. 1. C. 4. D. 2. Cu 55: Cht hu c X mch h c to ra t axit no A v etylen glicol. Bit rng a gam X th hi chim th tch bng th tch ca 6,4 gam oxi cng iu kin nhit v p sut; a gam X phn ng ht vi xt to ra 32,8 gam mui. Nu cho 200 gam A phn ng vi 50 gam etilenglicol ta thu c 87,6 gam este. Tn ca X v hiu sut phn ng to X l A. Etylen glicol iaxetat ; 74,4%. B. Etylen glicol ifomat ; 74,4%. C. Etylen glicol iaxetat ; 36,3%. D. Etylen glicol ifomat ; 36,6%. Cu 56: Oxi ho ancol etylic bng xc tc men gim, sau phn ng thu c hn hp X (gi s khng to ra anehit). Chia hn hp X thnh 2 phn bng nhau. Phn 1 cho tc dng vi Na d, thu c 6,272 lt H2 (ktc). Trung ho phn 2 bng dung dch NaOH 2M thy ht 120 ml. Hiu sut phn ng oxi ho ancol etylic l A. 42,86%. B. 66,7%. C. 85,7%. D. 75%. Cu 57: Oxi ho 9,2 gam ancol etylic bng CuO un nng thu c 13,2 gam hn hp gm anehit, axit, ancol d v nc. Hn hp ny tc dng vi Na sinh ra 3,36 lt H2 ( ktc). Phn trm ancol b oxi ho l A. 25%. B. 50%. C. 75%. D. 90%. Cu 58: C8H10O c bao nhiu ng phn cha vng benzen. Bit rng cc ng phn ny u tc dng c vi Na nhng khng tc dng c vi NaOH ? A. 4. B. 5. C. 8. D. 10. Cu 59: Hn hp X gm ancol metylic v mt ancol no, n chc A, mch h. Cho 2,76 gam X tc dng vi Na d o thu c 0,672 lt H2 (ktc), mt khc oxi ha hon ton 2,76 gam X bng CuO (t ) thu c hn hp anehit. Cho ton b lng anehit ny tc dng vi dung dch AgNO3/NH3 d thu c 19,44 gam cht kt ta. Cng thc cu to ca A l A. C2H5OH. B. CH3CH2CH2OH. C. CH3CH(CH3)OH. D. CH3CH2CH2CH2OH. Cu 60: Pht biu ng l A. Axit cha no khi chy lun cho s mol CO2 ln hn s mol H 2O. B. anehit tc dng vi H2 (xc tc Ni) lun to ancol bc nht. C. anehit va c tnh kh va c tnh oxi ha. D. A, B, C u ng. Cu 61: Cho cc cht sau : (1) CH2=CHCH2OH ; (2) CH3CH2CHO ; (3) CH3COCH3. Pht biu ng l A. 1, 2, 3 l cc ng phn. B. 3 tc dng vi H2 (xc tc Ni) to 1 ancol bc 2. C. 1, 2 tc dng vi H2 (xc tc Ni) u to ra 1 ancol. D. A, B, C u ng. Cu 62: Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na ; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v HCOOC2H5. B. HCOOC2H5 v HOCH2OCH3. C. HCOOC2H5 v HOCH2CH2CHO. D. C2H5COOH v CH3CH(OH)CHO. Cu 63: Cho dy cc cht : HCHO, CH3COOH, HCOONa, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 3. B. 6. C. 4. D. 5. Cu 64: Cho cc cht sau: (1) CH2=CHCH2OH ; (2) HOCCH2CHO ; (3) HCOOCH=CH2. Pht biu ng l A. 1, 2, 3 tc dng c vi Na. B. Trong A, B, C c 2 cht cho phn ng trng gng.

C. 1, 2, 3 l cc ng phn. D. 1, 2, 3 chy u cho s mol H2O b hn s mol CO2. Cu 65: Cho cc cht sau : phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 4. B. 3. C. 2. D. 1. Cu 66: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l A. CH3COOH, CH3COOCH3. B. (CH3)2CHOH, HCOOCH3. C. HCOOCH3, CH3COOH. D. CH3COOH, HCOOCH3. Cu 67: Cho tt c cc ng phn mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi : Na, NaOH, NaHCO3. S phn ng xy ra l A. 2. B. 5. C. 4. D. 3. Cu 68: Cho cc cht sau : CH3CH2CHO (1) ; CH2=CHCHO (2) ; CHCCHO (3) ; CH2=CHCH2OH (4) ; o (CH3)2CHOH (5). Nhng cht phn ng hon ton vi lng d H2 (Ni, t ) cng to ra mt sn phm l A. (2), (3), (4), (5). B. (1), (2), (4), (5). C. (1), (2), (3). D. (1), (2), (3), (4). Cu 69: Cho cc hp cht hu c : C2H4 ; C2H2 ; CH2O ; CH2O2 (mch h) ; C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. a. S cht tc dng c vi dung dch AgNO3/NH3 to ra Ag l A. 2. B. 4. C. 3. D. 5. b. S cht tc dng c vi dung dch AgNO3/NH3 to ra kt ta l A. 2. B. 4. C. 3. D. 5. Cu 71: C th phn bit 3 l mt nhn cha: HCOOH ; CH3COOH ; C2H5OH vi ha cht no di y ? A. dd AgNO3/NH3. B. NaOH. C. Na. D. Cu(OH)2/OH . Cu 72: Ch dng qu tm v nc brom c th phn bit c nhng cht no sau y ? A. axit fomic ; axit axetic ; axit acrylic ; axit propionic. B. Axit axetic ; axit acrylic ; anilin ; toluen ; axit fomic. C. Ancol etylic ; ancol metylic ; axit axetic ; axit propionic. D. Ancol etylic ; ancol metylic ; phenol ; anilin. Cu 73: Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX < My), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l A. HCHO v 50,56%. B. CH3CHO v 67,16%. C. CH3CHO v 49,44%. D. HCHO v 32,44%. Cu 74: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l A. HCHO. B. OHCCHO. C. CH3CHO. D. CH3CH(OH)CHO. Cu 75: phn bit 3 mu ha cht ring bit : phenol, axit acrylic, axit axetic bng mt thuc th, ngi ta dng thuc th A. dung dch Na2CO3. B. CaCO3. C. dung dch Br2. D. dung dch AgNO3/NH3. Cu 76: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 43,2 gam. B. 10,8 gam. C. 64,8 gam. D. 21,6 gam. Cu 77: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 35,00%. B. 65,00%. C. 53,85%. D. 46,15%. Cu 78: 17,7 gam hn hp X gm 2 anehit n chc phn ng hon ton vi dung dch AgNO3 trong NH3 (dng d) c 1,95 mol Ag v dung dch Y. Ton b Y tc dng vi dung dch HCl d c 0,45 mol CO2. Cc cht trong hn hp X l A. C2H3CHO v HCHO. B. C2H5CHO v HCHO. C. CH3CHO v HCHO. D. C2H5CHO v CH3CHO. Cu 79: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. C2H5COOH. B. CH3COOH. C. HCOOH. D. C3H7COOH

Cu 80: Cho 0,3 mol axit X n chc trn vi 0,25 mol ancol etylic em thc hin phn ng este ha thu c thu c 18 gam este. Tch ly lng ancol v axit d cho tc dng vi Na thy thot ra 2,128 lt H2. Vy cng thc ca axit v hiu sut phn ng este ha l A. CH3COOH, H% = 68%. B. CH2=CHCOOH, H%= 78%. C. CH2=CHCOOH, H% = 72%. D. CH3COOH, H% = 72%. Cu 81: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOCCOOH v 42,86%. B. HOOCCOOH v 60,00%. C. HOOCCH2COOH v 70,87%. D. HOOCCH2COOH v 54,88%. Cu 82: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. ancol o-hiroxibenzylic. B. axit aipic. C. axit 3-hiroxipropanoic. D. etylen glicol. Cu 83: Chia 0,3 mol axit cacobxylic A thnh hai phn bng nhau. - t chy phn 1 c 19,8 gam CO2. - Cho phn 2 tc dng hon ton vi 0,2 mol NaOH, thy sau phn ng khng cn NaOH. Vy A c cng thc phn t l A. C3H6O2. B. C3H4O2. C. C3H4O4. D. C6H8O4. Cu 84: Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc mch h l ng ng lin tip. t chy hn hp X v cho sn phm chy (CO2, hi nc) ln lt qua bnh 1 ng H 2SO4 c bnh 2 ng KOH thy khi lng bnh 2 tng nhiu hn bnh mt l 3,51 gam. Phn cht rn Y cn li sau khi t l Na2CO3 cn nng 2,65 gam. Cng thc phn t ca hai mui natri l A. C2H5COONa v C3H7COONa. B. C3H7COONa v C4H9COONa. C. CH3COONa v C2H5COONa. D. CH3COONa v C3H7COONa. Cu 85: Cho 19,8 gam mt anehit n chc A phn ng hon ton vi dung dch AgNO3/NH3 (d). Lng Ag sinh ra phn ng ht vi dung dch HNO3 long c 6,72 lt NO ktc. A c cng thc phn t l A. C2H4O. B. C3H6O. C. C3H4O. D. C4H8O. Cu 86: Cho 10,90 gam hn hp gm axit acrylic v axit propionic phn ng hon ton vi Na thot ra 1,68 lt kh (ktc). Nu cho hn hp trn tham gia phn ng cng H 2 hon ton th khi lng sn phm cui cng l A. 11,1 gam. B. 7,4 gam. C. 11,2 gam. D. 11,0 gam. Cu 87: Cho 3,15 gam hn hp X gm axit axetic, axit acrylic, axit propionic va lm mt mu hon ton dung dch cha 3,2 gam brom. trung han ton 3,15 gam hn hp X cn 90 ml dd NaOH 0,5M. Thnh phn phn trm khi lng ca axit axetic trong hn hp X l A. 35,24%. B. 45,71%. C. 19,05%. D. 23,49%. Cu 88: Ha tan 26,8 gam hn hp hai axit cacboxylic no, n chc, mch h vo nc c dung dch X. Chia X thnh hai phn bng nhau. Cho phn 1 phn ng hon ton vi dung dch AgNO3/NH3 d thu c 21,6 gam bc kim loi. trung ha hon ton phn 2 cn 200,0 ml dung dch NaOH 1,0M. Cng thc ca hai axit l A. HCOOH, C3H7COOH. B. CH3COOH, C2H5COOH. C. CH3COOH, C3H7COOH. D. HCOOH, C2H5COOH. Cu 89: Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng dy ng ng tc dng vi Na d, thu c 17,8 gam mui. Khi lng ca axit c s nguyn t cacbon t hn c trong X l A. 3,0 gam. B. 4,6 gam. C. 7,4 gam. D. 6,0 gam