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vn
TRNG THPT CHUYN NGUYNHU

THI TH I HC LN I NM HC MN HA HC

Thi gian lm bi: 90 pht; (60 cu trc nghim)

M thi 132

H, tn th sinh:.......................................................................... S bo danh:...............................................................................
I. Phn chung cho tt c cc th sinh( 40 cu, t cu {<1>} n cu {<40>})

Cu 1: X l mt ancol c cng thc phn t C3H8On, X c kh nng ha tan Cu(OH)2 nhit thng. S cht c th c ca X l: A. 3 B. 4 C. 2 D. 1 Cu 2: t chy hon ton 1 anhit X c nCO2 - nH2O = nX. Cho 11,52 gam X phn ng vi lng d AgNO3 trong NH3 c 69,12 gam Ag. Cng thc ca X l: A. CH2(CHO)2 . B. CH2=CH-CHO. C. CH3CHO. D. HCHO. Cu 3: T m kg khoai c cha 25% tinh bt, bng phng php ln men ngi ta iu ch c 100 lt ru 600.Gi tr ca m l: (bit khi lng ring ca C2H5OH l 0,8g/ml hiu sut chung ca c qu trnh l 90%) A. 375,65kg B. 338,09kg C. 676,2kg. D. 93,91kg Cu 4: Cht hu c X c cng thc phn t l C5 H8O2. Cho X tc dng vi dung dch Br2 thu c cht hu c Y c cng thc l C5H8O2Br2. un nng Y trong NaOH d thu c glixerol, NaBr v mu i cacboxylat ca axit Z. V y cng thc cu t o ca X l : A. HCOOCH(CH3)-CH=CH2 B. CH3-COOCH=CH-CH3 C. CH2=CH-COOCH2CH3 D. CH3COOCH2-CH=CH2 Cu 5: Ha tan hon ton 31,25 gam hn hp X gm Mg, Al v Zn trong dung dch HNO3, sau phn ng hon ton thu c dung dch Y v hn hp gm 0,1 mol N2O v 0,1 mol NO. C cn dung dch sau phn ng thu c 157,05 gam hn hp mui. Vy s mol HNO3 b kh trong phn ng trn l: A. 0,45 mol B. 0,5 mol C. 0,30 mol D. 0,40 mol Cu 6: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin, vinyl clorua. S cht trong dy khi th y phn trong dung dch NaOH long(d), un nng sinh ra ancol l: A. 4 B. 3 C. 5 D. 6 Cu 7: Mt - aminoaxit c cng thc phn t l C2H5NO2, khi t chy 0,1 mol oligopeptit X to nn t aminoaxit th thu c 12,6 gam nc.V y X l: A. tetrapeptit B. ipeptit C. tripeptit D. pentapeptit Cu 8: Kh CO2 tc dng c vi: (1) nc Gia-ven; (2) dung dch K2CO3; (3) nc Brom; (4) dung dch NaHSO3; (5) dung dch KOH, (6) dung dch NaHCO3, (7) Mg nung nng. A. 1, 2, 5, 6 B. 2, 4, 5, 7 C. 1, 2, 5, 7 D. 2, 3, 4, 5 Cu 9: t chy hon ton 29,16 gam hn hp X gm RCOOH, C2H3COOH, v (COOH)2 thu c m gam H2O v 21,952 lt CO2 (ktc). Mt khc, 29,16 gam hn hp X phn ng hon ton vi NaHCO3 d thu c 11,2 lt (ktc) kh CO2.Gi tr ca m l A. 10,8 gam B. 9 gam C. 8,1gam D. 12,6 gam Cu 10: Gi s gang c ng nh thp ch l hp kim ca St vi Cacbon v St ph liu ch g m St, Cacbon
t v Fe2O3. Coi phn ng xy ra trong l luyn thp Martanh l: Fe2O3 3C 2Fe 3CO
0

Kh i lng St ph liu (cha 40% Fe2O3, 1%C) cn dng khi luyn vi 6 tn gang 5%C trong l luyn thp Martanh, nhm thu c loi thp 1%C, l: A. 1,82 tn B. 2,73 tn C. 1,98 tn D. 2,93 tn

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Cu 11: t chy hon ton m gam cht bo X (cha triglixerit ca axit stearic,axit panmitic v cc axit bo t do ). Sau phn ng thu c 13,44 lt CO2 (ktc) v 10,44 gam nc. X phng ho m gam X (H=90%) th thu c kh i lng glixerol l: A. 2,484 gam B. 0,828 gam C. 1,656 gam D. 0,92 gam Cu 12: Cho t t 300ml dung dch NaHCO3 0,1M, K2CO3 0,2M vo 100ml dung dch HCl 0,2M; NaHSO4 0,6M thu c V lt CO2 thot ra ktc v dung dch X. Thm vo dung dch X 100ml dung dch KOH 0,6M; BaCl2 1,5M thu c m gam kt ta. Gi tr ca V v m l:
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A. 0,448 lt v 11,82g B. 0,448 lt v 25,8g C. 1,0752 lt v 23,436g D. 1,0752 lt v 24,224g Cu 13: Sc 13,44 lt CO2 ( ktc) vo 200 ml dung dch X gm Ba(OH)2 1,5M v NaOH 1M . Sau phn ng thu c m1 gam kt ta v dung dch X. Cho dung dch X tc dng vi 200ml dung dch BaCl2 1,2M; KOH 1,5M thu c m2 gam kt ta. Gi tr ca m2 l: A. 39,4 gam B. 47,28 gam C. 59,1 gam D. 66,98 gam Cu 14: Ho tan hon ton hn hp X (gm x mol Fe, y mol Cu, z mol Fe2O3 v t mol Fe3O4) trong dung dch HCl khng th y kh c kh bay ra kh i kh i bnh, dung dch thu c ch cha 2 mu i. M i quan h gia s mol cc cht c trong hn hp X l. A. x+ y = 2z +2t B. x +y = z +t C. x+y =2z +3t D. x+y =2z +2t Cu 15: Ha tan hon ton m gam hn hp g m Na, Na2O, NaOH v Na2CO3 trong dung dch axt H2SO4 40% (va ) thu c 8,96 lt h n hp kh c t kh i i vi H2 bng 16,75 v dung d ch Y c nng 51,449%. C cn Y thu c 170,4 gam mu i. Gi tr ca m l: A. 37,2 gam B. 50,4 gam C. 50,6 gam D. 23,8 gam Cu 16: Hn hp X g m hai aminoaxit mch h no c 1 nhm COOH v 1 nhm NH2 ng ng k tip c phn trm kh i lng oxi l 37,427%. Cho m gam X tc dng vi 800ml dung dch KOH 1M (d) sau khi phn ng kt thc c cn dung dch thu c 90,7gam cht rn khan. m c gi tr l : A. 67,8 gam B. 68,4 gam C. 58,14 gam D. 58,85 gam Cu 17: Cho s phn ng
NaOH du ,t CuO , t CH OH ,t , xt Cl ( a . s ) C6H5 CH3 B C O , x t D E .Tn gi ca E l: A A. phenyl axetat B. metyl benzoat C. axit benzoic D. phenl metyl ete Cu 18: Ha tan 32,52 gam photpho halogenua vo nc c dung dch X. trung ha hon ton dung dch X cn 300 ml dung dch KOH 2M. Cng thc ca photpho halogenua l: A. PCl5 B. PBr5 C. PBr3 D. PCl3. Cu 19: Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na, tho
0 0 0 2
2

Y Este c mi chui chn. Tn ca X l mn s chuyn ho sau: X A. 2-metylbutanal. B. pentanal. C. 3-metylbutanal. D. 2,2-imetylpropanal Cu 20: Cho dy cc cht: C r O 3 , C r 2 O 3 , SiO2, Cr(OH)3, CrO, Zn(OH)2, NaHCO3, Al2O3. S cht trong dy tc dng c vi dung dch NaOH (c, nng) l A. 4. B. 7. C. 6. D. 5. Cu 21: Hn hp kh X g m etilen, metan, propin v vinylaxetilen c t kh i so vi H2 l 17. t chy hon ton 0,1 mol hn hp X r i hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th kh i lng dung dch thay i: A. gim 10,4 gam. B. tng 7,8 gam. C. gim 7,8 gam. D. tng 14,6 gam. Cu 22: Cho C7H16 dng vi clo c chiu sng theo t l mol 1: 1 thu c hn hp gm 3 dn xut monoclo. S cng thc cu to ca C7H16 c th c l A. 4 B. 5 C. 2 D. 3 Cu 23: Ho tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al, H2S? A. 5 B. 8 C. 6 D. 7
H 2 ,Ni,t o

CH 3COOH,Xt H 2 SO 4

Cu 24: Xt phn ng thun nghch sau: SO2(k) + NO2(k) SO3(k) + NO(k). Cho 0,11(mol) SO2, 0,1(mol) NO2, 0,07(mol) SO3 vo bnh kn 1 lt. Khi t cn bng ha hc th cn li 0,02(mol)

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NO2. Vy hng s cn bng KC l A. 20 B. 18 C. 23 D. 0,05 Cu 25: Cht no sau y tn ti dng mng tinh th phn t? A. P trng, than ch B. kim cng, pht pho C. kim cng, P trng D. I2, nc Cu 26: C cc nhn nh sau:
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1)Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc chu k 4, nhm VIIIB. 2)Cc ion v nguyn t: Ne , Na+ , F c im chung l c cng s electron. 3) Bn knh ca cc vi ht sau c sp xp theo th t gim dn: Mg2+, Na+, F-, Na, K. 4)Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l K, Mg, Si, 5)Tnh baz ca dy cc hiroxit: NaOH, Al(OH)3 , Mg(OH)2 gim dn. Cho: N (Z = 7), F (Z=9), Ne (Z=10), Na (Z=11), Mg (Z=12), Al (Z=13), K (Z = 19), Si (Z = 14). S nh n nh ng: A. 5. B. 4. C. 3. D. 2. Cu 27: un nng fomandehit vi phenol (d) c axit lm xc tc thu c polime c cu trc: A. Mch phn nhnh B. Mch khng phn nhnh C. Khng xc nh c D. Mng li khng gian Cu 28: Cho Cacbon (C) ln lt tc dng v i H2, Al, H2 O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 5 B. 6 C. 7 D. 4 Cu 29: Cho cc dung d ch sau cng nng mol/l : NH2CH2COOH (1), CH3COOH (2), CH3CH2NH2 (3), NH3 (4). Th t pH tng dn ng l : A. (2), (1), (4), (3) B. (1), (2), (3), (4) C. (1), (2), (4), (3) D. (2), (1), (3), (4) Cu 30: Mt mu i X c cng thc C3H10O3N2. L y 17,08g X cho phn ng ht vi 200ml dung dch KOH 2M. C cn dung dch sau phn ng thu c phn hi v cht rn. Trong phn hi c mt cht hu c Y (bc 1), trong phn rn ch l hn hp cc cht v c. Kh i lng ca phn rn l: A. 16,16g B. 28,7g C. 16,6g D. 11,8g Cu 31: Cho cc cht: BaCl2; NaHSO3 ; NaHCO3 ; KHS; NH4Cl; AlCl3; CH3COONH4, Al2 O3, Zn, ZnO. S cht lng tnh l: A. 8 B. 7 C. 6 D. 5 Cu 32: Nhn nh no sau y khng ng? A. Phn t mantoz do 2 gc glucoz lin kt vi nhau qua nguyn t oxi, gc th nht C1, gc th hai C4(C1OC4) B. Phn t saccaroz do 2 gc glucoz v fructoz lin kt vi nhau qua nguyn t oxi, g c glucoz C1, gc fructoz C4(C1OC4) C. Tinh bt c 2 loi lin kt [1,4]glicozit v [1,6]glicozit D. Xenluloz c cc lin kt [1,4]glicozit Cu 33: in phn vi in cc tr dung d ch cha 0,3 mol AgNO3 vi cng dng in 2,68 A, trong thi gian t (gi) thu c dung dch X (hiu sut qu trnh in phn l 100%). Cho 22,4 gam bt Fe vo X thy thot ra kh NO (sn phm kh duy nht) v sau cc phn ng hon ton thu c 34,28 gam cht rn. Gi tr ca t l A. 0,60. B. 1,00. C. 0,25. D. 1,20. Cu 34: Sc 1,56g C2H2 vo dung dch cha HgSO4, H2SO4 trong nc 80oC thu c hn hp gm 2 cht kh (bit hiu sut phn ng t 80%). Tip tc cho hn hp kh thu c qua dung dch AgNO3/NH3 d thu c m gam kt ta. Gi tr ca m l: A. 13,248g B. 2,88g C. 12,96g D. 28,8g Cu 35: Cho cc phn ng: (a) Zn + HCl (long) (b) Fe3O4 + H2SO4 (long) (c) KClO3 + HCl (c) (d) Cu + H2SO4 (c)

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(e) Al + H2SO4 (long) (g) FeSO4 + KMnO4 + H2SO4 + S phn ng m H ca axit ng vai tr cht oxi ho l A. 5. B. 3. C. 6. D. 2. Cu 36: Cho t t 450 ml dd HCl 1M vo 500 ml dung dch X gm Na2CO3 v NaHCO3 th thu c 5,6 lt kh (ktc) v dung dch Y. Cho dung dch Y tc dng vi dung dch Ba(OH)2 d th thu c 19,7 gam kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dung dch X ln lt l: A. 0,2M v 0,15M B. 0,2M v 0,3M C. 0,3M v 0,4M D. 0,4M v 0,3M
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Cu 37: Cho cc polime sau: PE (1), PVC (2), cao su buna (3), poli isopren (4), amiloz (5), amilopectin (6), xenluloz (7), cao su lu ho (8), nha rezit (9). Cc polime c cu trc khng phn nhnh l A. 1,2,3,4,6,7. B. 1,3,4,5,8. C. 1,2,4,6,8. D. 1,2,3,4,5,7. Cu 38: Thc hin cc th nghim sau: (a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c). (c) Cho CaOCl2 vo dung dch HCl c. (d) Sc kh CO2 vo dung dch Ca(OH)2 (d). (e) Sc kh SO2 vo dung dch KMnO4. (g) Cho dung dch KHSO4 vo dung dch NaHCO3. h) Cho ZnS vo dung dch HCl (long). (i) Cho Na2CO3 vo dung dch Fe2(SO4)3. S th nghim sinh ra cht kh l A. 4. B. 5. C. 2. D. 6. Cu 39: Cho cc kim loi: Cr, W , Fe , Cu , Cs . Sp xp theo chiu tng dn cng t tri sang phi l A. Cu < Cs < Fe < Cr < W B. Cu < Cs < Fe < W < Cr C. Cs < Cu < Fe < Cr < W D. Cs < Cu < Fe < W < Cr Cu 40: Khi nhit phn hon ton m gam m i cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 nhiu nht l A. KNO3 B. AgNO3 C. KMnO4 D. KClO3
II. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh Chun ( t cu {<41>} n cu {<50>})

Cu 41: Oxi ho khng hon ton 0,16 mol hn hp g m ancol etylic v mt ancol n chc X bng CuO nung nng(H=100%), thu c hn hp cht hu c Y. Cho hn hp Y phn ng vi AgNO3 trong dung dch NH3 d thu c 51,84 gam bc. Tn gi ca X l A. propan-2-ol B. 2-metylpropan-2-ol C. propan-1-ol D. Metanol Cu 42: Dy gm cc cht c th iu ch trc tip c axit axetic l: A. C2H2, CH3CHO, HCOOCH3 B. C2H5OH, HCHO, CH3COOCH3 C. C2H5OH, CH3CHO, CH3COOCH3 D. C2H5OH, CH3CHO, HCOOCH3 Cu 43: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, K2O, MgO nung nhit cao. Sau ph n ng hn hp rn cn li l: A. Cu, Fe, K2O, MgO. B. Cu, Fe, K2O, Mg. C. Cu, FeO, KOH, MgO. D. Cu, Fe, KOH, MgO. Cu 44: Cho cc phn ng: (1) Ca(OH)2 + Cl2 (4) H2S + SO2 to (2) NO2 + NaOH (5) KClO + S 3 (3) PbS + O3 (6) Fe3O4 + HCl S phn ng oxi ho kh l A. 2. B. 4 C. 5. D. 3 Cu 45: Ho tan hon ton m gam Fe trong dung dch HNO3 thy c 0,3 mol kh NO2 sn phm kh duy nht thot ra, nh tip dung dch HCl va vo li thy c 0,02 mol kh NO duy nht bay ra. C cn dung dch sau phn ng thu c cht rn c khi lng l: A. 24,27 g B. 26,92 g C. 19,5 g D. 29,64 g Cu 46: Trong cc cht : propen (I) ; 2-metylbut-2-en(II) ; 3,4-imetylhex-3-en(III) ; 3-cloprop-1-en(IV) ; 1,2-icloeten (V), cht no c ng phn hnh hc : A. I, V B. III, V C. II, IV D. I, II, III, IV Cu 47: C cc dung dch sau (dung mi nc) : CH3NH2 (1); anilin (2); amoniac (3); HOOC-CH(NH2)COOH (4); H2N-CH(COOH)-NH2(5), lysin (6), axit glutamic (7). Cc cht lm qu tm chuyn thnh mu xanh l: A. (1), (2), (3) B. (1), (3), (5), (6) C. (1), (2), (3), (5) D. (1), (2), (3), (4), (5)

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Cu 48: X l mt -Aminoaxit no, cha 1 nhm -COOH v 1 nhm -NH2. T m gam X iu ch c m1 gam ipeptit. T 2m gam X iu ch c m2 gam tripeptit. t chy m1 gam ipeptit thu c 0,3 mol nc. t chy m2 gam tripeptit thu c 0,55 mol H2O. Gi tr ca m l: A. 11,25 gam B. 13,35 gam C. 22,50 gam D. 26,70 gam Cu 49: Tch ring Ag ra khi hn hp Ag, Cu, Ni, Fe dng bt. Dung dch cn dng l (vn gi nguyn khi lng ca Ag ban u) A. Dung dch FeCl3 B. Dung dch HNO3 c ngui
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C. Dung dch H2SO4 long D. Dung dch HCl Cu 50: Cc kh thi cng nghip v ca cc ng c t, xe my... l nguyn nhn ch yu gy ra ma axit. Thnh phn ha hc ch yu trong cc kh thi trc tip gy ra ma axit l: A. NO2, CO2, CO. B. SO2, CO, NO2. C. SO2, CO, NO. D. NO, NO2, SO2.
Phn II: Theo chng trnh nng cao

Cu 51: Thu phn hon ton 150 gam hn hp cc ipeptit thu c 159 gam cc aminoaxit. Bit rng cc ipeptit c to bi cc aminoaxit ch cha mt nguyn t N trong phn t. Nu ly 1/10 khi lng aminoaxit thu c tc dng vi HCl d th lng mui thu c l: A. 19,55 gam B. 20,735 gam C. 20,375 gam D. 23,2 gam Cu 52: Hn hp X g m: HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton h n hp X cn V lt O2 (ktc) sau phn ng thu c CO2 v H2O. Hp th ht sn phm chy vo nc vi trong d thu c 50 gam kt t a. Vy gi tr ca V tng ng l: A. 7,84 lt B. 8,40 lt C. 11,2 lt D. 16,8 lt Cu 53: Tnh pH ca dd A gm HF 0,1M v NaF 0,1M.Bit hng s axit ca HF l Ka = 6,8.10-4. A. 2,18 B. 1,18 C. 3,17 D. 1,37 Cu 54: A l mt hp cht mu lc thc t khng tan trong dung dch long axit v kim. Khi nu chy vi K2CO3 c
mt khng kh th chuyn thnh cht B c mu vng (d tan trong nc). Cho cht B tc dng vi H2SO4 long to thnh cht C c mu da cam. Cht C tc dng vi HCl c thy to thnh cht kh mu vng lc. A, B, C ln lt l A. Cr2O3, K2CrO4, K2Cr2O7. B. CrO3, K2CrO4, K2Cr2O7. C. CrO, K2Cr2O7, K2CrO4. D. Cr2O3, K2Cr2O7, K2CrO4.

Cu 55: C dung dch X gm (KNO3 v H2SO4). Cho ln lt tng cht sau: Fe2O3, FeCl2, Cu, FeCl3, Fe3O4, CuO, FeO tc dng vi dung dch X. S phn ng oxi ha kh xy ra l A. 5 B. 4 C. 3 D. 2 Cu 56: Khng th dng cht no sau y phn bit CO2 v SO2? A. Dung dch KMnO4 B. Kh H2S C. dung dch Br2. D. Ba(OH)2. Cu 57: Cho 7,52g hn hp hi g m C2H2 v CH3CHO tc dng vi dung dch AgNO3/NH3 d thu c 50,4g kt ta. Ha tan kt ta vo dung dch HCl d cn li m gam khng tan. Gi tr ca m l: A. 34,44 gam B. 38,82gam C. 56,04gam D. 13,44gam 0 Cu 58: T 180 lt ancol etylic 40 (khi lng ring ca ancol etylic nguyn cht l d = 0,8g/ml) iu ch c bao
nhiu kg cao su buna (hiu sut qu trnh l 75%) A. 25,357 kg B. 18,783 kg C. 28,174 kg Cu 59: Pht biu no sau y l ng: A. Trong n mn in ho trn cc m xy ra qu trnh oxi ho. B. Trong in phn dung dch NaCl trn catot xy ra qu trnh oxi ho nc. C. Than cc l nguyn liu cho qu trnh sn xut thp. D. Criolit c tc dng h nhit nng ch y ca Al.

D. 18,087 kg

Cu 60: Pht biu no sau y l ng? A. Trng hp stiren thu c poli(phenol-fomanehit). B. T nilon-6,6 c iu ch bng phn ng trng hp hexametylen iamin vi axit aipic. C. Trng hp buta-1,3-ien vi stiren c xc tc Na c cao su buna-S. D. T visco l t tng hp. ----------- HT ----------

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