Answer

AITS-CRT(Set-VI)-PCM(S)-JEE(Main)/13
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1

ANSWERS, HINTS & SOLUTIONS
CRT(SetVI)

ANSWERS KEY
PHYSICS CHEMISTRY MATHEMATICS
Q. No. ANSWER ANSWER ANSWER
1.
B B B
2.
A D A
3.
D D B
4.
B D A
5.
A D C
6.
A B B
7.
B A B
8.
C A C
9.
C D A
10.
B C B
11.
C B A
12.
B A C
13.
A C A
14.
D B B
15.
A B A
16.
D B B
17.
D A B
18.
B D A
19.
C C B
20.
C B C
21.
A D B
22.
C B D
23.
B C A
24.
D D D
25.
A D A
26.
D B C
27.
A B C
28.
D C C
29.
C A A
30.
A A B
A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

FIITJEE JEE (Main)-2013
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P
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4

i
n

T
o
p

1
0
,

1
0

i
n

T
o
p

2
0
,

4
3

i
n

T
o
p

1
0
0
,

7
5

i
n

T
o
p

2
0
0
,

1
5
9

i
n

T
o
p

5
0
0

R
a
n
k
s

&

3
5
4
2

t
o
t
a
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s
e
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2
0
1
2


2
P Ph hy ys si ic cs s PART I

1.
th
m
hc hc
= =

th
5525 =

2. ( )
V V
S 1 A = ; ( )
R r
S 1 A =
( ) ( )
V r
D A 1.54 1.52 20 = = = .02 20 = 0.4

3.
d D
d
d

= =
;
dy y x
x 2
D

= = =

( )
Y 0.1 10 20 4
2 2 2
02.5 25 25 5
= = = = =

= 0.25 y = 0.1

2
max
2
I I cos
5
=

4. Using the relation, stress =
2
F mr
A A
=
we get
2
m
S
A
l
=

5. For tendency of forward slipping friction acts backward.

6. There will be no effect of magnetic force on time period
because the magnetic force will be perpendicular to the
inclined plane.

q,m

7. Wavelength of first overtone in open pipe is = l

1
1
V
f
l
=
wavelength of the closed pipe for fundamental is
4
4
l = l
= ;
2
2
V V
f V
4 4 0.25 l
= = =
;
2 1
f f 5 =

1 1
340 340
340 5 340 5
l l
= =

8. From work energy in the frame which is attached to point A

2 2 2
xm m
1 1 1
max k x m(0) m(0)
2 2 2
+ =

max
2ma
x
k
= .

3
9.
av rms rm
P V I cos = ;
2
=
av
P 0 = .

11. P = i
2
R
2 2
1
i 6 i 24 =
1
i
i
2
= R 24 =

12.
2
.5 1.25
5 r
| |
=
|
+
\ .

13.
2
0
q
F qE
2A
= =

14. at t = 0,
Inductor will acts as an open circuit, no current will flow.

15.
2
T
T
=
eff
g
g
g
eff
=
2
3
g
T
2
=
3
2
T

16. dp =
p p
dx dy
x y

+

17. In all the options given, the term force is used.
But gravitational potential at a point is defined in terms of the work done in displacing a unit mass
from infinity to that point without change in kinetic energy.

18. PV = RT
PM
RT =

P
=
constant or

B B
A A
P
1
P

= <

B A
P P <

19.
n R nR
dQ dT dU = dT, dW = nRdT
1 1
,

dQ dw dU
y y 1 1
= =

: 1 : 1

20. TP
2/5
= constant ; Using gas equation was can write PV
5/3
= constant
It implies
5
3
= ; The process is adiabatic, thus Q = 0.

4
21.
x
x
,
T/ 2
= where
2 R
T

=

23. Time period
2 m
T
qB
=

2
T 1
2
= =
s.
Thus particle will beat point P after
1
t
12
= s.
P
v
y
x
30

v 10[cos30i sin30j] = +

3 1

v 10 i j 5 3 i j
2 2
(
(
= + = +
(

(

m/s.

24. ( )
2
2 2
1 1 1
R z 7.4
2 3

=
`
)

25.
1
2
2 1
1 2
( 1)
( 1)
| |
=
|

\ .
Z
Z

1
1 2
2
( 1)
(4)
( 1)
Z
Z

2 1
2( 1) ( 1) = Z Z

2 1
2 1 = Z Z

26. Fringe width =
D
d

When it is immersed in liquid
0
6000 D B
0.2mm
1.6 d 1.6
= = =

27.
1 1 1
V 40 30
=
;
1 1 1
V 120cm
V 30 40
= =
This image must be placed at focus of mirror
then rays reflected from mirror will be parallel to principal axis then similarly it will converge at
focus of lens.
16028. P =
I = m
1

2 2
1 2
x m ( x) +
I should be minimum.

29. Use the equation of conservation of mechanical energy.

30. wave length, e end correction

1 2
3
,
4 4
+ = + = l e l e


5
C Ch he em mi is st tr ry y PART II

2. -ve charge on electronegative atom increases stability and C N system is more stable than
C = C = N system so order is p > r > q.

3.
2
Cl
h
CH
2
Cl
+
Cl
+
Cl
+
Cl
4 stereo product
2 geometrical isomers

5. In polar protic solvent less hydrogen bonding nucleophile is more nucleophilic.

6. Reaction is an eg. of nucleophilic addition.
Rate of NA. R : acid halide > aldehyde > ketone > acid.

7.
14
3
||
OH aldol
2
3 3 CH CHO
O
CH CH CH CHO CH CH CH CHO CH CH CH CH CH C H
= = = =
8.
OH
( ) d
C H
3
CH
Et
O C
O
CH
3
C H
3
CH
Et
OH + C H
3
C O
O
Saponification
reaction

9. Product (i) and (ii) will be obtained by normal Backmann rearrangement mechanism of product
(iii) is:

O
O
CH
3
O
2
NH OH
O
O
CH
3
N H
5
PCl
O
O
N C CH
3
O
O
N
CH
3

10. Keto group increases the acidic character.
So,
CH
2
OH
O
will react fastest with sodium.


6
12.
2 2 2 2
1 2
1 1 1 1 1
R R
n n 1 n
(
(
= =
(
(

1/ 2
R
n
R 1
(
=
(

13. Binding energy of w = 7.5 120 = 900 MeV
Binding energy of 2y = 2(8.5 60) = 1020 MeV.
Binding energy (2y) > Binding energy (w)
Thus energy will be released.

14. P & Q contain n
1
& n
2
molecules
PV nKT

1
2
n 5
n 3
=
Internal energy is conserved, hence
( )
1 1 1 2 2
3 3 3
n KT n n KT KT
2 2 2
= = + =

2700
T K
8
= =

( )
1 2
1 1 1 1
n n
PV T
PV n T
+ (
=
(

On solving, we get 1.8 10
5
N/m
2

15. When two Fe
3+
ions are dopped, three Fe
2+
ions are replaced to neutralize the charge hence one
cationic valency creates.
Let the moles of Fe
3+
are x and moles of Fe
2+
ions are (0.93 x) in one mole of Fe
0.93
O.
3x + 2(0.93 x) = 2
3x + 1.86 2x = 2
x = 2 1.86 = 0.14
In 0.1 mole of compound 0.014 moles of Fe
3+
ions are present. Therefore 0.007 moles of cationic
vacancies i.e. 0.007 6.023 10
23
total no. of cationic vacancies are present.

16.
V
nRT
1000
=

B
B
W 1000
V RT
m
| |
=
|
\ .

B
B B
W 1000RT C 1000RT
V m m
| |
= =
|
\ .

When is plotted against C, the slope will be equal to
B
1000RT
m

3
B
1000 0.082 300
4 10
m

=

6
B
m 6 10 =


7
17.
2
2
2
H
cathode anode
cell 2
H
anode cathode
H P
0.59
E log
2
H P
+
+
( (

=
( (

5 3
b
OH CK 0.1 10 10 M

( = = =

14
11
3
anode
10
H 10 M
10
( = =

7 4
a
cathode
H CK 0.1 10 10 M
+
( = = =

( )
( )
2
4
cell 2
11
10 0.1
0.059
E log
2
10 1

= 0.40 V

18. Molecules with 2 b.p. and 3 l.p. have linear shape.

19. ( ) ( ) ( )
sp
AgBr s Ag aq. Br aq. K
+
+

( ) ( ) ( ) ( )
3
2
2 3 2 3 f
2
Ag s 2S O aq. Ag S O aq. K
+
+

( ) ( ) ( ) ( ) ( )
3
2
2 3 2 3 sp f
2
AgBr s 2S O aq. Ag S O aq. Br aq K K K 25

+ + = =

( )
2
2
x
K
0.1 2x
=

( )
2
2
x
25 , x 0.045 M
0.1 2x
= =

20. Benzoic acid C
6
H
5
COOH, M.W. = 122.
Heat liberated by the combustion of 1.89 g of benzoic acid - ms t
= 18.94 0.998 0.632 = 11.946 cal
Heat of combustion per mole of benzoic acid =
11.946
122
1.89

= - 771.1 kcal
22.
N
B
B
N
N H
HB
X
H
X
H
(i)
N
B
B
N
N
B
X
H
H
X
H
H
(ii)
N
B
B
N
N
B
X
X
H
H
H
H
(iii)
N
B
B
N
N
B
H
H
X
H
X
H
(iv)

23. 50 ml 2 N hydro solution 50 ml of 2 N I
2
solution.
50 ml 2 N Cl
2
solution 50 ml 2 N CaOCl
2
solution.
6.35 g CaOCl
2

6.35
% 100 63.5
10
= =

24. Fluorine does not form stable oxoacid.


8
26.
f f
T i K m i 1.86 0.1 = =
= 0.372 = 0.186 i
i = 2
This shows that complex gives 2 ions in solution. Thus the formula of the complex is
[Co(NH
3
)
4
Cl
2
]Cl.
( ) ( )
3 2 3 2
4 4
Co NH Cl Cl Co NH Cl Cl
+

( ( +

27.
( )
( )
( )
( )
2 4 2
x z
A y
CaC O CO CO CaO + +
( )
( )
2
2
B
CaO H O Ca OH +
( )
2 3 2
2
Milkiness
Ca OH CO CaCO H O + +

28. WolffKishner reduction involves (NH
2
NH
2
/KOH) a very strong base so, along with the reduction of
O
to

group, it also undergo E2 elimination in presence of strong base.
Hence, (C).

29. Lanthanide contraction is observed in these ions, i.e., ionic radius decreases as atomic number
increases.


9
M Ma at th he em ma at ti ic cs s PART III

2. Domain of the function x {1, 1}

3. Two lines are
x 0 y 0 z n
0 n
+
= =
and
x 0 y m z 0
0 m n

= =

applying the formulae of shortest distance we get
2 2 2 2
1 1 1 1
m n c
+ + =

5. Curves are x
2
+ y
2
= 25
2x + 2y = 8 x + y = 4
x y = 3
(1, ) lies in the shaded region then
( ) 4 6, 1
(, 2) lies in side so (1, 2)

6. Let n(B) = x n(A) = x + 2
n(F) = y n(C) = y + 3
n(D) = z n(E) = z + 5
x + y + z + x + 2 + y + 3 + z + 5 = 40
x + y + z = 15 but x 1 y 1 and z 1
So total ways of distribution is
14
C
2
= 91

8. For the lines to be coplanes
AB
, a
and b
should be coplanes

2 0 k
1 k 2 0
4 1 1 k
=

2(k k
2
+ 2) + k(1 4k) = 0
2k 2k
2
+ 4 + k 4k
2
= 0
(1, 2, 1)

a 2i 0j kk = +
B(3, +1, k)

b i kj 2k = +
6k
2
k + 4 = 0
6k
2
+ k 4 = 0
This equation has two distinct roots
So two such planes exist.

9. y = sin
2
x + cosec
2
x + 2 + cos
2
x + sec
2
x + 2 + tan
2
x + cot
2
x + 2
= 1 + 6 + 1 + tan
2
x + 1 cot
2
x + tan
2
x + cot
2
x
= 9 + 2(tan
2
x + cot
2
x)
= 9 + 2 [(tan x cot x)
2
+ 2]
= 13 + 2 (tan x cot x)
2

y
min
= 13 = p

p
4
3
(
=
(

10. C
1
: z z 2 z 1 + =
Put z = x + iy
2x = 2|x 1 + iy|
x
2
= (x 1)
2
+ y
2


10
y
2
= 2
1
x
2
| |
|
\ .

C
2
: arg(z (1 i) =
its a ray emanating from (1, 1) and making angle with the positive real axis.
C
1
and C
2
have exactly one point common.
C
2
must be tangent to C
1

y + 1 = m(x + 1)
Solving C
1
and C
2

m = 1
y = x = 1
P(z
0
) = 1 + i

0
z 2 =

11. For second equation to passes real roots
D 0
D = p
2
4q
as p, q [1, 10] and p, q N
such 32 quadratics are possible
and x
2
+ 5x + 3 = 0 difference of roots = |4 cos 2|
x
2
+ px + q = 0 difference of roots = |4 cos 2|
So p
2
4q = 25 12
p
2
4q = 13
So (p, q) an be (5, 3), (7, 9) two possible cases
So required probability =
2 1
32 16
=

12. a x a b =

( )
a x b 0 =
x b a =

x b a = + =
( ) ( ) ( )

2 i 1 2 j 1 3 k + + + +
Now a x 0 =
2 + + 2 + 4 + 3 + 9 = 0
14 = 7
=
1
2

3 1

x i 0j k
2 2
= + +

9 1 5
x
4 4 2
= + =

13. Let cos
1
x + cot
1
x = f(x)
Domain x [1, 1] and f(x) is decreasing function in its domain.
at x = 1
max
3 7
f(x)
4 4

= + =
at x = 1
min
f(x) 0
4 4

= + =

( )
7
f x
4 4

k can be 1, 2, 3, 4, 5


11
14.
12
sinA
13
= cos A can be
5
13
or
5
13
A is in 3
rd
or 4
th
quadrant

15
sinB
17
= cos B can be
7
17
or
7
17
B is in 1
st
or 2
nd
quadrant
cos (A B) = cos A cos B + sin A sin B
total 2 values are possible.

15.
A 6
tan
2 P
=
p = 6 cot
A
2

q = 6 cot
B
2

r = 6 cot
C
2

A
B C
6
P
A/2
p + q + r =
A B C
6 cot cot cot
2 2 2
| |
+ +
|
\ .

pqr =
3
A B C
6 cot cot cot
2 2 2
| |
|
\ .
and we know in ABC
A B C A B C
cot cot cot cot cot cot
2 2 2 2 2 2
+ + =

pqr
36
p q r
=
+ +

16. g(f(x)) = x if x = 0 so f(x) = 6
g(f(x)) f(x) = 1 g(f(0)) =
( )
1
f ' 0

( ) ( )
( )
1
g' f x
f ' x
=
( )
( )
1
g' 6 1
f ' 0
= =

17.
( )
( ) ( )
f 9 f 4
f ' c
9 4

4 9
2 3 / 2 2 3 / 2
0 0
t 2t t 2t
2 3 2 3
c c
5
| |

|
\ .
+ =
=
81 16
18 8
2 3
5
| | | |

| |
\ . \ .
=
45 8
119
2 3
5 30
=

18. 2x + 3y z = 9 on solving x = 1
x + 2y z = 5 y = 3
2x + y 4z = 3 z = 2

19. S
n
= C
0
C
1
+ C
1
C
2
+ C
2
C
3
+ .. + C
n 1
C
0

= C
0
C
n 1
+ C
1
C
n

2
+ C
2
C
n 3
+ .. + C
n 1
C
0
=
2n
n 1
C

n 1
n
S 15
S 4
+
=
2n 2
n
2n
n 1
C 15
4
C
+
= on solving n = 2 or 4

20. For ellipse
2
4 5 < 5 <
2
4 < 5
1 < ( 2)
2
< 9
( 2)
2
< 9
3 < ( 2) < 3

12
1 < < 5
R
+
0 < < 5

21. Clearly ABC is equilateral
arABC =
2 3
z wz
4

=
2 3 3
z 48 3
4
=
= |z|
2
= 64
|z| = 8
2 /3
2/3
z
(wz)
w
2

22.
n
n
x
2 1
6
| |
+
|
\ .

r
n n
r 1 r
x
T 2 C
6
+
| |
=
|
\ .

8
n n n n
7 8
7
1 1
2 C 2 C
6
6
| |
=
|
\ .

n n
7 8
6 C C = n = 55

23. Given z
3
+ iwz
2
= (1 + iw)z
1

z
3
z
1
= iw(z
1
z
2
)

3 1
2 1
z z
iw
z z

i / 6 3 1
2 1
z z
e
z z

3 1 2 1
z z z z = with A
6
=

24.
n
n n
r r
r 0
2
C C
r 1
=
| |
+
|
\ + .

= ( )
n n n n
n n n n 0 1 2 n
0 1 2 n
C C C C
C C C .......... C 2 .....
1 2 3 n 1
(
+ + + + +
(
+

=
( )
n
n n n 2 n n
0 1 2 n
1 x C C x C x ..... C x + = + + +
=
( )
( )
1 1
n
2 n
0 2 2 n
0 0
1 x dx C C x C x ..........C x dx + = + +

=
n 1
0 1 n
C C C 2 1
.....
n 1 1 2 n 1
+

= + + +
+ +

n
n
r
r 0
r 3
C
r 1
=
+ | |
|
\ + .
=
( )
n 1
n
2 1 2
2
n 1
+

+
+
=
( )
n n
n 1 2 4.2 2
n 1
+ +
+
=
( )
n 10
n 5 2 2 7.2 2
n 1 10
+
=
+
=
9
14 2 2
10

n = 9

25. tan C =
4
3
cos C =
3
5

2 2 2
a b c
cosC
2ab
+
=

( ) ( )
( )( )
2 2
2
3 n 1 n 2 n
5 2 n 1 n 2
+ + +
=
+ +


13
on solving n = 13
sides a = 14, b = 15, c = 13

1
ar ABC absinC
2
= =
1 4
14 15
2 5
= 84 unit
2

26.
2
3 1 3
1 sin x sinx 1
2 4
| |
+
+ +
|
\ .

2
3 1 3
sin x sinx sinx 0
2 2 4
+ =

3 1 3
sinx sinx sinx 0
2 2 2
| | | |
=
| |
\ . \ .

1 3
sinx sinx 0
2 2
| |
| |
=
| |
\ .\ .

1
sinx
2
= x =
6
and
5
6

3
sinx
2
= x =
3
and
2
3

27. Centroid of the given triangle = (4, 2)
So centroid of the image triangle is itself the image of the original centroid
G
1
(4, 2)
G
2
(4, 2)
G
3
(2, 4)
Area of G
1
, G
2
, G
3
=
4 2 1
1
4 2 1
2
2 4 1
= 20 unit
2

29. Let ( ) ( ) ( )
3 2
f x x bx cx 1. f 0 1 0, f 1 b c 0 = + + + = > = <
so, ( ) 1,0 . So, ( )
( )
1 1 2
2tan cosec tan 2sin sec

+
( )
1 1 1 1
2
1 2sin 1
2tan tan 2 tan tan sin
sin sin
1 sin

( | | | | | |
= + = +
| | | (

\ . \ . \ .

2
2
| |
= =
|
\ .
( ) as sin 0 <

30. By applying Pythagoreans theorem on various right triangles as BD and AC are diameters.
DEB, DAB, AEC and ABC are right triangles
In DEB, DE
2
+ BE
2
= BD
2

In DAB, AD
2
+ AB
2
= BD
2

DE
2
+ BE
2
= AD
2
+ AB
2
(1)
In AEC, AE
2
+ CE
2
= AC
2

In ABC, AB
2
+ BC
2
= AC
2

AE
2
+ CE
2
= AB
2
+ BC
2
(2)
Adding (1) and (2)
AE
2
+ CE
2
+ BE
2
+ DE
2
= AD
2
+ AB
2
+ AB
2
+ BC
2
= 256.

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AITS-CRT(Set-VI)-PCM(S)-JEE(Main)/13

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