Test - 8 (Answers & Hints )

All India Aakash Test Series for Medical-2013

T EST 8

ANSWERS
1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. (3) (2) (3) (2) (1) (4) (4) (1) (3) (3) (4) (4) (2) (3) (2) (3) (4) (1) (3) (2) (3) (4) (3) (2) (1) (2) (3) (4) (3) (3) (1) (1) (2) (2) (3) (4) 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. (1) (3) (1) (4) (4) (3) (3) (1) (1) (4) (2) (3) (1) (2) (1) (4) (1) (3) (4) (2) (3) (3) (3) (2) (1) (2) (4) (1) (4) (4) (1) (3) (2) (3) (2) (4) 73. 74. 75. 76. 77. 78. 79. 80. 81. 82. 83. 84. 85. 86. 87. 88. 89. 90. 91. 92. 93. 94. 95. 96. 97. 98. 99. (3) (4) (3) (1) (3) (4) (1) (2) (3) (4) (1) (1) (3) (4) (3) (2) (4) (4) (4) (4) (2) (3) (3) (3) (4) (4) (4) 109. (3) 110. (4) 111. (1) 112. (4) 113. (3) 114. (4) 115. (2) 116. (4) 117. (4) 118. (4) 119. (2) 120. (1) 121. (4) 122. (3) 123. (4) 124. (2) 125. (3) 126. (3) 127. (4) 128. (3) 129. (2) 130. (3) 131. (3) 132. (4) 133. (4) 134. (2) 135. (4) 136. (2) 137. (4) 138. (4) 139. (1) 140. (1) 141. (3) 142. (3) 143. (4) 144. (3) 145. (1) 146 (1) 147. (2) 148. (1) 149. (3) 150. (2) 151. (4) 152. (3) 153. (4) 154. (3) 155. (2) 156. (4) 157. (1) 158. (3) 159. (2) 160. (2) 161. (2) 162. (2) 163. (3) 164. (2) 165. (3) 166. (2) 167. (2) 168. (2) 169. (1) 170. (2) 171. (1) 172. (1) 173. (2) 174. (1) 175. (4) 176. (2) 177. (2) 178. (4) 179. (2) 180. (1)

100. (3) 101. (1) 102. (3) 103. (2) 104. (3) 105. (2) 106. (4) 107. (4) 108. (2)

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All India Aakash Test Series for Medical-2013

Test - 8 (Answers & Hints)

Hints to Selected Questions

[ PHYSICS]
1. 2. Answer (3) Answer (2)

m= f 12 12 4 = = = = 1.33 3 f u 12 + 3 9

12. Answer (4) 13. Answer (2)

I0 cos2 at = 0 2 I I= 0 2 14. Answer (3)

I=

i.e., image is virtual and erect. 3. Answer (3)

m = m1 m 2 m3 = 3 3 3 = 27

15. Answer (2)

4.

Answer (2)

h 2meV

16. Answer (3)

15 cm

5 cm

h 2mqV

h 2mk

17. Answer (4)

1 1 1 = v u f 1 1 1 = 15 u 20

18. Answer (1) 19. Answer (3) 20. Answer (2)

u = 60 cm away from lens. 5. 6. 7. Answer (1) Answer (4) Answer (4) Because in displacement method,
M1 = I1 v = O u

1 d2

For point source

21. Answer (3) 22. Answer (4) 23. Answer (3) E(eV) =
12400 = 54.38 228

For position L1

M2

I u = 2 = O v

For position L2

E=

13.6Z 2 n2

=2

24. Answer (2) 25. Answer (1)

then M1 M2 = 1 8. 9. Answer (1) Answer (3)

mat = fo and L = fo + fe fe

R A1/3
125 Rq = 27
26. Answer (2) 27. Answer (3) 28. Answer (4)
1/3

6 = 10 fermi

10. Answer (3) 11. Answer (4)

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Test - 8 (Answers & Hints ) 29. Answer (3) 30. Answer (3)

All India Aakash Test Series for Medical-2013 38. Answer (3) 39. Answer (1)

1 T1/ 2 N = N0 2 1 N = N0 2
T /2 T

Voltage gain =

Rf 10 k = = 10 1 k Ri

1 = N0 2

1/2

N0 2

Negative sign shows output is out of phase. 40. Answer (4)

31. Answer (1) Remaining after 1 day = 90% Remaining after 2 day = 81% So decay part = 19% 32. Answer (1) 33. Answer (2)

Y = A.B = A + B = A + B
41. Answer (4) 42. Answer (3) 43. Answer (3) 44. Answer (1)
d = 2Rh
= 2 6400 103 6.4

No current pass through diode

34. Answer (2) 35. Answer (3) 36. Answer (4) 37. Answer (1)

= 2 80 10 8
= 64 2 102

4r = a 2

r =

a 2 = 1.56 4

= 9 km 45. Answer (1)

[ CHEMISTRY]
46. Answer (4) 50. Answer (2)
CH 3CH 2Cl Ether CH3CH2MgCl Boil X
Mg Y

COOH CN
is the strongest acid due to the I and

Ethane

NO2
M effect of both CN and NO2 group. 47. Answer (2) Strongest nucleophile will be the species which will get hydrated to the least extent i.e., SH. 48. Answer (3)
CH 3 CH 3 CH CHO does not give aldol condensation

The given reaction will be fastest with most acidic compound. 51. Answer (1) Tropylium chloride will form tropylium cation when added to water. The tropylium cation is maximum stable among all the carbocations formed with other reactants. 52. Answer (4) For an SN2 reaction strong nucleophile is required so that it can replace the weaker one. Moreover less crowding at the electrophilic centre favours easy attack by the nucleophile.

reaction because the hydrogen is very less acidic. 49. Answer (1) -ketocarboxylic acids simply get decarboxylated on heating.

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All India Aakash Test Series for Medical-2013 53. Answer (1) 60. Answer (2)
O

Test - 8 (Answers & Hints)

NHCH3
is most activated due to +M effect of NH group. 54. Answer (3) 55. Answer (4) Haloform reaction is shown by the compounds having

O 2

OMg+Cl CH3
1

O + CH3MgCl
4 3

O Mg Cl ClMg+O
5 4 3 2 1

O ClMg+O
5 4 3 2 1

(A) H /H2O
+

HO HO
4 2 3 1 5

O
the ( C C CH3 ) linkage. CH3CH2CH(OH)CH3 gets oxidized to CH3CH2COCH3 during first step of haloform reaction. 56. Answer (2)
+

(B)
61. Answer (1) Attack of Br will be most favoured on the site where +M effect of both OH group operates and steric hindrance for the electrophilic attack is least. 62. Answer (2)

C2H5MgBr + CH2 CH2 O C2H5 CH2 CH2 O Mg Br H+/H2O C2H5CH2CH2OH

n-butyl alcohol
+

Cl CH3 CH2 CH CH CH CH3

Chiral centres are marked as * (asterisk). 63. Answer (4)

57. Answer (3)

CH3 CH3 CH CH CH2 H + t-BuO Br

CH3CH2MgX + CH3 C N X

CH3 C = NMgX CH2CH3

+

Sterically hindered base

CH3 CH3 CH CH = CH2 (Y)

58. Answer (3)

NH4++ Mg
64. Answer (1)

+ CH3 C = O OH CH CH
2

H /H2O

CH3 CH3 C CH2 Br

Br

CH3 CH3 C CH2 migration CH3 CH3

H
+

Methyl

CH3 CH Cl + OH Cl

CH3 CH OH OH CH3 CHO

(Ethanal)

CH3
Neopentyl bromide

H2O

CH3 C CH2 CH3 + CH3 CH3 C = CH CH3

59. Answer (3)

The pathway followed is E1.

Cl
Elimination reaction will be fastest in as it

65. Answer (4)

CH3 C C CH3 + Hg

2+

CH3 C = CH CH3 OH Tautomerises CH3 C CH2 CH3 O

(Butanone)

leads to the formation of an aromatic compound i.e., benzene. Moreover the -H atom is also most acidic as it is allylic in conjugation.

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Test - 8 (Answers & Hints ) 66. Answer (4) Ethanal can act as a reducing agent and gets converted to ethanoic acid. Ethanal can act as an oxidizing agent and gets reduced to ethyl alcohol. 67. Answer (1) 68. Answer (3)

All India Aakash Test Series for Medical-2013 74. Answer (4)

O O + (R C) CR

O
KCN

CH3 CHO + HCN

(X)

CH3 CH CN OH
H /H2O
+

(R C) can be generated by (R C Cl) or

O O (R C O C R) O
75. Answer (3)

CH3 CH COOH OH
(Lactic Acid)

69. Answer (2)

O H C OEt + RMgX (Y)

H C OEt R O RCH

EtO

O CH3 C O CH3 C O
76. Answer (1)
H
+

(i) LiAlH4 (ii) H2O

2CH3CH2OH
(Ethyl alcohol)

70. Answer (3) Fehling solution test is not given by aromatic aldehydes and ketones. 71. Answer (2) The conjugate base formed after the removal of at position (b) is most stable as the negative charge developed gets dispersed through resonance on phenyl ring and CHO group. 72. Answer (4) Formic acid gives tests of carboxylic acid and aldehydic group. 73. Answer (3) H+

+ H+ O

O (Resonance stabilised) CH3OH

O H

H CH3

O (A)
+

O CH3

CH3COOC2H5 + C2H5O Na

77. Answer (3)

CH2 C OC2H5 + C2H5OH

O O

CH3CH2COCH3 + NaOH + I2
(Butan-2-one)

CH3 C OC2H5 + CH2 C OC2H5 O C2H5O

CH3CH2COOH
(Propanoic acid)

H+

CH3CH2COONa + CHI3

O
78. Answer (4)
CHO COOH + NaOH CH2OH COONa + COONa COONa

CH3 C CH2 C OC2H5 OC2H5 O CH3 C CH2 COOC2H5

(Acetoacetic ester)

This is an example of Cannizzaros reaction.

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All India Aakash Test Series for Medical-2013 79. Answer (1) Most acidic compound will be the one in which the I effect showing atom (i.e., Cl) is attached most closely to the COOH group. 80. Answer (2)
R R C COOCH 3 does not undergo self Claisen R

Test - 8 (Answers & Hints) 85. Answer (3) Osazone formation takes place as
1

CHO CHOH

C6H5NHNH2 (excess)

HC = NNHC6H5
2

C = NNHC6H5

(CHOH)3
6

(CHOH)3
6

CH2 OH

CH2 OH

(Glucose)
86. Answer (4)

condensation as it does not have any acidic hydrogen. 81. Answer (3)

(Osazone)

CH3CH2Br + CN CH3CH2NH2
(Z)

SN2

CH3CH2CN
(X)

OH

Glucose and fructose are simplest sugars which are known as monosaccharides and hence does not undergo hydrolysis. 87. Answer (3) Nylon is a polyamide. 88. Answer (2)

H2O

Br2/KOH

CH3CH2CONH2
(Y)

(Y) undergoes Hofmann Bromoamide reaction to form (Z). 82. Answer (4)

Nylon-66 is a copolymer of adipic acid and hexamethylenediamine. 89. Answer (4)

R CN
(alkane nitrile)

[H]

RCH2NH2
(P-amine)

Fact 90. Answer (4) Sweetness value of alitame in comparison to cane sugar is 2000 times more and hence is the sweetest among the given sugars.

83. Answer (1) 84. Answer (1) The monomer of starch is glucose.

[ BIOLOGY ]
91. Answer (4) It is pyramid of biomass in aquatic ecosystem. 92. Answer (4) Brandy, whisky and rum produced by distillation, while wine and beer are produced without distillation. 93. Answer (2) 94. Answer (3) Cyclosporin A is used as immunosuppressive agent in organ transplant patients, and is produced by the fungus Trichoderma polysporum. 95. Answer (3) Monascus purpureus (yeast) 96. Answer (3) Flocs 97. Answer (4) Mango trees cannot grow in temperate countries. 98. Answer (4) Control of butterfly caterpillars 99. Answer (4) Rhizobium and Frankia are symbiotic N2 fixer. 100. Answer (3) 101. Answer (1) An overwhelming majority (99%) of animals and nearly all plants cannot maintain a constant internal environment. 102. Answer (3) Physiological 103. Answer (2)
8 = 0.2 40

104. Answer (3) Carrying capacity (K).

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Test - 8 (Answers & Hints ) 105. Answer (2) Commensalism is +, 0 interaction. 106. Answer (4) (+) and () sign for amensalism is incorrect. Point should be () and (0). 107. Answer (4) Gross primary productivity of an ecosystem is the rate of production of organic matter during photosynthesis. Gross primary productivity minus respiration losses (R), is the net primary productivity. Secondary productivity is defined as the rate of formation of new organic matter by consumer.

All India Aakash Test Series for Medical-2013 121. Answer (4) (1), (2) & (3) are concerned with ex-situ conservation. 122. Answer (3) The World Summit on Sustainable Development held in 2002 in Johannesburg. 123. Answer (4) The use of incinerators is crucial to disposal of hospital waste. 124. Answer (2) 0.6C 125. Answer (3) Eutrophication is the natural aging of a lake by nutrient enrichment of its water. Biomagnification refers to increase in concentration of the toxicant at successive trophic levels. 126. Answer (3) A. Water logging B. Soil salinity 127. Answer (4) Reducing deforestation. 128. Answer (3) Decibels is used to measure sound intensity. 129. Answer (2) DDT is non-degradable pollutant. 130. Answer (3) 131. Answer (3) 132. Answer (4) Zea mays is an energy crop. 133. Answer (4) It is O2 requiring process. 134. Answer (2) (1) 1974 (3) 1981 (4) UV-B 135. Answer (4) Both (2) & (3) 136. Answer (2) Outbreeding is crossing of superior males and females of same breed but of different populations or crossing of different breeds. 137. Answer (4) 138. Answer (4) 139. Answer (1)

108. Answer (2) 109. Answer (3) Mesic. 110. Answer (4) Rock 111. Answer (1) 112. Answer (4) 113. Answer (3) Z Regression coefficient. S Species richness, C Y-intercept A Area 114. Answer (4) In-situ conservation is possible by national parks, biosphere reserves, hot spots. 115. Answer (2) More species showed less year to year variation in total biomass. 116. Answer (4) Decrease in plant production. 117. Answer (4) Co-evolution is not a part of The Evil Quarted it should be co-extinctions. 118. Answer (4) Bioprospecting is example of narrowly utilitarian services. 119. Answer (2) Endemic species. 120. Answer (1)

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All India Aakash Test Series for Medical-2013 140. Answer (1) 141. Answer (3) 142. Answer (3) 143. Answer (4) 144. Answer (3) 145. Answer (1) Shahtoosh is produced by Chiru. 146 Answer (1) High temperature of 94C is aimed at disrupting H-bonds of DNA. 147. Answer (2) 148. Answer (1) 149. Answer (3) 150. Answer (2) 151. Answer (4) First restriction endonuclease isolated was Hind II isolated from Haemophilus influenzae. 152. Answer (3) 153. Answer (4) Pvu-I produces sticky ends. 154. Answer (3) Vector must be possessing minimum amount of nonessential DNA. 155. Answer (2) Bam HI is used to cut tet gene of pBR 322. 156. Answer (4) YAC carries 1 million base pairs. 157. Answer (1) Disarmed Ti plasmid of vector is used as a vector to carry desired genes. 166. Answer (2) 167. Answer (2) 168. Answer (2) 169. Answer (1) 170. Answer (2) 171. Answer (1) 172. Answer (1) 173. Answer (2) 174. Answer (1) 175. Answer (4) 176. Answer (2) 177. Answer (2) 178. Answer (4) 179. Answer (2) 180. Answer (1) 158. Answer (3) 159. Answer (2) 160. Answer (2) 161. Answer (2) 162. Answer (2) 163. Answer (3) 164. Answer (2)

Test - 8 (Answers & Hints)

Gene responsible for solubilisation of pectin is the gene that produces polygalactouronase enzyme. 165. Answer (3)

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