CPT-19

XII NEET (IC) (Date: 11-10-2021)

PHYSICS CHEMISTRY BOTANY ZOOLOGY
1. (4) 46. (2) 91. (4) 136. (1)
2. (2) 47. (3) 92. (3) 137. (2)
3. (4) 48. (3) 93. (1) 138. (2)
4. (3) 49. (3) 94. (4) 139. (1)
5. (3) 50. (2) 95. (2) 140. (2)
6. (2) 51. (4) 96. (3) 141. (4)
7. (3) 52. (2) 97. (1) 142. (1)
8. (3) 53. (2) 98. (1) 143. (4)
9. (1) 54. (1) 99. (2) 144. (2)
10. (1) 55. (3) 100. (3) 145. (1)
11. (3) 56. (2) 101. (2) 146. (1)
12. (1) 57. (1) 102. (4) 147. (4)
13. (2) 58. (4) 103. (1) 148. (1)
14. (4) 59. (4) 104. (2) 149. (3)
15. (2) 60. (4) 105. (4) 150. (1)
16. (1) 61. (2) 106. (1) 151. (3)
17. (2) 62. (4) 107. (3) 152. (4)
18. (2) 63. (1) 108. (4) 153. (2)
19. (2) 64. (1) 109. (4) 154. (1)
20. (4) 65. (4) 110. (4) 155. (4)
21. (1) 66. (2) 111. (1) 156. (1)
22. (2) 67. (1) 112 (2) 157. (2)
23. (4) 68. (4) 113 (2) 158. (4)
24. (4) 69. (1) 114 (2) 159. (3)
25. (3) 70. (1) 115 (2) 160. (2)
26. (4) 71. (3) 116 (1) 161. (3)
27. (4) 72. (1) 117 (1) 162. (1)
28. (1) 73. (2) 118 (3) 163. (3)
29. (3) 74. (1) 119 (3) 164. (3)
30. (1) 75. (1) 120 (2) 165. (3)
31. (3) 76. (1) 121 (4) 166. (3)
32. (2) 77. (4) 122 (3) 167. (2)
33. (3) 78. (3) 123 (2) 168. (1)
34. (1) 79. (3) 124 (1) 169. (4)
35. (2) 80. (3) 125 (3) 170. (4)
36. (4) 81. (1) 126 (2) 171. (1)
37. (1) 82. (1) 127 (3) 172. (2)
38. (3) 83. (4) 128 (3) 173. (4)
39. (2) 84. (3) 129 (1) 174. (4)
40. (2) 85. (1) 130 (3) 175. (1)
41. (2) 86. (2) 131 (3) 176. (2)
42. (3) 87. (2) 132 (1) 177. (1)
43. (2) 88. (3) 133 (2) 178. (3)
44. (2) 89. (2) 134 (1) 179. (1)
45. (2) 90. (1) 135 (3) 180. (4)
 HINTS & SOLUTION
PHYSICS

1 1 1
1. = +
Rp R1 R2
1 1 1
= +
6 / 5 2 R2
R2 = 3 
2. Conceptual
3. E − 3r = 10 ....(1)
E + 2r = 15 ....(2)
Solving these two equations, we get
r =1 
4. Conceptual
5. Conceptual
6. Internal resistance of cell using potentiometer is given by
l 
r =  1 − 1 R …(1)
 l2 
when l1 and l2 are balancing lengths for the e.m.f. of cell and voltage drop respectively.
Here l1 = 125 cm, l2 = 100 cm and R = 2
Substituting these values in equation (1), we get
r = 0.5 
1 ( q )( −2q ) 1 ( −2q )( q ) 1 ( q )( q )
7. Usystem = + +
40 a 40 a 40 2a
7q 2
Usystem = −
80a
8. Conceptual
9. Conceptual
10. Conceptual
k1 0 A1 k2 0 A2
11. CR = C1 + C2 = +
d d
A A
2  0 4  0
= 2 + 2 = 2  10 + 4  10 = 30 F
d d 2 2
12. Conceptual
13. Conceptual
14. Workdone = M  B = MB cos 90° = 0° i.e., workdone is zero.
 0 2m
15. The axial field (BA) of a bar magnet for r > > l is BA = .
4 r 3
0 I
16. B=
2r
17. Conceptual
18. Conceptual
19. Conceptual
20. Conceptual
21. Conceptual
22. Conceptual
d d
23. h= thus h = = 6t + 4 = 16V
dt dt
24. Conceptual
25. Conceptual
26. Conceptual
27. Conceptual
28. Conceptual
29. Conceptual
30. Conceptual
31. Conceptual
32. Conceptual
33. Conceptual
34. Conceptual
35. Conceptual
36. Conceptual
37. Conceptual
38. Conceptual
39. Conceptual
40. Conceptual
41. Conceptual
43. Conceptual
44. Conceptual
45. Conceptual

CHEMISTRY
46. 2C2H5I + Ag2O → C2H5OC2H5 + 2AgI
47. CH3OC2H5 +  → CH3 + C2H5OH. In the case of mixed ethers such as methyl ethyl ether,
the halogen attaches to simpler alkyl group. So the products are CH3 and C2H5OH, but not
the C2H5 and CH3OH.
48. Conceptual
49. Conceptual
50. Anisole is obtained by the reaction of phenol with NaOH and CH3I. It is phenyl methyl ether
OH ONa

+ NaOH ⎯
⎯→ + H2O

Sodium phenoxide
ONa OCH3

+ CH3I ⎯
⎯→ + NaI

sodiumphenate anisole
51. Here —OH is replaced by —H. Therefore, it is not a dehydroxylation process
52. Conceptual
53. Conceptual
54. Conceptual
55. Conceptual
56. Conceptual
57. Conceptual
58. Conceptual
59. Conceptual
HBr
OCH3 OH + CH3Br
60.
61. Conceptual
70. The correct statement in case of aliphatic aldehydes and ketons is that aldehydes are formed by
oxidation of primary alcohols and ketones by that of secondary alcohols.
O 7–2 / H +
CH3CH2OH ⎯Cr ⎯2 ⎯ ⎯ ⎯→ CH3CHO
ethanol (1º) acetaldehyde
CH3 Cr2O7–2 / H+ CH3
CHOH ⎯⎯⎯⎯
⎯→ C=O
CH3 CH3
isopropyl alcohol (2º) acetone
71. Methyl Cyanide on reacting with a Grignard’s reagent produces a ketone
+ CH Mgl
CH3 – C  N ⎯⎯ ⎯
3
⎯→ CH3–C = NMgl
|
methyl cyanide CH3
⎯+⎯ ⎯⎯→ CH3 – C = O
CH 3Mgl
– MglNH2 |
CH3
acetone
72. On strongly heating (dry distillation) of anhydrous calcium acetate, acetone is formed.
CH3CO.O  CH3
Ca ⎯⎯→ CO + CaCO3
CH3CO.O CH3
calcium Acetate acetone
73. Alkyl Cyanides on reduction with SnCl2 and HCl give aldimines which on hydrolysis yield
aldehydes. This reaction is known as Stephen’s reaction.
CH3 – C  N ⎯+⎯ ⎯
2H
→ CH3 – CH = NH
ethane nitrile acetaldimine
+ H 2O
⎯⎯⎯→ CH3CHO
– NH3

acetaldehyde
74. Methanal is highly soluble in water due to its ability to form H-bond with water. It’s 40%
solution in water is known as formalin and is used as a preservative for biological specimens.

hydrogen bond

H – C = O .......... H – O
| |
H H
75. The more reactive substance towards nucleophillic reagents is HCHO because in this case the
carbon atom of carbonyl < C + — O– group has greatest + charge, so it is more suspectible to
attack of nucleophillic reagents. In CH3CHO and CH3COCH3, the positive charge on the
carbon atom of > C = O group is decreased due to + I effect of CH3 groups attached to it.
76. The true statement is that carbonyl compounds undergo nucleophillic addition reactions
 R–C=O ⎯
⎯→ R – C+ – O–
| |
R' R'
E+Nu–

R – C+ – OE + Nu–
|
R'
Less stable
(hence not formed)

Nu Nu
| |
– +
R–C–OE 
⎯⎯ R–C–O + E
| |
R' R'
More stable
(hence formed)
77. Carbonyl compounds reacts with NaHSO3 to form a colorless crystalline product.
CH3CHO ⎯+⎯ ⎯⎯→ CH3CH(OH)–SO3Na
NaHSO 3

acetaldehyde acetaldehyde sodium

bisulphite
CH3
CH3 + NaHSO3
|
C = O ⎯⎯ ⎯⎯→ CH3 – C – SO3Na
CH3 |
OH
acetone acetone sodium bisulphite
78. Conceptual
79. Conceptual
80. Conceptual
81. Conceptual
82. Conceptual
83. Conceptual
84. Conceptual
85. Conceptual
86. Conceptual
87. Tb = Kb .m
88. T f = K f .m
89. Unit of rate constant for zero order reaction and unit of rate of the reaction are same (i.e.,)
mol.lit–1. Sec–1.
90. Conceptual