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DURATION ::200
DURATION Minutes
90 Minutes DATE : 26/04/2023 M. MARKS : 720
ANSWER KEY
[1]
SECTION – I (PHYSICS)
1. (1) Q 3
Q = ne n = =
x = 36t equation (i) e 1.6 10−19
2 y = 96t − 9.8t 2 . equation (ii) = 1.875 1019
From equation (i) and (ii)
2 7. (2)
x x v = 0 + 1 t
2 y = 96 − 9.8
36 36 dx
2 =t
48 9.8 x dt
y = x− dx = t dt
36 2 36
48 x t2
tan =
36 Then dx = 4 dt
4
tan = x t linear
3
4
= tan −1 8. (1)
3 v 2 = u 2 + 2aS
4
or = sin −1 (0)2 = (2)2 − 2 a
1
5 4
a = 8 m s−2
2. (1)
Potential energy = −2 (kinetic energy) aT = (10 + 8) = 18 m s −2 (retardation)
= −2E0 F = ma = 75 18 = 1350 N
9. (2)
3. (2)
Maximum load that can be lifted = 5000 kgf
Number of beats per second = n1 − n2
v v
Area of cross-section A = 5 10−4 m2
3= − Maximum force by load F = 5000 9.8 N
1 1.01
Maximum pressure on piston
0.01
v =3 F 5000 9.8
1.01 Pmax = = −
= 9.8 103 104
A 5 10 4
v = 303 m/s
= 9.8 107 Pa
This pressure is transmitted equally in all
4. (1)
directions.
mv
r= So. maximum pressure on smaller piston
qB
= 9.8 107 Pa
Charge of all particles are same but mass of
electron is smallest. 10. (1)
So, the path described by electron will have
F 45,000 106
minimum radius. Strain = = = 35.71 10−4
YA 4.2 1010 15 20
5. (1) 3.57 10−3
Silicon is a intrinsic semi-conductor
N-type semiconductor prepared by adding 11. (3)
impurity like phosphorus. E = 10 V
P-type semiconductor prepared by adding R = 3Ω
impurity like indium.
Depletion layer have immobile ion. I= = 0.5
R+r
6. (4) R + r = = 20
1
Electrons should be removed from the body to
R = 20 − 3 = 17Ω
acquire some positive charge:
[2]
12. (4) 1 rd
The speed of electromagnetic radiation in vacuum FBD for part of rope.
3
1
is given by .
00
m
F −T = a
13. (1) 12
By Benoulli’s theorem m 4 F 14 F
T =F− =
12 5m 15
18. (2)
P = bV 3
PV −3 = b
As PV n = constant
1 1
P + v12 = P1 v22 − gh n = −3
2 2
R
v22 = v12 + 2 gh Molar heat capacity C = Cv +
1− n
v2 = v12 + 2 gh For diatomic gas at normal temperature
5
Cv = R
= 12 + 2 10 0.15 = 2 m/s 2
Now a1v1 = a2v2 5 R 11R
C = R+ =
2 4 4
a2 = 6 10−5 m2
19. (4)
14. (2)
When V = 3V0
Electromagnetic waves are transverse in nature.
P0 P0
P= 3
=
15. (2) 3V 28
1+ 0
K1 60 − T A K 2 T − 20 A V0
=
L L For, PV = nRT at n = 1
[For steady state heat transfer] P0
3V0 = RT
K1 60 − T = K2 T − 20 28
K1 T − 20 T − 20 5 T=
3 P0V0
= =
K2 60 − T 60 − T 3 28 R
3T − 60 = 300 − 5T 3 3 3 P0V0 9
K .E = RT = R = P0V0
2 2 28 R 56
8T = 360
360
T= = 45 C 20. (3)
8
If a positive charged particle is released from rest
then it will move along the electric lines of force
16. (3)
only if the electric field is uniform.
Value of M is very low but in direction of H .
[3]
23. (2) 30. (2)
3h
( n = 3)
LH =
2
3h
LLi = ( n = 3)
2
LH = LLi
Z2
En = −13.6
n2
24. (2)
EH 1
hc =
min = ELi 9
eV
ELi EH
6.6 10−34 3 108
min =
1.6 10−19 50 103
31. (1)
min = 0.2475 10−26 1019 10−3 q
−10
i=
min = 0.2475 10 T
42. (3)
36. (1)
1
For balance condition: Resistance in 30Ω arm Amount of scattering
should be 10Ω . 4
R 30
x = 10 = (Placing in parallel) 43. (3)
R + 30
10 R + 300 = 30 R;20 R = 300 m
T = 2 , time period doesn't depend on
R = 15Ω k
amplitude.
37. (3)
44. (3)
Measured value should be integral multiple of
Transfer of heat from solar collector to heat
least count of the sce. transfer fluid occurs by convection.
46. (1)
This is the concept of electric image.
I
I =
4
39. (1)
As we go from earth to moon, the gravity first
decreases and then increases as we approach
moon. Thus time period of pendulum first
[5]
47. (3) Since, the spring constant is large for hard spring,
The principle of superposition does not state that therefore hard spring has a less periodic time as
the frequencies of the oscillation should be nearly compared to soft spring. Both Assertion and
equal. And for beats to be heard, the condition is Reason are correct and Reason is correct
that the difference in frequencies of the two explanation of Assertion.
oscillations should not be more than 10 times per
sec for a normal human ear to recognise it. Hence, 50. (2)
we cannot hear beats in the case of two tunning When a particle moves with speeds v1 , v2 , v3 . .
forks vibrating at frequencies 256 Hz and 512 Hz, during time intervals t1, t2 , t3 respectively. then
respectively.
total distance travelled v1t1 + v2t2 + v3t3 + and
Assertion is true but Reason is false
total time taken by particle = t1 + t2 + t1 +
48. (1)
Hence, average speed is given by
suspended bridge. In that situation, resonance will
v t + v t + v t +
take place, the amplitude of oscillation of the viv = 1 1 2 2 3 3
t1 + t2 + t3 +
suspended bridge will increase enormously, which
may cause the collapsing of the bridge. To avoid (Let, t1 = t2 = t3 = t )
such situations, the soldiers are advised to break ( v1 + v2 + v3 + ) t
steps on suspended bridge. Both Assertion and Then, vav =
nt
Reason are true and Reason is correet explanation Therefore, average speed is the arithmetic mean of
of Assertion
individual speeds.
49. (1)
The time period of a oscillating spring is given by
m 1
T = 2 T
k k
SECTION – II (CHEMISTRY)
51. (2) 55. (2)
From de-Broglie equation, The average kinetic energy of atom is given as
h 3
KT. It does not depends upon mass of any atom.
Wavelength, = . For same speed of different 2
mv
particles, i.e. electron, proton, neutron and -
56. (3)
l
particle . For reversible process under isothermal
m conditions.
As h is constant, greater the mass of matter waves,
p
lesser is wavelength and vice-versa. In these W = −2303nRT log 1
matter waves, -particle has higher mass. p2
Therefore, has shortest wavelength. 1.01 105
= −2.303 2 8.314 300 log
5.05 106
52. (1)
= 1.95 104 J
MnO−4 + −
+ 8H + 5e ⎯⎯
→ Mn 2+
+ 4H2O
57. (1)
53. (2)
[H + ] = CK a
8
Mole of fraction of O2 = 32 = 0.2 = 0.5 2 10−4 = 1.0 10−4
2 8
+ [H + ] = 10−2 M
2 32
pH = − log[H+ ] = − log (10−2 ) = 2
54. (2)
According to Arrhenius equation, rate of a
58. (4)
reaction increases with decrease in activation
Faraday's law of electrolysis,
energy.
W=Z×I×t
[6]
where, Z = electrochemical equivalent (g/C) 64. (3)
I = current (Amps) Reaction sequence is as follows:
t = time (sec)
63.6
W= 0.5 60 60
2 96500
W = 0.56 g.
59. (2)
Solubility of AgCl in water = K sp = S1
[7]
70. (4) On comparing this equation with equation of
Slag zone is present at the middle part of the straight line.
furnace (where, temperature is about 800- k
y = mx + c and m = −
1000°C). In this region, limestone decomposes to 2.303
from CaO and CO2. k
Slope (X) = −
2.303
71. (1) Intercept (c) = log[A]0 .
− + − +
CH3 CH 2 M gBr + H − O CH3 → C2 H 6
Ethyl magnesium Methanol Ethane 77. (4)
bromide Column-I Column-II
Distinguish By
72. (1)
A Methanol and ethanol r Iodoform test
ZnS has zinc blende structure Zn2+ occupy half of
tetrahedral voids and S2– occupy fcc lattice points B Phenol and s Ferric chloride
and coordination number of Zn2+ and S2– are 4 and cyclohexanol
4 respectively. C n-Butyl alcohol and tert- p Lucas regent
butyl alcohol
73. (3) D Methanol and diethyl q Sodium metal
The technique of protecting a metal from ether
corrosion by connecting it to a second metal that Hence, option (4) is correct.
is most easily oxidised is called cathodic
protection. 78. (3)
Most stable free radical is
74. (2)
Acidic character increases with increase in s-
character of the orbital. The increasing order of s-
character in the following molecules follows the
order:
Hexane < Benzene < Ethyne
sp3 sp2 sp It is due to conjugation.
(25%) (33.3%) (50%)
Thus, the acidic behaviour follows the same order. 79. (1)
As steric hindrance increases, reactivity decreases,
75. (3) i.e., I > III > II > IV, i.e., option (1) is correct.
According to Freundlich adsorption isotherm,
x 80. (3)
p1/n
m Molecules Total number of Magnetic
x electrons behaviour
= kp1/n
m Cl2O7 7×2+7×6 Diamagnetic
Taking log on both sides, = 14 + 42 = 56
x 1 Cl2O 7 × 2 + 6 = 20 Diamagnetic
log = log K + log p
m n ClO2 7 × 1 + 6 × 2 = 19 Paramagnetic
On comparing with equation of straight line, Cl2O5 7 × 2 + 6 × 5 = 44 Diamagnetic
x
y = mx + c, the graph between log
m 81. (4)
and log p comes out to be a straight line with All of the above given statements are correct.
intercept logK.
82. (1)
76. (3) Structure of bisulphate ion is
From first order rate equation.
kt
log[A] = log[A0 ] −
2.303
[8]
a result, weaker O – CH3 bond breaks forming
CH3Br and phenol.
C6 H 5 − O − CH 3 + H + →
Anisole
87. (1)
Number of moles of Cl– ions ionised from one
mole of CrCl3.6H2O.
2.665 Molecular mass of
= = 0.01
2665 CrCl3 .6H2O = 266.5
Moles of AgCl obtained
= Moles of Cl– ionised
2.87
= = 0.02
143.5
0.01 mole of complex CrCl3.6H2O gives
83. (1) 0.02 mole of Cl– on ionisation.
Alkyl fluorides which cannot be prepared by Thus, the formula of the complex is
Finkelstein reaction is best accomplished by [CrCl(H2O)5]Cl2.H2O.
Swarts reaction. In this reaction, the
corresponding fluoride is obtained by the action of 88. (3)
mercurous fluoride or antimony trifluoride on (i) O−2 = 8 + 8 + 1 = 17 Paramagnetic
corresponding chlorides. (ii) CN– = 8 + 7 + 1 = 16 Diamagnetic
The reaction is as follows: (iii) CO = 8 + 6 = 14 Diamagnetic
2CH3Cl + Hg2F2 → 2CH3F + Hg2Cl2 +
(iv) NO = 7 + 8 – 1 = 14 Diamagnetic
84. (3)
In dichromate ion, two CrO3 units have been 89. (1)
joined by O, i.e. each Cr is linked to four O- O O
atoms. The structure of dichromate ion is as R – +
CH3 – MgBr
follows: H O
(Excess)
H3C H
– +
CH3 – MgBr
OH OMgBr
+ H
H H3O
H3C H3C CH3
CH3
85. (3) Propan-2-ol
CuSO4 + 4KCN ⎯⎯
→ K 2[Cu(CN)4 ] + K 2SO4 90. (4)
Excess
The two most common pyrimidines of DNA are
[Cu(CN)4]2– is stable complex having k = 2 ×
cytosine (C) and thymine (T) and the two most
1027. It does not provide sufficient Cu2+ ion to
common purines of DNA are adenine (A) and
give precipitate of CuS.
guanine (G).
93. (1)
Aldehyde having no -hydrogen undergoes
97. (3)
Cannizzaro reaction in presence of base as
follows: → CH3+ + AlCl4−
CH3Cl + AlCl3 ⎯⎯
Electrophile
98. (2)
94. (1)
Cellulose in a biodegradable polymer which 99. (1)
occurs in nature and get decomposed easily. H = Hf (products) − Hf (reactants)
95. (1) H = Hf (HS− ) + Hf (H+ ) − Hf (H2S)
CH3CONH2 (acetamide) and CH3CH3NH2 x1 = x + x 3 – x 2
(ethylamine) are distinguished by reacting with x = (x1 + x2 – x3)
NaOH followed by heating.
The reactions is as follows:
100. (1)
O
||
NaOH/ 2R − Cl + Ag 2O ⎯⎯
→ R − O − R + 2AgCl
CH3 – C – NH 2 ⎯⎯⎯⎯→ NH 3 Ether
NaOH/
CH3CH2 NH2 ⎯⎯⎯⎯→ No reaction
[11]
Male zygote getting X from female is obvious as 130. (2)
ova will always contain one X but gender will be Majority of insect pollinated flowers are
decided by the sperm which must not posses any colourful, fragrant and nectar rich to attract
X to get male zygote. insects for pollination.
[12]
136. (1) 144. (2)
The water when drawn out of the cell through Ecologists have discovered that the value of Z
diffusion into the extracellular (outside cell) fluid lies in the range of 0.1 to 0.2, regardless of the
causes the protoplast to shrink away from the taxonomic group or the region (whether it is the
walls. The cell is said to be plasmolysed. So, plants in Britain, birds in California or molluscs
option 1 is correct as figure A is showing in New York state, the slopes of the regression
plasmolysis. line are amazingly similar). But, the species-area
relationships among very large areas like the
137. (2) entire continents, the slope of the line is much
Alfred Sturtevant used the frequency of steeper
recombination between gene pairs on the same (Z values in the range of 0.6 to 1.2).
chromosome as a measure of the distance
between genes. 145. (2)
Bicarpellary, syncarpous, bilocular, superior
138. (2) ovary are not the features of family Liliaceae.
DNA fingerprinting involves identifying
differences in some specific regions in DNA 146. (3)
sequence called as repetitive DNA. A small Pinus is monoecious whereas Cycas is dioecious.
stretch of DNA is repeated many times in these Gymnosperms have haploid endosperm. So, both
sequences. They do not encode protiens. the statements are correct.
143. (3)
Pollutants from man's activities like effluents
from the homes and industries can radically
accelerate the aging process of lakes. This
phenomenon is referred to as cultural
eutrophication.
[13]
SECTION – IV (ZOOLOGY)
151. (2) 163. (3)
In alveoli, where there is high pO2, low pCO2, Fungal cell wall is made up of chitin.
lesser H+ concentration and lower temperature, the
factors are all favourable for the formation of 164. (1)
oxyhaemoglobin. 12th NCERT Page 208
167. (1)
154. (2)
Neurohypophysis also known as posterior pituitary, 12th NCERT Page 141
stores and releases two hormones called oxytocin
and vasopressin, which are actually synthesised by 168. (2)
the hypothalamus and are transported axonally to Water vascular system is characteristic feature of
neurohypophysis. phylum echinodermata.
[15]