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DURATION ::200
DURATION Minutes
90 Minutes DATE : 26/03/2023 M. MARKS : 720
ANSWER KEY
[1]
SECTION – I (PHYSICS)
1. (4) 10. (1)
Motion of centre of mass is not affected by internal Maximum velocity in SHM = A =
forces so path of the centre of mass will remain Maximum acceleration in SHM = 2A =
unchanged. 2 2
= = T =
T
2. (3)
3 < 2 < 1. The steamlined shaped body experiences
11. (1)
less air resistance.
Adiabatic relation between T and V is
3. (1) T1V1−1 = Constant
T1V1−1 = T2V2−1
Fl
Y= 12. (3)
Al
YAl
F=
l
Y (3 A)l
F= =9F
(l / 3)
N = 30 N
4. (1)
No external force in horizontal direction so the 13. (3)
centre of mass will fall vertically downward. 1 T
v=
2 m
5. (3) To double v, the tension T must be made 4 times
v2 the original tension.
Acceleration towards centre
r
42 16 14. (2)
| a |= = = 8 towards centre For any gas,
2 2
3kBT
i.e. = a = 8( − ˆj ) vrms = =v
m
6. (3) v2
v2 T = Constant
As per founding off rule and significant figure. T
0.00274 becomes 0.0027.
15. (1)
7. (1) When K.E. = P.E.
a1a2 23 a 4
vmax = t= 10 = 12 m/s y= = = 2 2 cm
a1 + a2 2+3 2 2
x−2+1
9. (4) = + c = − x −1 + c
Q = 35 J −2 + 1
W = –15 J
17. (1)
Q = W + U
V = gxhy
35 = –15 + U
LT–1 = [LT–2]x [L]y
U = 50 J
–2x = –1
1 1
x= ,y=
2 2
[2]
18. (1) 25. (4)
L = 0.5 m, b = 0.2 m, h = 0.25 m 2
I = mR 2
Volume = length × breadth × 2.5 × 10–2 m3 5
So, the order of magnitude is 10–2m3. dL
As ext = 0 so, ext = =0
dt
19. (3)
L = constant
v = u + at
7.5 = 2.5 + 0.50 t
26. (2)
t = 10 sec
As V = Al ... (i)
Where A is the area of cross-section of the wire.
20. (2)
( F / A) Fl
Loss in P.E. = Gain in K.E. Young’s modulus, Y = =
(l / l ) Al
Fl Fl 2
l = = [Using (i)]
YA YV
l l2
Hence, the graph between l and l2 is a straight
line.
L 1 L 1 mL2 2
mg = I 2 mg =
2 2 2 2 3 27. (2)
Pressure amplitude, 0 = Akv2 = vA
3g
= .
L
As, v = =
k
21. (3) 22 n 2 a 2
= I Intensity, I =
v
1000 = 200 p0 = va
= 5 rad/s2
p0 a
= 0 + t
=0+5×3 When p0' , then a ' = 3a
= 15 rad/s I' = 9I
I
= 800%
22. (2) I
Use direct formula,
1 m1m2 28. (3)
Loss in K.E., K = (u1 − u2 )2 (1 − e2 )
2 m1 + m2 kT
EH 2 f
=
2
1 m 2m =2
K = (v0 − 0)2 [1 − (1/ 2)2 ] EO2 kT
2 m + 2m f N
2
1
= m v02 29. (2)
4
y1 = a sin ( t − kx ) ,
23. (2)
y2 = a sin t − kx +
I Whole disc
1
= (2M )r 2 = Mr 2 2
2 Phase difference is /2.
A = a12 + a22 + 2a1a2 cos
= a 2 + a 2 + 2a 2 cos = 2a
2
1
I Half disc = Mr 2
2 30. (2)
Time period of simple pendulum
24. (4)
l
Factual T = 2
g
[3]
g 39. (2)
When lift is ascending with , then
3 The two statements are independent
l Wcons = U = Ui − U f
T = 2
g If Ui = Positive, Uf = 0 Wdone > 0
g 4g
g = g + = 40. (4)
3 3
Work done in cyclic process is not zero.
3l 3
T = 2 = T
4g 2 41. (1)
31. (3)
1 mole gas 1 mole gas
7 4
1 = 2 =
5 3
(CP )mix n1 + n2 n n
mix = = 1 + 2
(CV )mix mix − 1 1 − 1 2 − 1
To keep the block at rest
1+1 1 1 15 F cos = mg sin
= + mix =
mix − 1 7
−1
4
−1 11 F = mg tan
5 3
42. (4)
32. (4) Taking mass of -particle = 4 units & applying law
Sound requires material medium to propagate. of conservation of linear momentum
4v + 234v' = 0
33. (3) −4v
v' =
T2 234
Efficiency = 1 −
T1
(273 + 27) 43. (1)
=1−
(273 + 627)
44. (1)
300 1 2 PE of block at top of inclined plane = mgh
=1− =1− =
900 3 3 = 5 × 10 × 4 = 200 J
Total work done = 250 J
34. (1) Work done against friction
v −4 4 = W – PE = 250 – 200
Gravitational field g = − = − = J/kg m
x 10 10 = 50 J
Work done in moving a moss of 2 kg from the
surface to a point 5 m above the surface. 45. (2)
Two spring on left of mass M are in series with
4 J
W = mgh = (2 kg) (5 m) = 4 J effective spring constant,
10 kgm 2k 2k
ks = =k
2 k + 2k
35. (4)
Two spring on right of mass M are in parallel with
From Kepler’s law : Areal velocity = constant so,
effective spring constant,
Area SCD Area SAB
= t1 = 2t2 kp = k + 2k = 3k
t1 t2 Now, ks and kp alongwith the intermediate mass M
are equivalent to a parallel combination.
36. (4) K = ks + kb = k + 3k = 4k
Modulus of elasticity is constant for a given
1 k 1 4k
material. T= =
2 m 2 M
37. (2) 46. (4)
The escape velocity is independent of the angle of
38. (1) projection.
[4]
47. (3) 49. (3)
From the free body diagram, Using the theorem of parallel axes,
F – R = ma 1 3
F = R + ma I = MR 2 + MR 2 = MR 2
a
2 2
F
50. (3)
m dV
At max-speed V(x) = min, so =0
dx
R
x3 – x = 0 x2 = 1 or x = 0
Rate of doing work
1 1 1
= P = Fv = (R + ma) v Minimum PE = − = −
4 2 4
48. (2) 1 9 1 2
So, KEmax = 2 + = = mvmax
4 4 2
3
Vmax =
2
SECTION – II (CHEMISTRY)
51. (4) 54. (2)
A + B C+D Zr3 (PO 4 )4 ] → 3Zr 4+ + 4PO34−
x x O O 3S 4S
x−y x−y y y
Ksp = (4S)4(3S)3
(D) = 2 [A] 1/7
Y = 2[A] K sp
S= .
Y = 2x – 2y 6912
2x
3y = 2x Y=
3 55. (2)
2
2x More stable benzylic carbocation favors SN1.
(Y)2
K= 3
56. (1)
(X − Y) 2
2X
2
X − More stable conjugated alkene is major product.
3
4x 2 57. (3)
4(X 2 ) 9 Option 3 is most stable due to extended
9
x
2
9 (X 2 ) conjugation.
3
4 58. (3)
With GR, tertiary alcohol is formed followed by
52. (2) dehydration, syn hydroxylation and then oxidation
Exothermic reactions are favoured in forward
direction at low temperatures. 59. (3)
Compound must have four “acidic” hydrogens
53. (2) present per molecule
Ka = 6.9 × 10–4
For given reaction, hydrolysis of F– ion 60. (1)
F– + H2O HF + OH–
Kw 10 –14
k eq = =
K a 6.9 10−4
Keq = 1.45 × 10–11
Keq = 1.45 × 10–11
[5]
61. (4) No. of orbitals will be (3l + 1) = (3 × 2 + 1) = 7
orbitals.
Now,
The spin quantum no. are only –1/2 and 1/2 which
means there can be two electrons maximum in each
orbital. Therefore, the maximum no. electrons in d-
subshell will be 7 × 2 = 14.
73. (4)
9th excited state for hydrogen means 10th shell. There
will be six lines in bracket series of this spectrum.
62. (1)
Follow Kolbe’s electrolysis 74. (4)
Due to lanthanide contraction the atomic radii of Zr
63. (2) and Hf, Mo and W are almost similar. In case of Co
Conceptual and Ni, increase in nuclear charge is almost
balanced by shielding effect and as a result, both
64. (1) have nearly the same atomic radii.
75. (3)
Ar has higher IE because it is a noble gas
and Ba has the lowest IE as it is in 6th period and
more metallic.
65. (2)
Option 2 gives aromatic anion
76. (3)
66. (3) Shape of XeF4 is square planar and it has two lone
pairs.
67. (4) Shape of XeF5− is pentagonal planar and shape of
SnCl2 is angular
1-Bromo-2E, 54-Heptadiene
68. (1)
Option 1 has one chiral carbon
77. (2)
69. (1)
Reaction: CH3F has highest dipole moment due to
GI is possible around central C=C here
its electronegativity but also due to its smallest size
70. (2) it is unstable & CH3Cl outlooks CH3F. Therefore,
CH3Cl has the highest dipole moment.
78. (2)
neq KHC2O4 = neq KMnO4
x 100 0.02
or 2 = 5 …….(1)
M 1000
2-Bromo-5-hydroxybenzonitrile
neq KHC2O4 = neq Ca(OH)2
y 100 0.05
71. (3) or 1 = 2 …….(2)
Follow IUPAC Rules M 1000
x 1
=
72. (2) y 2
We know that, for d- subshell the value of l = 2.
Acc. to the question,
[6]
79. (4) 84. (3)
Weight of metal + weight of oxygen = weight of At constant volume U = qv = nCvm T
metal oxide. at constant pressure H = qp = nCp,m T
Weight of metal + y = x
Wmetal = x – y 85. (3)
weight of metal = Eq.wt. of metal W = −nRT
weight of oxygen Eq.wt. of oxygen
x−y E 8(x − y) 86. (1)
= E= NaX is a weak acid-strong base salt.
y 8 y
So, hydrolysis
80. (1) Kh Kw 10−14
h= = = −5
= 10−4
0.2 1 C Ka C 10 0.1
Number of moles = =
44 220 So, % hydrolysis = 0.01
Number of moles = number of molecules 87. (3)
Avogadro's number
Attack of GR followed by intramolecular
Number of molecules = Avogadro’s number Williamson synthesis
88. (2)
× number of moles Wolff-Kishner reduction
No. of molecules = 6.022 × 1023 ×
89. (4)
1 1 Decarboxylation of β-keto carboxylic acid
= 2.73 1021 Molecules in moles
220 220
As 1021 molecules are removed, 90. (1)
No. of molecules left = 2.73 × 1021 – 1021 More electronegative -F stabilise carbanion
= 1.73 × 1021 intermediate to greater extent
1.73 1021
No. of moles = = 2.88 10−3 91. (2)
6.23 10 23
Follow CIP rules
82. (3)
units of 'a' - atm litre2mol−2
unit of 'b' : litre mol−1
93. (4)
83. (2)
Degree of unsaturation
1
For half mole gas, n = H + X − N
2 (C + 1) −
2
a(1/ 2)2 1 1
P + V − b = RT 21 + 0 − 1
= (20 + 1) −
2 2
2
V
2
a b RT 20
P + 2
V− = = 21 − = 21 − 10
4V 2 2 2
= 11
[7]
94. (2) 98. (3)
z
2 9A + 8 BO3 → 3 A3O4 + 4B2O3
mv 2 n z3 9 mole A 8 mole BO3
F= = 4
r n2 n 1 9
mole A 1 mole BO3
8
z
1.125 mole A required
but given 1 mole ‘A’
95. (3)
A is limiting reagent
An element with atomic number 117 is known as
tennessine. It is also called Ununseptium and has 9 mole A → 3 mole A3O4
symbol Uus. Roentgenium has atomic number 111 3 1
1 mole A →
and symbol Uuu/Rg. 9
1
96. (3) = mole A3O4
3
μ experimental = Dipole moment × 10–18
μ theoretical = Bond length×4.8×10–10 esu ×cm
99. (1)
experimental
Percentage ionic character = 100 p1V1 p2 V2 pV1 pV2
theoretical + = +
RT1 RT2 RT1 RT2
1.0 10−18 100
=
1.25 4.8 10−10 10−8 100. (2)
= 16.66% When both P and V are changing
H = U + (PV) = U + (P2V2 – P1P1)
97. (3)
H = 40 + (20 – 3) = 57 L-atm
neq KHC8H4O4 = neq Ba(OH)2
0.204 25 M
Or 1 = 2 M = 0.02
204 1000
[9]
115. (4) 124. (4)
Liliaceae family floral formula: * In monocotyledonous stem, the vascular
bundles are conjoint and closed.
* The monocot stem has a sclerenchymatous
hypodermis.
116. (3) * Phloem parenchyma is absent in most of the
The companion cells are specialised monocotyledons.
parenchymatous cells and nucleated.
125. (4)
117. (3) Nucleolus, Golgi complex and ER reappear
Sclereidsare commonly found in the fruit walls of during telophase.
nuts; pulp of fruits like guava, pear and sapota;
seed coats of legumes and leaves of tea. 126. (2)
23 bivalents are formed in meiocyte of human
118. (4) female.
* The peripheral region of the secondary
xylem, is lighter in colour and is known as the 127. (1)
sapwood. It is involved in the conduction of Increased positive pressure inside xylem of
water and minerals from root to leaf. herbaceous plant is responsible for guttation.
* The heartwood does not conduct water but it * Guttation is result of root pressure and it’s a
gives mechanical support to the stem. positive hydrostatic pressure.
[10]
* Ammonia is first oxidised to nitrite by the 143. (3)
bacteria Nitrosomonas and/or Nitrococcus. Vernalisation.-It prevents precocious reproductive
The nitrite is further oxidised to nitrate with development late in the growing season, and
the help of the bacterium Nitrobacter. These enables the plant to have sufficient time to reach
steps are called nitrification. maturity. Vernalisation refers specially to the
* Reductive amination: In these processes, promotion of flowering by a period of low
ammonia reacts with α-ketoglutaric acid and temperature.
forms glutamic acid. * Vernalisation is seen in biennial plants.
* Biennials are monocarpic plants that
133. (3) normally flower and die in the second season.
Light saturation occurs at 10 per cent of the full * Sugarbeet, cabbages, carrots are some of the
sunlight. common biennials.
[12]
170. (2) 179. (1)
Blood is oxygenated in gills Nucleases - Nucleic acid in basic medium
Fishes have single circulation i.e., the heart pumps Nucleotidases - Nucleotides
out deoxygenated blood which undergoes Nucleosidases – Nucleosides
oxygenation in the gills. The oxygenated blood is
then suppled to the body parts from where 180. (1)
deoxygenated blood is returned to the heart. This Photopigments present in rods is rhodopsin.
can be depicted as follows
181. (1)
S-waves in the ECG is due to depolarisation of
ventricles.
171. (4)
Diarrhoea : Abnormal frequency of 182. (4)
bowel movements and Cerebrum is the largest part of human brain. Optic
increased liquidity of lobes are present in midbrain. Midbrain, pons and
faecal discharge medulla form the brain stem. Brain stem forms the
Indigestion : Caused due to inadequate connection between the brain and spinal cord.
enzyme secretion
Constipation : Faeces are retained within 183. (2)
the colon Some reptiles are viviparous. Reptiles exhibit
Kwashiorkor : Protein-energy internal fertilisation and direct development
malnutrition without a larval stage.
188. (3)
177. (3)
Hormones like LH, ACTH, TSH, oxytocin, ADH
In ctenophores, body bears eight external rows of
and PRL are released from pituitary gland, whereas
ciliated comb plates, which help in locomotion.
GHIH is released from hypothalamus.
178. (1)
Basilar membrane and tectorial membrane are 189. (2)
structural constituents of organ of Corti. Incus is The hepatic portal vein carries blood from intestine
present in middle ear. to the liver before it is delivered to the systemic
circulation.
[13]
190. (3) 195. (2)
The myoglobin structure gives a 3-D view of There is 1000 mmol in 1 mole.
protein. The blood glucose concentration in a normal
Myoglobin (protein found in muscle cell) have healthy human is 4.2 mmol/l – 6.1 mmol/l.
tertiary structure of protein and haemoglobin have
quaternary structure of protein. It has four helical 196. (2)
polypeptide chains, 2-chains and 2-chains. The capability of concentrating the urine is largely
related to the length of the loop of Henle.
191. (1)
Hooks and suckers are peculiar features of parasitic 197. (4)
flatworms. In tapeworms, alimentary canal is Respiratory rhythm centre is situated in the medulla
absent and they absorb nutrients directly from hosts oblongata region of the brain.
through their body surface.
198. (2)
192. (4) The hindbrain consists of pons, cerebellum and
Total volume of air present in the lungs after medulla oblongata.
forceful inspiration.
TLC = TV + IRV + ERV + RV 199. (1)
TLC = IC + ERV + RV Myelin sheath, if present, is present on the axons.
TLC = EC + IRV + RV The gaps between two adjacent myelin sheaths are
called nodes of ranvier.
193. (3)
Veins carry blood from different organs and deliver 200. (4)
it to the heart. Columnar epithelium is composed of a single layer of
tall and slender cells. The function of cilia is to move
194. (3) particles or mucus in a specific direction over the
(1) Pleurobrachia – Paired tentacles epithelium.
(2) Fasciola – Oral sucker
(3) Spongilla – Collar cells
(4) Saccoglossus – Collar
[14]