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Chemistry

1. (3) 51. (3)

2. (3) 52. (2)

3. (2) 53. (2)

4. (4) 54. (3)

5. (2) 55. (3)

6. (2) 56. (2)

7. (1) 57. (4)

8. (4) 58. (2)

9. (1) 59. (3)

10. (1) 60. (3)

11. (2) 61. (3)

12. (4) 62. (1)

13. (3) 63. (2)

14. (3) 64. (3)

15. (3) 65. (3)

16. (3) 66. (4)

17. (1) 67. (2)

18. (2) 68. (1)

19. (2) 69. (1)

20. (1) 70. (1)

21. (3) 71. (2)

22. (1) 72. (1)

23. (2) 73. (4)

24. (2) 74. (4)

25. (3) 75. (3)

26. (3) 76. (1)

27. (1) 77. (3)

28. (2) 78. (3)

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29. (3) 79. (1)

30. (4) 80. (1)

31. (2) 81. (2)

32. (4) 82. (3)

33. (4) 83. (1)

34. (1) 84. (1)

35. (3) 85. (1)

36. (1) 86. (3)

37. (2) 87. (1)

38. (3) 88. (2)

39. (4) 89. (2)

40. (4) 90. (1)

41. (4) 91. (4)

42. (3) 92. (3)

43. (2) 93. (4)

44. (3) 94. (4)

45. (3) 95. (3)

46. (1) 96. (3)

47. (4) 97. (1)

48. (4) 98. (1)

49. (4) 99. (4)

50. (2) 100. (2)

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Hints and Solutions

Chemistry

(1) Answer : (3)

Solution:

Aldehyde and ketone can be differentiated by Tollens' reagent

(2) Answer : (3)

Solution:
NH corresponds to zero group.
+

(3) Answer : (2)

Solution:
Group reagent for precipitating group-V (Ba2+, Sr2+, Ca2+) is (NH4)2CO3 in presence of NH4OH.

(4) Answer : (4)

Solution:
Iron is in +2 oxidation state in Na2[Fe(CN)5NO] and also in Na4[Fe(CN)5NOS]

(5) Answer : (2)

Solution:
CuSO4 + B2 O3 → Cu ( BO2 )2 + SO3

(6) Answer : (2)

Solution:
( CH3 COO) Pb + H2 S → PbS + CH3 COOH
2
(Black)

(7) Answer : (1)

Solution:
K2 Cr2 O7 + H2 SO4 + SO2 → K2 SO4 + Cr2 ( SO4 ) + H2 O
3
(green)

(8) Answer : (4)

Solution:
2° and 3° amines will not give positive test with CHCl3/KOH.

(9) Answer : (1)

Solution:

(10) Answer : (1)

Solution:
Pentan-2-one gives positive iodoform test
Iodoform test is given by alkan-2-ols

or by methyl ketones

(11) Answer : (2)

Solution:
In redox reaction :

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+ – – 2+
8H + MnO4 + 5e → Mn + 4H2 O

Change in oxidation state of MnO4

–

= (+7) – (+2) = +5
∴ nfactor = 5
Number of equivalents
= nM V

1000
=
5×0.04×250

1000
= 0.05

(12) Answer : (4)

Solution:
2HNO2 + 2KI + 2CH3COOH → 2CH3COOK + 2H2O + 2NO + I2
I2 + Starch → Blue complex

(13) Answer : (3)

Solution:
Methyl orange, Methyl Red, Bromophenol blue are used for strong acid-weak base titrations.

(14) Answer : (3)

Solution:
Brown ring test is done for NO3
–
ions. Acidified sodium carbonate extract of bromide salt with AgNO3 gives pale yellow
precipitate.

(15) Answer : (3)

Solution:
Brown ring complex = [Fe(H2O)5(NO)]2+
Oxidation state of Fe = +1 due to charge transfer from NO to Fe.

(16) Answer : (3)

Solution:
– – 2–
MnO4 + e → MnO4

(17) Answer : (1)

Solution:
The point just after the equivalence point where colour change occurs in end point.

(18) Answer : (2)

Solution:
+ –
HPh ⇌ H + Ph
(Colourless) (Pink)

Phenolphthalein does not dissociate in acidic medium and remains in unionised form which is colourless.

(19) Answer : (2)

Solution:
(n × nf)oxidising agent = (n × nf)reducing agent
[Hence 'x' is moles of reducing agent i.e. FeSO4]
2.5 × 5 = x × 1
x = 12.5

(20) Answer : (1)

Solution:
Methyl orange is used for the titration of strong acid-strong base and strong acid-weak base.

(21) Answer : (3)

Solution:
The yellow precipitate formed is insoluble in ammonium hydroxide

(22) Answer : (1)

Solution:
Formic acid has aldehydic –H along with – COOH group, hence. It can give Tollen's test.

(23) Answer : (2)

Solution:
Schiff test is given by aldehyde only.

(24) Answer : (2)

Solution:
As KMnO4 is strong oxidising agent and oxalic acid being strong reducing agent undergo redox titration.

(25) Answer : (3)

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Solution:
KMnO4 being in +7 oxidation state has the strong tendency to get reduced. Hence, acts as strong oxidising agent.
Also, KMnO4 acts as self indicator; no external indicator is required.

(26) Answer : (3)

Solution:
Saturated and unsaturated hydrocarbons can be distinguished by Bayer's reagent.
Alkene decolorizes Baeyer's reagent
• Phenol forms orange dye while aniline forms yellows dye in azo dye test.

• Forms CHI3 in iodoform test

• Aniline gives positive carbylamine test.

(27) Answer : (1)

Solution:
• Benzene does not react with bromine water.
• Phenol reacts with bromine by electrophilic substitution reaction and decolorises it.

(28) Answer : (2)

Solution:
– + – 2+
MnO + 8H + 5e → Mn + 4H2 O
4

(29) Answer : (3)

Solution:
Solution of known concentration is known as titrant and substance being titrated is titrand.

(30) Answer : (4)

Solution:
• Ethene and ethyne both decolorizes Br2 water.
• Benedict reagent is more stable than Fehling's reagent because benedict solution is a single solution.

(31) Answer : (2)

Solution:

Solution of and CH3COOH acidic and converts blue litmus red.

(32) Answer : (4)

Solution:

(33) Answer : (4)

Solution:
Barium chromate is a yellow coloured precipitate.

(34) Answer : (1)

Solution:

(35) Answer : (3)

Solution:

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(36) Answer : (1)

Solution:

NH
+

4
ion belongs to zero group

(37) Answer : (2)

Solution:
Fe(OH)3 + 3HCl → FeCl3 + 3H2O

(38) Answer : (3)

Solution:
Pb2+ is present in both group I and II.

(39) Answer : (4)

Solution:
Group Radical Precipitates
I Pb2+ Chloride

III Al3+ Hydroxides

IV Zn2+ Sulphide

V Ca2+ Carbonate

(40) Answer : (4)

Solution:
2CuSO4 + K4[Fe(CN)6] → Cu2 [Fe (CN) ] + 2K2 SO4
6

Hexacyanoferrate(II)

(Chocolatebrownppt)

(41) Answer : (4)

Solution:
Metal ion Colour during flame test
Barium Apple green
Calcium Brick red

(42) Answer : (3)

Solution:
AgCl → Completely soluble
AgBr → Partially soluble
AgI → Insoluble

(43) Answer : (2)

Solution:
Fe4[Fe(CN)6]3 i.e. [Fe(CN)6]4–
Prussian blue
So; x – 6 = –4
x=6–4
Oxidation state of Fe in coordination sphere is = +2
(44) Answer : (3)
Solution:

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S2– + [Fe(CN)5NO]2– → [Fe(CN)5(NOS)]4–

Violet colour

(45) Answer : (3)

Solution:
Crystal of Mohr's salt is monoclinic.

(46) Answer : (1)

Solution:
Ag+ + Cl– → AgCl
(White ppt)
AgCl + 2NH3 → [Ag(NH3)2]Cl

(47) Answer : (4)

Solution:
Aldehyde and ketone reacts with 2,4-DNP to give yellow, orange or orange red precipitate.
(48) Answer : (4)
Solution:
On prolonged heating, Fe2+ gets oxidised to Fe3+.
Hence prolonged heating is avoided for Mohr's salt preparation.
(49) Answer : (4)
Solution:
Potash Alum flocculates negatively charged particle of impurities.
∴ Potash Alum is used in purification of water

(50) Answer : (2)

Solution:

(51) Answer : (3)

Solution:
Picric acid is stronger acid due to low pKa.

(52) Answer : (2)

Solution:

(53) Answer : (2)

Solution:
Aliphatic as well as aromatic primary amines give carbylamine test.
(54) Answer : (3)
Solution:

Ethanol gives positive iodoform test because of presence of group.

(55) Answer : (3)

Solution:

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(56) Answer : (2)

Solution:
Mohr's salt is FeSO4(NH4)2. 6H2O hence its aqueous solution will give test of Fe2+, NH
+

4
and 2–
SO
4

(57) Answer : (4)

Solution:
Potash Alum = K2SO4. Al2(SO4)3. 24H2O
Mohr's salt = FeSO4. (NH4)2SO4. 6H2O
Ratio of water of crystallisation = 4 : 1
(58) Answer : (2)
Solution:
In neutral medium, potash alum crystallises in octahedral structure.
(59) Answer : (3)
Solution:
Acetylation of aniline is carried out in the presence of strong base than amine like pyridine, which removes HCl so
formed and shifts the equilibrium towards forward direction.
(60) Answer : (3)
Solution:
Potash alum cannot be used as a reducing agent.
(61) Answer : (3)
Solution:
Oxidation by haloform reaction does not affect a carbon-carbon double bond.
(62) Answer : (1)
Solution:
Benzene diazonium chloride reacts with aniline in which aniline molecule at its para positions is coupled with the
diazonium salt to form p-amino azobenzene.

(63) Answer : (2)

Solution:

(64) Answer : (3)

Solution:
Few drops of dil. H2SO4 is added to the solution of ferrous sulphate and ammonium sulphate with minimum amount of
distilled water and concentrated by heating till the concentration point is reached.

(65) Answer : (3)

Solution:
Aldehydes and ketones having atleast one methyl group linked to the carbonyl carbon atom are oxidised by sodium
hypohalite to sodium salts of corresponding carboxylic acids having one carbon atom less than that of carbonyl

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compounds.

(66) Answer : (4)

Solution:

(67) Answer : (2)

Solution:
Precipitate = PbSO4 (White precipitate)

(68) Answer : (1)

Solution:
The lone pair of electrons on nitrogen of acetanilide interact with oxygen atom due to resonance

∴ The lone pair of electrons on nitrogen is less available for donation to benzene ring by resonance.
(69) Answer : (1)
Solution:

Confirmatory test for nitrite ions (NO –

2
)

Test solution should be very dilute.

(70) Answer : (1)

Solution:
Na2CO3 + H2SO4 → Na2SO4 + H2O + CO2(g)

(71) Answer : (2)

Solution:
2– +
CrO4 + 2H + 2H2 O2 → CrO5 + 3H2 O
(Butterfly structure)

Confirmatory test for Cl– ions

(72) Answer : (1)

Solution:

(73) Answer : (4)

Solution:

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PbS – Black ppt

PbCrO4 – Yellow ppt
AgBr – Pale yellow ppt
PbSO4 – White ppt

(74) Answer : (4)

Solution:
MnO2 + 2NaCl + 2H2SO4 → Na2SO4 + MnSO4 + 2H2O + Cl2
Cl2 = Greenish yellow gas.

(75) Answer : (3)

Solution:
Heat of neutralisation for (i) = 2x
Heat of neutralisation for (ii) = y
y = 4x
y
x =
4

(76) Answer : (1)

Solution:
Colloidal solution is a heterogeneous mixture and lyophillic sol are more stable than lyophobic sol.

(77) Answer : (3)

Solution:
Heat of neutralisation ∝ acidity of acid
1
∝
pKa

Acidity order → D > A > B > C

pKa order → C > B > A > D

(78) Answer : (3)

(79) Answer : (1)

Solution:
Eosin is negatively charged sol.
Methylene blue is positively charged sol.
Micelles are associated colloids.
(80) Answer : (1)
Solution:
Mole of H2SO4 = 0.4×1000

1000
= 0.4

Mole of H+ = 0.8 mol

Mole of NaOH =
0.4×1000

1000
= 0.4

0.4 mole of OH– neutralised by 0.4 mole of H+

Heat evolved = 57.1 × 0.4 = 22.84 kJ
(81) Answer : (2)
Solution:

(82) Answer : (3)

Solution:
Sol are stabilised by charge and solvation of colloidal particles.
(83) Answer : (1)
Solution:

(84) Answer : (1)

Solution:

–66.4 = –78.1 + x

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x = –66.4 + 78.1
x = +11.7 kJ
(85) Answer : (1)
Solution:
Blue colour appears on addition of starch.
(86) Answer : (3)
Solution:
With excess of KI, sol formed is AgI/I– (Negatively charged).

(87) Answer : (1)

Solution:
Na2 CO3 + H2 S O4 → Na2 SO4 + H2 O + CO2

(88) Answer : (2)

Solution:
ΔHionization = –51.4 – (– 57.1) = 5.7 kJ/mol

(89) Answer : (2)

Solution:

(A) gives iodoform test whereas (B) does not.

(90) Answer : (1)
Solution:
Na2 S + Na2 [Fe (CN) NO] → Na4 [Fe (CN) NOS]
5 5
Sodiumnitroprusside
Complex of purplecolour

(91) Answer : (4)

Solution:
Group-III reagent is NH4OH + NH4Cl

(92) Answer : (3)

Solution:
Number of milli equivalent of KMnO4 = Number of milli equivalent of H2C2O4
20 × 0.1 × 5 = 2 × M × V
M×V=5
M = 0.2, V = 25 ml

(93) Answer : (4)

Solution:
Cu+ does not belong to group-I.
(94) Answer : (4)
Solution:
Cr2 O
2–
7
(n = 1) (Mohr's salt)
+ 6 Fe
2+

+ 14H → 2Cr + 6Fe3+ + 7H2O

+ 3+

Equivalent of Fe2+ = moles of Mohr's salt

= equivalent of K2Cr2O7
= 500 × 10–3 × 6 × 1 = 3.0
Hence, mole per cent of Mohr's salt
3
= × 100 = 75
4

(95) Answer : (3)

Solution:
All are AB type of salt so, salt with maximum Ksp is most soluble.

(96) Answer : (3)

Solution:
Metal ion Colour of the flame

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Cu2+ Green with blue centre

Sr2+ Crimson red

Ba2+ Apple green

Ca2+ Brick red

(97) Answer : (1)

Solution:
I2 + Na2S2O3 → 2NaI + Na2S4O6

(98) Answer : (1)

Solution:
+ –
H + OH → H2 O Δr H =– 57. 1 kJ / mol

Enthalpy of ionisation = –49.86 + 57.1

= 7.24 kJ/mol

(99) Answer : (4)

Solution:
Chromyl chloride test is used to detect chloride ions.
Chromyl chloride test fails in case of chlorides of Hg, Pb, Ag etc. due to the formation of precipitates.
(100)Answer : (2)
Solution:
– 2+ + 3+
NO + 3 Fe + 4H → NO + 3 Fe + 2H2 O
3

2+ 2+
[Fe ( H2 O) ] + NO → [Fe ( H2 O) (NO)] + H2 O
6 5
Brown

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