Prayas JEE AIR (2024)

WEEKLY TEST - 07

DURATION ::180
DURATION Minutes
90 Minutes DATE : 17/09/2023 M. MARKS : 300

ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (1) 61. (3)
31. (3)
2. (3) 62. (1)
32. (4)
3. (1) 63. (1)
33. (3)
4. (1) 64. (3)
34. (1)
5. (1) 65. (1)
35. (4)
6. (2) 66. (1)
36. (4)
7. (1) 67. (2)
37. (2)
8. (3) 68. (2)
38. (4)
9. (1) 69. (1)
39 (3)
10. (3) 70. (3)
40. (2)
11. (4) 71. (3)
41. (4)
12. (1) 72. (1)
42. (2)
13. (1) 73. (2)
43. (1)
14. (1) 74. (2)
44. (3)
15. (2) 75. (4)
45. (3)
16. (1) 76. (3)
46. (4)
17. (1) 77. (2)
47. (3)
18. (1) 78. (4)
48. (3)
19. (3) 79. (3)
49. (3)
20. (1) 80. (1)
50. (1)
21. (2) 81. (29)
51. (6)
22. (16) 82. (2)
52. (2)
23. (5) 83. (3)
53. (14)
24. (5) 84. (12)
54. (22)
25. (3) 85. (2)
55. (6)
26. (3) 86. (3)
56. (5)
27. (6) 87. (8)
57. (7)
28. (4) 88. (2)
58. (56)
29. (10) 89. (4)
59. (1)
30. (50) 90. (7)
60. (5)

[1]
 SECTION-I (PHYSICS)
1. (1) 6. (2)
Use dimensional analysis 2g
x= ; from conservation of mechanical energy ;
K
2. (3) 1 1
From the given graph equation for velocity v = kx mgx = Kx2 + mv2 , here m = 5kg
2 2
on differentiation
dv
= kv … (i) 7. (1)
dt
1 1
dv w = KE = mv2 − mu 2
= k (kx) = k 2 x; 2 2
dt
a = k2x and v = – kx + v0
8. (3)
dv
on differentiation = −kv = −kv = −k (−kx + v0 ) For m1, F = ma = m1g ;
dt
For m2, T – m2g = m2a1
a = k2x – kv0 … (ii)
So, according to the eq. (ii) the shape of a-x graph
9. (1)
is as below.
PV PV PV P1V 2PV
= 1 1+ 2 2 ; =
T T1 T2 T T

10. (3)
PV PV P Al P Al
1 1
= 2 2 1 1= 2 2
T1 T2 T1 T2
Pl Pl
11
= 2 2 area remains constant
T1 T2
3. (1)
Whenever temperature of the glass tube changes
piston moves through a distance x. So that
pressure remains constant
Before heating

Relative velocity along x-axis is (vb cos 37° – 10) After change of temperature
Distance travelled by bullet along x-axis is
(vb cos37 −10)t = 2 …. (i)
Distance travelled by bullet along y-axis is
(vb sin37)t = 3 …. (ii)
l1 l2 45 − x 45 + x
Solving equation (1) and (2) we get t = 0.20s = ; =
T1 T2 273 546

4. (1)  x = 15 cm
For free expansion, dU = 0  dT = 0  T is Compare left hand side volumes in both cases
constant. P11l11 Pl
1
= 11
T1 T1
5. (1)
Divide the ring into infinitely small lengths of
mass dm. Even though mass distribution is non-
uniform, each mass 1 dm is at same distance R
from origin.
11. (4)
 MI of ring about z-axis is
The temperature of the gas is constant, therefore
= dm1R2 + dm2 R2 + ...... dmn R2 = MR2 PV = constant
dV dP
P +V =0
dt dt
[2]
 dP 18. (1)
V = −rP Oscillate together i.e. meff = m1 + m2
dt
dP 1 t keff = k1 + k2
  PP0 =−  0 rdt
P V0 meff
P −rt  T = 2
 ln = keff
P0 V0
 P = P0e−rt/V0 19. (3)
md
Shift =
12. (1) M +m
 mx (1 + 2 + 3 +. + n ) l
2 2 2 2

xcm = =
m (1 + 2 + 3 +.. + n ) 20. (1)
For adiabatic process Q = 0
Therefore U = – W  nCVdt = – PdV
13. (1)
nRT
We know that time period is directly proportional n(a + bT )dT = − dV
to the square root of its length. Two different V
pendulums can be in phase at the earliest with a a  dV
 T + b  dT = − V
difference in the number of oscillations being a  
maximum of one. NTShorter = (N – 1)TLonger Integrating both sides we get TaebTVR = constant
N 1 = ( N − 1) 16 ; N = ( N − 1)4 = 4 N − 4
4 21. (2)
3N = 4; N = As for ideal gas CP − CV = R and  = ( CP / CV ) ,
3
i.e., when 4 oscillations of the shorter and three of
the longer pendulum are over they will be in R R
 −1 = or Cv =
phase. So, choice (1) is correct and rest of the CV (  − 1)
choices are wrong.
R 3 R 5R
( CV )1 = = R ( CV ) 2 = =
14. (1) ( 5 / 3) − 1 2 ( 7 / 5) − 1 2
On sprinkling kerosene on water surface tension R 13
and ( CV )mix = = R
of water decreased hence insects may sink into (19 / 13) − 1 6
water sprinkled.
Now from the conservation of energy, i.e.,
ΔU = ΔU1 + ΔU2 ,
15. (2)
We get,
Q = msΔ, m = r 2l
Δl Δl  r 2 s 
(1 + 2 )( Cv )mix ΔT = 1 ( Cv )1 + 2 ( Cv )2  ΔT
Δ =  1 = 2  22  2  1
l Δl2 1 r1 s1 2 1 ( Cv )1 + 2 ( Cv )2
( Cv )mix =
1 + 2
16. (1) 3 5
1 R + 2  R ( 3 + 5 ) R
Expression Based 13
R= 2 2 = 2

6 1 + 2 2 (1 + 2 )
17. (1)
or13 +132 = 9 +152 , i.e., 2 = 2 g mole
1 1− y
At t = 0, y = , or x = = x1
1+ x 2
y 22. (16)
At t = 2 s, y =
1
=
1 MR2  M
I11 = I 22 ; I1 = , I 2 =  M +  R2
2 + x − 2 x 1 + ( x − 1)2
2
2  3
1− y 1− y
or, ( x − 1)2 = or, x = 1 + = x2 23. (5)
y y
AC a cos 
 Speed of the wave t= =
v v
Δx x2 − x1 1
v= = = = 0.5 m / s 2
Δt t2 − t1 2 − 0 32 
v cos  = v1 , t = 5 = 16 s
4 5 5
[3]
24. (5) 28. (4)
Tension in string AB is TAB = 6.4 kg = 64 N Thus Fl
Y=
speed of transverse wave in string AB is Al
TAB 64 l = lT
vAB = = = 6400 = 80 m / s
 AB 10 10−3 F = AY  T = 104 N
Tension in string CD is T = 3.2 kg = 32 N Thus
speed of transverse waves in string CD is 29. (10)
TCD 32
vCD = =
DC 80 10−3
vAB 80
= 400 = 20 m / s  = = 4:1
vCD 20
Applying Bernoulli's theorem at points A and B
25. (3)
1 1
W = 4R2T P0 + vA2 + gh = P0 + vB2
2 2
22
[n1/3 − 1] = 4   (10−2 )2  35 10−3 (100 − 1) 2gh 2 10 1.8
7  vB = = = 10 m / s
r 
2
1 − (0.8)2
= 4.35 10−3 J 1−  2 
 r1 
26. (3)
3 1 1 30. (50)
= +
y  3k T M ( g + a)
v= =
 
27. (6) 4(10 + 2)
Use this expression = = 50ms –1.
19.2 10−3
MgL
x =
2YA
SECTION-II (CHEMISTRY)
31. (3) 35. (4)
SIR effect Stability order

32. (4)
For tautomerism, molecule must have acidic
hydrogen with resonance
36. (4)
More E.W.G are adjacent to -ive charge

37. (2)
cannot show Tautomerism

33. (3)
38. (4)
In Lassaigne’s test of an organic compound, we do not
get tests for CN– and X– ions, if the compound has
nitrogen and halogen but not carbon.
DBE = 2 so not an structural isomer 39 (3)
CH3CHOOH
34. (1) pKa = 4.75
(II) have more number of α-H(10) than III order
is I > II > III

[4]
40. (2) 50. (1)
Both rings become aromatic. ERG decreases acidic strength. Inductive effect is
distance dependent. That’s why III is most acidic.
41. (4)
51. (6)
(i), (iii), (iv), (vii), (viii), (ix)

pKa = 9.95 pKa = 6.62 52. (2)

42. (2)
Electron withdrawing group increases acidic
strength and electron releasing group decreases
acidic strength. 53. (14)
DBE = 14
43. (1)
54. (22)
There are 22 sp3 hybridized carbons present in the
given molecule.

55. (6)
Ethyl-2-bromo-3-methylpentanoate

44. (3)
Stability order of negative charge

56. (5)
45. (3)

Except

More stable due to resonance

all are more electron dense that chlorobenzene.
46. (4)
All acids which are stronger than carbonic acid 57. (7)
will produces effervesence with sodium Except ‘f’ all are aromatic. Molecules with planar
bicarbonate. geometry and having (4n + 2)πe– are aromatic in
nature.
47. (3)
58. (56)
1.4 10
%N = = 56
0.25
Stability of conjugate base

59. (1)
48. (3)
HC ≡ CH NH3
pKa = 25 pKa = 35

49. (3) possible mono substituted derivative.

60. (5)
Naphthalene, Pyridine, Anilines, Thiophene and
Pyrrole are aromatic species.

[5]
 SECTION-III (MATHEMATICS)
61. (3)    
2  −   = 2 4 =  =
 1+ 3   8+4 3   4  2 8
tan −1  −1
 + sec  
 6+3 3  
 3+ 3    x = tan  x = 2 − 1 0.414
8
 1  −1  2  
= tan −1   + sec  =
 3  3 3 65. (1)
Let S = (tan–1 x)3 + (cot–1 x)3
62. (1) = (tan–1x + cot–1x)3 – 3tan–1 x. cot–1 x (tan–1 x + cot–1 x)
a2 – a1 = a3 – a2 = …. = a2022 – a2021 =1. 3 3 −1   
= − tan x  − tan −1 x 
 a −a   a −a  a −a  8 2 2 
 tan −1  2 1  + tan −1  3 2  +.. + tan −1  2022 2021 
 1 + a1 2
a  1 + a2 3
a  1 + a2021 2022 
a 2
3    3
=  tan −1 x −  +
2 4  32
 ( )
=  tan −1 a2 − tan −1 a1  +  tan −1 a3 − tan −1 a2  +.
   3 7
  S  3
+  tan −1 a2022 − tan −1 a2021  32 8
 
3 7
–1
= tan a2022 – tan a1–1 =  K 3  3
32 8

= tan −1 (2022) − tan −11 = tan −1 2022 − 1
K
7
4 32 8
 
=  − cot −1 (2022) 
 2  66. (1)
   cos–1x – 2sin–1 x – cos–1 2x
=  − cot −1 (2022)  −  
2  4 cos−1 x − 2  − cos−1 x  = cos−1 2 x
  2 
= − cot −1 (2022) (option 1) cos–1 x – π + 2cos–1 x = cos–1 2x
4
3 cos–1x = π + cos–1 2x …..(1)
cos(3 cos–1x) = cos (π + cos–1 2x)
63. (1) 4x3 – 3x = –2x
4 3
cos−1 = tan −1 4x3 = x
5 4 1
 x = 0, 
 77 3  2
 − 
 77 3
sin −1 = tan −1 − tan −1 = tan −1  36 4  All satisfy the original equation
17 36 4  1 + 77  3  1 1
 36 4  sum = − + 0 + = 0
2 2
 8 8
sin −1 = tan −1 = sin −1
17 15 17 67. (2)
 8 
 =  =8  4 
17 17 cosec  2cot −1 (5) + cos−1   
  5 
 sin–1 (sin 8) + cos–1 (cos 8)
 1  4 
= 3π – 8 + 8 – 2π cosec  2tan −1   + cos−1   
=π  5  5 
  1  
64. (3)   2   
 −1   5  −1  4  
= cosec  tan + cos   
0<x<1  2
5
  1 
 1 −    
 1− x   1 − x2   
2tan −1  = cos−1    5  
1+ x 
  1 + x2 
 
 5  4 
  = cosec  tan −1   + cos−1   
tan −1 x =   0,   x = tan    12   5 
 4
5 5 12
Let tan −1   =   sin  = ,cos  =
   
2tan −1  tan  −    = cos−1 ( cos2)  12  13 13
 4 

[6]
  4 4 3  t 
and cos−1   =   cos  = and sin  = k  
 
5 5 5
 tan−1  32 2 
= cosec (θ + ϕ) r =1 1+ t 
1  3 
=  2t 
sin  cos  + cos  sin  t−
k  
=
1
=
65  tan−1  32t 
5 4 12 3 56 r −1  1 + t. 
. + .  3
13 5 13 5 k
  2t  
 tan−1 (t ) − tan−1  3  
68. (2) r =1
−1 r +1 
 tan y k  −1  2 r −1  2 
2( a + b)
=k =
c   3 
 tan − tan  3  
  
r =1
c
= 2tan −1 y  2  2
k +1
a+b Sk = tan −1   − tan −1  
c  3  3
cos = cos2tan −1 y k +1
a+b  −1  2  −1  2 
S = lim  tan   − tan  
Let tan–1y = θ k →   3  3

y = tanθ
 2
1 − tan 2  1 − y 2 = tan −1   − tan −1 ( 0)
=  3
1 + tan 2  1 + y 2
 2  3
 S = tan −1   = cot −1  
 3  2
69. (1)
 a+b  
tan −1   =  a + b = 1 − ab 71. (3)
 1 − ab  4
3x 4x
 (1 + a) (1 + b) = 2 sin −1 + sin −1 = sin −1 x
5 5
 a 2 + b2   a3 + b3 
Now, ( a + b ) −  + ....  3x 
 2   3  sin −1  1−
16 x 2 4 x
+ 1−
9 x2  = sin −1 x
     5 25 5 25 
 
 a 2 a3   b2 b3 
= a − + ....  +  b − + ....  16 x2 4 x 9 x2
 3   2 3  3x
 2 1− + 1− =x
5 25 5 25
loge (1 + a) + loge (1 + b) = loge (1 + a) (1 + b) =
loge2 x = 0,3 25 − 16x2 + 4 25 − 9x2 = 25
4 25 − 9x2 = 25 − 3 25 − 16x2 squaring we get
70. (3)
16 (25 – 9x2) = 625 + 9 (25 – 16x2)
k  6r 
Sk =  tan −1  2r +1 2r +1  −150 25 − 16x2
2 +3 
r =1  
Divide by 3 2r 400 = 625 + 225 − 150 25 − 16x2
  2 r  25 − 16x2 = 3  25 − 16x2 = 9
k    
−1  3   x2 = 1
  2r
tan

r =1
  2  .2 + 3 
3  72. (1)
cot–1 (α) = cot –1 (2) + cot–1 (8) + cot–1 (18) +…..
 r 
  2  100
 2 
k   3  =  tan −1  2 
 tan −1    2r+1   n=1  4n 
r =1   2   ( 2n + 1) − ( 2n − 1) 
 3  3  + 1  100
 =  tan −1  
    n=1  1 + ( 2n + 1)( 2n − 1) 
r
 2 100
Let   = t =  tan −1 ( 2n + 1) − tan −1 ( 2n − 1)
 3 n=1

[7]
 = tan–1 201 – tan–1 1  only possibility that the equation is defined
 200  x2 + x = 0
= tan −1    x = 0; x = –1
 202 
None of these values satisfy
 202 
 cot −1 (  ) = cot −1    No of rotos = 0
 200 
α = 1.01 76. (3)
cos–1 (cos(–5)) + sin–1 (sin(6)) – tan–1 (tan(12))
73. (2)  (2π – 5) + (6 – 2π) – (12 – 4π)
 1  8  4π – 11
tan −1 ( x + 1) + cot −1   = tan −1
 x −1  31
77. (2)
Taking tangent both sides:- Given a = (sin–1x)2 – (cos–1x)2
( x + 1) + ( x − 1) = 8 = (sin–1x + cos–1x) (sin–1x – cos–1x)
(
1 − x2 − 1 ) 31  
=  − 2cos−1 x 

2 2 
2x 8
 =  2a
2− x 2 31  2cos−1 x = −
2 
 4x2 + 31x – 8 = 0
1 (
 cos−1 2 x2 − 1 = − )
 2a
2 
 x = −8,
4   2a 
 2 x2 − 1 = cos  − 
But, if x =
1 2  
4
  78. (4)
tan −1 ( x + 1)   0,  sin (cot–1 (1 + x)) = cos (tan–1x)
 2
 cosec2 (cot–1 (1 + x)) = sec2 (tan–1x)
 1   
&cot −1    ,   1 + [cot (cot–1 (1 + x))]2 = 1 + [tan (tan–1 x)]2
 x −1   2   (1 + x)2 = x2
  1
 LHS  & RHS   x=−
2 2 2
(Not possible)
Hence, x = – 8 79. (3)
Consider
74. (2)  3    3 
tan −1 cot  = tan −1 cot 10 + 
3 3 5  4    4 
tan −1 + tan −1 + tan −1
5 5 12  3 
x 0, y 0, xy 1 = tan −1 cot   cot ( 2n + ) = cot 
 4
6
   3 
tan −1 5 + tan −1
5 15
= tan −1 + tan −1
5 = tan −1  tan  − 
9 12 8 12   2 4 
1−
25 x0, y 0, xy1  3 2 − 3 
= − = =−
15 5 2 4 4 4
+
220
tan −1 8 12 = tan −1 80. (1)
15 5 21
1− .
8 12 Given that, cot −1 ( )
cos  − tan −1 ( )
cos  = x
 220  220
tan  tan −1

=
21  21
 1 
tan −1 
 cos  
 − tan
−1
(
cos  = x )
1
75. (4) − cos 
  tan −1 cos  =x
tan −1 x2 + x + sin −1 x2 + x + 1 = 1
4 1+ . cos 
cos 
For equation to be defined,
x2 + x  0 1 − cos 
 tan −1 =x
 x2 + x + 1  1 2 cos 

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 1 − cos  84. (12)
 tan x =
2 cos   
sin −1 sin  −  − sin −1 sin    0
2 cos  B 2 
 cot x = = 
1 − cos  P  sin −1 sin  
4
 P = (1 – cosα) and B = 2 cos 
1
 sin  
H = P2 + B2 = 1 + cos  2

 sin x = =
(
1 − cos  1 − 1 − 2sin  / 2
2
)   3 
So,   , 
1 + cos  1 + 2cos2  / 2 − 1 4 4 
  3 
   ,  = (a, b)
Or sin x = tan 2 4 4 
2

b − a = =  −
81. (29) 2

 1 1   =  −
50 tan  3tan −1 + 2cos−1  2
 2 5
 x2 + x + sin −1 ( x − 3)2 + 1 + cos−1 ( x − 3)2 + 1 = 0
   
1 
+4 2 tan  tan −1 2 2  
2  x = 3,9 + 3 + +0=0
2
 1  1 
= 50tan  tan −1 + 2  tan −1 + tan −1 2     
 9 + 3  −  + = 0
 2  2   2 2
1   12 −  = 0
+4 2 tan  tan −1 2 2 
 2  
=
 1  1 12
= 50tan  tan −1 + 2.  + 4 2 
 2 2 2
85. (2)
 1
= 50  tan tan −1  + 4 cos–1 (2x) – 2 cos–1 1− x2 = 
 2
= 25 + 4 = 29 ((
cos−1 (2 x) − cos−1 2 1 − x2 − 1 =  ) )
82. (2) (
cos−1 (2 x) − cos−1 1 − 2 x2 =  )
( )
Case I: x > 0
− cos−1 1 − 2 x2 =  − cos−1 (2 x)
2x 2x 
tan −1 + tan −1 = Taking cos both sides we get
1− x 2
1− x 2 3
x =2− 3 (
cos − cos−1 1 − 2 x2 ( )) = cos (  − cos −1
(2 x) )
Case II: x < 0 1– 2x = – 2x
2

2x 2x  2x2 – 2x– 1 = 0
tan −1 + tan −1 +=
1− x 2
1− x 2 3 1− 3 1+ 3
On solving, x = ,
−1 2 2
x=  = 2
3 1+ 3
As x = [−1/ 2,1/ 2], x = = rejected
2
83. (3) 1− 3 3
So x =  x2 − 1 = −
−  2 2
 sin −1 x,sin −1 y,sin −1 z 
 − 3  −2
2 2
( )
= 2sin −1 x2 − 1 = 2sin −1   =
−3
( ) ( ) ( ) 3  2 
3 3 3 3
  sin −1 x , sin −1 y , sin −1 z 
8 8
 Given equation holds good iff 86. (3)
 (x * 1) * 1 = x * (1 * 1)
sin–1 x = sin–1 y = sin–1 z = 2
(x + 1) * 1 = x * (2)
2 (x2 + 1)2 + 1 = x2 + 8
 x=y=z=1 x4 + x2 – 6 = 0  (x2 + 3) (x2 – 2) = 0
 2x – 3y + 4z = 2 – 3 + 4 = 3 x2 = 2

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 = 2sin (2sin–1x) cos(2sin–1 x)
−1 
x4 + x2 − 2  1
= 2sin −1  
 2sin  4
 x + x +2

2 
  2 (
= 4 x 1 − x2 1 − 2 x2 )

=
3 90. (7)
1 63 
tan  sin −1 
87. (8)
4 8 
      
 cos  4 − 4  − 1  cos − 1   63 
tan −1      tan −1 4 Let sin −1   = 
  
 sin   sin    8 
 4   4  63
sin  =
1− 2   8
tan −1   = −
 1  8

88. (2)
  1 1  1 
tan  2  tan −1 + tan −1  + tan −1   
  5 8  2 
 1  1  cos  =
1
= tan 2tan −1   + tan −1   8
  3  2 
 1
=2 2cos2 − 1 =
2 8
89. (4)  9
cos2 =
sin −1 x cos−1 x 2 16
= =k  3
  cos =
sin–1 x = kα 2 4
cos–1 x = kβ 
1 − tan 2
 4=3
k= …..(i)  4
2 (  + ) 1 + tan 2
4
 2 
sin  ( −1
 = sin 4sin x
  +
)  1
tan =
4 7

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