(B).

Product B is:
B2(A)
hv Dry ether

(d)
(a) (b)

-oK®. electrolysis (A) ; Major-product (A) is :

(Major)

(a) (b)
 (d) 0-
(C)

(A); Product (A) of the reaction is:

3. CH3MgBr + D , 0 0
(a) CH4 (b) CH3D (c) CH2D2 (d) CHD3
which ofthe following alkane will be formed in high yield by Wurtz reaction ?

b) d)

Br
Br 2Na
Product Ais:
(A);
dry ether

Br
Br ,Br

(b) (c)
Br Br
6. Which of the following has the lowest boiling point?
CH3
(c) CH3CHCHCH3
(a) CH,CH2CH,CHCH,CH, (6) CH,CH,CH2CHCH3
CH3 CH3

(e) CH CH,CH2CH CH,CH CH3

(d) CHCH,CHCH2CH 3
CH3
in CH,CH2CH2CH3?
. Which of the following has highest solubility
(b) CH,0 Na
(a) CH OH
(d) CH 0CH3
(e) (CH3), CH
(c) CHNH2
soluble in H;0?
0.
Which of the following is most
(b) CH,CH,OH
(a) CH OCH3 (e) CH,CHO
(c) CH,CH ,Cl (d) CH3CH,CH; following reactions has lowest
which of the
9. of methane,
During the free radical chlorination
collision frequency? (b) Cl+Cl2dCl
(a) Cl+CH CH3 CH,Cl Cl+
(d) CH +Cl2
(c)CH+CH CH4 +CH3
 CHBt +
HBr which
10. In the reaction Br, +CH ,Br of n e tollowing mecha chanism steps i
to occur?
relatively unlikely
productive, but
IBr +Cl1,Br (b) Br CH,Br
(a) Br+ CH ,Br CH,Br2
Br*
(d) Br+ CH
(c) Br +Br2 Br2 +
CHBr
termination
reactions 1s a step in the free
11 Which of the following radical chlorination o
methane
(b) Cl2 2C
(a) Cl2 +
Cl Cl +
Cl2
(d) CH4 +Cl HCICH3
(c).CH3+Cl CH,Cl
in t h e tTee
radical chlorination of
chain propagation step ethane?
12. Which of the following is
a

Cl- C H 3 +HCI (b) Cl2- 2C1

(a) CH, +

(d) CH3+ CH4 CH +CH

(c) Cl+ CH3 CH3CI
Br

A ) ; Product (A) is:

(ether
13.2
OH

(c) (d)
(b)

of the following reaction?

14. What is the major product
+ ?

Cl Cl
( ) CH,CH,CH,CH,CH, H, (1) (11D

Cl
(V)
(IV)
CI
Cl
(d) V (e) V
(a) (b) (c)II1
15. Compare the heats of combustion of the following compounds:

(i) (ii)

(a) i>ii>ii (b) ii>i>ii (c) iii>i>ii (d) ii>iii

16. Compare heats of combustion of the following compounds:

CH CH3 CH
CH3
(ii)
(ii)
CH3
CH3 CH3
(a) i>ii>ii (b) ii>i>ii (c) ii>i>ii (d) ii>ii>i
CI

Na,(x) Dimeric product (x) is

17. dry ether

(a) 1 (b) 2 (c) 3 (d) 4

Na
18. CI dry etherx). Products x is:

(a) 1 (b) 2 (c) 3 (d) 4

COH
19. 2NaOH A) electrolysis, (B): Product (B) is:
co,H

(a) HCCH (b) H2C =CH (c)

COH
20. 2KOH (A) electrolysis (B) + (C); Products(B) and (C) are:
coH (b) enantiomer
(a) geometrical isomers
(d) structural isomer
(c) positional isomer
reaction ?
formed in the given
41. How
many products will
CI
Na

dry ether
(d) 4
(c) 3
(a) 1 (b) 2 ?
reaction
formed in the
following
How many products will Na
CH-Cl+CH-CH2-C- dry e t h e r
4
(c)3
(d)
of increasing ring strain per
(b) 2 in o r d e r
(a) 1 cycloalkanes
ranks the
correctly
nch of the following cycloheptane
<
methylene? cyclobutane
<
cyclohexane

(a) cy
yclopropane
<
 < cyclobutane < cyclopropane
(b) cyclohexane < cyclopentane < cyclopentane < cyclopropane
(c) cyclopentane < cyclobutane < cyclohexane
cyclopropane < cyclobutane
(d) cyclopentane <

cyclopentane < cyclobutane < cyclohexane

(e) cyclopropane
<

in 1,1,2,2-tetrachloro ethene
and tetrachloromethane is:
24. Cl-C-Cl bond angle
(a) 120° and 109.5° (b) 90° and 109.5° (c) 109.5° and 90° (d) 109.5° and 120

25. d(X) mono chloro product: (including stereoisomer)

(a) 2 (b) 3 (d) 5 (c) 4
26. How many products are formed from the monochlorination of ethylcyclohexane? lon
nore
stereoisomers ?
CHCH3

(a) 6 (b)8(c) 5 (d) 9 (e)11

27. How many distinct dichlorination products can result when isobutane is subjected to fre
radical chlorination?
(a) 1 (b) 2 (c) 3 (d) 4 (e) 6
28. How many distinct monochlorinated
products, including stereoisomers, can result when the
alkane below is heated in the
presence of Cl2?

(a) 2 (b) 4 (c) 5 (d) 6 (e) 8

29. A sample of (R)-2-chlorobutane,
H

CH C
CHCH3
reacts with Br2 in the
presence of light, and all the we

isolated. Two possible isomers are shown below:

products having the formula C4HgD
CH3 CH3
Br C and
ClBr
CH,CH CHCH
of these:
(a) onlyI was formed
(b) both I and II were formed in equal amounts
 were formed in unequal amounts
(c) both I and II
(d) only Il w a s formed
w a s formed
(e) neither I nor II be isolated when (S)-2
30. How many dichlorinated products, including stereoisomers, can

chlorobutane reacts with Cl2/hv ?

CHCH3
C H
CH3
(S)-2-chlorobutane (e) 5
3 (d) 4
(a) 1 (b) 2 (c)