Subject Code: B2104

ITB. Pharmacy I Semester Regular Examinations

~
ovember - 2011

ADV A CED PHARMACEUTICAL ORGA IC CHEMISTRY

Time: 3 hours Max. Marks: 75 Answer any FIVE Questions from the following All Question carry equal marks
1.
2.

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Write the structures, and quinoline. Write the important and phenothiazine the terms: of symmetry (ii) Diastereoisomers (iv) Mesocompounds of important preparations characteristic and characteristic reactions reactions of Pyrrole, Pyridine Explain their basicity. of imidazole, oxazole, pyrazine

3. (a) Explain

(i) Elements

(iii) Enantiomers

(b) Explain about relative and absolute configuration. 4. (a) Explain about the pyranose structure of glucose and write the configurations
monosaccharides. (b) Write the following (i) Osazone (iii) Lobry-D(b) Explain (i) 6. reactions with glucose: (ii) Action of barium Van Ekenstein reaction (iv) Epimerisation. of starch, cellulose, ionic nature importance (ii) Zwitter of: reaction. formation. Bruynand pharmaceutical

hydroxide maltose, sucrose.

5. (a) Write the structures the terms: Glycoside

linkage point

(iii) Iso electric

(iv) Mutarotation.

Write the mechanism

(a) (b) (c) (d)

Beckmann Phillips Mannich Michael

rearrangement. raction. addition reaction. Write the primary, terminal concept. secondary and teritiary structures between of proteins. amino acids, Write the relationship of:

condensation

7. (a) Classify proteins.

(b) Explain peptides 8. about C & & proteins.

Write the mechanism

and application

(a) Wittig reaction. (b) Hoffmann rearrangement.

(c) Curtius rearrangement.

(d) Schmidt reaction. ./ Page 1 of 1

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