Chapter 9 Redox Reaction Assignment Balance following redox reactions by oxidation number method 1) CH3CHO + Cr2O7-2 CH3COOH + Cr+3

2) FeS + NO3-1 Fe+3 + NO + S (B) -1 + -3 3) As2S3 + NO3 + H AsO4 + S + NO2 4) FeS2 + O2 Fe2O3 + SO2 (A) 5) Ag2S + CN + O2 Ag(CN)2 + S + OH -1 +2 2 6) CuS + NO3 Cu + SO4 + NO (A) 7) K2MnO4 + H 2O KMnO4 + MnO2 + KOH (B) 8) KMnO4 + HCl KCl + MnCl2 + H2O + Cl2 (A) +2 9) Co + KNO2 + CH3COOH K3Co(NO2)6 + NO + H2O + CH3COO (A) 10) As2S5 + HNO3 H3AsO4 + S + NO2 + H2O (A) 11) ClO2 + SbO2 ClO2 + Sb(OH)6 (B) 12) Na2HPO3 Na3PO4 + Na4P2O7 + PH3 + H2O (B) 13) Cl2 + IO3 Cl + IO4 (B) 14) Ag+ + AsH3 H3AsO3 + H+ + Ag (A) 15) As2S3 + NO3-1 H2AsO4 + NO + S (A) 16) Fe2S3 + HCl Fe+2 + H2S + S (A) HNO -1 2 3 17) SCN + NO3 SO4 + CO2 + NO 18) Metallic Zinc + nitrite ion + NaOH in alkaline medium Zn + NO2 + ZnO22 + NH3 19) Arsenic sulphide + hydrogen peroxide in ammonia basic medium AsO43 + SO42 + H2O (B) HCl 20) IO3 + I2 ICl Balance following redox reactions by half reaction method. 21) Ag2S + CN + O2 Ag(CN)2 + S + OH (B) 22) FeS2 + O2 Fe2O3 + SO2 (A) + 23) FeC2O4 + MnO4 + H Fe+3 + CO2 + Mn+2 (A) 24) As4O6 + MnO4 Mn+2 + H3 AsO4 (A) 25) Cu3P + Cr2O7-2 Cu+2 + H3PO4 + Cr+3 (A) 4 + +3 26) [Fe(CN)6] + H + MnO4 Fe + CO2 + NO3-1 + Mn2+ (A) 27) MnO2 + H2O2 MnO4 + H2O (A) 28) Pb(N3)2 + Co(MnO4)3 CoO + MnO2 + Pb3O4 + NO (A) 29) KOH + K4[Fe(CN)6] + Ce(NO3)4 Fe(OH)3 + Ce(OH)3 + K2CO3 + KNO3 + H2O (B) 2+ -2 30) Cu2S+ N03 Cu + SO4 + NO (A) 31) K3[Fe(CN)6] + Cr2O3 + KOH K4[Fe(CN)6] + K2CrO4 + H2O 32) Ca3(PO4)3 + SiO2 + C CaSiO3 + P4 (B) 33) FeP + HNO3 Fe(NO3)3 + H3PO4 + NO2 + H2O 34) CrI3 + OH + Cl2 CrO42 + IO4 + Cl + H2O 35) CrI3 + KOH + Cl2 K2CrO7 + KIO4 + KCl + H2O 36) FeS2 + H2O + H2SO4 Fe+3 + Na2SO4 + SO2 37) Mn SO4 + (NH4)2 S2O8 + H2O MnO2 + H2SO4 + (NH4)2SO4 2 38) Au + CN + O2 Au(CN)4 + H2O + OH

Calculate oxidation number for underlined elements in following compounds or polyatomic ions. 1) Na20, Na202, MgO, -A120a, Si02, P4O10, SF6 2) Calculate oxidation number of P in following substances. Mg3P2, PH3, AlP, Li3P, PH4+, P2H4, P4, H3P02, NaH2P02, H2P02, Na2HPO3, HP02, NaP02, P02,PCl5, PF5 , P4O10, PCl4, PF4+, PCl6, PF6, H3PO4,PO43,Na3 PO4, H4P207,P2074-, Na4P207, HPO3, PO3,NaPO3. 3) Calculate oxidation number of C in following substances. 4) CH4 , C2H6, RCH3, CH3Cl, CH3Br, CH3I , CH3OH, RCH2R,CH2 = CH2, RCH = CH2, HC CH, R3 CH.
CHO

5) Calculate oxidation number of each C individually in following substances. CH3CHO, CH3COOH,CH3CONH2, CH3CN, CH3O CH3, CH3OCOO CH3, CH3COO CH3.