Bi Tp Hirocacbon Bi Tp t Chy Cu 1: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t.

. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit ,p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 4. B. 2. C. 3. D. 5.

Cu 2: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. 2-Metylpropan. C. 2,2-imetylpropan. D. etan.

Cu 3: t chy hon ton 3,4g cht hu c A mch h thu c H2O v CO2 .Hp th hon ton sn phm chy bng nc vi trong d thy khi lng bnh ng dd Ca(OH)2 tng 14,6g v trong bnh c 25g kt ta .Cng thc phn t ca A l: A.C3H4 B.C5H8 C.C5H10 D.C4H8

Cu 4: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l A. C2H6. B. C3H6. C. C3H8. D. C3H4.

Cu 5: t hon ton hn hp 2 hidrocacbon X, Y thuc cng mt dy ng ng (ankan, anken, ankin), hp thu sn phm chy vo 4,5 lit dung dch Ca(OH)2 0,02M th thu c kt ta, khi lng dung dch tng ln 3,78g. Cho dung dch Ba(OH)2 d vo dung dch thu c kt ta. Tng kt ca 2 ln nng 18,85g. Bit rng s mol X bng 60% tng s mol X, Y trong hn hp. Xc nh cng thc phn t ca X, Y?. A. C2H4 v C3H6 B. C3H4 v C5H6 C. C2H6 v C3H8 D. C2H2 v C4H6

Cu 6: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Zgp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta A. 40. B. 30 C. 20. D. 10.

Cu 7: Hn hp X gm mt ankan v mt anken c s mol bng nhau, s nguyen t cacbon ca ankan gp 2 ln s nguyn t cacbon ca anken. Ly a gam X th lm mt mu va 100gam dd Br2 16%. t chy hon ton a gam X ri cho ton b sn phm chy vo dung dch Ca(OH)2 d thu c 60 gam kt ta. CTPT ca chng l:

A. C4H10 v C2H4

B. C2H6 v C4H8

C. C6H14 v C3H6

D. C8H18 v C4H8

Cu 8: t chy hon ton 11,2 lt hn hp kh X gm 2 hirocacbon thuc cng dy ng ng cn 40,32 lt O2 v to ta 26,88 lt CO2. Thm vo 22,4 lt hh X mt hirocacbon Y v t chy hon ton th thu c 60,48 lt CO2 v 50,4 gam H2O. Cc th tch o ktc. CTPT ca Y l: A. C3H6 B. C3H8 C. C4H8 D. C4H10

Cu 9: t chy hon ton mt hh c s mol bng nhau ca 2 hirocacbon c cng s nguyn t C trong phn t thu c 3,52g CO2 v 1,62g H2O .Cng thc phn t ca 2 hirocacbon l: A. C2H4 ,C2H6 B. C3H6, C3H8 C. C3H4, C3H8 D. C4H8 , C4H10

Cu 10: Hn hp X gm 1 ankan v 1 anken c cng s nguyn t cacbon trong phn t v c cng s mol. Bit m gam hh X lm mt mu va 80 gam dung dch Br2 20%. t chy hon ton m gam hh X thu c 13,44 lt CO2 (ktc). CTPT ca ankan va anken l: A. C2H6 v C2H4 B. C3H8 v C3H6 C. C4H10 v C4H8 D. C5H12 v C5H10

Cu 11: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l A. C3H4. B. C3H6. C. C4H8. D. C3H8.

Cu 12: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 18,60 g. B. 18,96 g. C. 20,40 g. D. 16,80 g.

Cu 13: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H4. B. CH4. C. C2H6. D. C3H8.

Cu 14: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A. 35% v 65%. 50%. Cu 15: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trongkhng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l A. 56,0 lt. B. 78,4 lt. C. 70,0 lt. D. 84,0 lt. B. 75% v 25%. C. 20% v 80%. D. 50% v

Cu 16: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A. 25,8. B. 12,9. C. 22,2. D. 11,1.

Cu 17: t chy hon ton 4 lt hh 2 hirocacbon A,B thu c 6 lt CO2 v 6 lt hi H2O (cc th tch o cng iu kin t0, p) .Cng thc phn t ca A,B l: A.CH4;C2H2 B. CH4; C3H4 C. C2H6; C2H2 D. C2H6 ;C4H6

Cu 18: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C3H6. D. CH4 v C4H8.

Cu 19: Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3, t0), thu c hn hp Y ch c hai hirocacbon. Cng thc phn t ca X l A. C2H2 B. C5H8 C. C4H6 D. C3H4

Cu 21: X,Y,Z l 3 hirocacbon mch h v u l cht kh iu kin thng .t chy mi kh vi s mol nh nhau s thu c lng nc bng nhau. Trn X vi O2 2730C, p sut l p ( lng O2 ly gp i lng cn thit t chy ht X ) thu c hh A .t chy hon ton X sau a v 2730C ,p sut p th tng th tch hh sau p/ gp 1,05 ln th tch hh A. Cng thc ca X,Y,Z l: A.C3H6 , C2H6 , C2H4 C. CH4 , C2H4 , C3H4 B. C3H6 , C2H6 , C4H6 C. C B v C

Cu 22: t chy hon ton 2 lt hn hp gm axetilen v mt hirocacbon no X, thu c 4 lt CO2 v 4 lt H2O (cc th tch o cng iu kin nhit v p sut). Cng thc phn t ca hirocacbon no X v phn trm theo th tch ca X trong hn hp l A. CH4 v 40%. B. CH4 v 50%. C. C2H6 v 40%. D. C2H6 v 50%.

Cu 23: t chy hon ton 2,24 lt (ktc) hn hp kh X gm: CH4, C2H4, C2H6, C3H8 v C4H10 thu c 6,16 gam CO2 v 4,14 gam H2O. S mol ca C2H4 trong hn hp X l A. 0,09. B. 0,01. C. 0,08. D. 0,02.

Cu 24: Crackinh 5,8 gam C4H10 thu c hn hp kh X. t chy hon ton hn hp kh X ri cho ton b sn phm chy qua bnh ng dung dch Ca(OH)2 d. Kt thc th nghim, khi lng dung dch thu c tng hay gim bao nhiu gam so vi dung dch Ca(OH)2 ban u? A. tng 26,6 gam. B. gim 13,4 gam. C. gim 40,0 gam. D. gim 22,4 gam.

Cu 25: t chy hon ton 0,01 mol hn hp hai ankan th thu c 0,72 gam nc. Cho sn phm t chy i qua bnh ng dung dch nc vi trong d th. khi lng kt ta thu c l A. 0,3 gam. B. 3,0 gam. C. 0,6 gam. D. 6,0 gam.

Cu 26: t chy hon ton mt lng hirocacbon X cn ti thiu 7,68 gam O2. Ton b sn phm chy c dn qua bnh (1) ng H2SO4 c, d, sau qua bnh (2) ng dung dch Ca(OH)2 d. Kt thc th nghim thy bnh (1) tng 4,32 gam v bnh (2) thu c m gam kt ta. Cng thc phn t ca X v gi tr ca m ln lt l A. C2H6 v 10. B. C2H4 v 11. C. C3H8 v 9. D. CH4 v 12.

Cu 27: t chy hon ton hn hp hai hirocacbon c khi lng phn t hn km nhau 28 vC thu c 4,48 lt CO2 (ktc) v 5,4 gam H2O. Cng thc phn t ca 2 hirocacbon ln lt l A. C2H4 v C4H8. B. CH4 v C3H8. C. C2H6 v C4H10. D. C2H2 v C4H6.

Cu 28: t chy hon ton 7,0 mg hp cht X thu c 11,2 ml kh CO2 (ktc) v 9,0 mg H2O. T khi hi ca X so vi nit bng 2,5. Khi clo ho X vi t l s mol 1:1 ch thu c mt dn xut monoclo duy nht. X c tn gi l A. metylxiclobutan. C. 1,2-imetylxiclopropan. B. xiclopentan. D. xiclohexan.

Cu 29: t chy hon ton 0,1 mol hn hp X gm propan v xiclopropan th thu c 0,35 mol H2O. Thnh phn trm theo th tch propan trong hn hp X l A. 50%. B. 40%. C. 30%. D. 25%.

Cu 30: t chy hon ton 0,11 mol hn hp X gm CH4, C3H8 v C2H4 thu c 0,17 mol CO2 v 0,25 mol H2O. S mol ca anken trong hn hp X l A. 0,02 mol. B. 0,09 mol. C. 0,03 mol. D. 0,08 mol.

Cu 31: t chy hon ton m gam hn hp X gm propan, but-2-en, axetilen thu c 47,96 gam CO2 v 21,42 gam H2O. Gi tr ca m l A. 15,46. B. 12,46. C. 11,52. D. 20,15.

Cu 32: Dn hn hp X gm 0,05 mol C2H2; 0,1 mol C3H4 v 0,1 mol H2 qua ng cha ng cha Ni nung nng mt thi gian, thu c hn hp Y gm 7 cht. t chy hon ton Y ri cho sn phm chy hp th ht vo 700 ml dung dch NaOH 1M, thu c dung dch Z. Tng khi lng cht tan trong Z l

A. 35,8.

B. 45,6.

C. 40,2.

D. 38,2.

Cu 33: t chy hon ton 0,14 mol hn hp gm C3H6, C2H2, C3H4 th thu c 8,288 lt kh CO2 (ktc) v 0,26 mol H2O. S mol anken c trong hn hp l A. 0,11 mol. B. 0,12 mol. C. 0,04 mol. D. 0,03 mol.

Cu 34: t chy hon ton hn hp M gm mt ankan c nhnh X v mt ankin Y thu c kh cacbonic v hi nc vi s mol bng nhau. T khi ca hn hp M so vi hiro l 21. Cng thc phn t ca X v Y ln lt l A. C4H10 v C2H2. B. C3H8 v C3H4. C. C5H12 v C2H2. D. C5H12 v C3H4. Cu 35: t chy hon ton 11,2 lt gm C3H6 v C2H2 thu c s mol CO2 nhiu hn s mol H2O l 0,4 mol. Thnh phn phn trm theo th tch ca mi kh trong hn hp u l A. 50% v 50%. B. 30% v 70%. C. 70% v 30%. D. 20% v 80%.

Cu 36 t chy hon ton 2,24 lt hn hp X (ktc) gm C3H8, C3H6, C3H4 (X c t khi so vi H2 bng 21), ri dn ton b sn phm chy vo bnh ng dung dch nc vi trong th tng khi lng ca bnh l A. 4,2 gam. B. 5,4 gam. C. 13,2 gam. D. 18,6 gam.

Cu 37: Crackinh 11,6 gam C4H10 thu c hn hp kh X gm 7 cht: C4H8, C3H6, C2H6, C2H4, CH4, H2, C4H10 d. t chy hon ton hn hp X cn ti thiu bao nhiu th tch khng kh ktc? (Bit oxi chim 20% th tch khng kh). A. 34,944 lt. B. 145,60 lt. C. 29,12 lt. D. 174,72 lt.

Cu 38: un nng 11,6 gam butan mt thi gian, thu c hn hp X gm H2, CH4, C2H6, C4H8, C3H6, C2H4, C4H10. Gi s ch c cc phn ng: C4H10 C4H8 + H2 (1) C4H10 CH4 + C3H6 (2) C4H10 C2H6 + C2H4 (3) t chy hon ton X ri cho sn phm chy hp th ht vo dung dch Ca(OH)2 d, thy khi lng bnh tng thm m gam. Gi tr ca m l A. 35,2. B. 53,2. C. 80,0. D. 18,0.

Cu 39: t chy hon ton m gam hn hp X gm etan, etilen, axetilen v buta-1,3-ddien. Cho ton b sn phm chy hp th vo dung dch nc vi trong d, thu c 100 gam kt ta v khi lng dung dch thu c sau phn ng gim 39,8 gam. Gi tr ca m l

A. 58,75.

B. 13,8.

C. 37,4.

D. 60,2.

Cu 40: t chy hon ton 0,5 lt ( 273oC v 1,3432 atm) mt ankaien lin hp X. Sn phm chy c hp th hon ton vo 40 ml dung dch Ba(OH)2 1,5M, sau phn ng thu c 8,865 gam kt ta. Cng thc phn t ca X l A. C3H4. B. C4H6. C. C5H8. D. C6H10.

Cu 41: t chy hon ton 0,1 mol hn hp X (CH4, C2H4, C3H4, C4H4) c t khi hi so vi H2 bng 17. Dn ton b sn phm chy thu c vo bnh ng dung dch Ca(OH)2 d th. khi lng b.nh Ca(OH)2 sau phn ng tng ln A. 11 gam. B. 3,6 gam. C. 8,8 gam. D. 14,6 gam.

Cu 42: t chy hon ton m gam hn hp X gm C2H2, C4H4, C6H6, C8H8 trong O2 d ri dn ton b sn phm chy thu c vo bnh ng dung dch Ca(OH)2 d thy khi lng b.nh tng 21,2 gam. Gi tr ca m l A. 2,6. B. 3,9. C. 6,5. D. 5,2.

Phn ng Cng Cu 1: Dn hn hp kh X cha eten v hiro. T khi ca X i vi hiro l 7,5. Dn X i qua cht xc niken nung nng th X bin thnh hn hp kh Y c t khi so vi hiro l 9,0. Hiu sut phn ng cng hiro ca eten l A. 20%. B. 33,33%. C. 50%. D. 66,66%.

Cu 2: Hn hp kh X cha hiro v mt anken. T khi ca X i vi hiro l 6,0. un nng nh hn hp X c mt cht xc tc Ni th X bin thnh hn hp kh Y khng lm mt mu nc brom v c t khi i vi hiro bng 8,0. Cng thc phn t ca anken v phn trm theo th tch ca ankan trong hn hp Y ln lt l A. C2H4 v 25%. B. C2H4 v 33,3%. C. C3H6 v 25%. D. C3H6 v 33,3%.

Cu 3: Hn hp kh X cha hiro v 2 anken k tip nhau trong d.y ng ng. T khi ca X i vi hiro l 8,26. un nng nh hn hp kh X c mt cht xc tc Ni th X bin thnh hn hp kh Y khng lm mt mu nc brom v c t khi hi so vi hiro l 11,80. Cng thc phn t ca 2 anken v phn trm theo th tch ca hiro trong hn hp X l A. C2H4, C3H6 v 60%. C. C2H4, C3H6 v 80%. B. C3H6, C4H8 v 70%. D. C3H6, C4H8 v 80%.

Cu 4: Hn hp kh X cha hiro, mt ankan v mt anken. Dn 13,44 lt X i qua cht xc tc Ni nung nng th thu c 10,08 lt hn hp kh Y. Dn qua bnh ng nc brom th mu ca dung dch nht i, khi lng ca bnh tng thm 3,15 gam. Sau th nghim, c.n li 8,40 lt hn hp kh Z c t khi i vi hiro l 17,8. Bit cc th tch c o ktc v cc phn ng xy ra hon ton. Cng thc phn t ca ankan v anken trong hn hp X l A. CH4 v C2H4. B. C2H6 v C2H4. C. C2H6 v C3H6. D. C3H8 v C3H6.

Cu 5: Cho hn hp X gm etilen v H2 c t khi so vi H2 bng 4,25. Dn X qua bt niken nung nng (hiu sut hiro ho anken bng 75%), thu c hn hp Y. Cc th tch o iu kin tiu chun. T khi ca Y so vi H2 l A. 5,32. B. 5,23. C. 4,80. D. 4,60.

Cu 6. Hn hp X gm mt hirocacbon th kh v H2 (t khi hi ca X so vi H2 bng 4,8). Cho X i qua Ni un nng n phn ng hon ton thu c hn hp Y (t khi hi ca Y so vi CH4 bng 1). CTPT ca hirocacbon l A. C2H2 B. C3H6 C. C3H4 D. C2H4

Cu 7. Hn hp A gm H2 v 2 hircacbon(mt no, mt cha no). Cho A vo bnh kn c niken lm xc tc, un nng bnh mt thi gian thu c hn hp B. Pht biu no sau y ng: A. S mol A - S mol B = s mol H2 tham gia phn ng. B. Tng s mol hircacbon c trong B lun bng tng s mol hircacbon c trong A C. S mol CO2 v H2O to ra khi t chy hon ton A bng s mol CO2 v H2O to ra khi t chy hon ton B D. C A, B, C u ng Cu 8:Trong bnh kn cha 1 mol hh kh X gm H2, C2H4, C3H6 v 1 t bt l 7,6 v ca Y A. 0,05 l 8,455. B. 0,08 Tnh s mol H2 p/C. 0,1 ? D. 0,12 xc

tc. un nng bnh mt thi gian thu -c hh Y. T khi i vi H2 ca X

Cu 9: Dn hn hp X gm CnH2n v H2 (c s mol bng nhau) qua Ni nung nng thu c hn hp Y. T khi hi ca Y so vi X l 1,6. Hiu sut ca phn ng l A. 40%. B. 60%. C. 65%. D. 75%.

Cu 10: Trong bnh kn cha hn hp kh X gm C2H4 v H2 vi lng nh bt Ni (cht rn chim th tch khn ng k). T khi ca X so vi H2 bng 6,2. un nng bnh mt thi gian thu c hn hp kh Y c t khi hi so vi H2 bng 8. Hiu sut ca phn ng hiro ho C2H4 l A. 62,50%. B. 56,25%. C. 43,75%. D. 37,50%. Cu 11: Hn hp X gm mt anken v hiro c t khi so vi H2 bng 6,4. Cho X i qua bt Ni nung nng c hn hp Y c t khi so vi H2 bng 8 (gi thit cc phn ng xy ra hon ton). Cng thc phn t ca anken l A. C3H4. B. C3H6. C. C4H8. D. C5H10.

Cu 12. Hn hp X gm mt anken A, mt ankan B v H2. Ly 392 ml hh X cho i qua ng cha Ni nung nng. Kh i ra khi ng chim th tch 280 ml v ch gm 2 ankan. T khi ca hn hp ny so vi khng kh bng 1,228. Cc th tch khi o cng iu kin. CTPT ca A v B l: A. C2H4 v CH4 B. C3H6 v C2H6 C. C3H6 v CH4 D. C4H8 v C3H8

Cu 13. un nng m gam hn hp X gm C2H2, C2H4 v H2 vi xc tc Ni n phn ng xy ra hon ton, thu c 8,96 lt (ktc) hn hp Y (c t khi so vi hir bng 8). t chy hon ton cng lng hn hp X trn, ri cho sn phm chy hp th hon ton trong dung dch nc vi trong d th khi lng kt ta thu c l A. 20 gam B. 40 gam C. 30 gam D. 50 gam

Cu 14: Trong mt bnh kn cha hn hp kh gm hidrocacbon A v hiro c Ni lm xc tc(th tch khng ng ke). Nung nng bnh mt thi gian thu c mot kh B duy nht. cng nhit , p sut trong bnh trc khi nung nng gp 3 ln p sut sau khi nung nng. t chy mt lng B thu c 8,8 gam CO2 v 5,4 gam H2O. Cng thc phn t ca X l: A.C2H2 B.C2H4 C. C3H4 D. C4H4

Cu 15: Cho 10 lt hn hp kh CH4 v C2H2 tc dng vi 10 lt H2 (Ni, to). Sau khi phn ng xy ra hon ton thu c 16 lt hn hp kh (cc kh u o cng iu kin nhit p sut). Th tch ca CH4 v C2H2 trc phn ng l A. 2 lt v 8 lt. B. 3 lt v 7 lt. C. 8 lt v 2 lt. D. 2,5 lt v 7,5 lt.