TI LIU LUYN THI I HC, CAO NG

GV: V Minh Hin 0905 260 732 *trang 1*

CHUYN ESTE-LIPIT
A. CNG THC TNG QUT
1. Este c to bi axit cacboxylic no, n chc mch h v ancol no, n chc, mch h (este no, n
chc, mch h): C
m
H
2m+1
COOC
m
H
2m+1
hay C
n
H
2n
O
2
(m 0; m 1; n 2 ).
2. Este a chc c to bi axit cacboxylic a chc v ancol n chc: R(COOR)
n

3. Este a chc c to bi axit cacboxylic n chc v ancol a chc: (RCOO)
n
R
4. Este a chc c to bi axit cacboxylic a chc v ancol a chc (cng c n nhm chc):
R(COO)
n
R
5. CTTQ ca este: C
x
H
y
O
z
(x, z 2; y l s chn, y s 2x)
B. CC DNG BI TP V CH KHI GII BI TP
Dng 01: Bi ton v phn ng thu phn este
1. Thu phn mt este n chc
- Trong mi trng axit: Phn ng xy ra thun nghch.
RCOOR + HOH

H
+,
t
o
RCOOH + ROH
- Trong mi trng kim (phn ng x phng ho): Phn ng mt chiu.
RCOOR + NaOH
0
t
RCOOH + ROH
. Mt s nhn xt :
C Nu n
NaOH phn ng
= n
Este
Este n chc.
C Nu RCOOR (este n chc), trong R l C
6
H
5
- hoc vng benzen c nhm th
n
NaOH phn ng
= 2.n
este
v sn phm cho 2 mui, trong c phenolat:
VD: RCOOC
6
H
5
+ 2NaOH RCOONa + C
6
H
5
ONa + H
2
O
C Nu n
NaOH phn ng
= o.n
este
(o >1 v R khng phi C
6
H
5
- hoc vng benzen c nhm th) Este a
chc.
C Nu phn ng thu phn este cho 1 anehit (hoc xeton), ta coi nh ancol (ng phn vi andehit) c
nhm OH gn trc tip vo lin kt C=C vn tn tai gii v t CTCT ca este.
C Nu sau khi thy phn thu c mui (hoc khi c cn thu c cht rn khan) m m
mui
= m
este
+
m
NaOH
th este phi c cu to mch vng (lacton):
C = O
O

NaOH +

HO-CH
2
CH
2
CH
2
COONa

Nu gc hidrocacbon ca R, mt nguyn t C gn vi nhiu gc este hoc c cha nguyn t
halogen th khi thy phn c th chuyn ha thnh andehit hoc xeton hoc axit cacboxylic
VD: C
2
H
5
COOCHClCH
3
+ NaOH
0
t
C
2
H
5
COONa + CH
3
CHO

CH
3
-COO
CH
3
-COO
CH + NaOH CH
3
-COONa + HCHO

C Bi ton v hn hp cc este th nn s dng phng php trung bnh.

> Bi 1: Thc hin phn ng x phng ho cht hu c X n chc vi dung dch NaOH thu c mt
mui Y v ancol Z. t chy hon ton 2,07 gam Z cn 3,024 lt O
2
(ktc) thu c lng CO
2
nhiu hn
khi lng nc l 1,53 gam. Nung Y vi vi ti xt thu c kh T c t khi so vi khng kh bng 1,03.
Cng thc cu to ca X l
A. C
2
H
5
COOCH
3
B. CH
3
COOC
2
H
5
C. C
2
H
5
COOC
3
H
7
D. C
2
H
5
COOC
2
H
5

Gii:
Theo bi: X n chc, tc dng vi NaOH sinh ra mui v ancol X l este n chc: RCOOR.
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GV: V Minh Hin 0905 260 732 *trang 2*


Mt khc: m
X
+
2
O
m =
2
CO
m +
O H
m
2
44.
2
CO
n + 18.
O H
n
2
= 2,07 + (3,024/22,4).32 = 6,39 gam
V 44.
2
CO
n - 18.
O H
n
2
= 1,53 gam
2
CO
n = 0,09 mol ;
O H
n
2
= 0,135 mol

O H
n
2
>
2
CO
n Z l ancol no, n chc, mch h c cng thc: C
n
H
2n+1
OH (n 1)
T phn ng t chy Z
2
2
CO
O H
n
n
=
n
n 1 +
=
09 , 0
135 , 0
n = 2.
Y c dng: C
x
H
y
COONa T: C
x
H
y+1
M
T
= 12x + y + 1 = 1,03.29

=
=
6
2
y
x
C
2
H
5
COOC
2
H
5
p n D
> Bi 2: un 20,4 gam mt cht hu c A n chc vi 300 ml dung dch NaOH 1 M thu c mui B
v hp cht hu c C. Cho C phn ng vi Na d thu c 2,24 lit H
2
(ktc). Nung B vi NaOH rn thu
c kh D c t khi i vi O
2
bng 0,5. Khi oxi ha C bng CuO c cht hu c E khng phn ng
vi AgNO
3
/NH
3
. Xc nh CTCT ca A?
A. CH
3
COOCH
2
CH
2
CH
3
B. CH
3
COO-CH(CH
3
)
2

C. C
2
H
5
COOCH
2
CH
2
CH
3
D. C
2
H
5
COOCH(CH
3
)
2


Gii:
Cht C tc dng vi Na sinh ra kh H
2
C l ancol. Oxi ha C ra E khng phn ng vi AgNO
3
C
khng l ancol bc 1. Cc p n cho A l este n chc. Vy B l mui ca Na.
Nung B vi NaOH rn to ra D c M
D
= 32.0,5 = 16. Vy D l CH
4
Gc R trong D l CH
3
-.
t cng thc ca A l RCOOR
CH
3
COOR + NaOH CH
3
COONa + ROH
ROH + Na RONa + H
2
Ta c:
2
H
n = 0,1 mol n
Ancol
= 2.0,1 = 0,2 mol
n
NaOH
= 0,3 mol > n
Ancol
NaOH d, este phn ng ht.
n
Este
= n
Ancol
= 0,2 mol M
este
= 20,4/0,2 = 102
R = 102 59 = 43 gc R l C
3
H
7
- v ancol bc 2 p n B ng
> Bi 3: X l mt cht hu c n chc c M = 88. Nu em un 2,2 gam X vi dung dch NaOH d,
thu c 2,75 gam mui. Cng thc cu to thu gn ca cht no sau y ph hp vi X
A. HCOOCH
2
CH
2
CH
3
. B. CH
3
CH
2
CH
2
COOH. C. C
2
H
5
COOCH
3
. D. HCOOCH(CH
3
)
2
.
Gii:
* Nhn xt: Vi lp lun X l cht hu c no, n chc, phn ng vi dung dch NaOH nn X l axit
hoc este (loi kh nng l phenol v M
phenol
94 > 88 (
OH H C
M
5 6
= 94)).
V nguyn tc ta c th gii tm ra kt qu (p n B).
Tuy nhin, nu lu mt cht ta c th tm ra p n m khng cn li gii:
Do X n chc phn ng vi NaOH d nn n
mui
= n
X
. M li c m
mui
> m
X
nn M
mui
> M
X
Vy R < M
Na
= 23. Vy R ch c th l H- hoc CH
3
-. Vy ch c p n B ng.
Lu :
+ Nu bi cho bit X (c th l axit hoc este, c cng thc RCOOR) phn ng vi NaOH, m
m
mui
> m
X
th R < M
Na
=23. R ch c th l H- hoc CH
3
-
+ Nu cho r X l este m c m
mui
> m
este
th n phi l este ca ancol CH
3
OH (M
R
= 15, R l CH
3
-)

> Bi 4: Cho 4,2 g este n chc no E tc dng ht vi dung dch NaOH ta thu c 4,76 g mui natri.
Vy cng thc cu to ca E c th l:
A. CH
3
COOCH
3
B. HCOOCH
3
C. CH
3
COOC
2
H
5
D. HCOOC
2
H
5
Gii:
Ta thy: Khi thy phn este m m
mui
>m
este
, vy gc R l CH
3
- loi p n C v D
V RCOOR RCOONa
Theo phng php tng gim khi lng: C 1 mol este phn ng th khi lng m
tng
= 23 15 = 8
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TI LIU LUYN THI I HC, CAO NG
GV: V Minh Hin 0905 260 732 *trang 3*


Khi lng tng thc t l 4,76 4,2 = 0,56 g
n
este
= n
mui
= 0,56/8 = 0,07 (mol) M
mui
= 4,76/0,07 = 68
R = 68 67 = 1 (R l H). Vy p n B ng.


2. Thu phn hn hp cc este

> Bi 5: Mt hn hp A gm 2 este n chc X, Y (M
X
< M
y
). un nng 12,5 gam hn hp A vi mt
lng dung dch NaOH va thu c 7,6 gam hn hp ancol no B, n chc c khi lng phn t hn
km nhau 14 vC v hn hp hai mui Z. t chy 7,6 gam B thu c 7,84 lt kh CO
2
(ktc) v 9 gam
H
2
O. Phn trm khi lng ca X, Y trong hn hp A ln lt l:
A. 59,2%; 40,8% B. 50%; 50% C. 40,8%; 59,2% C. 66,67%; 33,33%
Gii:
T bi A cha 2 este ca 2 ancol ng ng k tip
t cng thc chung ca ancol l OH H C
1 n 2 n +


2
CO
n = 7,84/22,4 = 0,35 mol;
O H
2
n = 9/18 = 0,5 mol n
B
=
O H
2
n -
2
CO
n = 0,5 0,35 = 0,15 mol
n =
B
CO
n
n
2

= 2,33. Vy B

mol 05 , 0 : OH H C
mol 1 , 0 : OH H C
7 3
5 2

t cng thc chung ca hai este l R COO R ' n
este
= n
NaOH
= n
mui
= n
Y
= 0,15 mol
m
Z
= 12,5 + 0,15.40 7,6 = 10,9 g mui M =
R
M + 67 =
15 , 0
9 , 10
=72,67
R
M = 5,67
Nh vy trong hai mui c mt mui l HCOONa
Hai este X, Y c th l:
(I)

7 3
5 2
H COOC H C
H HCOOC
y x
hoc (II)

5 2 y x
7 3
H COOC H C
H HCOOC

- Trng hp (I)

=
=
3 y
1 x

- Trng hp (II) 12x + y = 8 ( loi)
Vy A

% 8 , 40 : H COOC CH : Y
% 2 , 59 : H HCOOC : X
7 3 3
5 2
p n A
3. Thu phn este a chc
R(COOR)
n
+ nNaOH R(COONa)
n
+ nROH n
ancol
= n.n
mui
(RCOO)
n
R + nNaOH nRCOONa + R(OH)
n
n
mui
= n.n
ancol

R(COO)
n
R + nNaOH R(COONa)
n
+ R(OH)
n
, n
ancol
= n
mui
> Bi 6: Cho 0,01 mol mt este X ca axit hu c phn ng va vi 100 ml dung dch NaOH 0,2 M,
sn phm to thnh ch gm mt ancol Y v mt mui Z vi s mol bng nhau. Mt khc, khi x phng ho
hon ton 1,29 gam este bng mt lng va l 60 ml dung dch KOH 0,25 M, sau khi phn ng kt
thc em c cn dung dch c 1,665 gam mui khan. Cng thc ca este X l
A. C
2
H
4
(COO)
2
C
4
H
8
B. C
4
H
8
(COO)
2
C
2
H
4
C. C
2
H
4
(COOC
4
H
9
)
2
D. C
4
H
8
(COO C
2
H
5
)
2

Gii:
Ta c: n
Z
= n
Y
X ch cha chc este
S nhm chc este l:
X
NaOH
n
n
=
01 , 0
2 , 0 . 1 , 0
= 2 CT ca X c dng: R(COO)
2
R

T phn ng thy phn: n
axit
= n
mui
=
2
1
n
KOH
=
2
1
.0,06.0,25 = 0,0075 mol
M
mui
= M
R
+ 83.2 =
0075 , 0
665 , 1
= 222 M
R
= 56 R l: -C
4
H
8
-
M
este
= 1,29/0,0075 = 172 R + 2.44 + R = 172 R = 28 (-C
2
H
4
-)
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GV: V Minh Hin 0905 260 732 *trang 4*


Vy X l: C
4
H
8
(COO)
2
C
2
H
4
p n B.
Dng 02: Bi ton v phn ng este ho.

RCOOR' + H
2
O
H
2
SO
4
, t
0
RCOOH + R'-OH

c im ca phn ng este ho l thun nghch nn c th gn vi cc dng bi ton:
C Tnh hng s cn bng K:
K
cb
=
RCOOR' H
2
O
RCOOH R'OH

C Tnh hiu sut phn ng este ho:
H =
l-ng este thu -c theo thc t
l-ng este thu -c theo l thuyt
. 100%

C Tnh lng este to thnh hoc axit cacboxylic cn dng, lng ancol
> Bi 7: Hn hp A gm axit axetic v etanol. Chia A thnh ba phn bng nhau:
+ Phn 1 tc dng vi Kali d thy c 3,36 lt kh thot ra;
+ Phn 2 tc dng vi Na
2
CO
3
d thy c 1,12 lt kh CO
2
thot ra. Cc th tch kh o ktc;
+ Phn 3 c thm vo vi git dung dch H
2
SO
4
, sau un si hn hp mt thi gian. Bit hiu sut
ca phn ng este ho bng 60%. Khi lng este to thnh l bao nhiu?
A. 8,80 gam B. 5,20 gam C. 10,56 gam D. 5,28 gam
Gii:
Hn hp A

mol b : OH H C
mol a : COOH CH
5 2
3

= =
= = + =
mol 1 , 0 n 2 a
mol 3 , 0 n 2 b a n
2
2
CO
H A

=
=
mol 2 , 0 b
mol 1 , 0 a

V a < b ( hiu sut tnh theo axit) s mol este thc t thu c: n = 0,1.60% = mol 06 , 0
Khi lng este thc t thu c: m = 0,06.88 = 5,28 gam p n D
Dng 03: Bi ton v phn ng t chy este
- t cng thc ca este cn tm c dng: C
x
H
y
O
z
( x, z 2; y l s chn; y s 2x )
Phn ng chy: O H
y
xCO O
z y
x O H C
t
z y x 2 2 2
2
)
2 4
(
0
+ + +
C Nu t chy este A m thu c
O H
n
2
=
2
CO
n Este A l este no, n chc, mch h
C Nu t chy axit cacboxylic a chc hoc este a chc, s c t 2 lin kt t tr ln
O H
n
2
<
2
CO
n
C Phn ng t chy mui C
n
H
2n+1
COONa:
2C
n
H
2n+1
COONa + (3n+1)O
2
Na
2
CO
3
+ (2n+1)CO
2
+ (2n+1)H
2
O
> Bi 8: t chy hon ton mt lng hn hp hai este X, Y, n chc, no, mch h cn 3,976 lt oxi
(ktc) thu c 6,38 gam CO
2
. Cho lng este ny tc dng va vi KOH thu c hn hp hai ancol
k tip v 3,92 gam mui ca mt axit hu c. Cng thc cu to ca X, Y ln lt l
A. C
2
H
5
COOC
2
H
5
v C
2
H
5
COOC
3
H
7
B. C
2
H
5
COOCH
3
v C
2
H
5
COOC
2
H
5

C. CH
3
COOCH
3
v CH
3
COOC
2
H
5
D. HCOOC
3
H
7
v HCOOC
4
H
9

Gii:
t cng thc trung bnh ca 2 este X, Y l: C
n
H
2n+1
COO
1 m 2 m
H C
+

V X, Y u l este n chc, no, mch h nn:
O H
n
2
=
2
CO
n = 6,38/44 = 0,145 mol
m
este
+
2
O
m = 44.
2
CO
n + 18.
O H
n
2
m
este
= 3,31 gam
Ta c : m
O

(trong este)
= m
este
m
C
m
H
= 3,31 12.0,145 2.1.0,145 = 1,28 g
n
O
= 1,28/16 = 0,08 mol n
este
= 0,04 mol
n
mui
= n
este
= 0,04 mol M
mui
= 14n + 84 = 3,92/0,04 = 98 n = 1
Mt khc: este M = 3,31/0,04 = 82,75 12.1 + 46 + 14m = 82,75 m= 1,77
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GV: V Minh Hin 0905 260 732 *trang 5*


Vy: X l CH
3
COOCH
3
v Y l CH
3
COOC
2
H
5
p n C
Dng 04: Bi ton hn hp este v cc cht hu c khc ( ancol, axit cacboxylic, ...)
Khi bi cho 2 cht hu c khi tc dng vi NaOH hoc KOH m to ra:
C 2 mui v 1 ancol th c kh nng 2 cht hu c l
+ RCOOR v RCOOR c n
NaOH
= n
ROH

+ Hoc: RCOOR v RCOOH c n
NaOH
> n
ROH

C 1 mui v 1 ancol c nhng kh nng sau
+ RCOOR v ROH
+ Hoc: RCOOR v RCOOH
+ Hoc: RCOOH v ROH
C 1 mui v 2 ancol th c nhng kh nng sau
+ RCOOR v RCOOR
+ Hoc: RCOOR v ROH
> Bi 9: Hn hp A gm ba cht hu c X, Y, Z n chc ng phn ca nhau, u tc dng c vi
NaOH. un nng 13,875 gam hn hp A vi dung dch NaOH va thu c 15,375 gam hn hp mui
v hn hp ancol c t khi hi so vi H
2
bng 20,67. 136,5
0
C, 1 atm th tch hi ca 4,625 gam X bng
2,1 lt. Phn trm khi lng ca X, Y, Z (theo th t KLPT gc axit tng dn) ln lt l:
A. 40%; 40%; 20% B. 40%; 20%; 40% C. 25%; 50%; 25% D. 20%; 40%; 40%
Gii:
Ta c : mol 0625 , 0
) 5 , 136 273 ( 082 , 0
1 , 2 . 1
n
X
=
+
= M
X
= 74
0625 , 0
625 , 4
=
Mt khc: X, Y, Z n chc, tc dng c vi NaOH X, Y, Z l axit hoc este
CTPT dng: C
x
H
y
O
2
, d dng

=
=
6 y
3 x

Vy A

mol c : H HCOOC : Z
mol b : COOCH CH : Y
mol a : COOH H C : X
5 2
3 3
5 2

= + + =
=
+
+
=
= + + =
gam 375 , 15 c 68 b 82 a 96 m
67 , 20
) c b ( 2
c 46 b 32
d
mol 1875 , 0 c b a n
mui
H / ancol
A
2

=
=
=
075 , 0 c
0375 , 0 b
075 , 0 a

p n B
Dng 05: Bi ton xc nh cc ch s ca cht bo: ch s axit, ch s x phng ho, ch s iot...
lm cc bi tp dng ny, cn nm vng cc khi nim sau:
O Ch s axit (a
axit
): l s mg KOH cn trung ho axit bo t do c trong 1 gam cht bo
O Ch s x phng ho (a
xp
): l s mg KOH cn x phng ho glixerit v trung ho axit bo t do c
trong 1 g cht bo
O Ch s este (a
este
): l s mg KOH cn x phng ho glixerit ca 1 gam cht bo
O Ch s iot (a
iot
): l s gam iot c th cng vo ni i C=C ca 100 gam cht bo
> Bi 10: x phng ho 35 kg triolein cn 4,939 kg NaOH thu c 36,207 kg x phng. Ch s axit
ca mu cht bo trn l
A. 7 B. 8 C. 9 D. 10
Gii:
Theo bi: n
RCOONa (x phng)
= mol 102 , 119
304
1000 . 207 , 36
=
n
NaOH
(dng x phng ho) = 119,102 mol
n
NaOH
( trung ho axit bo t do) = mol 375 , 4 102 , 119
40
1000 . 939 , 4
=
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GV: V Minh Hin 0905 260 732 *trang 6*


n
KOH
( trung ho axit bo t do) = 4,375 mol
m
KOH
(trong 1 g cht bo) = mg 7 1000 .
35000
56 . 375 , 4
=
ch s axit = 7 p n A

> Bi 11: Mt loi cht bo c ch s x phng ho l 188,72 cha axit stearic v tristearin. trung
ho axit t do c trong 100 g mu cht bo trn th cn bao nhiu ml dung dch NaOH 0,05 M
A. 100 ml B. 675 ml C. 200 ml D. 125 ml
Gii :
a
xp
= 188,72.10
-3
phn ng vi 100 g cht bo cn m
KOH
= 188,72.10
-3
.100 = 18,872 g
n
KOH
= ) ( 337 , 0
56
872 , 18
mol = n
NaOH
= 0,337 mol

= + =
= + =
g 100 n 890 n 284 m
mol 337 , 0 n 3 n n
tristearin axit chtbo
tristearin axit NaOH

=
=
mol 109 , 0 n
mol 01 , 0 n
tristearin
axit

Vy: Trong 100 g mu cht bo c 0,01 mol axit t do n
NaOH (p)
= 0,01 mol
V
dd NaOH
= 200 ml p n C
BI TP P DNG
Cu 1: Mnh khng ng l:
A. CH
3
CH
2
COOCH=CH
2
tc dng vi dung dch NaOH thu c anehit v mui.
B. CH
3
CH
2
COOCH=CH
2
tc dng c vi dung dch Br
2
.
C. CH
3
CH
2
COOCH=CH
2
c th trng hp to polime.
D. CH
3
CH
2
COOCH=CH
2
cng dy ng ng vi CH
2
=CHCOOCH
3
.
Cu 2: S ng phn este ng vi cng thc phn t C
4
H
8
O
2
l
A. 4. B. 6. C. 5. D. 2.
Cu 3: S hp cht l ng phn cu to, c cng cng thc phn t C
4
H
8
O
2
, tc dng c vi dung dch
NaOH nhng khng tc dng c vi Na l
A. 1. B. 3. C. 4. D. 2.
Cu 4: Pht biu ng l:
A. Phn ng thy phn este trong mi trng axit l phn ng thun nghch.
B. Phn ng gia axit v ru khi c H
2
SO
4
c l phn ng mt chiu.
C. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v (ancol).
D. Khi thy phn cht bo lun thu c C
2
H
4
(OH)
2
.
Cu 5: Pht biu no sau y sai?
A. S nguyn t hiro trong phn t este n v a chc lun l mt s chn.
B. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol.
C. Nhit si ca este thp hn hn so vi ancol c cng phn t khi.
D. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn.
Cu 6: Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na,
Cu(OH)
2
, CH
3
OH, dung dch Br
2
, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l
A. 5. B. 2. C. 4. D. 3.
Cu 7: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO
3
trong
NH
3
. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O
2
(cng iu kin v nhit v p
sut). Khi t chy hon ton 1 gam X th th tch kh CO
2
thu c vt qu 0,7 lt ( ktc). Cng thc cu
to ca X l
A. HCOOC
2
H
5
. B. HOOC-CHO. C. CH
3
COOCH
3
. D. O=CH-CH
2
-CH
2
OH.
Cu 8: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi
ng bng th tch ca 0,7 gam N
2
(o cng iu kin). Cng thc cu to thu gn ca X v Y l
A. C
2
H
5
COOCH
3
v HCOOCH(CH
3
)
2
. B. C
2
H
3
COOC
2
H
5
v C
2
H
5
COOC
2
H
3
.
C. HCOOCH
2
CH
2
CH
3
v CH
3
COOC
2
H
5
. D. HCOOC
2
H
5
v CH
3
COOCH
3
.
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Cu 9: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va
3,976 lt kh O
2
( ktc), thu c 6,38 gam CO
2
. Mt khc, X tc dng vi dung dch NaOH, thu c mt
mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l
A. C
2
H
4
O
2
v C
3
H
6
O
2
. B. C
2
H
4
O
2
v C
5
H
10
O
2
.
C. C
3
H
6
O
2
v C
4
H
8
O
2
. D. C
3
H
4
O
2
v C
4
H
6
O
2
.
Cu 10: Khi t chy hon ton mt este no, n chc th s mol CO
2
sinh ra bng s mol O
2
phn ng.
Tn gi ca este l:
A. metyl axetat. B. etyl axetat. C. metyl fomiat. D. n-propyl axetat.
Cu 11: X phng ho mt hp cht c cng thc phn t C
10
H
14
O
6
trong dung dch NaOH (d), thu c
glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l:
A. HCOONa, CHC-COONa v CH
3
-CH
2
-COONa.
B. CH
2
=CH-COONa, HCOONa v CHC-COONa.
C. CH
3
-COONa, HCOONa v CH
3
-CH=CH-COONa.
D. CH
2
=CH-COONa, CH
3
-CH
2
-COONa v HCOONa.
Cu 12: Mt este c cng thc phn t l C
4
H
6
O
2
, khi thu phn trong mi trng axit thu c
axetanehit. Cng thc cu to thu gn ca este l
A. HCOO-C(CH
3
)=CH
2
. B. HCOO-CH=CH-CH
3
.
C. CH
2
=CH-COO-CH
3
. D. CH
3
COO-CH=CH
2
.
Cu 13: Thy phn este c cng thc phn t C
4
H
8
O
2
(vi xc tc axit), thu c 2 sn phm hu c X v
Y. T X c th iu ch trc tip ra Y. Vy cht X l
A. etyl axetat. B. axit fomic. C. ru etylic. D. ru metylic.
Cu 14: Este X c cc c im sau:
- t chy hon ton X to thnh CO
2
v H
2
O c s mol bng nhau;
- Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s
nguyn t cacbon bng mt na s nguyn t cacbon trong X);
Pht biu khng ng l:
A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO
2
v 2 mol H
2
O.
B. Cht Y tan v hn trong nc.
C. Cht X thuc loi este no, n chc.
D. un Z vi dung dch H
2
SO
4
c 170
0
C thu c anken.
Cu 15: Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng
ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X?
A. 5. B. 4. C. 2. D. 3.
Cu 16: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c
cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO
3
(hoc Ag
2
O) trong dung dch NH
3
thu c cht
hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l
A. CH
3
COOCH=CH-CH
3
. B. CH
3
COOCH=CH
2
.
C. HCOOCH
3
. D. HCOOCH=CH
2
.
Cu 17: Cht hu c X c cng thc phn t C
5
H
8
O
2
. Cho 5 gam X tc dng va ht vi dung dch NaOH,
thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l
A. HCOOCH
2
CH=CHCH
3
. B. CH
3
COOC(CH
3
)=CH
2
.
C. HCOOCH=CHCH
2
CH
3
. D. HCOOC(CH
3
)=CHCH
3
.
Cu 18: Hai cht hu c X
1
v X
2
u c khi lng phn t bng 60 vC. X
1
c kh nng phn ng vi:
Na, NaOH, Na
2
CO
3
. X
2
phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca
X
1
, X
2
ln lt l:
A. CH
3
-COOH, H-COO-CH
3
. B. H-COO-CH
3
, CH
3
-COOH.
C. CH
3
-COOH, CH
3
-COO-CH
3
. D. (CH
3
)
2
CH-OH, H-COO-CH
3
.
Cu 19: Cht hu c X c cng thc phn t C
4
H
6
O
4
tc dng vi dung dch NaOH (un nng) theo
phng trnh phn ng: C
4
H
6
O
4
+ 2NaOH 2Z + Y. oxi ho ht a mol Y th cn va 2a mol CuO
(un nng), sau phn ng to thnh a mol cht T (bit Y, Z, T l cc hp cht hu c). Khi lng phn t
ca T l
A. 118 vC. B. 58 vC. C. 82 vC. D. 44 vC.
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Cu 20: Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung dch cha
11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht vi Na
thu c 3,36 lt kh H
2
( ktc). Hai cht hu c l:
A. mt este v mt ancol. B. hai axit.
C. hai este. D. mt este v mt axit.
Cu 21: Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi 500 ml dung dch
KOH 1M. Sau phn ng, thu c hn hp Y gm hai mui ca hai axit cacboxylic v mt ru (ancol).
Cho ton b lng ru thu c trn tc dng vi Na (d), sinh ra 3,36 lt H
2
( ktc). Hn hp X gm
A. mt axit v mt ru. B. mt axit v mt este.
C. hai este. D. mt este v mt ru.
Cu 22: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH
0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn,
sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)
2
(d) th khi lng bnh tng 6,82
gam. Cng thc ca hai hp cht hu c trong X l:
A. CH
3
COOH v CH
3
COOC
2
H
5
. B. HCOOH v HCOOC
2
H
5
.
C. HCOOH v HCOOC
3
H
7
. D. C
2
H
5
COOH v C
2
H
5
COOCH
3
.
Cu 23: X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC
2
H
5
v CH
3
COOCH
3
bng dung
dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l
A. 300 ml. B. 400 ml. C. 150 ml. D. 200 ml.
Cu 24: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra
hon ton, c cn dung dch thu c cht rn khan c khi lng l
A. 10,4 gam. B. 3,28 gam. C. 8,2 gam. D. 8,56 gam.
Cu 25: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi
so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M,
thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l
A. 26,25. B. 24,25. C. 27,75. D. 29,75.
Cu 26: X l mt este no n chc, c t khi hi i vi CH
4
l 5,5. Nu em un 2,2 gam este X vi
dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l
A. C
2
H
5
COOCH
3
. B. HCOOCH
2
CH
2
CH
3
. C. HCOOCH(CH
3
)
2
. D. CH
3
COOC
2
H
5
.
Cu 27: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt
CO
2
( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi
phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l
A. etyl axetat. B. metyl propionat. C. etyl propionat. D. isopropyl axetat.
Cu 28: Este n chc X c t khi hi so vi CH
4
l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch
KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to
ca X l
A. CH
2
=CH-CH
2
-COO-CH
3
. B. CH
3
-CH
2
-COO-CH=CH
2
.
C. CH
2
=CH-COO-CH
2
-CH
3
. D. CH
3
-COO-CH=CH-CH
3
.
Cu 29: Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M.
Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l
A. CH
3
COOCH=CHCH
3
. B. CH
2
=CHCOOC
2
H
5
.
C. CH
2
=CHCH
2
COOCH
3
. D. C
2
H
5
COOCH=CH
2
.
Cu 30: Hp cht hu c no, a chc X c cng thc phn t C
7
H
12
O
4
. Cho 0,1 mol X tc dng va vi
100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu
gn ca X l
A. CH
3
COO-(CH
2
)
2
-OOCC
2
H
5
. B. CH
3
OOC-(CH
2
)
2
-COOC
2
H
5
.
C. CH
3
COO-(CH
2
)
2
-COOC
2
H
5
. D. CH
3
OOC-CH
2
-COO-C
3
H
7
.
Cu 31: X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam
mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai
este l
A. C
2
H
5
COOCH
3
v C
2
H
5
COOC
2
H
5
. B. CH
3
COOC
2
H
5
v CH
3
COOC
3
H
7
.
C. HCOOCH
3
v HCOOC
2
H
5
. D. CH
3
COOCH
3
v CH
3
COOC
2
H
5
.
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Cu 32: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau
phn ng thu c khi lng x phng l
A. 17,80 gam. B. 18,38 gam. C. 18,24 gam. D. 16,68 gam.
Cu 33: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo.
Hai loi axit bo l:
A. C
17
H
31
COOH v C
17
H
33
COOH. B. C
15
H
31
COOH v C
17
H
35
COOH.
C. C
17
H
33
COOH v C
17
H
35
COOH. D. C
17
H
33
COOH v C
15
H
31
COOH.
Cu 34: Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C
17
H
35
COOH v C
15
H
31
COOH, s loi
trieste c to ra ti a l
A. 4. B. 3. C. 6. D. 5.
Cu 35: un nng 6,0 gam CH
3
COOH vi 6,0 gam C
2
H
5
OH (c H
2
SO
4
lm xc tc, hiu sut phn ng
este ho bng 50%). Khi lng este to thnh l
A. 8,8 gam. B. 6,0 gam. C. 5,2 gam. D. 4,4 gam.
Cu 36: Hn hp X gm axit HCOOH v axit CH
3
COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng
vi 5,75 gam C
2
H
5
OH (c xc tc H
2
SO
4
c) thu c m gam hn hp este (hiu sut ca cc phn ng
este ho u bng 80%). Gi tr ca m l
A. 10,12. B. 16,20. C. 8,10. D. 6,48.
Cu 37: un 12 gam axit axetic vi 13,8 gam etanol (c H
2
SO
4
c lm xc tc) n khi phn ng t ti
trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l
A. 55%. B. 75%. C. 50%. D. 62,5%.
Cu 38. Khi thc hin phn ng este ho 1 mol CH
3
COOH v 1 mol C
2
H
5
OH, lng este ln nht thu c
l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH
3
COOH cn s
mol C
2
H
5
OH l (bit cc phn ng este ho thc hin cng nhit )
A. 0,342. B. 2,412. C. 2,925. D. 0,456.
Cu 39. trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M.
Ch s axit ca mu cht bo trn l
A. 5,5. B. 6,0. C. 7,2. D. 4,8.
Cu 40: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C
5
H
10
O
2
, phn ng
c vi dung dch NaOH nhng khng c phn ng trng bc l
A. 4. B. 5. C. 8. D. 9.
Cu 41: Tng s cht hu c mch h, c cng cng thc phn t C
2
H
4
O
2
l
A. 2. B. 4. C. 1. D. 3.
Cu 42: Cho s chuyn ho: Z Y X Triolein
HCl t du NaOH t Ni du H

+ + +
0
0
2
, ) , (
. Tn ca Z l
A. axit stearic. B. axit panmitic. C. axit oleic. D. axit linoleic.
Cu 43: Cho s chuyn ho: E T Z Y X H C
xt t OH CH t O CuO NaOH Br dd

, , ,
6 3
0
3
0
2 2
(este a
chc). Tn gi ca Y l
A. glixerol. B. propan-2-ol. C. propan-1,2-iol. D. propan-1,3-iol.
Cu 44: Hp cht hu c mch h X c cng thc phn t C
5
H
10
O. Cht X khng phn ng vi Na, tho
mn s chuyn ho sau:
+ + C t xt COOH CH C t xt H
Y X
0
3
0
2
, / , /
Este c mi chui chn. Tn ca X l
A. 2,2-imetylpropanal. B. 3-metylbutanal.
C. pentanal. D. 2-metylbutanal.
Cu 45: Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong
dy ng ng (M
X
< M
Y
). t chy hon ton m gam Z cn dng 6,16 lt kh O
2
(ktc), thu c 5,6 lt kh
CO
2
(ktc) v 4,5 gam H
2
O. Cng thc este X v gi tr ca m tng ng l
A. HCOOCH
3
v 6,7. B. CH
3
COOCH
3
v 6,7.
C. HCOOC
2
H
5
v 9,5. D. (HCOO)
2
C
2
H
4
v 6,6.
Cu 46: Thu phn cht hu c X trong dung dch NaOH (d), un nng, thu c sn phm gm 2 mui
v ancol etylic. Cht X l:
A. ClCH
2
COOC
2
H
5
. B. CH
3
COOCH
2
CH
3
.
C. CH
3
COOCH(Cl)CH
3
. D. CH
3
COOCH
2
CH
2
Cl.
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Cu 47: Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu
c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l
A. HCOOH v C
2
H
5
COOH. B. HCOOH v CH
3
COOH.
C. CH
3
COOH v C
2
H
5
COOH. D. C
2
H
5
COOH v C
3
H
7
COOH.
Cu 48: Cho 0,15 mol H
2
NC
3
H
5
(COOH)
2
(axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung
dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng
l
A. 0,50. B. 0,65. C. 0,55. D. 0,70.
Cu 49: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c
th tch kh CO
2
bng 6/7 th tch kh O
2
phn ng (cc th tch kh o cng iu kin). Cho m gam X
tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam
cht rn khan. Gi tr ca m l
A. 6,66. B. 7,20. C. 10,56. D. 8,88.
Cu 50: Cht bo A c ch s axit l 7. x phng ho 10kg A, ngi ta un nng n vi dung dch cha
1,420 kg NaOH. Sau khi phn ng xy ra hon ton trung ho hn hp cn dng 500ml dung dch HCl
1M. Khi lng x phng (kg) thu c l
A. 10,3425. B. 10,3435. C. 10,3445. D. 10,3455.
Cu 51: Cho cc este : etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4), phenyl axetat (5). Dy
gm cc este u phn ng c vi dung dch NaOH (un nng) sinh ra ancol l
A. (1), (2), (3). B. (1), (3), (4). C. (2), (3), (5). D. (3), (4), (5).
Cu 52: Cho cc pht biu sau:
(a) Cht bo c gi chung l triglixerit hay triaxylglixerol.
(b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c.
(c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch.
(d) Tristearin, triolein c cng thc ln lt l (C
17
H
33
COO)
3
C
3
H
5
v (C
17
H
35
COO)
3
C
3
H
5
.
S pht biu ng l
A. 3. B. 2. C. 4. D. 1.
Cu 53: Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng th tch ca 1,6 gam
kh oxi (o cng iu kin). Mt khc, thy phn hon ton 11 gam X bng dung dch NaOH d, thu c
10,25 gam mui. Cng thc ca X l
A. C
2
H
5
COOCH
3
. B. CH
3
COOC
2
H
5
. C. C
2
H
5
COOC
2
H
5
. D. HCOOC
3
H
7
Cu 54: t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v mt ancol
n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO
2
v 0,4 mol H
2
O. Thc
hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l
A. 4,08. B. 6,12. C. 8,16. D. 2,04.
Cu 55: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O
2
, thu c
23,52 lt kh CO
2
v 18,9 gam H
2
O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn
dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z
(M
Y
< M
Z
). Cc th tch kh u o iu kin tiu chun. T l a : b l
A. 2 : 3. B. 4 : 3. C. 3 : 2. D. 3 : 5.
Cu 56: Thy phn este X mch h c cng thc phn t C
4
H
6
O
2
, sn phm thu c c kh nng trng
bc. S este X tha mn tnh cht trn l
A. 4. B. 3. C. 6. D. 5.
Cu 57: t chy hon ton m gam hn hp X gm hai ancol n chc, cng dy ng ng, thu c
15,68 lt kh CO
2
(ktc) v 17,1 gam nc. Mt khc, thc hin phn ng este ha m gam X vi 15,6 gam
axit axetic, thu c a gam este. Bit hiu sut phn ng este ha ca hai ancol u bng 60%. Gi tr ca a
l
A. 15,48. B. 25,79. C. 24,80. D. 14,88.
Cu 58: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s
nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th
lng NaOH phn ng l 10 gam. Gi tr ca m l
A. 14,5. B. 17,5. C. 15,5. D. 16,5.
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TI LIU LUYN THI I HC, CAO NG
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Cu 59: S trieste khi thy phn u thu c sn phm gm glixerol, axit CH
3
COOH v axit C
2
H
5
COOH
l
A. 9. B. 4. C. 6. D. 2.
Cu 60: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol
n chc) thu c 0,22 gam CO
2
v 0,09 gam H
2
O. S este ng phn ca X l:
A. 2 B. 5 C. 6 D. 4
Cu 61: x phng ho hon ton 52,8 gam hn hp hai este no, n chc , mch h l ng phn ca
nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc.
Cng thc ca hai este l
A. CH
3
COOC
2
H
5
v HCOOC
3
H
7
B. C
2
H
5
COOC
2
H
5
v C
3
H
7
COOCH
3

C. HCOOC
4
H
9
v CH
3
COOC
3
H
7
D. C
2
H
5
COOCH
3
v CH
3
COOC
2
H
5

Cu 62: Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm
chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH)
2
th vn thu c kt ta.
Thu phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng
nhau. Phn trm khi lng ca oxi trong X l
A. 43,24% B. 53,33% C. 37,21% D. 36,36%
Cu 63: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu
c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l:
A. 31 gam B. 32,36 gam C. 30 gam D. 31,45 gam
Cu 64: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc
th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng
phn cu to ca X tha mn cc tnh cht trn l
A. 4 B. 5 C. 6 D. 2
Cu 65: Cng thc ca triolein l
A. (CH
3
[CH
2
]
16
COO)
3
C
3
H
5
B. (CH
3
[CH
2
]
7
CH=CH[CH
2
]
5
COO)
3
C
3
H
5
C. (CH
3
[CH
2
]
7
CH=CH[CH
2
]
7
COO)
3
C
3
H
5
D. (CH
3
[CH
2
]
14
COO)
3
C
3
H
5
.
Cu 66: Pht biu no sau y l ng?
A. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ha hc, ch cn dng
thuc th l nc brom.
B. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip
thc phm, m phm.
C. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi
thm ca chui chn.
D. Trong phn ng este ha gia CH
3
COOH vi CH
3
OH, H
2
O to nn t -OH trong nhm -COOH ca
axit v H trong nhm -OH ca ancol.
Cu 67: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c
2,16 gam H
2
O. Phn trm s mol ca vinyl axetat trong X l:
A. 25% B. 27,92% C. 72,08% D. 75%
Cu 68: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic,
ri hp th ton b sn phm chy vo dung dch Ca(OH)
2
(d). Sau phn ng thu c 18 gam kt ta v
dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)
2
ban u thay i nh th no?
A. Tng 2,70 gam. B. Gim 7,74 gam. C. Tng 7,92 gam. D. Gim 7,38 gam.
Cu 69: phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y (M
x
< M
Y
) cn va
300 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton thu c 24,6 gam mui ca mt axit
hu c v m gam mt ancol. t chy hon ton lng ancol trn thu c 4,48 lt CO
2
(ktc) v 5,4 gam
H
2
O. Cng thc ca Y l
A. CH
3
COOC
2
H
5
B. CH
3
COOCH
3
C. CH
2
=CHCOOCH
3
D. C
2
H
5
COOC
2
H
5

Cu 70: Cho s phn ng:
Este X (C
4
H
n
O
2
)
0
NaOH
t
+
Y
3 3
0
/ AgNO NH
t
+
Z
0
NaOH
t
+
C
2
H
3
O
2
Na.
Cng thc cu to ca X tha mn s cho l
A. CH
2
=CHCOOCH
3
. B. CH
3
COOCH
2
CH
3
. C. HCOOCH
2
CH
2
CH
3
. D. CH
3
COOCH=CH
2
.
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