B GIO DC V O TO CHNH THC

( thi c 05 trang)

THI TUYN SINH I HC, CAO NG NM 2007 Mn thi: HO HC, Khi B Thi gian lm bi: 90 pht. M thi 285

H, tn th sinh:.......................................................................... S bo danh:............................................................................
PHN CHUNG CHO TT C TH SINH (44 cu, t cu 1 n cu 44): Cu 1: Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l (cho H = 1, C =12, O = 16) A. 0,92. B. 0,32. C. 0,64. D. 0,46. Cu 2: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l A. 1. B. 4. C. 3. D. 2. Cu 3: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. Cu 4: Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s A. nhn 13 electron. B. nhn 12 electron. C. nhng 13 electron. D. nhng 12 electron. Cu 5: Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s electron ca anion v tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi ha duy nht. Cng thc XY l A. AlN. B. MgO. C. LiF. D. NaF. Cu 6: Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, NaCl, Na2SO4. B. HNO3, Ca(OH)2, KHSO4, Na2SO4. D. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. C. NaCl, Na2SO4, Ca(OH)2. Cu 7: Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6 gam. Gi tr ln nht ca V l (cho H = 1, O = 16, Al = 27) A. 1,2. B. 1,8. C. 2,4. D. 2. Cu 8: Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,9oC, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l A. C2H4 O2. B. CH2O2. C. C4H8O2. D. C3H6O2. Cu 9: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l A. 2. B. 5. C. 4. D. 3. Cu 10: Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c (cho Fe = 56) A. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4. B. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d. C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4. D. 0,12 mol FeSO4. Cu 11: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 2. B. 4. C. 3. D. 1.

Trang 1/5 - M thi 285

Cu 12: Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong dung dch HNO3 (d), thot ra 0,56 lt ( ktc) NO (l sn phm kh duy nht). Gi tr ca m l (cho O = 16, Fe = 56) A. 2,52. B. 2,22. C. 2,62. D. 2,32. Cu 13: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l (cho H = 1, C =12, N = 14, O = 16) A. 42 kg. B. 10 kg. C. 30 kg. D. 21 kg. Cu 14: Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100oC. Sau khi phn ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l (cho Cl = 35,5; K = 39) A. 0,24M. B. 0,48M. C. 0,4M. D. 0,2M. Cu 15: t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l A. 8,96. B. 11,2. C. 6,72. D. 4,48. Cu 16: Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. protit lun cha chc hiroxyl. B. protit lun cha nit. C. protit lun l cht hu c no. D. protit c khi lng phn t ln hn. Cu 17: Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm IIA (phn nhm chnh nhm II) tc dng ht vi dung dch HCl (d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l (cho Be = 9, Mg = 24, Ca = 40, Sr = 87, Ba = 137) A. Be v Mg. B. Mg v Ca. C. Sr v Ba. D. Ca v Sr. Cu 18: Dy gm cc cht c dng tng hp cao su Buna-S l: A. CH2=C(CH3)-CH=CH2, C6H5CH=CH2. B. CH2=CH-CH=CH2, C6H5CH=CH2. C. CH2=CH-CH=CH2, lu hunh. D. CH2=CH-CH=CH2, CH3-CH=CH2. Cu 19: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. Cu 20: Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic (Z) v imetyl ete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l A. T, Z, Y, X. B. Z, T, Y, X. C. T, X, Y, Z. D. Y, T, X, Z. Cu 21: Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh. Nu cng cho m gam X vo dung dch NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na trong X l (bit cc th tch kh o trong cng iu kin, cho Na = 23, Al = 27) A. 39,87%. B. 77,31%. C. 49,87%. D. 29,87%. Cu 22: Nung 13,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht rn v kh X. Lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng l (cho H = 1, C = 12, O = 16, Na = 23) A. 5,8 gam. B. 6,5 gam. C. 4,2 gam. D. 6,3 gam. Cu 23: Khi cho Cu tc dng vi dung dch cha H2SO4 long v NaNO3, vai tr ca NaNO3 trong phn ng l A. cht xc tc. B. cht oxi ho. C. mi trng. D. cht kh. Cu 24: X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l (cho H = 1, C =12, O = 16, Na = 23) A. HCOOCH2CH2CH3. B. C2H5COOCH3. C. CH3COOC2H5. D. HCOOCH(CH3)2. Cu 25: Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O (d), un nng, dung dch thu c cha A. NaCl, NaOH, BaCl2. B. NaCl, NaOH. C. NaCl, NaHCO3, NH4Cl, BaCl2. D. NaCl.

Trang 2/5 - M thi 285

Cu 26: Cho cc phn ng xy ra sau y: (1) AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag (2) Mn + 2HCl MnCl2 + H2 Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l B. Ag+, Fe3+, H+, Mn2+. A. Mn2+, H+, Fe3+, Ag+. C. Ag+ , Mn2+, H+, Fe3+. D. Mn2+, H+, Ag+, Fe3+. Cu 27: trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l (cho H = 1, C = 12, O = 16, Na = 23) A. CH3COOH. B. HCOOH. C. C2H5COOH. D. C3H7COOH. Cu 28: Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to ra ti a l A. 6. B. 3. C. 5. D. 4. Cu 29: Trong phng th nghim, ngi ta thng iu ch HNO3 t A. NaNO2 v H2SO4 c. B. NaNO3 v H2SO4 c. C. NH3 v O2. D. NaNO3 v HCl c. Cu 30: C th phn bit 3 dung dch: KOH, HCl, H2SO4 (long) bng mt thuc th l A. giy qu tm. B. Zn. C. Al. D. BaCO3. Cu 31: C 4 dung dch ring bit: a) HCl, b) CuCl2, c) FeCl3, d) HCl c ln CuCl2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l A. 0. B. 1. C. 2. D. 3. Cu 32: in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn xp). dung dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l (bit ion SO42- khng b in phn trong dung dch) A. b > 2a. B. b = 2a. C. b < 2a. D. 2b = a. Cu 33: Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch (gm H2SO4 0,0375M v HCl 0,0125M), thu c dung dch X. Gi tr pH ca dung dch X l A. 7. B. 2. C. 1. D. 6. Cu 34: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l (cho C =12, O = 16) A. C2H5C6H4OH. B. HOCH2C6H4COOH. C. HOC6H4CH2OH. D. C6H4(OH)2. Cu 35: Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII), theo chiu tng ca in tch ht nhn nguyn t th A. tnh phi kim gim dn, bn knh nguyn t tng dn. B. tnh kim loi tng dn, m in tng dn. C. m in gim dn, tnh phi kim tng dn. D. tnh kim loi tng dn, bn knh nguyn t gim dn. Cu 36: thu c Al2O3 t hn hp Al2O3 v Fe2O3, ngi ta ln lt: A. dng kh H2 nhit cao, dung dch NaOH (d). B. dng kh CO nhit cao, dung dch HCl (d). C. dng dung dch NaOH (d), dung dch HCl (d), ri nung nng. D. dng dung dch NaOH (d), kh CO2 (d), ri nung nng. Cu 37: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l (cho C = 12, O = 16) A. C2H4(OH)2. B. C3H7OH. C. C3H5(OH)3. D. C3H6(OH)2. Cu 38: Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu c dung dch ch cha mt cht tan v kim loi d. Cht tan l A. Cu(NO3)2. B. HNO3. C. Fe(NO3)2. D. Fe(NO3)3. Cu 39: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 4. B. 6. C. 5. D. 3.

Trang 3/5 - M thi 285

Cu 40: Thc hin hai th nghim: 1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. 2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l (cho Cu = 64) A. V2 = V1. B. V2 = 2V1. C. V2 = 2,5V1. D. V2 = 1,5V1. Cu 41: t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. no, n chc. B. khng no c hai ni i, n chc. C. khng no c mt ni i, n chc. D. no, hai chc. Cu 42: Pht biu khng ng l A. Dung dch fructoz ho tan c Cu(OH)2. B. Thy phn (xc tc H+, to) saccaroz cng nh mantoz u cho cng mt monosaccarit. C. Sn phm thy phn xenluloz (xc tc H+, to) c th tham gia phn ng trng gng. D. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O. Cu 43: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l (cho H = 1, C = 12, N = 14, O = 16) B. C2H3COOC2H5 v C2H5COOC2H3. A. HCOOC2H5 v CH3COOCH3. C. C2H5COOCH3 v HCOOCH(CH3)2. D. HCOOCH2CH2CH3 v CH3COOC2H5. Cu 44: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II). Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50): Cu 45: Cho 4 phn ng: (1) Fe + 2HCl FeCl2 + H2 (2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O (3) BaCl2 + Na2CO3 BaCO3 + 2NaCl (4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4 Cc phn ng thuc loi phn ng axit - baz l A. (2), (4). B. (3), (4). C. (2), (3). D. (1), (2). Cu 46: Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic. B. etyl axetat. C. axit fomic. D. ru etylic. Cu 47: Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn hp bt ban u l (cho Fe = 56, Cu = 64, Zn = 65) A. 90,27%. B. 85,30%. C. 82,20%. D. 12,67%. Cu 48: Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng (d), thot ra 0,112 lt ( ktc) kh SO2 (l sn phm kh duy nht). Cng thc ca hp cht st l A. FeS. B. FeS2. C. FeO D. FeCO3. Cu 49: Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l (cho H = 1, C = 12, O = 16) A. HCHO. B. C2H3CHO. C. C2H5CHO. D. CH3CHO. Cu 50: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80) A. 3,3-imetylhecxan. B. 2,2-imetylpropan. C. isopentan. D. 2,2,3-trimetylpentan.
Trang 4/5 - M thi 285

Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56): Cu 51: Trong pin in ha Zn-Cu, qu trnh kh trong pin l A. Zn2+ + 2e Zn. B. Cu Cu2+ + 2e. C. Cu2+ + 2e Cu. D. Zn Zn2+ + 2e. Cu 52: Cho cc phn ng: to to (1) Cu2O + Cu2S (2) Cu(NO3)2 to to (3) CuO + CO (4) CuO + NH3 S phn ng to ra kim loi Cu l A. 2. B. 3. C. 1. D. 4. Cu 53: Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l (cho H = 1, C = 12, N = 14, O = 16) A. 70%. B. 50%. C. 60%. D. 80%. Cu 54: Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton, thu c 23,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl (d) thot ra V lt kh H2 ( ktc). Gi tr ca V l (cho O = 16, Al = 27, Cr = 52) A. 7,84. B. 4,48. C. 3,36. D. 10,08. Cu 55: Cho s phn ng: + HONO + CuO + CH3I Z. NH3 Y X to (t l mol 1:1) Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l: A. C2H5OH, HCHO. B. C2H5OH, CH3CHO. C. CH3OH, HCHO. D. CH3OH, HCOOH. Cu 56: Dy gm cc cht u phn ng vi phenol l: A. dung dch NaCl, dung dch NaOH, kim loi Na. B. nc brom, anhirit axetic, dung dch NaOH. C. nc brom, axit axetic, dung dch NaOH. D. nc brom, anehit axetic, dung dch NaOH.
-----------------------------------------------

----------------------------------------------------- HT ----------

Trang 5/5 - M thi 285