Experiment No.

5 Vapour Pressure Data Representation by Polynomials and Equations

b):
Temperature T 0C
-36.7
-19.6
-11.5

Pressure P mmHg
1
5
10

-2.6
7.6
15.4
26.1
42.2
60.6
80.1

20
40
60
100
200
400
760

A
8.751446832

B
2035.168944

c): log P = A - B/(T+C)

A
B
C

1.630036644
-2.809390044
-1.649071938

a):
a0
a1

64.40597198
5.890719588

Clausius - Clayperon equation: logP = A-B/(T+273.15)

P - mmHg
0
T- C
Initial Guess: A=1 B=1 C=1

2
log P
A-B/(T+273.15) Residue Residue
0
0.144261617 0.144262 0.020811
0.69897
0.724750149
0.02578 0.000665
1
0.973235695 -0.02676 0.000716
1.30103
1.229107361 -0.07192 0.005173
1.60206
1.502403398 -0.09966 0.009931
1.7781513
1.69835744
-0.07979 0.006367
2
1.950548105 -0.04945 0.002445
2.30103
2.2977638
-0.00327 1.07E-05
2.60206
2.653562356 0.051502 0.002652
2.8808136 2.990175936 0.109362 0.01196

log P
0
0.69897
1
1.30103
1.60206
1.7781513
2
2.30103
2.60206
2.8808136

A - B/(T+C)
1.556778286
1.49782428
1.416379737
0.968859313
2.102129403
1.83434213
1.744935761
1.699317181
1.677693062
1.665847439

POLY1
-151.7834369
-51.05213195
-3.337303282

SUMSQ

0.060732

Residue
1.556778
0.798854
0.41638
-0.33217
0.500069
0.056191
-0.25506
-0.60171
-0.92437
-1.21497

Residue2
2.423559
0.638168
0.173372
0.110337
0.250069
0.003157
0.065058
0.362058
0.854454
1.476143

SUMSQ

6.356376

P
1
5
10

Residue2
Residue
152.7834 23342.77859
56.05213 3141.841496
13.3373 177.8836588

49.09010105
109.1754409
155.1230536
218.1537532
312.9943386
421.383579
536.252611

a0
a1
a2

a0
a1
a2
a3

a0
a1
a2
a3
a4

-0.582064593
2.067148356
0.086152565

24.45936698
1.198215117
0.039452579
0.000744819

24.66029405
1.605915747
0.03629353
0.000428099
3.72922E-06

POLY2
39.59161959
-8.00180284
-12.96059391
-5.374258978
20.1044351
51.68396252
112.0584966
240.0755307
441.070361
717.7522402

POLY3
-3.193886502
10.52231252
14.76472025
21.59761617
36.1715405
54.98872897
95.85084206
201.2569992
407.711023
756.3436855

POLY4
0.210516462
4.453837622
10.40622199
20.72290352
39.16193453
59.77204887
100.6401588
201.0619567
400.8260256

20
40
60
100
200
400
760

P
1
5
10
20
40
60
100
200
400
760

P
1
5
10
20
40
60
100
200
400
760

P
1
5
10
20
40
60
100
200
400

-29.0901
-69.1754
-95.1231
-118.154
-112.994
-21.3836
223.7474

846.2339793
4785.241617
9048.395334
13960.3094
12767.72056
457.2574523
50062.89408

SumSq

118590.5562

Residue
-38.5916
13.0018
22.96059
25.37426
19.89556
8.316037
-12.0585
-40.0755
-41.0704
42.24776

Residue
1489.313103
169.0468771
527.1888729
643.8530187
395.8335029
69.15647942
145.4073407
1606.04816
1686.774556
1784.873211

SumSq
Residue
4.193887
-5.52231
-4.76472
-1.59762
3.828459
5.011271
4.149158
-1.257
-7.71102
3.656314

8517.495121
Residue2
17.58868399
30.49593562
22.70255906
2.552377439
14.65710212
25.11283733
17.2155116
1.580046918
59.45987638
13.36863568

SumSq

204.7335662

Residue
-0.78948
-0.54616
0.406222
0.722904
-0.83807
-0.22795
0.640159
1.061957
0.826026

Residue
0.623284256
0.298293344
0.165016303
0.522589495
0.702353729
0.051961716
0.409803263
1.12775196
0.682318283

759.6773023

a0
a1
a2
a3
a4
a5

22.92353403
1.833174578
0.04469179
0.000174037
1.91768E-07
6.31766E-08

POLY5
3.379876417
2.697252175
7.478474027
18.456339
39.5156983
62.45466413
105.1623499
202.0148214
391.0875637
762.153505

760

P
1
5
10
20
40
60
100
200
400
760

-0.3227

0.10413382

SumSq

4.687506167

Residue
-2.37988
2.302748
2.521526
1.543661
0.484302
-2.45466
-5.16235
-2.01482
8.912436
-2.15351

100
5.663811758
5.302647547
6.358093235
2.382889273
0.234548133
6.025375978
26.64985651
4.059505307
79.43152022
4.637583931

SumSq

140.7458319