ANSWERS TO PRACTICE PROBLEMS FOR STUDENT USE

CHAPTER 4: DETERMINATION OF THE PHYSICAL PROPERTIES OF MOLECULES

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2.93 1019 J. 797 g per 24-hr sample. This is an unusually high copper level in urine and indicates a pathologic condition. At 285 nm, c = 2.6 106 mole/liter; at 276 nm, c = 2.1 106 mole/liter; and at 226 nm, c = 2.3 107 mole/liter. The 1/4-grain sodium saccharin tablet in a 50-mL solution provides a concentration of 1.58 103 mole/liter, which is larger than the minimum detectable concentrations at 285, 276, and 226 nm. Any of these three wavelengths is suitable for the analysis. Partial Answer: When at high concentration, the molecule interaction interferes with the absorptivity. Pi = 54.73 cm3 /mole; p = 2.17 1023 cm3 . The average molar absorptivity is = 4.29 104 liter mole1 cm1 . = 6512 liter mole1 cm1 .
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The standard isoniazid sample of 0.80 g/mL yields a uorescence emission intensity of 60.5 1.2, or 59.3, where 1.2 is a correction for the blank. The isoniazid in the serum sample produces a uorescence intensity of 38.4 1.2. Thus, by the method of proportions, one directly obtains the isoniazid concentration, 0.50 g/mL. { } D25 = 131 deg. Look up the structure of codeine and cocaine, and consult an infrared spectrum absorption table from an organic chemistry textbook or spectroscopy handbook. 25 mg of diphenhydramine hydrochloride per capsule. (a) The values in Table 41 yield Rm for methanol as 8.343 cm3 /mole; and with the density of methanol as 0.7866 g/cm3 at 25 C, equation (424) yields the value Rm = 8.218; (b) As (a), the unit (cm3 /mole) should be readily attached to Rm . From equation (428), the molar ellipticity, [ ], is 364 deg liter mole1 dm1 . 25 deg 45 min.

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