I HC QUC GIA H NI

THI TUYN SINH LP 10

TRNG I HC KHOA HC T NHIN
H THPT CHUYN NM 2011
MN: HA HC
Thi gian lm bi: 120 pht (Khng k thi gian pht )

Cu I: (1,5 im) Thi dng kh CO i qua ng s cha 6,1 gam hn hp A gm CuO, Al 2O3
v mt oxit ca kim loi R t nng, ti khi phn ng hon ton th cht rn cn li trong ng
c khi lng 4,82 gam. Ton b lng cht rn ny phn ng va vi 150 ml dung dch
HCl 1M. Sau phn ng thy thot ra 1,008 lt kh H 2 ( ktc) v cn li 1,28 gam cht rn
khng tan.
(a) Vit cc phng trnh phn ng xy ra.
(b) Xc nh kim loi R v cng thc oxit ca R trong hn hp A.
Cu II: (1,5 im) Ha tan ht 37,725 gam hn hp B gm nhng lng bng nhau v s mol
ca NaHCO3, KHCO3, CaCl2 v BaCl2 vo 130 ml nc ct, sau thm tip 4,65 gam Na 2O.
Khuy u cho cc phn ng xy ra hon ton, sau lc b kt ta, thu c dung dch C.
Hy tnh nng % ca tng cht c trong dung dch C. Gi thit rng kt ta dng khan,
cc cht khng b tht thot trong qu trnh th nghim.
Cu III: (1,5 im) t chy hon ton 0,1 mol cht hu c D, sn phm ch gm 4,48 lt kh
CO2 ( ktc) v 5,4 gam H2O. Vit cng thc cu to cc cht tha mn tnh cht trn ca D.
Cu IV: (1,5 im) Cht hu c E c to bi ba loi nguyn t v ch cha mt loi nhm
chc, trong hidro chim 6,85%; oxi chim 43,84% khi lng ca E. Khi lng mol ca E
nh hn 250 gam. Ly 4,38 gam E cho tc dng vi dung dch NaOH va , sn phm gm
ancol v 4,92 gam mui. Tm cng thc phn t v vit cng thc cu to ca E.
Cu V: (2,0 im) Dung dch X l dung dch HCl. Dung dch Y l dung dch NaOH. Cho 60
ml dung dch vo cc cha 100 gam dung dch Y, to ra dung dch ch cha mt cht tan. C
cn dung dch, thu c 14,175 gam cht rn Z. Nung Z n khi lng khng i, th ch cn
li 8,775 gam cht rn.
(a) Tm nng CM ca dung dch X, nng C% ca dung dch Y v cng thc ca Z.
(b) Cho 16,4 gam hn hp X 1 gm Al, Fe vo cc ng 840 ml dung dch X. Sau phn ng
thm tip 1600 gam dung dch Y vo cc. Khuy u cho phn ng hon ton, lc ly kt ta,
em nung ngoi khng kh n khi lng khng i, thu c 13,1 gam cht rn Y 1. Tm
thnh phn % theo khi lng ca mi kim loi trong hn hp X1.
Cu VI: (2,0 im) Cho ancol A1 c khi lng mol bng 76 gam tc dng vi axit cacboxylic
B1 c cht M mch h. Mi cht A 1 v B1 ch cha mt loi nhm chc. Khi t chy hon
ton 17,2 gam cht M, cn dng va ht 14,56 lt O 2 (ktc). Sn phm chy ch gm CO 2 v
H2O theo t l s mol tng ng l 7: 4. Mt khc, c 17,2 gam M phn ng va ht vi 8 gam
NaOH. Bit M c cng thc phn t trng vi cng thc n gin nht. Xc nh cng thc
cu to ca A1, M v B1.
Cho nguyn t khi: H = 1; C = 12; O = 16; Na = 23; Mg = 24; Al = 27; Cl = 35,5; K =
39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba = 137; Pb = 207.

Cn b coi thi khng gii thch g thm.