Mark scheme 5070/4 Alternative to Practical November 2001

Syringe

2(a)

Blue

(b)

3.85 g

(c)

White

(d)(i)
(ii)

2.50 g
1.35 g

1
1

(e)(i)
(ii)

160
18

1
1

(f)(i)
(ii)

0.0156
0.075

1
1

(g)

X = 4.81 (1) CuSO4 . 5H2O (1)

3(a)

Water flowing wrong round condenser

(b)(i)
(ii)

Fractionating tube
To separate vapour, mixture

1
1

(i)
(ii)

Condenser
To convert vapour to liquid

1
1

(d)

Components are flammable

(e)(i)
(ii)
(iii)

80C
Benzene
Temperature rises

1
1
1

(c)

(a)

(d)

(b)

(b)

9(a)

1.65 g

(b)(i)
(ii)
(iii)

Air oxidises Fe2+ ions to Fe3+ ions (1)

Hydrogen
Pops in a flame

1
1

(c)

Colourless (or pale green) to purple (or pink)

(d)

27.8
0 .0
27.8

32.1
5 .7
26.4

47.3
20.7
26.6

(1) mark for each row or column

Mean value = 26.5 cm

3
1

(e)

0.000532

(f)

0.00266

(g)

0.0266

(h)

1.49 g

(i)

1.49 x 100 = 90%

1.65

10

1 Colourless solution
2 White ppt (1) Soluble in excess (1)
3 White ppt (1) Soluble in excess (1)
4 Aq. AgNO3 (1) Aq. HNO3 (1) White (1) ppt (1)
ZnCl2 (1)

1
2
2
4
1

11(a)

80, 56, 39, 26

All correct
Solubility expt 2 = 100, expt 4 = 50
both correct

(b)

Graph: all points correct

Smooth curve through vertical axis

1
1

(c)(i)
(c)(ii)

35
142

1
1

(d)

60 C

(e)

150g to 86g (1) = 64g (1)

[For parts (c), (d) and (e), mark as per candidates graph]