MSC Chemistry Syllabus CSSPG2010

UNIVERSITY OF CALICUT
(Abstract)
MSc programme n Chemstry under Credt Semester System (PG)-
Scheme and Syabus -approved mpemented-wth effect from 2010
admsson - Orders ssued.
_________________________________________________________________________
GENERAL & ACADEMIC BRANCH-IV J SECTION
No. GA IV/|2/ 4684/10 Dated, Cacut Unversty PO, 30.07.2010.
Read:1. U.O.No. GAIV/|1/1373/08 dated, 23.07.2010.
2. Item no.2 of the mnutes of the meetng of the Board of Studes
n Chemstry hed on 21.06.2010
O R D E R
As per Unversty Order read as frst, Credt Semester System was
mpemented to PG programmes n affated Arts and Scence Coeges
and Sef Fnancng Centres of the Unversty wth effect from 2010
admsson onwards.
The Board of Studes n Chemstry ,vde paper read as
second,consdered the number of courses to be offered ,course
content,evauaton and gradng,etc of the MSc. Chemstry programme of
affated coeges under CSS pattern to be mpemented from the
academc year 2010-11. The recommendatons of the Board n respect of
courses to be offered for M.Sc Chemstry under CSS and the syabus
were aso fnazed.
The Vce Chanceor has approved the mnutes sub|ect to
ratfcaton by the Academc Counc.
Sancton has therefore been accorded for mpementng the
scheme and Syabus of Ist Semester of MSc programme n Chemstry
wth effect from 2010 admsson.
Orders are ssued accordngy. Scheme and Syabus appended.
Sd/-
DEPUTY REGISTRAR (G & A-IV)
For REGISTRAR
To
The Prncpas of affated Coeges offerng MSc programme n Chemstry
Copy to:
PS to VC,PA to Regstrar,Charman,B/S
Chemstry,CE,EX,DRIII,DR,PG,EGI,Enqury,System Admnstrator wth a
request to upoad n the Unversty webste,Informaton Centes,GAI`F``G`
GAII,III
Forwarded/By Order
Sd/-
SECTION OFFICER
(Abstract)
M.Sc programme n Chemstry under Credt Semester System (PG)-
Scheme and Syabus II, III, & IV semesters-approved mpemented-
wth effect from 2010 admssons-Orders ssued.
_________________________________________________________________________
GENERAL & ACADEMIC BRANCH-IV J SECTION
No. GA IV/|2/4684/10 Cacut Unversty PO, Dated.19.01.2011
Read:1. U.O.No. GAIV/|1/1373/08 dated, 23.07.2010.
2. U.O. No. GAIV/|2/4684/08 dated, 30.07.2010.
3. Mnutes of the meetng of the Board of Studes n
Chemstry hed on 20.12.2010.
4. Orders of the Vce-Chanceor on 18.01.2011
O R D E R
As per Unversty Order read as frst, Credt Semester System was
mpemented to a PG programmes n affated Arts and Scence
Coeges and Sef Fnancng Centres of the Unversty wth effect from
2010 admsson onwards.
The scheme and syabus for the 1
st
semester of M.Sc Programme
n Chemstry under CSS PG was mpemented vde paper read as second
above.
The Board of Studes n Chemstry PG vde paper read as thrd
above, fnazed the syabus of M.Sc. Chemstry programme under CSS
PG for the II, III, & IV semesters.
The Vce-Chanceor exercsng the power of the Academc Counc
approved the mnutes sub|ect to ratfcaton by the Academc Counc
vde paper read as 4 above.
Sancton has therefore been accorded for mpementng the
scheme and Syabus for the II, III, & IV Semester of M.Sc programme n
Chemstry under CSS PG 2010 wth effect from 2010 admsson.
Orders are ssued accordngy. Scheme and Syabus appended.
Sd/-
DEPUTY REGISTRAR (G & A-IV)
For REGISTRAR
To
The Prncpas of affated Coeges offerng MSc programme n
Chemstry
Copy to:
PS to VC,PA to Regstrar,Charman,B/S Chemstry
PG,CE,EX,DRIII,DR,PG,EGI,Enqury,System Admnstrator (wth a request
to upoad n the Unversty webste),Informaton Centres,GAI`F``G`,
GAII,III/SF/FC/DF
Forwarded/By Order
Sd/-
SECTION OFFICER
2
!Sc! C"EISTRY (CSS PATTERN)
R#$%&at'o(s a(d S)&&ab%s
*'t+ #,,#ct ,ro- ./0/ ad-'ss'o(
Pr#a-b&#
The Board of Studes n Chemstry (PG) at ts meetng hed on 21.06.2010
consdered the ntroducton of Credt Semester System (CSS) n affated
coeges for the PG programmes n Chemstry and resoved to mpement the
CSS pattern from 2010 admsson onwards. The revsed course pattern,
syabus, dstrbuton of credts and scheme of evauaton, etc. approved by the
Board are gven beow:
Co%rs# Patt#r(
(a) The name of the course sha be M.Sc. Chemstry under CSS pattern.
(b) The course sha be offered n four semesters wthn a perod of two
academc years.
(c) Egbty for admsson w be as per the rues ad down by the
Unversty from tme to tme.
(d) Detas of the courses offered for the programme are gven n Tabe I.
The course sha be conducted n accordance wth the course pattern,
scheme of examnaton and syabus prescrbed. Of the 25 hours per
week, 12 hours sha be aotted for theory, 12 hours for practcas and 1
hour for semnar.
T+#or) Pa1#rs
In each semester there w be three theory papers. A the theory papers
n the frst and second semesters are core papers. In the thrd semester there
w be two core theory papers and one eectve paper. Coeges can choose
any one of the eectve papers gven n tabe 1. In the fourth semester there
w be one core paper and two eectve papers. Coege can choose any two
eectve papers from those gven n tabe 1. However a canddate may be
permtted to choose any other eectve papers wthout gvng any ecture
casses.
Pract'ca&s2 In each semester there w be three core practca papers (2
credts each). However practca examnaton w be conducted ony at the
end of the second semester for CHPO1, CHPO2, CHPO3 and at the end of
fourth semester for CHPO4, CHPO5, CHPO6.
Pro3#ct a(d V'4a Voc#2 Each student w have to do an ndependent
research pro|ect work durng the entre course under the gudance of a facuty
member of the coege/ scentsts of recognzed research nsttutons and
submt the dssertaton at the end of the fourth semester for evauaton (5
credts). There w be a comprehensve vva voce (3 credts) at the end of the
fourth semester. The vva voce w be based on the theory and practca
papers and the pro|ect work.
3
Dr. K. Krshnankutty
Charman
BOS n Chemstry (PG)
4
TABLE I
Co%rs#s o,,#r#d ,or !Sc! C+#-'str) Pro$ra--# %(d#r CCSS '(
A,,'&'at#d Co&&#$#s
Course
Code
Course Tte
Instructon
/ Week
Credts
S
E
M
E
S
T
E
R

I
CH1CO1 Theoretca Chemstry I 4 4
CH1CO2 Inorganc Chemstry I 4 4
CH1CO3 Organc Chemstry I 4 4
CH1PO1 Inorganc Chemstry Practca I 4
CH1PO2 Organc Chemstry Practca I 4
CH1PO3 Physca Chemstry Practca I 4
Tota Credts (Core) 12
S
E
M
E
S
T
E
R

I
I
CH2CO4 Theoretca Chemstry II 4 4
CH2CO5 Physca Chemstry I 4 4
CH2CO6 Organc Chemstry II 4 4
CH2PO1 Inorganc Practca I 4 4
CH2PO2 Organc Practca I 4 4
CH2PO3 Physca Practca I 4 4
Tota Credts (Core) 24
S
E
M
E
S
T
E
R

I
I
I
CH3CO7 Physca Chemstry II 4 4
CH3CO8 Inorganc Chemstry II 4 4
CH3PO4 Inorganc Practcas II 4
CH3PO5 Organc Practcas II 4
CH3PO6 Physca Practcas II 4
CH3EO1 Synthetc Organc Chemstry 4 4
CH3EO2 Natura Products 4 4
CH3EO3 Poymer Chemstry 4 4
Tota Credts Core
Eectve
8
4
5
S
E
M
E
S
T
E
R

I
V
CH4CO9
Advanced Topcs n
Chemstry
4 4
CH4PO4
Inorganc Chemstry
Practca II
4 4
CH4PO5
Organc Chemstry Practca
II
4 4
CH4PO6
Physca Chemstry
Practca II
4 4
CH4EO4
Instrumenta Methods of
Anayss
4 4
CH4EO5 Computatona Chemstry 4 4
CH4EO6 Matera Scence 4 4
CH4EO7 Industra Catayss 4 4
CH4EO8
Bonorganc and
Organometac Chemstry
4 4
CH4PrO1
Research Pro|ect and Vva
Voce
5+3=8
Tota Credts - Core
Eectve
Pro|ect
16
8
8
TOTAL CREDITS OF T"E
PROGRAE
CORE 60
ELECTIVE 12
PRO5ECT AND VIVA VOCE 8
Tota& Cr#d'ts 6/
6
!Sc! C"EISTRY CSS PATTERN 7 SEESTER I
C"0CO0 7 T"EORETICAL C"EISTRY 7 I (8 Cr#d'ts) (9. +)
UNIT I 2 T+# Fo%(dat'o(s o, :%a(t%- #c+a('cs (; +)! Hstorca
background of quantum mechancs. Detaed dscusson of postuates of
quantum mechancs State functon or wave functon postuate, Born
nterpretaton of the wave functon, we behaved functons,
orthonormaty of wave functons; Operator postuate, operator agebra,
near and nonnear operators, Lapacan operator, Hermtan operators
and ther propertes, egen functons and egen vaues of an operator;
Egen vaue postuate, egen vaue equaton, egen functons of
commutng operators; Expectaton vaue postuate; Postuate of tme-
dependent Schrdnger equaton of moton, conservatve systems and
tme-ndependent Schrdnger equaton.
UNIT II 2 :%a(t%- -#c+a('cs o, tra(s&at'o(a& & 4'brat'o(a& -ot'o(s (;
+)! Partce n a one-dmensona box wth nfnte potenta was,
mportant features of the probem; Free partce n one-dmenson;
Partce n a one-dmensona box wth fnte potenta was (or partce n
a rectanguar we) tunneng; Partce n a three dmensona box,
separaton of varabes, degeneracy.
One-dmensona harmonc oscator (compete treatment):- Method of
power seres, Hermte equaton and Hermte poynomas, recurson
reaton, wave functons and energes, mportant features of the probem,
harmonc oscator mode and moecuar vbratons.
UNIT III 2 :%a(t%- -#c+a('cs o, Rotat'o(a& -ot'o( (; +)! Co-ordnate
systems:- Cartesan, cyndrca poar and spherca poar coordnates and
ther reatonshps. Rgd rotator (compete treatment): The wave
equaton n spherca poar coordnates, panar rgd rotor (or partce on
a rng), the Ph-equaton, souton of the Ph-equaton, handng of
magnary wave functons, wave functons n the rea form; Non-panar
rgd rotor (or partce on a sphere), separaton of varabes, the Ph-
equaton and the Theta-equaton and ther soutons, Legendre and
assocated Legendre equatons, Legendre and assocated Legendre
poynomas, Rodrgue's formua, spherca harmoncs (magnary and
rea forms), poar dagrams of spherca harmoncs.
Ouantzaton of anguar momentum, quantum mechanca operators
correspondng to anguar momenta ((L
x
, L
x'
, L
x
), commutaton reatons
between these operators, spherca harmoncs as egen functons of
anguar momentum operators L
x
& L
x
, Ladder operator method for
anguar momentum, space quantzaton.
UNIT IV 2 :%a(t%- #c+a('cs o, ")dro$#(-&'<# Ato-s (;+)! Potenta
energy of hydrogen-ke systems, the wave equaton n spherca poar
coordnates, separaton of varabes, the R, Theta and Ph equatons and
ther soutons, Laguerre and assocated Laguerre poynomas, wave
functons and energes of hydrogen-ke atoms, orbtas, rada functons
and rada dstrbuton functons and ther pots. anguar functons
(spherca harmoncs) and ther pots. The postuate of spn by
Uhenbeck and Goudsmth, Drac's reatvstc equaton for hydrogen
7
atom and dscovery of spn (quatatve treatment), spn orbtas,
constructon of spn orbtas from orbtas and spn functons.
UNIT V 2 A11ro='-at'o( -#t+ods '( >%a(t%- -#c+a('cs (; +)! Many-
body probem and the need of approxmaton methods; Independent
partce mode; Varaton method varaton theorem wth proof,
ustraton of varaton theorem usng a tra functon |e.g.,
x (a-x)| for partce n a 1D-box and usng the tra functon e
-ar
for the
hydrogen atom, varaton treatment for the ground state of heum atom;
Perturbaton method tme-ndependent perturbaton method (non-
degenerate case ony), ustraton by appcaton to partce n a ID-box
wth santed bottom, perturbaton treatment of the ground state of the
heum atom.
UNIT VI 2 :%a(t%- -#c+a('cs o, -a()-#&#ctro( ato-s (; +)! Hartree
Sef-Consstent Fed method for atoms; Spn orbtas for many eectron
atoms, symmetrc and antsymmetrc wave functons, Pau's
antsymmetry prncpe; Sater determnants; Hartree-Fock Sef-
Consstent Fed (HF-SCF) method for atoms, Hartree-Fock equatons
(dervaton not requred) & the Fock operator; Roothan's concept of bass
functons Sater type orbtas (STO) and Gaussan type orbtas (GTO).
UNIT VII 2 C+#-'ca& bo(d'($ '( d'ato-'c -o&#c%&# (; +)! Schrdnger
equaton for a moecue, Born Oppenhemer approxmaton; Vaence
Bond (VB) theory VB theory of H
2
moecue, snget and trpet state
functons (spn orbtas) of H
2
; Moecuar Orbta (MO) theory MO theory
of H
2
+
on, MO theory of H
2
moecue, MO treatment of homonucear
datomc moecues L
2
, Be
2
, C
2
, N
2
, O
2
& F
2
and hetero nucear datomc
moecues LH, CO, NO & HF, bond order, correaton dagrams, non-
crossng rue; Spectroscopc term symbos for datomc moecues;
Comparson of MO and VB theores.
UNIT VIII 2 C+#-'ca& ?o(d'($ '( 1o&)ato-'c -o&#c%&#s (; +)!
Hybrdzaton quantum mechanca treatment of sp, sp
2
& sp
3
hybrdsaton; Sem emprca MO treatment of panar con|ugated
moecues Hcke Moecuar Orbta (HMO) theory of ethyene,
butadene & ayc anon, charge dstrbutons and bond orders from the
coeffcents of HMO, cacuaton of free vaence, HMO theory of aromatc
hydrocarbons (benzene); formua for the roots of the Hcke
determnanta equaton, Frost-Hcke crce mnemonc devce for cycc
poyenes.
R#,#r#(c#s
1. F.L. Par, Elementary Quantum Chemistry, McGraw-H, 1968.
2. I.N. Levne, Quantum Chemistry, 6
th
Edton, Pearson Educaton Inc.,
2009.
3. I.N. Levne, Student Solutions Manual for Quantum Chemistry 6
th
Edition,
Pearson Educaton Inc., 2009.
4. P.W. Atkns and R.S. Fredman, Molecular Quantum Mechanics, 4
th
Edton, Oxford Unversty Press, 2005.
5. M.W. Hanna, Quantum Mechanics in Chemistry, 2
nd
Edton, W.A.
Ben|amn Inc., 1969.
6. Donad, A. McOuarre, Quantum Chemistry, Unversty Scence Books,
1983 (frst Indan edton, Vva books, 2003).
7. Thomas Enge, Ouantum Chemstry & Spectroscopy, Pearson Educaton,
2006.
8
8. |.P. Lowe, Quantum Chemistry, 2
nd
Edton, Academc Press Inc., 1993.
9. Hora Metu, Physical Chemistry Quantum Mechanics, Tayor & Francs,
2006.
10. A.K. Chandra, Introduction to Quantum Chemistry, 4
th
Edton, Tata
McGraw-H, 1994.
11. L. Paung and E.B. Wson, Introduction to Quantum Mechanics, McGraw-
H, 1935 (A good source book for many dervatons).
12. R.L. Furry, |r., Quantum Chemistry, Prentce Ha, 1983.
13. R.K. Prasad, Quantum Chemistry, 3
rd
Edton, New Age Internatona,
2006.
14. M.S. Pathana, Quantum Chemistry and Spectroscopy (Problems &
Solutions, Vsha Pubcatons, 1984.
15. C.N. Datta, !ectures on Chemical "ondin# and Quantum Chemistry,
Prsm Books Pvt. Ltd., 1998.
16. |ack Smons, $n Introduction to %heoretical Chemistry, Cambrdge
Unversty Press, 2003.
9
!Sc! C"EISTRY CSS SYSTE 7 SEESTER I
C"0CO. 7 INORGANIC C"EISTRY 7 I - 8 CREDIT (9. +)
UNIT I 2 (; +)! Acd base theores strength of acds and bases, Factors
governng acd strength, sovent eveng, effect of hard and soft acds
and bases, super acds, chemstry of non aqueous sovents qud NH
3
,
SO
2
, H
2
SO
4
and HF. Heterogeneous acd-base reactons surface acdty,
Sod and moten acds n ndustra processes.
UNIT II (; +)! Eectron defcent compounds synthess, reactons, structure
and bondng. Boron hydrdes, styx numbers, Boron custer compounds,
Wade's rue, Hydroborate anons, Organoboranes and hydroboraton,
Poyhedra anons, Carboranes, Metaoboranes, Boraznes and Bordes.
UNIT III (; +)! Phosphorus-ntrogen compounds; Phosphazene, cyco- and
near phosphazenes. Phosphorus-suphur compounds; Suphur-ntrogen
rng and chan compounds synthess, structure, bondng and uses.
Scones Synthess, structure and appcatons. Carbdes and scdes.
Scates and aumnoscates framework of scates, structure and
appcaton,
UNIT IV (; +)! Standard reducton potentas and ther dagrammatc
representatons Engham dagram. Latmer and Frost dagram.
Pourbaux dagrams. Metac corroson and passvty, Isopoy and
heteropoy anons of eary transton metas.
UNIT V (; +)! Errors and treatment of anaytca data, mtatons of anaytca
methods, accuracy and precson, cassfcaton and mnmzaton of
errors, sgnfcant fgures, standard devaton, statstca treatment of
data, students tests, confdence mt, O test, Method of east squares.
UNIT VI (; +)! Theory Indcators, Acd-base, redox, absorpton,
compexometrc and umnescent ndcators, Ttratons n non-aqueous
sovents, Compex formaton ttratons, Prncpes of gravmetrc anayss,
Formaton and propertes of precptates, Co-precptaton, Precptaton
from homogeneous souton, Washng of the precptate, gnton of the
precptate, Fractona precptaton, Organc precptants.
UNIT VII (; +)! Introducton to co-ordnaton Chemstry Stereochemstry of
coordnaton compounds. Formaton constants, factors nfuencng
stabty, methods of determnaton of stabty constants, stabzaton of
unusua oxdaton states. Cheate-macrocycc and tempate effects,
ambdentate and macrocycc gands. Vaence bond theory and ts
mtatons.
UNIT VII (; +)! The crysta fed and gand fed theores, orbta spttng n
octahedra, tetrahedra and square panar feds. Factors affectng crysta
fed spttng, spectrochemca and nepheauxetc seres, Racah
parameters, |ahn-Teer effect, MO theory composton of gand group
orbtas. MO dagram of compexes wth and wthout p-bondng. The f-
orbtas and f-bock compexes.
R#,#r#(c#s
10
1. D.F. Shrver, P.W. Atkns and C.H. Langford, Inor#anic Chemistry, ELBS,
1990.
2. |.E. Huheey, e.A. Keter and R.L. Keter, Inor#anic Chemistry, Principles,
Structure and &eacti'ity, Pearson Educaton, 1990.
3. F.A. Cotton and G. Wknson, $d'anced Inor#anic Chemistry, 5
th
Edton,
|ohn Wey and Sons, 1988.
4. B. Dougous, D.H. McDanas and |.|. Aexander, Concepts and Models in
Inor#anic Chemistry, Oxford and IBH Pubshng Co. Pvt. Ltd., 1965.
5. L.V. Azaroff, Introduction to Solids, McGraw H, NY, 1960.
6. G.H. |effery, |. Bassett, |. Mendham and R.C. Denny, (o#el)s %e*t boo+ of
Quantitati'e Chemicals $nalysis, 5
th
Edton, ELBS, 1989.
7. Skoog, West and Hoer, ,undamentals of $nalytical Chenustry, 8
th
Edton, Thomson and Brooks, 2004.
8. C.E. Houecroft, Cluster molecules of p-bloc+ elements. Oxford Scentfc
Pubcatons, 1994.
9. D. Sutton, Electronic Spectra of %ransition Metal Comple*es, McGraw H,
1968.
10. |.C. Bar, |r. (Ed.), %he Chemistry of Coordination Compounds, Renhod
Pub. Cor., 1960.
11. L.F. Lndoy, %he Chemistry of Macrocyclic !i#ands and Comple*es,
Cambrdge Unversty Press, 1989.
12. |.D. Lee, Concise Inor#anic Chemistry, 5
th
Edton, Oxford Unversty
Press, 2008.
13. Wahd U Mak, G.D. Tu, R.D. Madan, Seected Topcs n Inorganc
Chemstry, S. Chand and Company Reprnt 2009.
11
!Sc! C"EISTRY(CSS PATTERN) 7 SEESTER I
C"0CO@ 7 ORGANIC C"EISTRY 7 I (8 Cr#d'ts) (9. +)
UNIT I 2 (; +)! Deocazed chemca bondng, Eectron Deocazaton,
Resonance and Aromatcty: Ouatatve appcaton of Hucke MO theory
and perturbaton theory to systems contanng deocazed eectrons.
Deocazed eectrons and Resonance, Resonance hybrd and resonance
energy. Crtera for Aromatcty and Antaromatcty, MO descrpton of
Aromatcty and Antaromatcty. Homoaromatcty, Mobus twst and
Aromatcty. Aromatcty of Annueens and heteroannuenes, Fuernes,
and fused rng systems. Stabty of benzyc catons and radcas. Effect
of deocazed eectrons on pKa.
Hydrogen bondng: Inter- and ntramecuar hydrogen bondng. Range of
the energy of hydrogen bondng. Effect of hydrogen bond on
conformaton, physca and chemca propertes of organc compounds,
vatty, acdty, bascty and stabty of hydrates of carbony
compounds. Stabzaton of hydrates of gyoxa and chora, and
nnhydrn. Hgh acd strength of maec acd compared to fumarc acd.
UNIT II 2 (; +)! Basc concepts n the study of organc reacton mechansms:
Appcaton of Expermenta crtera to mechanstc studes,
Thermodynamc and knetc data, Curtus-Hammet prncpes, Knetc
versus thermodynamc contro. Acdty constant, Hammet acdty
functon. Reactve ntermedates and ther characterzatn. Isotope effect
(abeng experments), Stereochemca correatons.
Neghbourng group partcpaton, partcpaton of carboxyate on,
haogen, hydroxy group, acetoxy group, pheny group and p-bond.
Structure and reactvty, Transton state theory, Potenta energy vs
Reacton co-ordnate curve, Substtuent effects (nductve, mesomerc,
nductomerc, eectomerc and fed effects) on reactvty. Ouatatve
study of substtuton effects n SN1-SN2 reactons. Semquanttatve
study of substtuent effects on the acdty of carboxyc acds.
Ouanttatve correaton of substtuent effects on reactvty. Lnear free
energy reatonshps. Hammet and Taft equaton for poar effects and
Taft's sterc, substtuent constant for sterc effect.
R#,#r#(c#s2 (U('t I a(d II)
1. |. March, $d'anced .r#anic Chemistry, 4
th
Edton, |ohn Wey and Sons,
1992.
2. T.H. Lowry and K.S. Rchardson, Mechanism and %heory in .r#anic
Chemistry, Harper Cons, 1987.
3. F.A. Carey and R.|. Sundberg, $d'anced .r#anic Chemistry (Parts A & B),
3
rd
Edton, Penum Press, 1990.
4. R.A.Y. |ones, Physical and Mechanistic .r#anic Chemistry, Cambrdge
UNIT III 2 Iso-#r's--I (; +)2 Concept of Chraty, Recognton of
symmetry eements and chra structures, Condtons for optca actvty,
Optca purty, Specfc rotaton and ts varaton n sgn and magntude under
dfferent condtons, Reatve and absoute confguratons, Fsher pro|ecton
formua, Sequence rue R and S notatons n cycc and acycc compounds.
12
Optca somersm of compounds contanng one or more asymmetrc
carbon atoms, Enantotopc, Homotopc, Dastereotopc hydrogen atoms,
Prochra centre.
Optca somersm n Bphenys, Aenes and Ntrogen and Suphur
compounds, Condtons for optca actvty, R and S notatons.
Restrcted rotaton n bphenys Moecuar overcrowdng. Chraty due
to fodng of heca structures.
Geometrca somersm E and Z notaton of compounds wth one and
more doube bonds n acycc systems. Methods of determnaton of the
confguraton of geometrca somers n acycc acd cycc systems, nter
converson of geometrca somers.
Stereochemstry of Adoxmes and ketomnes Namng somersm
methods of determnng confguratons.
UNIT IV 2 Iso-#r's--II (; +)2 Asymmetrc Synthess: The chra poo: Apha
amno acds n the synthess of benzodazepnes, carbohydrates (benzy
D mannose to Swansonne/preparaton of tomoo from D-mannto),
Fekn-Ahn mode and Cram's cheaton contro.
Chra auxares: Oxazodnones, Chra sufoxdes n controng the
reducton of ketones, Camphor dervatve n Des Ader reacton and
radca reactons.
Chra reagents: BINOL, tartrates, thum d(1-pheny ethy) amde.
Chra cataysts: Rhodum and ruthenum cataysts wth chra phosphne
gands ke (R)BINAP, (R,R)DIOP. Enzymatc methods.
R#,#r#(c#s
th
1992.
2. Naspur, Stereochemistry of .r#anic Compounds, 2
nd
Edton, New Age
Internatona.
3. Kas, Stereochemistry of .r#anic Compounds, Wey Eastern.
4. |. Cayden, N. Greeves, S. Warren and P. Wothers, .r#anic Chemistry,
Oxford Unversty Press, 2001.
5. E. Ee and S.H. Wen, Stereochemistry of .r#anic Compounds, |ohn
Wey, 1994.
UNIT V 2 Co(,or-at'o(a& A(a&)s's 7 I (; +)2 Dfference between
confguraton and confrmaton. Interna factors affectng the stabty of
moecues dpoe nteracton, bond opposton stran, bond ange stran.
Perspectve and Newman pro|ectons representaton of dfferent
conformatons. Conformaton of acycc compounds Ethane, n-butane,
akene dhades,gycos, choro hydrnes, tartarc acd, erythro and threo
somers, adehydesand ketones (acetadehyde, acetone).
Interconverson of axa and equatora bonds n char conformaton
dstance between the varous H atoms and C atoms n both char and
boat conformatons. Monosubsttuted cycohexane methy and t-buty
cycohexanes fexbe and rgd systems. Conformaton of dsubsttuted
cycohexanes (1:1; 1:2; 1:3 and 1:4). Conformaton of substtuted
cycohexanone-2-bromocycohexanone, dbromocyco hexanone, (cs &
trans), 2-bromo-4,4-dmethy cycohexanone. Anchorng group and
13
conformatonay based moecues. Conformatons of 1:4 cs and trans
dsubsttuted cycohexanes n whch one of the substtuent s 1-buty and
ther mportance n assessng the reactvty of an axa or equatora
substtuent. Conformatons of decane, adamentane, sucrose and
actose.
UNIT VI 2 Co(,or-at'o(a& A(a&)s's 7 II (; +)2 Effect of conformaton on the
course and rate of reactons n (a) Debromnaton of d and meso 2,3-
dbromobutane or stbene dbromde usng KI. (b) Sempnacoc
deamnaton of erythro and threo 1,2-dpheny-1-(p-choropheny)-2-
amno ethano. (c) Acton of methy magnesum bromde on 2-
phenyproponadehyde (Stereo chemca drecton of asymmeetrc
nducton). (d) Dehydrohaognaton of stbenedhade (d and meso) and
erythreo threo- bromo-1,2-dpheny propane.
Effect of conformaton on the course and rate of reactons n cycohexane
systems ustrated by: (a) S
N
2 and S
N
1 reactons for () an axa
substtuent, and () an equatora substtuent n fexbe and rgd
systems. (b) E1, E2 emnatons ustrated by the foowng compounds.
() 4-t-Butycycohexy tosyate (cs and trans) () 2-Phenycycohexano
(cs and trans) () Menthy and neomenthy chordes and benzene
hexachordes. (c) Pyroytc emnaton of esters (cs emnaton) (d)
Sempnacoc deamnaton of cs and trans-2-amnocycohexano (e)
Esterfcaton of axa as we as equatora hydroxy and hydroyss of
ther esters n rgd and fexbe systems. (Compare the rate of
esterfcaton of methano, somentho, neomentho and neosomentho).
(f) Esterfcaton of axa as we as equatora carboxy groups and
hydroyss of ther esters. (g) Hydroyss of axa and equatora tosyates.
(h) Oxdaton of secondary axa and equatora hydroxy group to
ketones by chronc acd.
UNIT VII 2 (') R#act'o(s o, Carbo(-+#t#ro-%&t'1&# bo(ds (9 +)2 Addton
of carbon-oxygen mutpe bond: Addton of water, acohos, amnes and
hydrazne. Ado, Perkn, Canson, Deckmann, Stobbe and benzon
condensaton. Darzons, Knoevenage, Reformatosky, Wttg, Cannzaro,
Mannch and Prns reactons. MPV reducton and Oppenaur oxdaton.
Cram's rue. Hydroyss, acohoyss and reducton of ntres. Rtter
reactn and Thorpe condensaton.
('') Est#r','cat'o( a(d ")dro&)s's (. +)2 Mechansm of Ester
hydroyss and esterfcaton, Acy-oxygen and aky oxygen ceavage.
Esterfcaton of axa and equatora acohos and acds ther hydroyss.
R#,#r#(c#s
th
1992.
2. Morrson & Boyd, Organc Chemstry, Prentce Ha.
3. F.A. Carey and R.|. Sundberg, $d'anced .r#anic Chemistry /Parts $ & ",
3
rd
4. E.S. Goud, Mechanism and structure in or#anic chemistry, Hot, Rnehart
and Wnston, 1959.
UNIT VIII 2 I(trod%ct'o( to Po&)-#r C+#-'str) (; +)2 Casses of
poymers, Synthetc and bopoymers. Synthetc poymers: Chan
reacton poymerzaton and step reacton poymerzaton. Lnear,
14
crossnked and network poymers. Copoymers, Free-radca and onc
poymerzaton. Natura and synthetc rubbers.
Bopoymers: Prmary, secondary and tertary structure of protens, Sod
phase peptde synthess, Protectng groups, Sequence determnaton of
peptdes and protens, Structure and synthess of gutathone, Structure
of RNA and DNA, Structure of ceuose and starch, Converson of
ceuose to Rayon.
R#,#r#(c#s
1. Saunders, .r#anic Polymer Chemistry, Chapman and Ha.
2. S.H. Pne, |.B. Hendrckson, D.|. Cram and G.S. Hammond, .r#anic
Chemistry, McGraw H Internatona Book Company, 1981.
3. I.L. Fnar, .r#anic Chemistry, Vo. II, 5
th
Edton, ELBS, 1975.
4. |ordean, %he Chemistry of 0ucleic $cids, Buttorworths.
15
!Sc! C"EISTRY (CSS PATTERN) 7 SEESTER II
C".CO8 - T"EORETICAL C"EISTRY II (8 cr#d'ts)
(9. +)
UNIT I 7 Fo%(dat'o(s o, $ro%1 t+#or) & -o&#c%&ar s)--#tr) (; +)2
"asic principles of #roup theory - the defnng propertes of mathematca
groups, fnte and nfnte groups, Abean and cycc groups, group
mutpcaton tabes (GMT), smarty transformaton, sub groups &
casses n a group;
Molecular Symmetry & point #roups - symmetry eements and symmetry
operatons n moecues, reatons between symmetry operatons,
compete set of symmetry operatons of a moecue, pont groups and
ther systematc dentfcaton, GMT and casses of pont groups;
Mathematical preliminaries - matrx agebra, addton and mutpcaton
of matrces, nverse of a matrx, square matrx, character of a square
matrx, dagona matrx, drect product and drect sum of square
matrces, bock factored matrces, sovng near equatons by the
method of matrces; Matrx representaton of symmetry operatons.
UNIT II 7 R#1r#s#(tat'o(s o, 1o'(t $ro%1s & t+#or#-s (; +)2
&epresentations of point #roups - bass for a representaton,
representatons usng vectors, atomc orbtas and cartesan coordnates
postoned on the atoms of moecue (H
2
O

as exampe) as bases,
reducbe representatons and rreducbe representatons (IR) of pont
groups, constructon of IR by reducton (quatatve demonstraton ony),
Great orthogonaty theorem (GOT) (no dervaton) and ts consequences,
dervaton of characters of IR usng GOT, constructon of character
tabes of pont groups (C
2V
, C
3V
, C
2h
and C
4V
as exampes), nomencature
of IR - Muken symbos, symmetry speces;
&eduction formula - dervaton of reducton formua usng GOT, reducton
of reducbe representatons, (e.g.,
cart
) usng the reducton formua;
&elation bet1een #roup theory and 2uantum mechanics wavefunctons
(orbtas) as bases for IR of pont groups.
UNIT III A11&'cat'o(s o, Gro%1 T+#or) to o&#c%&ar S1#ctrosco1)
(; +)2 Spectral transition probabilities - drect product of rreducbe
representatons and ts use n dentfyng vanshng and non-vanshng
ntegras, transton moment ntegra and spectra transton probabtes,
overap ntegras and condtons for overap.
Molecular 'ibrations - symmetry speces of norma modes of vbraton,
constructon of
cart
, norma coordnates and drawngs of norma
modes (e.g., H
2
O and NH
3
), seecton rues for IR and Raman actvtes
based on symmetry arguments, determnaton of IR actve and Raman
actve modes of moecues (e.g., H
2
O, NH
3
, CH
4
, SF
6
), compementary
character of IR and Raman spectra.
Electronic Spectra eectronc transtons and seecton rues, Laporte
seecton rue for centro symmetrc moecues.
UNIT IV - A11&'cat'o(s o, Gro%1 T+#or) to C+#-'ca& ?o(d'($ (; +)2
3ybridisation - treatment of hybrdzaton n BF
3
and CH
4
, nverse
transformaton and constructon of hybrd orbtas.
16
Moecuar orbta theory - H
2
O & BH
3
as exampes, cassfcaton of atomc
orbtas nvoved nto symmetry speces, group orbtas, symmetry
adapted near combnatons (SALC), pro|ecton operator, constructon of
SALC usng pro|ecton operator, use of pro|ecton operator n constructng
SALCs for the n MOs n cycopropeny (C
3
H
3
+
) caton.
UNIT V (; +) 2 "asic Principles of Molecular Spectroscopy - Eectromagnetc
radaton & ts dfferent regons, nteracton of matter wth radaton and
ts effect on the energy of a moecue; Orgn of moecuar spectra -
Theory of the orgn of rotatona, vbratona and eectronc spectra,
ntensty of spectra nes, dependence of ntensty on popuaton,
transton probabtes, transton moment ntegra & seecton rues, ne
wdths, Dopper broadenng, fetme broadenng.
Micro1a'e spectroscopy - Rotaton spectra of datomc and poy atomc
moecues - rgd and non-rgd rotator modes, asymmetrc, symmetrc
and spherca tops, sotope effect on rotaton spectra, Stark effect,
nucear and eectron spn nteractons, rotatona transtons and
seecton rues, determnaton of bond ength usng mcrowave spectra
data.
UNIT VI I(,rar#d & Ra-a( S1#ctrosco1) (; +)2 (ibrational spectroscopy -
Norma modes of vbraton of a moecue; Vbratona spectra of datomc
moecues - harmonc oscator mode, anharmoncty, vbratona
transtons and seecton rues, Morse potenta, fundamentas, overtones,
hot bands, combnaton bands, dfference bands; Vbratona spectra of
poyatomc moecues; Vbraton-rotaton spectra of datomc and
poyatomc moecues, spectra branches -P, O & R branches; Fourer
transform nfrared (FTIR) spectroscopy (quatatve treatment).
&aman spectroscopy - Pure rotatona & pure vbratona Raman spectra,
vbratona-rotatona Raman spectra, seecton rues, mutua excuson
prncpe; Resonance Raman spectroscopy & coherent ant-stokes Raman
spectroscopy (basc prncpes ony); Laser Raman spectroscopy.
UNIT VII E&#ctro('c s1#ctrosco1) (; +)2 Electronic spectroscopy of $toms
The energes of hydrogen atomc orbtas & hydrogen spectrum,
coupng of orbta and spn anguar momentum, fne structure of H
spectrum, The anguar momentum of many eectron atoms coupng of
anguar momenta, LS coupng & |-| coupng, spectroscopc term symbos
for atoms, seecton rues.
Electronic spectroscopy of molecules - Characterstcs of eectronc
transtons Vbratona coarse structure, ntensty of eectronc
transtons, Franck - Condon prncpe, types of eectronc transtons;
Dssocaton and pre-dssocaton; Ground and excted eectronc states of
datomc moecues; Rotatona fne structure of eectronc-vbraton
transtons; Eectronc spectra of poyatomc moecues; Eectronc
spectra of con|ugated moecues; Photoeectron spectroscopy (PES)
utravoet PES and X-ray PES (quatatve treatment).
UNIT VIII S1'( R#so(a(c# S1#ctrosco1) (; +)2 0uclear Ma#netic
&esonance (0M& spectroscopy - Magnetc propertes of nuce, theory
and measurement technques, sovents used, chemca shft and factors
nfuencng chemca shft, shedng effects, spn-spn nteracton,
coupng constant, factors nfuencng coupng constant, effects of
chemca exchange, fuxona moecues, hndered rotaton on NMR
spectrum, Kars reatonshps; FTNMR; Prncpes of 2D NMR
spectroscopy - COSY.
17
Electron Spin &esonance (ES& spectroscopy - Theory and measurement
technques, g factor, hyperfne nteractons, equvaent & non-equvaent
protons, Kramers theorem.
Mossbauer spectroscopy - The Mossbauer effect, hyperfne nteractons,
somer shft, eectrc quadrupe and magnetc hyperfne nteractons.
R#,#r#(c#
U('ts I to IV
1. F.A. Cotton, Chemical applications of 4roup %heory, 3
rd
Edton, |ohn Wey
&Sons Inc., 2003.
2. H. H. |affe and M. Orchn, Symmetry in Chemistry, |ohn Wey &Sons Inc.,
1965.
3. L.H. Ha, 4roup %heory and Symmetry in Chemistry, McGraw H, 1969.
4. R. McWeeny, Symmetry5 $n Introduction to 4roup %heory and its
$pplications, Pergamon Press, London, 1963.
5. P.H. Waton, "e#innin# 4roup %heory for Chemistry, Oxford Unversty
Press Inc., New York, 1998.
6. Mark Ladd, Symmetry & 4roup %heory in Chemistry, Horwood 1998.
7. A. Saahuddn Kun|u & G. Krshnan, 4roup %heory & its $pplications in
Chemistry, PHI Learnng Pvt. Ltd. 20106
8. Arthur M Lesk, Introduction to Symmetry & 4roup theory for Chemists,
Kuwer Academc Pubshers, 2004.
9. K.Veera Reddy, Symmetry & Spectroscopy of Molecules 7
nd
Edn6, New Age
Internatona 2009.
10. A.W. |osh, Elements of 4roup %heory for Physicists, New Age Internatona
Pubshers, 1997.

U('ts V to VIII
11. G.M. Barrow, Introduction to Molecular Spectroscopy, McGraw H, 1962.
12. C.N. Banwe & E. M. McCash, ,undamentals of Molecular Spectroscopy,
Tata McGraw H, New Deh, 1994.
13. Thomas Enge, Quantum Chemistry & Spectroscopy, Pearson educaton,
2006.
14. P. Atkns & |. De Paua, $t+ins8s Physical Chemistry, 8
th
Edton, W.H.
Freeman & Co., 2006.
15. D.A. McOuarre and |.D. Smon, Physical Chemistry - $ Molecular
$pproach, Unversty Scence Books, 1997.
16. K.|.Lader, |.H.Meser and B. C. Sanctuary, Physical Chemistry, Houghton
Mffn Company, New York, 2003.
17. D.N. Sathyanarayana, Electronic $bsorption Spectroscopy and &elated
%echni2ues, Unversty Press, 2000.
18. R.S. Drago, Physical methods in Inor#anic Chemistry, Affated East-West
Press Pvt. Ltd., 1977.
19. Wam Kemp, .r#anic Spectroscopy, 3
rd
Edn., Pagrave, 1991.
18
!Sc! C"EISTRY (CSS PATTERN) 7 SEESTER II
C".COA - P"YSICAL C"EISTRY - I (8 cr#d'ts)B (9. +)
U('t I E&#ctroc+#-'str) 7 I (;+)2 Anomaous behavor of strong
eectroytes, theory of strong eectroytes, onc atmosphere, varaton of
onc speeds, reaxaton tme, mechansm of eectroytc conductance,
reaxaton and eectrophoretc effects, dervaton of Debye-Hcke-
Onsager equaton, devaton from Debye-Hcke-Onsager equaton,
degree of dssocaton and ts determnaton, conductance rato, Debye-
Fakenhagen effect, Wen effect.
Actvty and actvty coeffcents of eectroytes - onc strength, varaton
of actvty coeffcent wth concentraton; Dervaton of Debye-Hcke
mtng aw and ts varous forms, quatatve & quanttatve verfcaton
of the Debye- Hcke mtng aw.
U('t II E&#ctroc+#-'str) 7 II (;+)2 Poarzaton - eectroytc poarzaton,
dssouton and deposton potentas, concentraton poarzaton;
Decomposton votage and ts determnaton; Over votage - hydrogen
over votage, oxygen overvotage, meta deposton over votage and ts
determnaton, theores of over votage; Prncpes of poarography -
droppng mercury eectrode, the haf wave potenta.
UNIT III The Solid State I (9h) Cr!stal s!""etr!: Symmetry elements and symmetry
operations, mathematical proof for the none!istence of 5fold a!is of symmetry, crystal
systems, "ra#ais lattices and crystal classes, $rystallo%raphic point %ro&ps Sch'nflies (
)erman * +a%&in notations, Stereo%raphic pro,ections of the 27 a!ial point %ro&ps,
translational symmetry elements ( symmetry operations scre- a!es and %lide planes,
introd&ction to space %ro&ps. Imperfectons n sods - pont, ne and pane
defects, Non-stochometry.
UNIT IV T+# So&'d Stat# 7 II (;+)2 Eectronc structure of sods - free
eectron theory, band theory & Zone theory, Broun zones; Eectrca
propertes - eectrca conductvty, Ha effect, deectrc propertes, pezo
eectrcty, ferro-eectrcty and onc conductvty; Superconductvty -
Mesner effect, bref dscusson of Cooper theory of superconductvty;
Optca propertes - photo conductvty, umnescence, coour centers,
asers, refracton & brefrngence; Magnetc propertes - damagnetsm,
paramagnetsm, ferromagnetsm, antferromagnetsm & ferrmagnetsm;
Therma propertes - therma conductvty & specfc heat.
UNIT V I(trod%ct'o( to Co-1%tat'o(a& :%a(t%- C+#-'str) (;+)2
Cassfcaton of computatona chemstry methods, ab nto methods -
revew of Hartree-Fock SCF method, eectron correaton, The bass set
approxmaton use of STOs & GTOs as bass functons, mnma, doube
zeta, trpe zeta, spt-vaence, poarzaton & dffuse bass sets,
contracted bass sets, Pope-stye bass sets and ther nomencature;
Mode chemstry.
Cacuatons usng Gaussan Programme - Specfcaton of moecuar
geometry usng cartesan coordnates & nterna coordnates, The Z-
matrx, Z-matrces of some smpe moecues (e.g., H
2
, H
2
O, H
2
O
2
,
ammona & ethane ecpsed & staggered conformatons), The structure
19
of a Gaussan Input fe, Gaussan keywords - OPT and FREO as
exampes.
UNIT VI P+otoc+#-'str) (;+)2 Photochemca reactons - dmersaton of
anthracene, H
2
- Br
2
reacton & H
2
- C
2
reactons, photopoymerzaton;
Prncpes of utsaton of soar energy - soar ces and ther workng;
Photochemca processes - Radatve and non-radatve transtons,
chemumnescence photoumnescence, boumnescence, thermo-
umnescence; Fuorescence - theory of fuorescence, |abonsk dagram,
stokes antstokes and resonance fuorescence; Photosenstzaton -
senstzed fuorescence - quenchng of fuorescence.
UNIT VII N%c&#ar a(d Rad'at'o( C+#-'str) (;+) 2 Nucear structure and
nucear stabty, Nucear Modes Ferm gas, coectve and optca
modes; Nucear reactons: Types, conservaton, reacton cross secton,
compound nuceus theory, specfc nucear reactons, photonucear and
thermonucear reactons, neutron actvaton anayss.
Radaton chemstry - nteracton of radaton wth matter - processes
responsbe for energy oss, range and range energy reaton; Methods
of detecton & measurement of radaton - prncpes and workng of GM
and scntaton counters; Physca and chemca radaton effects n
sods, radaton chemstry of water and aqueous ferrous suphate
soutons, radaton hazards and therapeutcs, dosmetry.
UNIT VIII (;+)2 Technques & nstrumentaton of IR spectroscopy snge
beam and doube beam spectrometers, radaton sources, detectors,
sampe handng; FTIR spectrophotometer Technques & nstrumentaton
of Raman spectroscopy radaton sources, detectors, sampe handng &
umnaton.
Technques & Instrumentaton of UV-Vsbe spectroscopy radaton
sources, fters & monochromators, ces & sampng devces, detectors.
Instrumentaton of NMR spectroscopy - Contnuous-wave nmr
spectrometers the magnet, the probe unt; Pused FTNMR
spectrometer.
20
R#,#r#(c#
U('ts I & II
1. S. Gasstone, Introduction to Electrochemistry, East-West Press Pvt. Ltd., 1965
(Reprnt 2008).
2. |.O.M. Bockrs and A.K.N. Reddy, Modern Electrochemistry, (ol6 I and II, Kuwer
Academc / Penum Pubshers, 2000.
3. Car. H. Hamann, A. Hamnett, W.Vestch, Electrochemistry 7
nd
edn., Wey-VCH,
2007.
4. Php H Reger, Electrochemistry 7
nd
edn., Chapman & Ha, 1994.
5. Praveen Tyag, Electrochemistry, Dscovery Pubshng House, 2006.
6. D.A. McInnes, %he Principles of Electrochemistry, Dover pubcatons, 1961.
U('ts III & IV
7. L.V. Azaroff, Introduction to Solids, McGraw H, NY, 1960.
8. A.R. West, "asic Solid State Chemistry 7
nd
edn6, |ohn Wey & Sons, 1999.
9. A.R. West, Solid State Chemistry & its $pplications, |ohn Wey & Sons, 2003
(Reprnt 2007).
10. Chares Ktte, Introduction to Solid State Physics 9
th
edn, |ohn Wey & Sons,
2004 (Reprnt 2009).
11. Mark Ladd, Crystal Structures5 !attices & Solids in Stereo'ie1, Horwood, 1999.
12. Rchard Tey, Crystals & Crystal Structures, |ohn Wey & Sons, 2006.
13. C. Gacovazzo (ed.) ,undamentals of Crystallo#raphy 7
nd
edn6, Oxford Uty. Press,
2002.
14. Werner Massa, Crystal Structure :etermination 7
nd
edn., Sprnger 2004.
15. N.B. Hanna, Solid state Chemistry, Prentce Ha.
U('t V
16. C. |. Cramer, Essentials of computational Chemistry5 %heories and models, |ohn
Wey & Sons 2002.
17. Frank |ensen, Introduction to Computational Chemistry, |ohn Wey & Sons LTD
1999.
18. |. Foresman & Aeeen Frsch, E*plorin# Chemistry 1ith Electronic Structure
Methods, Gaussan Inc., 2000.
19. Erro G. Lewars, Computational Chemistry5 Introduction to the theory and
applications of molecular 2uantum mechanics, 7
nd
edn6, Sprnger 2011.
20. Thomas Enge & W. Hehre, Quantum Chemistry and Spectroscopy, Pearson
Educaton Inc. 2006.
th
Edton, Pearson Educaton Inc., 2009.
22. P.W. Atkns & R.S. Fredman, Molecular 2uantum mechanics, 4
th
Edton, Oxford
23. Davd Young, Computational Chemistry, Wey-Interscence, 2001.
U('t VI
24. C.H. DePuy & O.L.Chapman, Molecular reactions and Photochemistry , Prentce
Ha, 1972.
25. Aan Cox & |ames Kemp, Introductory photochemistry, McGraw H, 1971.
26. P. Suppan, Chemistry and !i#ht, RSC London 1994.
th
Edton, W.H. Freeman &
Co., 2006.
28. K.|.Lader, |.H.Meser and B. C. Sanctuary, Physical Chemistry, Houghton Mffn
Company, New York, 2003.
29. G. Ra| and H. Msra, Photochemistry, Goe Pubshng House.
U('t VII
30. Fredander and |.W. Kennedy, Introduction to &adiochemistry, |ohn Wey &
Sons, 1981.
21
31. S. Gasstone, Source "oo+ on $tomic Ener#y, 3
rd
edn., Affated East-West Press
Pvt. Ltd., 1967.
32. H.|. Arnkar, Essentials of 0uclear Chemistry, 4
th
edn., New Age Internatona,
1995 (Reprnt 2005).
33. W.D.Loveand, D.|.Morrssey, G.T.Seaborg, Modern 0uclear Chemistry, Wey,
2006.
34. G.R.Choppn, |.O.L|enzn, |.Rydberg, &adiochemistry & 0uclear Chemistry,
Butterworth-Henemann, 2002.
35. Kenneth S. Krane, Introductory 0uclear Physics, |ohn Wey & Sons, 1988 (Reprnt
2008).
36. D.C. Taya, 0uclear Physics ;
th
edn., Hmaya Pubshng House, 2008.
U('t VIII
37. H.H. Ward, L.L. Merrtt,|r., |.A. Dean & F.A. Sette |r., Instrumental Methods of
$nalysis 9
th
edn6, CBS Pubshers, 1986.
38. C.N. Banwe & E. M. McCash, ,undamentals of Molecular Spectroscopy, Tata
McGraw H, New Deh, 1994.
39. Wam Kemp, .r#anic Spectroscopy, <
rd
Edn., Pagrave, 1991 (Reprnt 2005).
40. G.W. Ewng, Instrumental Methods of Chemical $nalysis ;
th
edn6, Mc-Graw-H,
1985.
41. Robert D Brown, Introduction to Instrumental $nalysis, PharmaMed Press,1987
(Reprnt 2006).
42. G.H. |effery, |. Bassett, |. Mendham & R.C. Denny, (o#el8s %e*t boo+ of
Quantitati'e Chemical $nalysis, 5
th
Edton, ELBS, 1989.
43. D.A. Skoog, D.M. West & F. |. Hoer, ,undamentals of $nalytical Chemistry, =
th
edn6, Thomson and Brooks, 2004.
44. D. A. Skoog, F. |. Hoer & S. R. Crouch, Principles of Instrumental $nalysis,
Thomson and Brooks, 2007.
22
!Sc! C"EISTRY (CSS PATTERN) - SEESTER II
C".COC ORGANIC C"EISTRY II (8 Cr#d't) (9. +o%rs)
UNIT I2 (a) S%bst't%t'o( a(d #&'-'(at'o( r#act'o( (@ +r)2
Nuceophc aromatc substtuton - Dazonum on as synthetc
ntermedate - E1cB Mechansm - Emnaton at brdge head carbon-
Bredts rue Chugav reacton.
(b) Fr## rad'ca&s (C +r)2 Formaton, detecton, stabty of Free radcas.
Free radca addton and substtuton reactons Carbenes and ntrenes
(Formaton and reactons).
UNIT II2 P#r'c)c&'c r#act'o(s (; +r)2 Defnton and types of percycc
reactons - Cycoaddton and cycoreverson, eectrocycc rng cosure
and rng openng, Sgmatropc rearrangement, ene reactons, Cheotropc
reactons. Theoretca modes of percycc reactons - Orbta correaton
method, Transton state aromatcty method, Fronter moecuar orbta
method. Des - Ader Reactons, and Sommeet - Hauser, Cope and
Casen rearrangements. Seecton rues and ther appcaton to the
above reactons.
R#,#r#(c#s2
1. T.H. Lowry and K.S. Rchardson, Mechanism and %heory in .r#anic
Chemistry, Harpere Cons.
2. S.H. Pne, |.B. Hendrckson, D.|. Cram and G.S.Hammond, .r#anic
3. F.A. Carey and R.|. Sundberg, $d'anced .r#anic Chemistry (Part $ & ",
3
rd
4. I. Femmng, ,rontier .rbitals and .r#anic Chemical &eactions, Wey,
London, 1976.
5. |. Cayden, N. Greeves, S. Warren, and P. Wothers, .r#anic Chemistry,
UNIT III2 o&#c%&ar R#arra($#-#(ts a(d Na-#d r#act'o(s (; +r)2
Rearrangement nvovng eectron defcent carbon, ntrogen and oxygen
atoms. Wagner- Meerwen, Woff Hoffmann, Beckmann, Schmdt and
Baeyer- Vger, Pnacoe-pnacoons, rearrangements.
Anonc rearrangements: Benz-Benzc acd, Favorsk. Orten-Casen
and Fres rearrangements. Suzuk coupng. Heck, Peterson, Woodward
and Prevost hydroxyaton reactons.
R#,#r#(c#s2
1. P. Sykes, A gudebook to mechansms n Organc chemstry, Orent
Longmans, 2002.
2. S.H. Pne, |.B. Hendrckson, D.|. Cram and G.S. Hammond, Organc
Chemstry, McGraw.
3. |. March, Advanced Organc Chemstry 4
th
edton |ohn Wey and Sons,
1992.
4. |e |ack L Name reactons 2
nd
edton.
UNIT IV (; +) 2 Spectroscopc Technques n organc structura determnaton
probem sovng approach.
23
UV-4's'b&#2 Characterstc absorpton of organc compounds- emprca rues
for cacuatng absorpton maxma of denes, enones and aromatc
systems.
IR2 Characterstc group absorptons of organc moecues- Akanes, akenes,
akynes, and aromatc hydrocarbons. Acohos, phenos, ethers, carbony
compounds, amnes, amdes and ntres.
Optca rotatory dsperson pan and mutpe cotton effect curves -
uses. Axa haoketone rue and ts appcaton. Octant rue-
determnaton of conformaton and confguraton of 3-methy
cycohexanone. ORD curves of cs- and trans- decaones, crcuar
dchrosm curves.
R#,#r#(c#s2 IV a(d V
1. R.M. Sversten, G.C.Bassar and T.C.Morr, Spectroscopc dentfcaton
of organc compounds, |ohn Wey and Sons, 1991.
2. W. Kemp, Organc Spectroscopy, 3
rd
edton, M.C.Mon, 1991.
3. P.S. Kas, Spectroscopy of Organc compound; New age Internatona,
1998.
4. D.L. Pava; G.M. Lampman and G.S. Krz; Introducton to spectroscopy,
Saunders Goden Sunburst seres.
5. W. Kemp and I. Femng, Organc Spectroscopy.
6. D. Naspur, Staeochemstry of Organc Compounds, Wey Eastern.
7. I.L. Fnar, Organc Chemstry, Vo. II, 5
th
edton, ELBS, 1975.
UNIT V2 NR a(d ass s1#ctra (; +)2 The chemca shft, oca
damagnetc shedng and magnetc equvaence, spn-spn coupng,
coupng constant, coupng of protons to other nuce, quadrupoe
broadng frst and second order spectra. Homotopc, enantotopc and
dastero topc protons. Nucear overhauser effect (NOE), enhancement
smpfcaton of NMR spectra, use of shft reagent Hgh fed strength.
Spn decoupng and doube resonance deuterum abeng and exchange
vcna and germna coupng n rgd systems. Chemca shft correaton
charts proton couped, offresonence, decouped and nose decouped
spectra.
ass s1#ctra2 Determnaton of moecuar mass- moecuar formuae from
sotopc rato- fragmentaton pattern n dfferent casses of compounds.
Meta stabe ons.
UNIT VI2 S)(t+#t'c r#a$#(ts (; +r): Use of the foowng reagents n
organc synthess and functona group transformatons: Compex meta
hydrdes - LAH
4
, sodum borohydrde and ther dervatves, Trmethy tn
hydrde, Gmans reagent Lthum dmethy cuprate, Lthum dspropy
amde (LDA), Trmethy sy chorde, 1,3-Dthane, Crown ethers,
Wknsons catayst, peroxy acds, perodc acds, DCC, DDO and
dborane.
R#,#r#(c#s2
1. F.A. Carey and R.|. Sundberg, $d'anced .r#anic Chemistry (Parts $ & ",
3
rd
2. H.O. House, Principles of .r#anic Synthesis6
th
1992.
24
UNIT VII2 P+otoc+#-'str) (; +r)2 Fundamenta concepts, moecuar
exctaton, |abonsk dagram and the snget and trpet states
photosenstzaton. Reacton nvovng the oefnc doube bonds,
reactons of carbony compounds and reactons of aromatc compounds.
D- -methane rearrangement Barton reacton and Photofres
rearrangement photopoymersaton and photochemca degradaton of
poymers photochemstry of dyes and pgments.
R#,#r#(c#s2
1. R.O.Kan Organc Photochemstry, McGraw H.
2. O.L. Chapman, Organc photochemstry, Vo.I & II, Marce Decker.
UNIT VIII2 C+#-'str) o, Nat%ra& Prod%cts (; +r)2 Chemca cassfcaton
of Natura products cassfcaton of akaods based on rng structure,
Isoaton and genera methods of structure eucdaton based on
degradatve reactons. Structure of atropne-synthess of qunne.
Terpenods - Isoaton and cassfcaton of terpenods, structure of
sterods cassfcaton of sterods, Woodward synthess of choestero
converson of choestero to testosterone. Favones and Isofavones-
synthess ony.
R#,#r#(c#s2
th
Edton, ELBS, 1975.
2. P.S. Kas, Chemstry of Natura products, Wey Eastern.
25
!Sc! C"EISTRY 7 SEESTER I & II
C"0PO0 & C".PO0 7 INORGANIC C"EISTRY PRACTICALS7 I (8
Cr#d'ts)
UNIT I
Separaton and dentfcaton of four meta ons of whch two are ess
famar eements ke W, Se Te, Mo, Ce, Th, T, Zr, V, U and L.
(Emnatng acd radcas not present). Confrmaton by spot tests.
UNIT II
Voumetrc Determnatons usng:
(a) EDTA (A, Ba, Ca, Cu, Fe, N, Co, hardness of water)
(b) Cermetry (Fe
2+
, ntrte)
(c) Potassum Iodate (Iodde, Sn
2+
)
UNIT III
Coormetrc Determnatons of meta ons
Fe, Cr, N, Mn and T.
R#,#r#(c#s
1. G.H. |effery, |. Basseett, |. Mendham and R.C. Denny, (o#el)s %e*t boo+
of Quantitati'e Chemical $nalysis, 5
th
Edton, ELBS, 1989.
2. D.A. Skoog and D.M. West, $nalytical Chemistry, $n Introduction, 4
th
Edton, CBS Pubshng |apan Ltd., 1986.
3. E.|. Meehan, S. Bruckensten and I.M. Kothoff and E.B. Sande,
Quantitati'e Chemical $nalysis, 4
th
Edton, The Macman Company,
1969.
4. R.A. Day (|r.) and A.L. Underwood, Quantitati'e $nalysis, 6
th
Edton,
Prentce Ha of Inda, 1993.
26
!Sc! C"EISTRY 7 SEESTER I & II
C"0PO.B C".PO. 7 ORGANIC C"EISTRY 7 I (8 Cr#d'ts)
UNIT I 2 Laborator) T#c+('>%#s
Methods of Separaton and Purfcaton of Organc Compounds
fractona, steam and ow-pressure dstatons, fractona crystasaton
and submaton.
UNIT II 2 S#1arat'o( a(d 'd#(t','cat'o( o, t+# co-1o(#(ts o, or$a('c
b'(ar) -'=t%r#s!
Anayss of about ten mxtures, some of whch contanng compounds
wth more than one functona group.
R#,#r#(c#s
1. B.S. Furns, A.|. Hannaford, P.W.G. Smth and A.R. Tatche, (o#el)s
%e*tboo+ of Practical .r#anic Chemistry, ELBS/Longman, 1989.
2. Shrner, Fuson and Cartn, Systematic Identification of .r#anic
Compounds, 1964.
3. Feser, E*periments in .r#anic Chemistry, 1957.
4. Dey, Staraman and Govndachar, $ !aboratory Manual of .r#anic
Chemistry, 3
rd
Edton, 1957.
5. P.R. Sngh, D.C. Gupta and K.S. Ba|pa, E*perimental .r#anic Chemistry,
Vo. I and II, 1980.
6. Vshno, Practical .r#anic Chemistry.
27
!Sc! C"EISTRY (I & II S#-#st#rs)
C"0PO@B C".PO@ - P+)s'ca& C+#-'str) Pract'ca& 7 I
(8 cr#d'ts)
SECTION A
UNIT I! So&%b'&'t) a(d "#at o, so&%t'o( (-'('-%- . #=1#r'-#(ts)
1. Determnaton of moar heat of souton of a substance (e.g., ammonum
oxaate, succnc acd) from soubty data - anaytca method and
graphca method
UNIT II! P+as# E>%'&'br'a (-'('-%- @ #=1#r'-#(ts)
1. (a) Determnaton of phase dagram of a smpe eutectc system (e.g.,
Naphthaene
Bpheny, Naphthaene-Dpheny amne)
(b) Determnaton of the composton of a bnary sod mxture.
2. Determnaton of phase dagram of a bnary sod system formng a
compound (e.g., Naphthaene m-dntrobenzene).
UNIT III! V'scos't) (-'('-%- . #=1#r'-#(ts)
1. Vscosty of mxtures - Verfcaton of Kendas equaton (e.g., benzene-
ntrobenzene, water-acoho).
2. Determnaton of moecuar weght of a poymer (e.g., poystyrene n
touene).
UNIT IV! D'str'b%t'o( La* (-'('-%- @ #=1#r'-#(ts)
1. Determnaton of dstrbuton coeffcent of I
2
between CC
4
and H
2
O.
2. Determnaton of equbrum constant of KI + I
2
= KI
3
3. Determnaton of concentraton of KI souton
SECTION ?
UNIT V - R#,racto-#tr) (-'('-%- @ #=1#r'-#(ts)
1. Determnaton of moar refractons of pure quds (e.g., water, methano,
ethano, choroform, carbon tetrachorde, gycero)
2. Determnaton of composton of qud mxtures (e.g., acoho-water,
gycero-water)
3. Determnaton of moar refracton and refractve ndex of a sod
substance
UNIT VI - Co(d%ct'4't) (-'('-%- 8 #=1#r'-#(ts)

1. Determnaton of equvaent conductance of a weak eectroyte (e.g.,
acetc acd), verfcaton of Ostwad's duton aw and cacuaton of
dssocaton constant.
2. Determnaton of soubty product of a sparngy soube sat (e.g., AgC,
BaS0
4
)
28
3. Conductometrc ttratons
(a) HC vs NaOH
./0 (HC + CH
3
COOH) vs NaOH
4. Determnaton of the degree of hydroyss of anne hydrochorde
UNIT VII - Pot#(t'o-#tr) (-'('-%- @ #=1#r'-#(ts)
1. Potentometrc ttraton: HC vs NaOH, CH
3
-COOH vs NaOH
2. Redox ttraton: KI vs KMnO
4
, FeS0
4
vs K
2
Cr
2
O
7
3. Determnaton of dssocaton constant of acetc acd by potentometrc
ttraton
R#,#r#(c#s
1. A. Fnay, Practical Physical Chemistry, Longmans Green & Co.
2. |.B. Frth, Practical Physical Chemistry, Read Books (Reprnt 2008).
3. A.M. |ames, Practical Physical Chemistry, Longman, 1974.
4. F. Dane, |.W. Wams, P. Bender, R.A. Aberty, C.D. Cornwe and |.E.
Harrman, E*perimental Physical Chemistry, McGraw H, 1970.
5. W.G. Pamer, E*perimental Physical Chemistry, 2
nd
Edton, Cambrdge
6. D.P. Shoemaker and C.W. Garand, E*perimental Physical Chemistry,
McGraw H.
7. |. B. Yadav, $d'anced Practical Physical Chemistry, 4oel Publications, 1989.
8. B. Vswanathan & R.S. Raghavan, Practical Physical Chemistry, Vva Books,
2009.
29
!Sc! C"EISTRY (CSS PATTERN) 7 SEESTER III
C"@CO9 - P"YSICAL C"EISTRY II (8 cr#d'ts)
(9. +)
UNIT I - Stat'st'ca& #c+a('cs - I (; +)2 Fundamentas concept of
dstrbuton, thermodynamc probabty and most probabe dstrbuton,
ensembes, statstca mechancs for systems of ndependent partces
and ts mportance n chemstry, thermodynamc probabty & entropy,
dea of mcrostates and macrostates, statstca weght factor (g),
Sterng approxmaton, Maxwe-Botzman statstcs.
The moecuar partton functon and ts reaton to the thermodynamc
propertes, dervaton of thrd aw of thermodynamcs, equbrum
constant & equ-partton prncpe n terms of partton functons, reaton
between moecuar & moar partton functons, factorsaton of the
moecuar partton functon nto transatona, rotatona, vbratona and
eectronc parts, the correspondng contrbutons to the thermodynamc
propertes; Evauaton of partton functons and thermodynamc
propertes for dea mono-atomc and datomc gases.
UNIT II - Stat'st'ca& #c+a('cs - II (; +)2 Heat capactes of sods -
cassca and quantum theores, Enstens theory of atomc crystas and
Debyes modfcaton.
Heat capactes of gases - cassca and quantum theores, the anomaous
heat capacty of hydrogen, ortho and para hydrogens.
UNIT III Stat'st'ca& #c+a('cs III (; +)2 Quantum statistics - Bose -
Ensten dstrbuton aw, Bose-Ensten condensaton, appcaton to
qud heum; Ferm - Drac dstrbuton aw, appcaton to eectrons n
metas; Reatonshp between Maxwe-Botzman, Bose-Ensten, and
Ferm-Drac statstcs.
%he li2uid state - Structure of quds, X-ray dffracton studes of smpe
quds, short range order, rada dstrbuton functon, confguratona
partton functon for quds, theores of quds - free voume theory &
smpe hoe theory, communa entropy n quds.
UNIT IV T+#r-od)(a-'cs o, Irr#4#rs'b&# Proc#ss#s (; +)2 Smpe
exampes of rreversbe processes, genera theory of non-equbrum
processes, entropy producton, the phenomenoogca reatons, Onsager
recproca reatons, appcaton to the theory of dffuson, therma
dffuson, thermo-osmoss and thermo-moecuar pressure dfference,
eectro-knetc effects, the Gansdorf-Pregogne equaton.
UNIT V 7 C+#-'ca& D'(#t'cs (; +) 2 >inetics of reactions in'ol'in# reacti'e
atoms and free radicals - Rce - Herzfed mechansm and steady state
approxmaton n the knetcs of organc gas phase decompostons
(acetadehyde & ethane); >inetics of chain reactions branchng chan
and exposon mts (H
2
-O
2
reacton as an exampe); Knetcs of fast
reactons- reaxaton methods, moecuar beams, fash photoyss;
Solution +inetics5 Factors affectng reacton rates n souton, Effect of
sovent and onc strength (prmary sat effect) on the rate constant,
secondary sat effects.
30
UNIT VI 7 o&#c%&ar R#act'o( D)(a-'cs (; +)2 &eacti'e encounters5
Coson theory, dffuson controed reactons, the matera baance
equaton, $cti'ated Comple* theory the Eyrng equaton,
thermodynamc aspects of ACT; Comparson of coson and actvated
compex theores; %he dynamics of molecular collisions - Moecuar
beams, prncpe of crossed-moecuar beams; Potential ener#y surfaces -
attractve and repusve surfaces, London equaton, Statstca
dstrbuton of moecuar energes; %heories of unimolecular reactions -
Lndemanns theory, Hnshewoods modfcaton, Rce-Ramsperger and
Kasse (RRK) mode.
UNIT VII 7 S%r,ac# C+#-'str) (; +)2 Adsorpton: Adsorpton sotherms,
Langmur's unmoecuar theory of adsorpton, Statstca dervaton of
Langmur sotherm. BET equaton, dervaton, determnaton of surface
area of adsorbents, heat of adsorpton and ts determnaton;
Expermenta methods for studyng surfaces - Prncpes of SEM, STM,
ESCA & Auger spectroscopy.
UNIT VIII 7 Cata&)s's (;+)2 Homogeneous catayss mechansm -
Arrhenus ntermedates and vant Hoff ntermedates- acd base catayss
specfc and genera acd catayss enzyme catayss- Mchaes-
Menten Mechansm- Auto catayss - oscatng reactons mechansms
of oscatng reactons (Lotko-Voterra, brusseator and oregonator)
Heterogenous catayss adsorpton and catayss- unmoecuar surface
reactons bmoecuar surface reacton Langmur-Hnshewood
mechansm and Eey-Rdea mechansm ustraton usng the reacton
2CO + O
2
2CO
2

R#,#r#(c#
U('ts I to IV
1. G.S. Rush Brooke, Statistical mechanics, Oxford
Unversty Press.
2. T.L. H, Introduction to statistical thermodynamics,
Addson Wesey.
3. K. Huary, Statistical mechanics, %hermodynamics and
>inetics, |ohn Wey.
4. O.K.Rce, Statistical mechanics, %hermodynamics and
>inetics, Freeman and Co.
5. F.C. Andrews, E2uilibrium statistical mechanics, |ohn
Wey and sons, 1963.
6. |.A. Berker, !attice theories of li2uid states, Pergamon
Press.
7. G.K. Vemuapa, Physical Chemistry, Prnce Ha Inda.
8. M.C. Guptha, Statistical %hermodynamics, Wey
eastern Ltd., 1993.
9. S. Gasstone, %hermodynamics for Chemists, East-
West, 1973
10. Pgoggne, $n introduction to %hermodynamics of
irre'ersible processes, Interscence
11. B.G. Kye, Chemical and Process %hermodynamics, 2
nd
Edn, Prentce Ha of Inda
U('ts V & VIII
31
th
Edton, W.H.
Freeman & Co., 2006.
2. Keth |. Lader, Chemical >inetics <
rd
edn., Pearson Educaton, 1987
(Indan reprnt 2008).
3. Stenfed, Francsco and Hase, Chemical >inetics and :ynamics 7
nd
edition, Prentce Ha Internatona . Inc
4. Santhosh K. Upadhyay, Chemical >inetics and &eaction :ynamics,
Sprnger, 2006.
5. Rchard I. Mase, Chemical >inetics and Catalysis, Wey Interscence,
2001.
6. K.|.Lader, |.H.Meser and B. C. Sanctuary, Physical Chemistry, Houghton
Mffn Company, New York, 2003.
7. A.W. Adamson, Physical Chemistry of surfaces, 4
th
edton, Interscence,
New York, 1982.
8. G. K. Vemuapa, Physical Chemistry, Prntce Ha of Inda.
9. M.K. Adam, %he Physics and Chemistry of surfaces, Dover Pubcatons
32
!Sc! C"EISTRY (CSS PATTERN) SEESTER III
C"@CO6 - INORGANIC C"EISTRY II (8 Cr#d'ts) (9. +)
U('t I (; +r)2 Eectronc spectra of compexes, Term of d
n
confguratons,
seecton rues. Effect of gand fed on RS terms. Orga dagram and ts
uses. Tanabe-Sugano dagrams, Charge transfer spectra, Spectra of f-
bock compexes.
U('t II (; +r)2 Magnetc propertes of meta compexes- types of magnetc
propertes paramagnetsm and dagmagnetsm- Cure an Cure-Wess
aw. ,
1+s
and spn ony expressons. Orbta magnetc
moment and ts quenchng, Spn-orbt coupng. Temperature
ndependent paramagnetsm. Spn cross over n coordnaton
compexes, magnetc propertes of f-bock eements. Ferro and antferro
magnetc nteractons. Determnaton of magnetc moment- Gouy
method.
U('t III (; +r)2 Reacton mechansms of meta compexes. Cassfcaton, Rate
aws, Substtuton reactons n octahedra compexes. A, D and I
mechansms. Aquaton and base hydroyss, Fuoss- Egen equaton.
Substtutons n square panar compexes. Trans effect- theores and
appcatons. The cs-effect.
U('t IV (; +r)2 Redox racton mechansm, cassfcaton, outer sphere and
nner sphere eectron transfer. Marcus equaton. Brdgng group effects,
photochemca reactons of meta compexes. Photosubsttuton,
photoaquaton and gand exchange reactons- meta compex
senstzers, photochemca reactons of chromum and ruthenum
compexes.
U('t V (; +r)2 Infrared spectra of meta compexes, Group frequency concept.
Changes n gand vbratons on coordnaton- meta gand vbratons.
Spectora appcaton of coordnaton compounds - IR spectra of meta
carbonys - ESR spectra- appcaton to copper compexes, Mossbauer
spectra- appcaton to ron compexes - Appcaton of NMR spectra of
damagnetc compexes.
U('t VI (; +r)2 Organometac compounds I - Cassfcaton and nomencature,
Carbon - donors, Akys and arys of man group metas- synthess,
structure, bondng and appcatons. Organometac compounds of
transton metas. The 18 eectron rue, syntheses, structure and
bondng n meta carbonys, carbenes, carbynes.
U('t VII (; +r)2 Organometac compounds II - Coordnaton of transton
metas to carbon mutpe bonds, synthess, structure, bondng and
appcatons of compexes of ethyene, ay, butadene and acetyenes.
Synthess, structure, bondng and reactons of typca transton meta
compexes of C
4
H
4
, C
5
H
5
and C
6
H
6
.
U('t VIII (; +r)2 Introducton to bonorganc chemstry, occurrence of
norganc eements n boogca system, buk and trace meta ons,
coordnaton stes n boogcay mportant gands. Effect of the nature
of meta ons and gand on the stabty of the compexes. Roe of
sodum, potassum and cacum n boogca system. Metaoenzymes:
33
Zn(II) contanng enzymes, ron enzymes, peroxdase, copper enzymes-
oxdase, tyrosnase, superoxde dsmutase, Vtamn B
12
and coenzymes.
Cytochromes and ron-suphur protens. Ntrogenases, boogca
ntrogen fxaton, chorophy-photosystem 1 and I.
R#,#r#(c#s2
1. D.F. Shrver, P.W. Atkns and C.H. Langford, Inor#anic Chemistry,
ELBS, 1990.
2. |.E. Huhey, E.A. Keter and R.L. Keter, Inor#anic Chemistry, Principles,
Structure and &eacti'ity, Pearson Education, 2001.
3. F.A. Cotton and G. Wknson, $d'anced Inor#anic Chemistry, Wey.
4. R.S. Drago, Physical methods in Inor#anic Chemistry, Affated East-
West Press Pvt. Ltd., 1977.
5. R.L. Dutta and A. Shyama, Elements of Ma#netochemistry, S. Chand
& Co., 1982.
6. A. Earnshaw, Introduction to Ma#netochemistry, Academc Press,
1968.
7. D. Sutton, Electronic Spectra of %ransition Metal Comple*es, McGraw
H, 1968.
8. |.C. Bar |r. (Ed.)., %he Chemistry of Coordination Compounds,
Renhod Pub. Cor., 1960.
9. L.F. Lndoy, %he Chemistry of Macrocyclic !i#ands and Comple*es,
Cambrdge Unversty Press, 1989.
10. G.Wufsberg, Inor#anic Chemistry, Unversty Scence Books, 2000.
11. Hoeman- Wberg, Inor#anic Chemistry, Academc Press, 1995.
12. G.L. Messer and D.A. Tarr, Inor#anic Chemistry, Person Educaton,
2004.
13. P. Powe, Principles of .r#anometallic Chemistry, 2
nd
Edton, ELBS,
1988.
14. R.C. Mehrothra and A. Sngh, .r#anometallic Chemistry, $ ?nified
$pproach, Wey Eastern, 1991.
15. R.W. Hay, "ioinor#anic Chemistry, Es Horwood Ltd., 1984.
16. D.E. Fenton, "iocoordination Chemistry, Oxford Unversty Press,
1995.
17. L.F. Lndoy, %he Chemistry for Macrocyclic !i#ands and Comple*es,
Cambrdge Books, 1994.
18. S.|. Lppard and |.M. Berg, Principles of "ioinor#anic Chemistry,
Unversty Scence Books, 1994.
19. I. Bertn, H.B. Gray, S.|. Lppard and |.S. Vaentne, "ioinor#anic
Chemistry, Vva Books Pvt. Ltd., 1998.
34
C"@EO0 S)(t+#t'c Or$a('c C+#-'str) (E&#ct'4#) (8 cr#d'ts)
UNIT I2 For-at'o( o, Carbo(-Carbo( bo(d (; +r)2 Carbon- Carbon bond
formaton va Eectrophtc and nuceophc carbon speces. Base
cataysed condensatons, Mannch base as ntermedates n organc
synthess, four centre reacton- Des Ader reacton, 1,3-dpoar
addtons.
R#,#r#(c#s2
1. R.O.C. Norman, Prncpes of Organc Synthess.
2. R.K. Mchae and B. Smth, Organc synthess.
3. Hendrckson, Cram and Hammond, Organc Chemstry.
4. F.A. Carey and R.|. Sundberg, Advanced Organc Chemstry Part B, 3
rd
Edton, Penum Press.
5. S. Warren, Organc Synthess, The Dsconnecton Approach, |ohn Wey.
UNIT II (; +r)2 (') For-at'o( o, Carbo(-N'tro$#( ?o(d (; +r)2
Nuceophc ntrogen and eectrophc carbon, Eectrophc ntrogen and
nuceophc carbon skrarp synthess, Bscher- Naparask reacton.
('') For-at'o( o, Carbo(-"a&o$#( ?o(d2 Ayc haogenaton by
NBS, NCS and NIS photochemca methods of organc synthess (sutabe
exampe).
R#,#r#(c#s2
rd
Edton, Penum Press.
3. R.K. Mchae and B. Smth, Organc Synthess.
4. |. March, Advanced Organc Chemstry, 4
th
edton, |ohn Wey and Sons,
1992.
UNIT III2 R#d%ct'o( a(d O='dat'o( (; +)2 Cataytc hydrogenaton, Meta
hydrde reductons, dssovng meta reductons. Reducton of specfc
functona group- reducton of akenes, akynes of adehydes and ketones
to acohos. Ketones to methyene group reductve rng openng of
epoxdes. Reducton of unsaturated carbony compounds, reducton of
aromatc and heterocycc compounds.
Oxdaton wth transton meta oxdants (Cr, Mn) Oxygen, O
3
, and
peroxdes, ead tetra acetate and ScO
2
oxdaton of carbon- carbon
doube bonds, acohos, gycos, ketones, and adehydes, ayc oxdaton,
oxdatve-decarboxyaton.
R#,#r#(c#s2
1. W. Carruthers, Modern Methods of Organc Synthess, Cambrdge
2. H.O. House, Modern Synthetc Reacton, W.A. Ben|amn, 1965.
35
UNIT IV2 R#a$#(ts '( Or$a('c S)(t+#s's (; +r)2 Use of the foowng
reagents n organc synthess and functona group transformaton
compex meta hydrdes, Gmans reagent, Tr-n-buty tn hydrde,
organometac reagents of Aumnum, Cadmum, Znc, and Fe. Benzene
Trcarbony Chromum, preparaton and reacton wth carbanons.
R#,#r#(c#s2
1. Feser and Feser, Reagents n Organc Synthess.
2. S.G. Daus, Organotranston meta chemstry appcaton to Organc
Synthess, Pergman Press, London, 1982.
3. H.O. House, Modern Synthetc Reactons.
4. W. Carnethers, Some modern methods of Organc Synthess, Ben|amn
Pubcatons, Caforna, 1972.
5. V.K. Ahuwaa and R. Agarwa Organc Synthess, Speca technques,
Narose.
6. M.B. Smth, Organc Synthess, 2
nd
edton, McGraw H.
7. P.R. |enkns, Organometac reagents n synthess, Ou prmer 3 oup.
UNIT V2 %&t' st#1 S)(t+#s's (; +r)2 Synthetc anayss and pannng,
Eements of a Synthess (Reacton methods, reagents, cataysts,
sovents, protectve groups for hydroxy, amno, Carbony and carboxyc
acds, actvatng groups, eavng groups synthess and synthetc
equvaents. Types of seectvtes (Chemo, rego, stereo seectvtes)
synthetc pannng ustrated by smpe moecues, dsconnectons and
functona group nterconversons, upong reactons and use n synthess,
Retrosynthetc anayss of a compex moecue- a case study.
R#,#r#(c#s2
1. |ohn McMurry, Organc Chemstry, 5
th
Edton, 2000, or newer.
2. Stuart Warren Desgnng, Organc Synthess, Programmed ntroducton to
the synthess approach, 1994.
3. Casscs n Tota synthess K.C.Ncoaou, E.|. Sorenson, VCH, 1996.
4. Organc synthess, Mchea Smth, 2
nd
Edton, McGraw H, 2004.
rd
Edton, Penum Press.
UNIT VI2 S)(t+#s's o, Nat%ra& Prod%cts (; +r)2 Synthetc studes on
Longfoene, Reserpne, Prostaganden E, Cephaosporn, Vtamn A.
R#,#r#(c#s2
1. I. Femng, Seected Organc Synthess, |ohn Wey and Sons, 1982.
2. T. Landbery, Strateges and Tactcs n Organc Synthess, Academc
Press, London,1989.
3. E. Corey and I.M. Chang, Logc of Chemca Synthess, |ohn Wey, New
York, 1989.
th
Edton, ELBS, 1925.
UNIT VII2 Pa&&ad'%- Cata&)s#d Co%1&'($ R#act'o( (; +)2 Paadum
Cataysts for C-N and C-O bond formaton, Paadum catayzed amne
aryaton (Mechansm and Synthetc appcatons). Sonogashra cross
coupng reacton (Mechansm, Synthetc appcatons n Cycc peptdes)
Ste carbonyatve cross coupng reacton (Mechansm and synthetc
appcatons).
36
R#,#r#(c#s2
1. Meta Cataysed cross coupng reactons, Deckrch, F and Stang P.|,
Eds., Wey, VCH, New York, 1988.
2. V. Farne, V, Krshnamurthy, Scott W.|., The ste reacton, |ohn Wey and
Sons, New York, 1998.
3. Lazzo Kurt and Barbosa Czako, Strategc appcaton of Named reactons
n Organc synthess, Ecener Academc Press, 2005.
UNIT VIII2 "#t#roc)c&'c co-1o%(ds (; +r)2 Aromatc and nonaromatc
heterocycc, common structured types, structure, synthess and
reactons of oxazoe, pyrazoe, mdazoe and thazoe synthess of uraco,
thymne and cytosne. Synthess of adenne and guanne. Synthess of
urc acd, caffene, pyrazne, synthess of furanones, tetrazoe.
R#,#r#(c#s2
1. I.L. Fnar, Organc Chemstry, Vo.II, 5
th
Edton, ELBS, 1975.
2. Acheson, An ntroducton to the chemstry of Heterocycc compounds,
Interscence, 1960.
3. Badger, The Chemstry of Heterocycc Compounds, Academc Press,
1961.
37
!Sc! C"EISTRY (CSS PATTERN) SEESTER III
C"@EO. 2 NATURAL PRODUCTS (E&#ct'4#) (8 Cr#d'ts)
UNIT I2 (; +r)2 (') Ta=o(o-) o, P&a(ts2 Locaton, dentfcaton, cutvaton,
coecton, storage and uses of the foowng medcna pants- Ocmum
sanctum, Phyanthus, adathoda Vasca and Rawofa serpentna.
('') C&ass','cat'o( o, Nat%ra& Prod%cts2 Cassfcaton of Natura
products based on chemca structure, physoogca actvty, taxonomy
and Bogeness. Carbohydrates, Terpenods, Carotenods, akaods,
sterods, anthocyanns etc. Methods of soaton of each cass of
compound.
R#,#r#(c#s2
1. V.V. Svara|an and Mana K.S., ,lora of Calicut6
2. H, Economic "otany6
3. Lawrence, %a*onomy of (ascular Plants, New Deh, 1974.
4. A.B. Rende, %he Classification of ,lo1erin# Plants, Cambrdge Unversty
Press, 1871.
5. |.S. Gambe, ,lora of the Presidency of Madras, Bot. Survey of Inda,
Cacutta, 1957.
6. Ko| Nakansh, Tosho Goto, Sho Ito, Shnsaku Nator, and Shge Nozoe
(Eds.), 0atural Products Chemistry, Vo. I, Kodansha Scentfc Ltd., 1974.
7. N.R. Krshnaswamy, Natura Products Chemstry, Oxford Unversty Press.
UNIT II2 T#r1#(o'ds (; +r)2 Methods of soaton, Cassfcaton and
genera structure eucdaton of terpenods, soprene rue. Synthess of
Lupeo and -amyrn, structure eucdaton of Farneso and Mentho,
stereochemstry of camphor and abetc acd.
R#,#r#(c#s2
1. P. De Meyo, %he hi#her %erpenoids6
2. A.R. Pnder, %he Chemistry of %erpenes6
3. Smonson, Terpenods.
4. A.A. Newman (Ed.), %he Chemistry of %erpenoids6
5. I.L. Fnar, .r#anic Chemistry, Vo.II, 5
th
edton, ELBS, 1975.
UNIT III2 St#ro'ds (; +r)2 Cassfcaton and soaton of sterods. Detaed
study ncudng structure eucdaton, synthess and stereo-chemstry of
the foowng.
Choestero, Ergostero, Ergocacfero, Oesterone, Dosgenn, Oestrado,
Oestro, Equenne, Androsterone, Testosterone, Progestrone, Be acds,
Choc acd, Cortsone and Cortcosterone.
R#,#r#(c#s2
1. Feser and Feser, Steroids, Asa Pubshng House, 1959.
2. Kyne, %he chemistry of steroids6
3. Shoppe, Chemstry of the sterods.
4. Tempeton, $n Introduction to the Chemistry of the %erpenoids and
Steroids6
th
Edton, ELBS, 1975.
38
UNIT IV2 A&<a&o'ds (; +r)2 Nomencature, cassfcaton, soaton,
chromatography and other technques of purfcaton. Detaed study of
the foowng. Morphne, Reserpne, Tyophorn and Lysergc acd.
R#,#r#(c#s2
1. K.W. Bentey, $l+aloids, Interscence Pubshers, 1965.
2. R.H.F. Manske and H.L. Homass, %he $l+aloids-chemistry and
Physiolo#y, Academc Press Inc., 1952.
3. Henry, %he Plant $l+aloids6
th
Edton, ELBS, 1975.
UNIT V (; +r)2 (') A(t+oc)a('(s2 Introducton, Genera Nature and
Structure of Anthocyandns. Favone, Favono, Ouercetn, Isofavone
(Dadezen) and Chacone.
R#,#r#(c#s2
1. Bentey, %he 0atural pi#ments,, Interscence.
2. Gessman (ed.), %he Chemistry of ,la'onoid Compounds, Pergamon.
3. Bernfe (ed.), "io#enesis of 0atural Compounds, Pergamon6
4. Harborne, Comparati'e "iochemistry of ,la'onoids, Academc Press,
1967.
th
Edton, ELBS, 1975.
('') Prosta$&a(d'(s2 Chemstry of Prostagandns- Isoaton,
Cassfcaton, Structura eucdaton and Synthess of PGE, PGF, PGA and
PGB groups of prostagandns.
R#,#r#(c#s2
1. S.H. Pne, |.B. Hendrckson, D. |. Cram and G.S. Hammond, .r#anic
UNIT VI (; +r)2 (') A11&'cat'o( of IR, UV, NMR, Mass, CD and ORD n the
structura eucdaton of Natura products.
R#,#r#(c#s2
1. :etermination of .r#anic Structure by Physical Methods, Vo.I to IV,
Academc Press.
2. Schwarz (Ed.), Physical Methods in .r#anic Chemistry, Over and Boud,
1964.
3. D|ersass, .ptical &otatory :ispersion, McGraw H, 1960.
4. Crabbe, .ptical &otatory :ispersion and Circular :ichroism in .r#anic
Chemistry, Hodern Day, 1965.
5. Wam and Femng, Spectroscopic methods in .r#anic Chemistry,
McGraw H, 1966.
6. Bbe, Interpretation of 0M& spectra, Penum Press, 1965.
'') "a#-'( a(d C+&oro1+)&2 Structure and synthess of Porphyrns,
Chemstry of Haemn and Chorophy.
R#,#r#(c#s2
1. I.L. Fnar, .r#anic Chemistry, Vo. II, 5
th
edton, ELBS, 1975.
39
2. D. Neson and M. Cox, !enein#er8s Principles of "iochemistry, Worth
Pubshers, New York.
UNIT VII2 Ess#(t'a& O'&s a(d Aro-at'cs (; +r)2 Isoaton and study of
mportant consttuents of emon grass o, ctronea o, agowan o,
cnnamon o, pamarosa o, rosemary o, patchou o, peppermnt o,
turpentne o, cove o, sandawood o, avender o, rose o. Essenta
os of turmerc and gnger. Oeoresns of pepper, chy, gnger and
turmerc, use of essenta o n medcne- Aromatherapy.
R#,#r#(c#s2
1. The essenta os, The consttuent of essenta os by Ernest Guenther,
1975.
2. Organc Chemstry by I.L. Fnar, Vo. II.
UNIT VIII2 V'ta-'(s (; +r)2 Occurrence, soaton, boogca sgnfcance
(bref dea) and synthess of the foowng vtamns: Vtamn A, E, K,
Thamne, Rbofavn, Pyrdoxne, Nacn, Pantothenc acd and ascorbc
acd.
R#,#r#(c#s2
1. Organc Chemstry by I.C. Fnar, Vo. II.
2. Chemstry of Natura Products by Bhat, Nagasampag and Svakumar,
2005, Narosa Pubshng.
40
C"@EO@! Po&)-#r C+#-'str) (E&#ct'4#) (8 Cr#d'ts)
UNIT I2 #t+ods o, Po&)-#r'Eat'o( (; +r)2 Step reacton (Condensaton)
Poymerzaton: Mechansm, types and Knetcs of condensaton
poymerzaton. Interfaca condensaton. Rng verses chan formaton.
Bfunctona and Poyfunctona step reacton poymerzaton- geaton,
gepont- expermenta, observaton, Moecuar weght dstrbuton, Rng
scsson poymerzaton.
Radca Chan (Addton) Poymerzaton: Vny poymerzaton, Vny
monomers, Mechansm of Vny poymerzaton, Expermenta methods n
Vny poymerzaton. Knetcs of free radca poymerzaton, Degree of
poymerzaton-chan transfer. Moecuar weghts and ts dstrbuton.
Effect of temperature and pressure on chan poymerzaton.
Ionc Poymerzaton: Anonc poymerzaton- Intaton and Propagaton
Mechansms, Knetcs, Lvng poymerzaton, Ionc equbrum. Moar
mass dstrbuton. Transfer and termnaton, stereocontro, catonc
poymerzaton- Mechans, Knetcs, Radaton actvated poymerzaton.
UNIT II2 #t+od o, Po&)-#r'Eat'o( II (; +r)2 Suspenson and emuson
poymerzaton of mono and hetrodsperse poymers.
Co-ordnaton Chan Poymerzaton: Zeger- Natta Catayss.
Mechansm, Knetcs- Rng openng poymerzaton.
Co-poymerzaton: Dfferent types of copoymers, knetcs of co-
poymersaton (Free rada and Ionc). The co-poymerzaton equatons,
composton of copoymers, Mechansm of co-poymerzaton- Monmer
reactvty ratos and co-poymersaton parameters. Chemstry of co-
poymerzaton, Reactvty and structure of monomers and radcas.
Poymerzaton n homogenous and heterogeneous systems. Gas phase
poymerzaton, Buk poymerzaton and poymer precptate.
UNIT III2 C+#-'ca& r#act'o(s o, 1o&)-#rs (; +r)2 Basc prncpes,
Moecuar and chemca groups. Reactvty of functona groups. Post
reactons of poymers- Chan Extenson, Branchng and gross nkng
reactons, poymer anaogues reactons. Poymer Degradaton reactons,
Poymer bends, Functonazaton of poystyrene. Preparaton of on
exchange resns, poymer-bound reagents, mmobzed enzymes. Sod
phase peptde synthess (SPPS) merts and demerts.
UNIT IV2 C&ass','cat'o( o, Po&)-#rs (; +r)2 Pastcs, rubbers and fbers,
thermosets and thermopastc, near, branched and cross-nked
poymers, random, bock and graft co-poymers and stereo specfc
poymers.
UNIT V2 Po&)-#r So&%t'o(s (; +r)2 Genera roe of poymer soubty
parameters Fory-Huggns treatment of poymer souton, enthapy,
entropy an free energy change n poymer dssouton. Unperturbed
chan dmenson, vscosty of poymer souton, osmotc pressure,
41
sweng of poymers, fractonaton of poymers, phase separaton n
poymers.
UNIT VI (; +)2 Studes on the therma, optca, eectrca and mechanca
propertes of poymers, correaton of structure to these propertes. Frst
order and second order transton ponts. Gass transton temperature,
Metng temperature- Expermenta method of ther determnatons.
Method of moecuar weght determnaton of poymers. End-group
anayss, cogatve property measurement, concentraton dependence
of cogatve propertes, Vapour pressure owerng, cryoscopy and
osmometry, Lght-scatterng methods. Utra centrfugaton, Souton
vscosty and moecuar sze, expermenta methods, treatment of data,
staudnger ndex, emprca correatons between ntrnsc vscosty and
moecuar sze of poymer structure. Ge permeaton chromatograph and
other chatographc technques n the fractonaton poymers.
UNIT VII2 Po&)-#r D#$radat'o( (; +r)2 Mechansm of Poymer degradaton.
Therma, mechanca and photochemca degradatons. Oxdaton and
ozone attack. Acd and base hydroyss, Bo-degradaton of poymers.
UNIT VIII2 Str%ct%r# a(d a11&'cat'o(s o, t+# ,o&&o*'($ (; +r)2
a) Ceuose and ceuose based poymers- Natve and modfed cotton
Rayon. Ceuose ntrate, ceuose acetate.
b) Poyoefns- Poyethyene and Poypropyene.
c) Vnypoymers- PVC, Poystyrene, acryc poymers.
d) Furocarbon poymers- Tefon.
e) Pheno formadehyde and urea formadehyde resns.
f) Poyamdes (Nyon) and Poyesters (Teryenes)
g) Carproactam based poymers.
42
R#,#r#(c#s
1. F.W. Bmeyer, Text Book of Poymer Scence, Wey-Inter Scences
(1976).
2. G.Odan, Prncpes of Poymerzaton, McGraw H, 1970.
3. Eas, Macromoecues Penum Press, 1980.
4. M.L. Mer, The structure of Poymers Renhod, 1968.
5. C.M. Bow and C.Hephrun (eds.) Rubber Technoogy and Manufacture,
Buthesworthes, 1982.
6. I.M. Campbe, Introducton to poymers, Oxford Scentfc Pubcatons,
1994.
7. K. |. Saunders, Organc Poymer Chemstry Chapman and Ha, London,
Mathur, Narang and Wams, Poymers as Ads n Organc Chemstry,
Academc Press, London.
43
!Sc! C"EISTRY (CSS PATTERN) 7 SEESTER IV
C"8CO; Ad4a(c#d To1'cs '( C+#-'str) (8 Cr#d'ts)
UNIT I 2 #ta& C&%st#rs (; +)2 Meta-meta bonds and meta custers- snge,
doube, trpe and quadrupe bonded non-carbony custers. The sooba
anaoges custer structure and eectron count. The Wade- Mngos-
Lauher rues, Hgher carbony custers.
UNIT II 2 R#act'o( 1at+*a)s o, Or$a(o-#ta&&'c co-1o%(ds (; +)2
Oxdatve addton and reductve emnaton- mechansm, Oxdatve
coupng and reductve ceavage. Inserton reactons nvovng CO, NO,
Isocyande, akenes, akynes, CO
2
and SO
2
. , emnatons.
Nuceophc addtons and abstractons to coordnated egends such as
CO, poyenes, akys and acys Eectrophec addton and abstracton to
aky groups. Carbonyaton by Comans reagent.
UNIT III 2 Cata&)s's b) or$a(o-#ta&&'c co-1&#=#s (; +)2 Akene
hydrogenaton, somersaton, hydroboraton and hydroformyaton of
akenes, Monsanto acetc acd process, Wacker process Dmerzaton,
Ogomerzaton and Poymerzaton, Fscher-Trops reacton, Watergas
shft reacton.
UNIT IV 2 #d'c'(a& C+#-'str) (; +)2 Drugs: Introducton, dfferent casses
of drug, drug acton, drug desgn, prodrugs, factors governng drug
desgn, ratona approach to drug desgn, SAR and OSAR, physco-
chemca factors and boogca actvtes, factors governng abty of
drugs. Genera methods of drug synthess. Anagescs (Phenazones and
Phenybutzone as exampes), Antpyretc (Paracetamo), Antbotcs,
Pencns, Choramphanco.
UNIT V 7 Gr##( C+#-'str) (; +)2 Introducton, the need of green chemstry,
prncpes of green chemstry, pannng of green synthess, toos of green
chemstry; Green reactons - Ado condensaton, Cannzaro reacton and
Grgnard reacton, comparson of the above wth cassca reactons;
Green preparatons, Appcatons phase transfer cataysts, Introducton to
Mcrowave organc synthess, Appcatons: envronmenta, sovents, tme
and energy benefts.
UNIT VI 7 Na(osc'#(c# a(d T#c+(o&o$) (; +)2 Introducton,
nanostructures: tubes, fbers, wres, brcks and budng bocks,
nanostructure formaton: thography, sef-assemby,moecuar
synthess,crysta growth and poymerzaton, measurement of
nanostructure: spectroscopy,mcroscopy and eectrochemstry, nano
CAD.
UNIT VII - Na(o-at#r'a&s (; +)2 Nanocompostes, consumer goods, smart
materas, Appcatons to varous feds:optcs, teecommuncaton,
eectroncs, dgta technoogy and envronment, Bomedca appcatons:
dagnosaton, protc engneerng, mappng of genes, drug devery,
bommetcs, quantum dots.
UNIT VIII 7 S%1ra-o&#c%&ar C+#-'str) (; +)2 Molecular reco#nition5
Receptors, desgn and synthess of co-receptors and Mutpe recognton,
44
Hydrogen bonds, strong, weak and very weak H-bonds, Utsaton of H-
bonds to create supramoecuar structures, Use of H-bonds n crysta
engneerng and moecuar recognton.
Caton bndng hosts, bndng of anons, bndng of neutra moecues,
bndng of organc moecues. Supramoecuar reactvty and catayss.
Transport processes and carrer desgn. Supramoecuar devces,
supramoecuar photochemstry. Nove qud crystas, Geators fbres
and adhesves, Dendrmers, organc sods, organc conductors and
organc superconductors, catenanes and rotaxanes
R#,#r#(c#s
1. F.A. Cotton, G. Wknson, C.A. Muro and M. Bochmann, Advanced
Inorganc Chemstry, 6
th
edton, Wey, Chchester, 1999.
2. |.N. Degado and W.A. Remers, (Ed.), @ilson and 4is'old)s %e*tboo+ of
.r#anic Medicinal and Pharmaceutical Chemistry, 10
th
Edton, Lppncott
Raven Pubshers, 1998.
3. Harkshan Sngh and V.K. Kapoor, Medicinal and Pharmaceutical
Chemistry, Vaabh Prakashan, 2008.
4. G. Thomas, ,undamentals of Medicinal Chemistry, Wey.
5. A. Grngauz, Introduction to Medical Chemistry, Wey VCH, 1997.
6. P.T. Anastas and |.C. Warner, 4reen Chemistry5 %heory and Practice,
Oxford Unversty Press, Oxford, 1998.
7. |ames Cark and Duncan Macquarre, 3andboo+ of 4reen Chemistry and
%echnolo#y, Backwe Scence, 2002.
8. |.H. Cark, %he Chemistry of @aste MinimiAation, Backe Academc,
London, 1995.
9. |epng Zhu and Hugues Benayme (Ed.), Multi Component &eactions,
Wey VCH Veag GmbH & Co., KGaA, Wenhem, 2005.
10. |.M. Martnez Durat, R.|. Martn Pama and F. Aguo Rueda,
0anotechnolo#y for Microelectronics and .ptoelectronics, Esever, 2003.
11. G.A. Ozn and A.C. Arsenaut, 0anochemistry, RSC Pubshng, 2008.
12. C.P. Pooe (|r.) and F.|. Owens, Introduction to 0anotechnolo#y, Wey,
2007.
13. F. Vgte, Supramolecular Chemistry, |ohn Wey & Sons, Chchester,
1991.
14. H. Dugas (Ed.), "ioinor#anic Chemistry, Sprnger Verag, New York, 1996.
45
!Sc! C"EISTRY (CSS PATTERN) SEESTER IV
C"8E/8 INSTRUENTAL ET"ODS OF ANALYSIS (E&#ct'4#)
(8 Cr#d'ts)
U('t I2 O1t'ca& #t+ods-I (; "rs)2 Theory, Instrumentaton and Appcatons
of (a) Atomc Absorpton Spectrometry (AAS) (b) Atomc Fuorescence
Spectrometry (AFS) (c) UV-Vsbes IR spectrometry (d) Nepheometry
and Turbdometry and (e) Fame Photometry.
U('t II2 O1t'ca& #t+ods-II (; "rs)2 Theory, Instrumentaton and
Appcatons of (a) X-ray absorpton and X-ray dffracton, (b) X-ray
Photoeectron Spectrometry (XPES), (c) Utravoet Photo Eectron
Spectrometry (UPES), (d) Auger Eectron Spectroscopy (AES), (e)
Scannng Eectron Mcroscopy (SEM) and (f) Scannng Tunneng Eectron
Mcroscopy (STEM)
U('t III2 E&#ctro A(a&)t'ca& #t+ods (; "rs)2 Theory, Instrumentaton and
Appcatons of a) Eectro grammetry b) Couometry c) Amperometry
d) Cycc Votammetry e) Poarography f) Chronopotentometry and
g) Strppng anayss.
U('t IV2 T+#r-a& a(d Rad'oc+#-'ca& #t+ods (; "rs)2 Theory
Instrumentaton and Appcatons of: (a) Thermogrammetrc Anayss
(TGA), (b) Dfferenta Therma Anayss (DTA), (c) Dfferenta Scannng
Caormetry (DSC), (d) Thermometrc Ttratons, (e) Thermo Mechanca
Anayss (TMA) and (f) Daatometrc Anayss (DMA).
U('t V2 S#1arat'o( T#c+('>%#s ( ; "rs)2 Theory and appcatons of
sovent extracton and on exchange methods. Uses of oxne, dthazone,
hgh moecuar weght amnes, dthocarbamate and crown ethers n
extracton.
Chromatography- Cassfcaton, Theory, Instrumentaton and uses of
Paper, thn ayer, qud, coumn and gas chromatography, HPLC.
U('t VI2 E(4'ro(-#(ta& A(a&)s's (; "rs)2 Ar poutants, Ar quaty
standards, sampng technques and montorng of ar poutants.
Water poutants- Organc and Inorganc water quaty parameters and
standards, BOD, COD and TOC determnatons.
U('t VII2 A(a&)s's o, Dr%$s a(d P+ar-ac#%t'ca&s (; "rs)2 Modern
methods of drug anayss- Prncpe of estmaton of hemogobn,
choestero and Bood sugar.
Theory of anayss of mk, butter, starch based food products and
beverages.
Anayss of fats and os- Iodne vaue and saponfcaton vaue ther
sgnfcance.
U('t VIII2 I(trod%ct'o( to Co-1%tat'o(a& :%a(t%- C+#-'str) (; "rs)2
Eectronc structures of moecues- Revew of Hartree- Fock SCF method,
Bass sets STOs and GTOs- Nomencature of Bass sets. Sem emprca
46
and ab nto methods. Cacuatons usng Gaussan Programme.
Specfcaton of moecuar geometry usng a) Cartsan coordnates and
b) Interna coordnates. The Z-matrx, Z matrces of some smpe
moecues ke H
2
, Water, forma dehyde, ammona, and methano.
R#,#r#(c#s2
1. Voges, Test book of Ouanttatve Inorganc Anayss.
2. Skoog and West, Prncpes of Instrument Anayss.
3. Ward, Merrt and Dean, Instrumenta Methods of Anayss.
4. Offca Methods of Anayss of the A.O.A.C.
5. |.G. Dck, Anaytca Chemstry.
6. C.L. Wson and D.W. Wson, Comprehensve Anaytca Chemstry.
7. A.K. De, Envronmenta Chemstry.
8. Donad F Cabreath, Cnca Chemstry- A fundamenta Textbook.
9. Pecksock, Sheds, Carms and McWam, Modern Methods of
Chemca anayss.
10. D.A. Mc Ouarre and |.D. Smon, Physca Chemstry, A moecuar
approach.
11. I.N. Levn, Ouantum Chemstry 5
th
Edn.
12. T. Cane, A Hand Book of Computatona Chemstry.
13. F.|ensen, Introducton to Computatona Chemstry.
47
!Sc! C"EISTRY 7 SEESTER IV
C"8EOA - COPUTATIONAL C"EISTRY (8 cr#d'ts) (9. +)
U('t I I(trod%ct'o( (; +)2 Theory, computaton & modeng Defnton of
terms; Need of approxmate methods n quantum mechancs;
Computabe Ouanttes structure, potenta energy surfaces and
chemca propertes; Cost & Effcency reatve CPU tme, software &
hardware; Cassfcaton of computatona methods.
U('t II Co-1%t#r s'-%&at'o( -#t+ods I (; +)2 Introducton moecuar
dynamcs and Monte Caro methods, cacuaton of smpe
thermodynamc propertes - energy, heat capacty, pressure and
temperature, phase space, practca aspects of computer smuaton,
perodc boundary condtons, Montorng the equbraton, anayzng the
resuts of a smuaton, error estmaton.
U('t III Co-1%t#r s'-%&at'o( -#t+ods II (; +)2 Moecuar dynamcs (MD)
method moecuar dynamcs usng smpe modes MD wth contnuous
potentas, fnte dfference methods, choosng the tme step, settng up
and runnng a MD smuaton; Monte Caro (MC) method - cacuatng
propertes by ntegraton, Metropos method, random number
generators, MC smuaton of rgd moecues.
UNIT IV ab '(t'o -#t+ods '( co-1%tat'o(a& c+#-'str) (;+)2 Revew of
Hartree Fock method for atoms, SCF treatment of poyatomc
moecues; Cosed she systems - restrcted HF cacuatons; Open she
systems ROHF and UHF cacuatons; The Roothan Ha equatons,
Koopmans theorem, HF mt & eectron correaton, Introducton to
eectron correaton (post-HF) methods.
UNIT V D#(s't) F%(ct'o(a& #t+ods (; +)2 Introducton to densty
matrces, N-reprentabty & V-represetabty probems, Hohenberg
Kohn theorems, Kohn-Sham orbtas; Exchange correaton functonas
Thomas-Ferm-Drac mode, Loca densty approxmaton, generased
gradent approxmaton, hybrd functonas; Comparson between DFT
and HF methods.
UNIT VI ?as's s#t a11ro='-at'o( (; +)2 Hydrogen-ke, Sater-type &
Gaussan type bass functons, cassfcaton of bass sets mnma,
doube zeta, trpe zeta, spt-vaence, poarzaton & dffuse bass sets,
even tempered & we tempered bass sets, contracted bass sets, Pope-
stye bass sets and ther nomencature, correaton consstent bass sets,
bass set truncaton error, effect of choce of method/ bass set (mode
chemstres) on cpu tme.

UNIT VII I(trod%ct'o( to Ga%ss'a( /@ Pro$ra- (;+)2 Input fes
convertng a structure from a graphcs program Man features of
Gaussan output fes Use of graphcs programs ke Gaussvew,
Chemcraft, Moda and Moden n anayzng Gaussan output data -
Identfcaton and vsuazaton of norma modes of vbraton - Cacuaton
and nterpretaton moecuar orbtas.
48
UNIT VIII Ca&c%&at'o(s %s'($ G/@ Pro$ra- (; +)2 Snge pont energy
cacuatons; Geometry optmzaton & Frequency cacuatons - ocatng
oca mnma and sadde ponts on potenta energy surfaces, scang
frequences and zero pont energes; Transton state optmzatons
characterzng transton states, the norma mode and IRC anayses.
R#,#r#(c#
T#=t ?oo<s
1. C. |. Cramer, Essentials of computational Chemistry5 %heories and
models, |ohn Wey & Sons 2002.
2. Frank |ensen, Introduction to Computational Chemistry, |ohn Wey &
Sons LTD 1999.
3. |. Foresman & Aeeen Frsch, E*plorin# Chemistry 1ith Electronic
Structure Methods, Gaussan Inc., 2000.
F%rt+#r R#ad'($
1. Davd Young, Computational Chemistry- $ Practical 4uide for $pplyin#
%echni2ues to &eal-@orld ProblemsB, Wey-Interscence, 2001.
2. Erro G. Lewars, Computational Chemistry5 Introduction to the theory and
applications of molecular 2uantum mechanics, 7
nd
edn6, Sprnger 2011.
th
Edton, Pearson Educaton Inc.,
2009.
4. P.W. Atkns & R.S. Fredman, Molecular 2uantum mechanics, 4
th
Edton,
5. W. Koch, M.C. Hothausen, C$ Chemist8s 4uide to :ensity ,unctional
%heoryB, Wey-VCH Verag 2000.
49
!Sc! C"EISTRY (CSS PATTERN) 7 SEESTER IV
C"8E /C - ATERIAL SCIENCE (8 cr#d'ts) (9. +)
UNIT I I(trod%ct'o( to at#r'a& Sc'#(c# (;+)2 Introducton, cassfcaton
of materas, functona cassfcaton, cassfcaton based on structure,
envronmenta and other effects, matera desgn and seecton;
Mechanca propertes sgnfcance and termnoogy, the tense test,
true stress and true stran, bend test, hardness of materas.
UNIT II C#ra-'c -at#r'a&s (;+)2 Defnton of ceramcs, tradtona and
new ceramcs, structure of ceramcs, atomc nteractons and types of
bonds, phase equbra n ceramc systems, one component and mut
component systems, use of phase dagrams n predctng matera
behavour, eectrca, magnetc, and optca propertes of ceramc
materas.
UNIT III Na(o-at#r'a&s a(d (a(ot#c+(o&o$) (;+)2 Nano materas, nano
structures, sef assemby, Nano partces - methods of synthess, so-ge
process, hydroyss of sats and akoxdes, precptaton, condensaton
reactons, eectroknetc potenta and peptzaton reactons; Geaton
network - xeroges, aeroges, dryng of ges; Chemca modfcaton of
nano surfaces, appcatons of so-ge process, so-ge coatng, porous
sods, cataysts, dspersons and powders.
UNIT IV at#r'a&s ,or s1#c'a& 1%r1os#s 7 I (;+)2 Producton of utra pure
materas - zone refnng, vacuum dstaton and eectro refnng;
Ferroeectrc and pezoeectrc materas - genera propertes,
cassfcaton of ferroeectrc materas, theory of ferroeectrcty,
ferroeectrc domans, appcatons, pezoeectrc materas and
appcatons; Metac gasses - preparaton, propertes and appcatons.
UNIT V 7 at#r'a&s ,or s1#c'a& 1%r1os#s 7 II (;+)2 Magnetc materas, ferr
and ferro magnetsm, metac magnets, soft, hard & superconductng
magnets; Ceramc magnets, ow conductng and superconductng
magnets; Superconductng materas - metac and ceramc
superconductng materas, theores of superconductvty, Messner
effect; Hgh temperature superconductors - structure and appcatons.
UNIT VI 7 So-# s1#c'a& 1o&)-#rs (;+)2 Functona poymers -
photoconductve, eectroconductve, pezoeectrc and ght senstve
poymers; Industra poymers - producton, propertes, & compoundng of
ndustra poymers; Commodty pastcs such as PP, PE, PVC, & PS;
Engneerng pastcs such as poyacety, poyamde (nyon 6 and nyon
66), poyacryate, poycarbonate, poyester (PET, PBT), poyether
ketones; Thermosettng pastcs such as PF, UF & MF.
UNIT VII 7 Co-1os't# at#r'a&s (;+)2 Defnton and cassfcaton of
compostes, fbres and matrces; Compostes wth metac matrces
processng, sod and qud state processng, deposton;
Ceramc matrx composte materas processng, mxng & Pressng,
qud state processng, so-ge processng & vapor deposton technque;
50
Interfaces n compostes - mechanca & mcrostructura characterstcs;
Appcatons of compostes.
UNIT VIII 7 Fract%r# #c+a('cs (;+)2 Importance of fracture mechancs,
mcro structura features of fracture n metas, ceramcs, gasses &
compostes , Webu statstcs for faure, strength anayss; Fatgue,
appcaton of fatgue testng - creep, stress rupture & stress behavor,
evauaton of creep behavor.
R#,#r#(c#s
1. W.D. Engery, H.K. Dowen and R.D. Uhman, Introduction to Ceramics, |ohn
Wey.
2. A.G. Guy, Essentials of Material Science, McGraw H.
3. M.|. Starfed and Shrager, Introductory Material Science, McGraw H.
4. S.K. Ha|ra Choudhary, Material Science and En#ineerin#, Indan Book Dst.
Co., Cacutta.
5. M.W. Barsoum, Fundamentas of Ceramcs, McGraw H, 1997.
6. M. Tnkham, Introduction to Superconducti'ity, McGraw H, 1975.
7. A.V. Narkar and S.N.Edbote, Superconducti'ity and Superconductin#
Materials, South Asan Pubshers, New Deh, 1983.
8. S.V. Subramanyan and E.S. Ra|agopa, 3i#h %emperature
Superconductors, Wey Eastern Ltd., 1988.
9. Azaroff and Brophy, Electronic Processes in Materials, McGraw H, 1985.
10. C.M. Srvastava and C. Srnvasan, Scence of Engneerng Materas, Wey
Eastern Ltd., 1987.
11. R.|. Young, Introduction to Polymer Science, |ohn Wey and Sons.
12. V.R. Gowrker and Others, Polymer Science, Wey Eastern Ltd.
13. H. Urch, Introduction to Industrial Polymers, Hansen Pubshers, 1982.
14. F.R. |ones, 3andboo+ of Polymer ,ibre Composites, Longman Scentfc
and Tech.
15. K.K. Chowa, Composite Materials, Sprnger-Verag, NY, 1987.
51
!Sc! C"EISTRY (CCS PATTERN) SEESTER IV
C"8EO6 ?IOINORGANIC AND ORGANOETALLIC
C"EISTRY (E&#ct'4#) (8 Cr#d'ts)
U('t I2 ?'o'(or$a('c C+#-'str)-I (; +)2 Coordnaton stes n boogcay
mportant gands. Thermodynamc and knetc aspects of stabty.
Eectronc and geometrca structures of meta ons n boogy. Roe of
aka meta ons n boogca systems. Ionophores and passve
transport. Sodum pump and actve transport.
U('t II2 ?'o'(or$a('c C+#-'str) II (; +)2 Metao enzymes and eectron
carrer metao protens. Lews acd. Roe of Zn (II) and Mg (II) contanng
enzymes. Redox enzymes. Iron enzymes- cytochrome P-450, cataase,
peroxdase.
Copper enzymes- Oxdase, superoxde dsmutase vtamn B
12
and Co-
enzyme.
U('t III2 ?'o'(or$a('c C+#-'str) III (; +)2 Transport of oxygen by Heme
protens- hemogobn and myogobn. Non heme oxygen carrers,
hemerythrn hemocyann and hemovanadns.
Structure and functon of protens n eectron transport process,
cytochromes and ron suphur protens.
U('t IV2 ?'o'(or$a('c C+#-'str) IV (; +)2 Boenergetcs and ATP cyce,
gucose storage, chorophy photosystem I and II. Ntrogenases-
Boogca ntrogen fxaton, other ntrogenases, mode systems.
Meta defcency and dseases, toxc effects of metas, meta compexes
used for dagnoss and chemotherapy, Antcancer drugs.
U('t V (; +)2 Genera characterstcs of organometac compexes.
Nomencature, cassfcaton, theoretca aspects of 16 and 18 eectro
rues. Transton meta compexes of H
2
, N
2
and Oxygen- Formaton
structure, bondng and reactons.
U('t VI (; +)2 Appcatons of organometac compounds n Organc synthess
an catagyss- oxdatve addton- reductve emnaton and nserton
reactons. Substtuton reactons n carbony compexes- nuceophc and
eectrophc attack on coordnated egands, carbonyaton by Comanns
reagent.
U('t VII (; +)2 Catayss, genera prncpes, homogeneous and
heterogeneous reactons, cataytc steps.
Homogeneous catayss: Hydrogenaton of akenes, asymmetrc
hydrogenaton cycoaddtons and poymerzaton of akynes.
Hydroformyaton of akenes, Monsanto acetc acd process, Wacker
process.
U('t VIII2 Heterogeneous cataysts: Zeger Natta Catayss, ammona
synthess, SO
2
oxdaton, zeote based heterogeneous catayss cataytc
appcatons nvovng paadum.
52
R#,#r#(c#s2
1. S.L. Lppard and |.M. Berry, Prncpes of Bonorganc Chemstry,
Unversty Scence Books, Caforna, 1997.
2. D.E. Fenton, Bocoordnaton Chemstry, Oxford Unversty Press,
Oxford, 1995.
3. Ivam Bertn, Harry B Gray, Stephen. |. Lppard and |oan Severstone,
Vaentne, Bonorganc Chemstry, Unversty Scence Books, 1994.
4. R.W. Hay, Bonorganc Chemstry, Es Horwoord, 1984.
5. D.F. Shrver, P.W. Atkns and C.H. Langford, Inorganc Chemstry,
ELBS, 1990.
6. |.E. Huheey, E.A. Kerter and R.L. Keter, Inorganc Chemstry,
Prncpes Structure and Reactvty, Pearson, 2001.
7. F.A. Cotton and G. Wknson, C.A Muro and M. Bochmann, Advanced
Inorganc Chemstry, |ohn Wey & Sons, 1999.
8. P. Powe, Prncpes of Organometac Chemstry, 2
nd
Edton, ELBS,
1988.
9. R.C. Mehrothra and A. Sngh, Organometac Chemstry a unfed
approach, Wey Eastern, 1991.
53
!Sc! C"EISTRY (CSS PATTERN) SEESTER III & IV
C"@PO8 a(d C"8PO8 7 INORGANIC C"EISTRY PRACTICALS
II (8 Cr#d'ts)
1. Estmaton nvovng quanttatve separaton of sutabe bnary mxtures
of ons n souton (Cu
2+
, N
2+
, Zn
2+
, Fe
3+
, Ca
2+
, Mg
2+
, Ba
2+
and Cr
2
O
1
2-
) by
voumetrc coormetrc or gravmetrc methods ony one of the
components to be estmated.
2. Coormetrc estmaton of N, Cu, Fe and Mo after separaton from other
ons n souton by sovent extracton.
3. Ion- exchange separaton and estmaton of bnary mxtures (Co
2+
& N
2+
,
Zn
2+
& Mg
2+
Hardness of water).
4. Preparaton of Inorganc Compexes. (5 Nos)
R#,#r#(c#s2
1. Voges Text Book of Ouatatve Inorganc Anayss.
2. I.M. Kothoff and E.A. Sanderson, Ouanttatve Chemca Anayss.
3. D.A. Adams and |.B. Rayner, Advanced Practca Inorganc Chemstry.
4. W.G.Pamer, Expermenta Inorganc Chemstry.
5. G. Brauer, Hand book of Preparatve Inorganc Chemstry.
54
!Sc! C"EISTRY (CSS PATTERN) SEESTER III & IV
C"@POAB C"8POA 7 ORGANIC C"EISTRY (8 CREDITS)
UNIT I 2 :%a(t'tat'4# Or$a('c A(a&)s's
Estmaton of equvaent weght of acds by Sver Sat method,
Estmaton of ntrogen by K|edah method, Determnaton of Acd vaue,
odne vaue and saponfcaton vaue of os and fats (at east one each),
Estmaton of reducng sugars, Estmaton of amno group, phenoc
group and esters. Coourmetrc estmatons: Vtamns (Ascorbc acd),
Drugs supha drug (Supha dazne, suphaguandne), Antbotcs
Pencn, Stroptomycn.
R#,#r#(c#s
1. B.S. Furns, A.|. Hannaford, P.W.G. Smth and A.R. Tatche, (o#el)s
%e*tboo+ of Practical .r#anic Chemistry, ELBS/Longman, 1989.
2. Beebet, Pharmacuetical $nalysi.
UNIT II 2 Extracton of Natura products and purfcaton by coumn
chromatography and TLC Caffene from Tea waste, Choroph Sterods,
Favonod (Soxhet extracton), ctra from emon gass (steam
dstaton). Casen from mk.
UNIT III 2 Practca appcaton of PC and TLC, Preparaton of TLC pates,
Actvaton, Identfcaton of the foowng casses of compounds usng
one- and two-dmensona technques. Identfcaton by usng spray
reagents and co-chromatography by authentc sampes and aso from Rf
vaues.
Food addtves and Dyes, Artfca sweeteners: Saccharne, cycamates,
Ducn. Favour aduterants pperona, Benzaacetate, ethy acetate
antoxdants: Butyated hydroxytouene (BHT) Butyated hydroxy ansoe
(BHA), Hydroqunone.
Food coours: Permtted Amaranth, Erythrosne, Tatrazne, susnet
yeow, Fast green, Brant Bue, Nonpermtted coours: Auramne,
Congo red, Maachte green, Metan yeow, Orange II, Sudan II, Congo
red.
Amno acds (Proten hydroysates), Sugars, Terpnods, Akaods,
Favonods, Sterods.
Pestcdes and herbcdes: Oragonochorne pestcdes organo phosphates
and carbamate postcdes, Herbcdes.
Pant growth stmuants: Indoacetc acd.
R#,#r#(c#s
1. E. Hoftmann, Chromato#raphy, non Nostrand Renhod Company, New
York, 1975.
2. |. Sherma and G. Zwg, %!C and !C analysis of pesticides of international
importance, Vo. VI & VII, Academc Press.
55
3. H. Wagner, S. Badt, E.M. Zganst Tram, Th. A. Scott., Plant :ru#
$nalysis, Sprnger-Verag, Tokyo, 1984.
56
!Sc! C"EISTRY (III & IV S#-#st#rs)
C"@POCB C"8POC 7 P"YSICAL C"EISTRY PRACTICAL II
(4 credts) (36 LS)
UNIT I 2 C+#-'ca& D'(#t'cs (8 #=1#r'-#(ts)
1. Determnaton of specfc reacton rate of acd hydroyss of an
ester (methy acetate or ethy acetate) and concentraton of the
gven acds.
2. Determnaton of Arrhenus parameters of acd hydroyss of an
ester.
3. Determnaton of specfc reacton rate of saponfcaton of ethy
acetate.
4. Iodnaton of acetone n acd medum Determnaton of order of
reacton wth respect of odne and acetone.
UNIT II Adsor1t'o( (@ #=1#r'-#(ts)
1. Verfcaton of Langmur adsorpton sotherm charcoa-acetc
acd system.
Determanton of the concentraton of a gven acetc acd souton
usng the sotherm
2. Verfcaton of Langmur adsorpton sothem charcoa-oxac
acd system.
Determnaton of the concentraton of a gven acetc acd souton
usng the sothem.
3. Determnaton of surface area of adsorbent.
UNIT III P+as# E>%'&'br'a (. #=1#r'-#(ts)
1. (a) Determnaton of phase dagram of a ternary qud system (e.g.,
choroform acetc acd water Benzene acetc acd water)
(b) Determnaton of the composton of a bnary qud mxture (e.g.,
choroform-acetc acd, benzene-acetc acd)
2. (a) Determnaton of mutua mscbty curve of a bnary qud system
(e.g., pheno water) and crtca souton temperature (CST).
(b) Effect of mpurtes (e.g, NaC, KC, succnc acd, sacyc acd) on the
CST of water-pheno system)
(c) Effect of a gven mpurty (e.g., KC) on the CST of water-pheno
system and determnaton of the concentraton of the gven souton of
KC.
UNIT IV Cr)osco1) 7 ?#c<-a( t+#r-o-#t#r -#t+od (@ #=1#r'-#(ts)
1. Determnaton of cyroscopc constant of a qud (water, benzene)
57
2. Determnaton of moecuar mass of a soute (urea, gucose, cane sugar,
mannto) by studyng the depresson n freezng pont of a qud sovent
(water, benzene)
3. Determnaton of Van't Hoff factor and percentage of dssocaton of
NaC.
4. Study of the reacton 2K + Hg
2
K
2
Hg
4
and determnaton of the
concentraton of the gven K souton.
UNIT V Po&ar'-#tr) ( @ #=1#r'-#(ts)
1. Determnaton of specfc and moar optca rotatons of gucose, fructose
and sucrose.
2. Determnaton of specfc rate of nverson of cane sugar n presence of
HC.
3. Determnaton of concentraton of HC
UNIT VI S1#ctro1+oto-#tr) (@ #=1#r'-#(ts)
1. Determnaton of equbrum constants of acd-base ndcators.
2. Smutaneous of determnaton Mn and Cr n a souton of KMnO
4
and
K
2
Ce
2
O
7
3. Investgaton of compex formaton between Fe (III) and thocyanate.
R#,#r#(c#
1. A. Fnay and |.A. Ktchener, Practical Physical Chemistry, Longman.
2. F. Danes and |.H. Mathews, E*perimental Physical Chemistry, Longman.
3. A.H. |ames, Practical Physical Chemistry, |.A. Church Ltd., 1961.
4. H.H. Ward, L.L. Mert and |.A. Dean, Instrumental Methods of $nalysis,
4
th
Educaton, Affated East-West Press Pvt. Ltd., 1965.
5. D.P. Shoemaker and C.W. Garand, E*perimental Physical Chemistry,
McGraw H.
6. |.B. Yadav, $d'anced Practical Physical Chemistry, 4oel Publications,
1989.
58
SECTION ?
UNIT VII Co-1%t#r A11&'cat'o(s '( C+#-'str)(6 #=1#r'-#(ts)
(The experment consst of wrtng a computer programme n C anguage for a
probem of chemca nterest and ts executon usng a computer. The student
sha generate a hard copy of the programme and the resuts usng a prnter
for submsson)
1. Cacuaton of dpoe moments of dsubstuted benzenes.
2. Cacuaton of deocazaton energy.
3. Determnaton of attce energy of onc crystas musng Born Lande
equaton.
4. Determnaton of soubty of sparngy soube sats.
5. Determnaton of haf fe & average fe of a radoactve eement.
6. Determnaton of moecuar weght of an organc compound.
7. Determnaton of frst ten energy eves of ) an eectron ) a heum atom
) carbon 60 and v) a partce of mass g confned n a one-
dmensona box of ength 100nm and comparson of energy spacng of
these systems.
8. Comparson of the transatona quantum numbers of ) an eectron
) heum atom ) carobon-60 and v) a 1- g partce confned n a
one-dmensona box of ength 100nm at room temperature (E =
n
2
h
2
/8ma
2
= kT/2).
9. Determnaton of Arrhenus parameters of acd hydroyss of methy
acetate by the method of east squares by wrtng a C programme
(Necessary knetc data are provded).
10. Verfcaton of Langmur and Freundsch adsorpton sothems by the
method of east square by wrtng a C programme and determnaton of
adsorpton parameters. (Necessary adsorpton data are provded)
R#,#r#(c#
1. K.V. Raman, Computer in Chemistry, Tata McGraw H, 1993.
2. E. Baaguruswamy, Pro#rammin# in C. Macman Inda Ltd., 1991.
3. Mchae, A. Vne, C6 Pro#rammin# for the $bsolute "e#inner, Thompson
Course Technoogy, 2007.
4. Dan Gookn, C6 Pro#rammin#, |ohn Wey and Sons, 2004.
5. K.B. Wberg, Computer Pro#rammin# for Chemists, Ben|amn Inc, NY,
1965.
6. P.Lykose, Personal Computers in Chemistry, |ohn Wey and sons, NY,
1981.
:UESTION PAPER
1. Each student s requred to answer two questons, one based on one or
more unts n Secton A (60 marks) and the other from Secton B (20
marks)
2. Each student n a batch sha be gven separate questons.
59

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