1.

EKSTRAKSI Co
Konsentrasi (ppm)
0
1
2
4
6
8
10

Absorbansi
-0.002
0.010
0.023
0.043
0.058
0.083
0.100

0.120

Kurva Standar

Absorbansi

0.090
0.060
0.030
0.000
0

-0.030

pH sampel
1.9
4.13
6.1
7.93
10.11
12.11

Absorbansi (y)
0.068
0.061
0.041
0.014
0.004
0.004

Konsentrasi (x)
6.703
6.010
4.030
1.356
0.366
0.366

Konsentrasi (ppm)

[Mn+]air (ppm)
10.054
9.015
6.045
2.035
0.550
0.550

[Mn+]organik (ppm)
-0.054
0.985
3.955
7.965
9.450
9.450

10

14

Kurva log D Vs pH
2.00

log D

1.00
0.00
0

12

-1.00
y = 0.3516x - 2.5356
R = 0.935

-2.00

pH

-3.00

pH ekstraksi
2.31
5.63

%E
0.545
9.851

39.554
79.653
94.505
94.505

%E vs pH
120.0
90.0

%E

6.41
7.05
7.94
11.16

60.0
30.0
0.0
0
-30.0

pH ekstraksi

rva Standar
y = 0,0101x + 0,0003
dimana
y= absorbansi
x= konsentrasi = (y-b)/a
y = 0.0101x + 0.0003
R = 0.9964

10

y=ax +b
a=
b=

0.0101
0.0003
[Mn+]awal=

12

[Mn+]air (ppm) =

Konsentrasi (ppm)

x . Fp

[Mn+]organik (ppm) =
log D
-2.266
-0.961
-0.184
0.593
1.235
1.235

%E
-0.545
9.851
39.554
79.653
94.505
94.505

pH awal
1.9
4.13
6.1
7.93
10.11
12.11

Log D
-2.266
-0.961
-0.184
0.593
1.235
1.235

D
-0.005
0.109
0.654
3.915
17.198
17.198

y = 0,3516x - 2,5356
y= ax + b

Ar Co=

dimana,
y=
b=
a=
x=

58.93

log D
log Kex + n Log [HRn] =
n=
0.3516
pH

Log Kex=
Kex=

b- n log [HRn]
antilog (b- n log[HRn])

Kex=
Kex=

antilog (-2,5356- (0,3516 log (0,001)^0,3516))

6.84E-03 (kalkulator)

E vs pH
7.94, 94.505

y = 12.518x - 31.393
R = 0.736
8

pH ekstraksi

10

12

10 ppm
dimana Fp=

1.5

10 ppm - [Mn+]air

-2.5356

Kurva Standar

Absorbansi
0.002
0.013
0.025
0.047
0.068
0.092
0.108

0.120

Absorbansi

2. EKSTRAKSI Ni
Konsentrasi (ppm)
0
1
2
4
6
8
10

0.090
0.060
0.030
0.000
0

Konsentrasi (ppm)

pH sampel
2.12
4.04
6.00
8.07
10.12
12.10

Absorbansi (y)
0.076
0.065
0.056
0.047
0.014
0.006

Konsentrasi (x)
6.759
5.741
4.907
4.074
1.019
0.278

[Mn+]air (ppm)
10.139
8.611
7.361
6.111
1.528
0.417

[Mn+]organik (ppm)
-0.139
1.389
2.639
3.889
8.472
9.583

Kurva log D Vs pH
2.00

0.00
0.00

5.00

10.00

15.00

-1.00
y = 0.2986x - 2.3111
R = 0.9648

-2.00

pH

-3.00

pH ekstraksi
2.62
6.04
6.66
7.12
7.04

%E
1.389
13.889
26.389
38.889
84.722

120.00
90.00
60.00

%E

log D

1.00

95.833

%E

60.00

11.25

30.00

-30.00

a Standar

y = 0,0108x + 0,003
y=
x=
y = 0.0108x + 0.003
R = 0.9981

10

absorbansi
konsentrasi=

b=
a=

0.003
0.0108

12

Konsentrasi (ppm)

[Mn+]awal=
[Mn+]air (ppm) =

x . Fp

%E
-1.389
13.889
26.389
38.889
84.722
95.833

pH awal
2.12
4.04
6.00
8.07
10.12
12.10

log D
-1.863
-0.792
-0.446
-0.196
0.744
1.362

D
-0.014
0.161
0.358
0.636
5.545
23.000

Ar Ni=

y=
b=
a=
x=

Kex=
Kex=

antilog(-2,3111-(0,2986 log (0,001)^0,2986))

9.04E-03 (kalkulator)

60.00

10 ppm - [Mn+]air

58.71

log D
log Kex + n Log [HRn]
n=
0.2986
pH

b- n log [HRn]
antilog (b- n log[HRn])

90.00

1.5

y = 0,2986x - 2,3111

Log Kex=
Kex=

120.00

10 ppm
dimana Fp=

[Mn+]organik (ppm) =
log D
-1.863
-0.792
-0.446
-0.196
0.744
1.362

(y-b)/a

%E vs pH

11.25, 95.833

-2.3111

60.00
y = 11.628x - 35.416
R = 0.6947

30.00
0.00
0.00
-30.00

2.00

4.00

6.00

pH ekstraksi

8.00

10.00

12.00