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CM 1401 Formulae Sheet: E = hc/λ K = (RT) K

This document contains a list of common formulae used in chemistry, including equations for heat transfer, entropy, Gibbs free energy, reaction stoichiometry, ideal gas law, cell potentials, reaction kinetics, and acid-base equilibria. Some key constants provided include the gas constant R, Faraday's constant F, Boltzmann's constant k, and the equilibrium constant for water Kw.

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69 views1 page

CM 1401 Formulae Sheet: E = hc/λ K = (RT) K

This document contains a list of common formulae used in chemistry, including equations for heat transfer, entropy, Gibbs free energy, reaction stoichiometry, ideal gas law, cell potentials, reaction kinetics, and acid-base equilibria. Some key constants provided include the gas constant R, Faraday's constant F, Boltzmann's constant k, and the equilibrium constant for water Kw.

Uploaded by

hagdinclooble
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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CM 1401 Formulae Sheet

HT2 = HT1 + CP(T2 T1)

Constants

rHo =vfHo(products) vfHo(reactants)

h = 6.626 x 10-34 J s
8

c = 3 x 10 m s

S = k ln W

-1

Suniv = Ssystem + Ssurroundings

-1

R = 8.314 J K mol

-1

Ssystem = nCp,m ln (T2/T1)


-1

-1

Stransition = Htransition/T

= 0.0821 L atm mol K

1 atm = 760 Torr = 1.01325 bar = 101325 Pa

Ssurroundings = -Hsystem/T

= 760 mm Hg

rSo = vSoproducts vSoreactants


G = H TS

0 C = 273 K
F = 96485 C mol

-1

rGo = vfGo(products)vf Go(reactants)

Kw = 1 x 10-14

G = G + RT ln Q
23

Avogradros number: 6.022 x 10 mol

-1

G = -RT ln K => K = exp(-G/RT)


ln (K2/K1) = (-H/R) (1/T2 1/T1)

Formulae

Kp = (RT)n Kc

E = hc/
E = -2.18 x 10

-18

E = -2.18 x 10

(Z /n )

-18

x . m u h/4
PV = nRT
U = q + w
q = mCsT
q = nCmT
U = qv = nCv,mT
H = qp = nCp,mT
w = -PexV

J (Z /nfinal Z /ninital )

= h/mu

H = U + PV

Eocell = Eo (cathode) Eo (anode)

Go = -nFEocell
Ecell = Ecell (RT/nF) ln Q
Ecell = Ecell (0.0591/n) lg Q (at 298 K)
Ecell = (RT/nF) ln K
Ecell = (0.0591/n) lg K (at 298 K)
[A]t = -kt + [A]0 (zero-order)
ln [A]t = -kt + ln [A]0 (first-order)
1/[A]t = kt + 1/[A]0 (second-order)
k = A exp(-Ea/RT)
ln (k2/k1) = (-Ea/R) (1/T2 1/T1)
pH = pKa + log10 ([base]/[acid])

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