CHEMISTRY 001 INFORMATION SHEET W24

The following data have been taken from the CRC Handbook. Some of the values may be different from those in the textbook.
For atomic masses, use the Periodic Table.

General Information:

Avogadro's number = 6.022045 x 1023/mol Gas constant, R = 8.314 kPa L/mol K

Specific heat of water = 4.184 J g- 1 oC - 1 = 8.314 J/mol K
= 0.08206 L atm/mol K
Conversion Factors:

LENGTH 1 cm = 1.0 x 108 Å MASS 1g = 0.03527 oz.

1 cm = 0.3937 in. 1 kg = 35.27 oz.
1m = 39.3701 in. 1 kg = 2.205 lb.
1m = 3.281 ft. 1 kg = 9.84 x 10 - 4 ton
1m = 1.0936 yd 1 kg = 1.00 x 10 - 3 tonne
1 km = 3280.840 ft. 1 ton = 2240 lb.
1 km = 0.6214 mi.
1 mi = 1760 yd. PRESSURE 1 atm = 760 mm Hg
1 atm = 101.33 kPa
VOLUME 1 cm3 = 1 mL 1 atm = 760 torr.
1L = 1000 cm3 1 atm = 14.69 lb in - 2
1L = 61.025 in3
1L = 0.03532 ft3 ENERGY 1J = 1 kg m2 s - 2
1L = 1.760 pt. 1J = 1 kPa L
1L = 0.8799 qt. 1 cal = 4.184 J
1L = 0.220 Cdn.Gal. 1 ev = 1.60 x 10 - 19 J
1 fl. oz. = 28.41 cm3
1 qt. = 2 pt.
1 gal. = 8 pt.

Solubility products (at 25oC):

BROMIDES FLUORIDES IODIDES

PbBr2 6.60 x 10 - 6 BaF2 1.84 x 10 - 7 HgI2 2.82 x 10 - 29

AgBr 5.35 x 10 - 13 CaF2 1.46 x 10 - 10 PbI2 8.49 x 10 - 9
CrF3 6.60 x 10 - 11 AgI 8.51 x 10 - 17
CARBONATES FeF2 2.36 x 10 - 6
SrF2 4.33 x10 - 9 SULFATES
BaCO3 2.58 x 10 - 9 ZnF2 3.04 x 10 - 2
CaCO3 4.96 x 10 - 9 BaSO4 1.07 x 10 - 10
MgCO3 6.82 x 10 - 6 HYDROXIDES PbSO4 1.82 x 10 - 6
Ag2CO3 8.45 x 10 - 12 Ag2SO4 1.20 x 10 - 5
Al(OH)3 1.90 x 10 - 33
CHLORIDES Ca(OH)2 4.68 x 10 - 6 SULFIDES
Fe(OH)3 2.64 x 10 - 39
PbCl2 1.17 x 10 - 5 Mg(OH)2 5.61 x 10 - 12 Bi2S3 1.82 x 10 - 99
AgCl 1.77 x 10 - 10 Ni(OH)2 5.47 x 10 - 16 FeS 1.59 x 10 - 19
Sn(OH)2 5.45 x 10 - 27 PbS 9.04 x 10 - 29
CHROMATES Ag2S 6.69 x 10 - 50
ZnS 2.93 x 10 - 25
PbCrO4 2.0 x 10 - 16
Ag2CrO4 1.12 x 10 - 12

ix
Dissociation Constants (at 25oC):

Ka acetic acid CH3COOH 1.8 x 10 - 5 Kb ammonia NH3 1.8 x 10 - 5

benzoic acid C6H5COOH 6.5 x 10 - 5 aniline C6H6NH2 4.3 x 10 - 10
formic acid HCOOH 1.8 x 10 - 4 methylamine CH3NH2 3.7 x 10 - 4
hydrocyanic acid HCN 4.9 x 10 - 10 pyridine C5H5N 1.8 x 10 - 9
hydrofluoric acid HF 3.5 x 10 - 4 trimethylamine (CH3)3N 6.4 x 10 - 5
nitrous acid HNO2 4.6 x 10 - 4
propanoic acid C2H5COOH 1.3 x 10 - 5 Kw water H2O 1.0 x 10 - 14

Thermodynamic Data (25oC, 1 atm or 1 mol/L):

ΔHof (kJ/mol) ΔHof (kJ/mol) ΔHof (kJ/mol)

Al(s) - COCl2(g) - 218.8 N2(g) -

Al2O3(s) - 1675.7 F2(g) - NH3(g) - 46.11
Br2(l) - Fe(s) - NO(g) 90.25
Br2(g) 30.91 Fe2O3(s) - 824.2 NO2(g) 33.18
C(s) - H2(g) - NaCl(s) - 411.1
CH4(g) - 74.81 H2O(g) - 241.8 NH4Cl(s) - 314.4
C2H2(g) 226.7 H2O(l) - 285.9 O2(g) -
C2H4(g) 52.26 H+(aq) 0.00 O3(g) 142.7
C2H6(g) - 84.68 OH - (aq) - 230.0 P(s) -
CH3I(g) 13.0 HCl(g) - 92.31 PCl3(g) - 287.0
CH3Cl(g) - 80.83 HBr(g) - 36.40 PCl5(g) - 398.9
Cl2(g) - HI(g) 26.48 SO2(g) - 296.8
CO(g) - 110.5 H2S(g) - 20.6 SO3(g) - 395.7
CO2(g) - 393.5 I2(s) - SiO2 - 903.5

Electrode Potentials (Eo volts at 25oC):

Li+ + e - Æ Li - 3.040 2H+ + 2e - Æ H2 0.000
Ca2+ + 2e - Æ Ca - 2.868 AgBr + e - Æ Ag + Br - 0.071
+ - 4+ - 2+
Na + e Æ Na - 2.714 Sn + 2e Æ Sn 0.151
Mg2+ + 2e - Æ Mg - 2.372 AgCl + e - Æ Ag + Cl - 0.222
3+ - 2+ -
Al + 3e Æ Al - 1.662 Cu + 2e Æ Cu 0.342
2H2O + 2e - Æ H2 + 2OH - - 0.828 I2 + 2e - Æ 2I - 0.536
2+ - + -
Zn + 2e Æ Zn - 0.762 O2 + 2H + 2e Æ H2O2 0.695
Cr3+ + 3e - Æ Cr - 0.744 Fe3+ + e - Æ Fe2+ 0.771
- 2- + -
Ag2S + 2e Æ 2Ag + S - 0.691 Ag + e Æ Ag 0.799
S + 2e - Æ S2 - - 0.476 Hg2+ + 2e - Æ Hg 0.851
2+ - - -
Fe + 2e Æ Fe - 0.447 Br2 + 2e Æ 2Br 1.066
Cr3+ + e - Æ Cr2+ - 0.407 O2 + 4H+ + 4e - Æ 2H2O 1.229
- 2- - -
PbSO4 + 2e Æ Pb + SO4 - 0.359 Cl2 + 2e Æ 2Cl 1.358
Ni2+ + 2e - Æ Ni - 0.257 PbO2 + SO42 - + 4H+ + 2e - Æ PbSO4 + 2 H2O 1.691
- - + -
AgI + e Æ Ag + I - 0.152 O3 + 2H + 2e Æ O 2 + H 2O 2.076
Sn2+ + 2e - Æ Sn - 0.138 F2 + 2e - Æ 2F - 2.866
2+ -
Pb + 2e Æ Pb - 0.126

x
Nomenclature

https://studylib.net/doc/25509016/flowchart-for-naming-chemical-compounds-