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Tng quan
Title
Tng quan v VL
Mt s c trng
c bn ca VL
Tnh hnh sn xut
v ng dng
Tng quan v vt liu
Titan ioxit l cht rn mu trng, khi nung nng c
mu vng, khi lm lnh tr li mu trng. TiO
2
c
cng cao, kh nng chy (Tnc = 1870
0
C).
Tng quan v vt liu
Cu trc mng li tinh th ca rutile, anatase v
brookite u c xy dng t cc a din phi tr
tm mt (octahedral) TiO
6
ni vi nhau qua cnh hoc
qua nh oxi chung, mi ion Ti
4+
c bao quanh bi
tm mt to bi su ion O
2-
Tng quan v vt liu
Ngoi 3 th hnh ni trn th TiO2 cn tn ti dng
v nh hnh nhng khng bn do lu trong khng
kh nhit phng hoc khi c nung nng th
chuyn sang dng anatase.
Dng v nh hnh c iu ch bng cch
thy phn mui c c Ti
4+
hoc cc dng hp cht
hu c titan trong nc nhit thp thu c kt
ta TiO
2
v nh hnh.
Trong cc dng th hnh TiO
2
th dng anatase th
hin hot tnh quang xc tc cao hn cc dng cn
li.

Tnh hnh sn xut
Trn Th gii: Cng ngh nano ang l mt cuc cch
mng si ng: cc nc pht trin nh M, Nht Bn
ang dn u trong lnh vc cng ngh mi nhn ny. Cc
nc chm pht trin cng k vng thot ngho nh cng
ngh nano. Theo s liu ca Hi ngh quc t v cng ngh
nano nm 2007 c t chc ti M, tng u t vo cng
ngh nano nm 2005 l 8 t USD, d kin n nm 2010 s
l 21 t USD. Nhiu sn phm nano TiO2 c thng
mi ho nh: vt liu nano TiO
2
(M, Nht Bn), my lm
sch khng kh khi nm mc, vi khun, virus v kh mi
trong bnh vin, vn phng, nh (M); khu trang nano
phng chng ly nhim qua ng h hp (Nht Bn); vi t
lm sch, giy kh mi dit vi khun (c, c), gch lt
ng phn hu kh thi xe hi (H Lan); pin mt tri ( Thu
S, M).
Tnh hnh sn xut
Vit Nam: Vt liu nano TiO
2
c nhiu nh
khoa hc quan tm vi nhng thnh cng ng khch
l. Gn 100 cng trnh v vt liu nano TiO
2
c
cng b trong v ngoi nc. Tuy nhin, cc kt qu
ny thin v nghin cu c bn. Vic a vo ng
dng thc tin cn b hn ch do cn phi vt qua
ro cn v hiu qu kinh t v khoa hc v cng
ngh (KH&CN). Mt s sn phm ng dng c
pht trin nh: cm bin tia t ngoi nanocomposit,
thit b o cng bc x t ngoi; in cc trong
sut dn in; lm sch mi trng nc, khng kh
b nhim ho cht v vi sinh vt cng c
nghin cu pht trin nh khu trang nano chng
cm gia cm, vi nano, vt liu lc nc nano
ng dng
Vt liu t lm sch
(1) Bi bn bm trn knh
c lp mng cha tinh
th TiO
2

(2) nh mt tri chiu tia
cc tm kch thch phn
ng quang ha trong lp
TiO
2
, b gy cc phn t
bi.
(3) Khi nc ri trn mt knh to ra hiu ng thm
nc. Nc tri u ra b mt thay v thnh git, cun
theo cht bn i xung.
ng dng
Vt liu t lm sch
B mt thay i dn theo
thi gian chiu UV
ng dng
Vt liu t lm sch
ng dng trong vt liu
t lm sch
ng dng
Vt liu t lm sch
ng dng
X l nc b nhim
ng dng
X l nc b nhim
T nm 1996, cc vin thuc Trung tm KHTN v
Cng ngh quc gia, bao gm Vin Vt l ng dng v
Thit b khoa hc, Vin ha hc, Phn vin Vt liu ti
TP. HCM, Vin k thut nhit i hp tc s dng
cng ngh nano nghin cu vt liu bn dn ny.
ti tp trung vo nghin cu ch to lp ph TiO
2

c kch thc ht nano ln mt s vt liu khc nhau,
dng phn hy cc hp cht hu c gy nhim
nh khi thi xe c, khi thuc l v cc hp cht c
trong nc thi, thuc tr su nh tc dng khuch
tn ca nh sng.
ng dng
X l nc b nhim
Di tc dng ca nh sng khuch tn, VL bn dn
c kch thc nano c th ph v cc lin kt hu c
c hi.
Cc ht TiO
2
di tc dng ca nh sng s sinh ra
cc tc nhn xy ha cc mnh nh H
2
O
2
, OH
-
nh
c th phn hy hu ht cc hp cht hu c, khi
thi c hi, vi khun, ru
ng dng: gch men t lm sch v dit khun dng
cho bnh vin; h thng lc nc s dng nh sng t
ngoi v TiO
2
, tm panen quang xc tc TiO
2
trong my
kh mi, lm sch khng kh, h thng lc nc
ng dng
Phn hy ixin
Ph VL nano TiO
2
ln cc ht ct trn vi t
nhim ixin, u im ca pp:
- Nano TiO
2
khng b cun theo nc;
- Nano TiO
2
hot tnh cao c th phn hy TiO
2
trong
iu kin thiu nh sng.
- Nano TiO
2
v cc sn phm phn hy ixin khng
c hi nn y l gii php c tnh trit trong vic
kh c ixin.
ng dng
Khu trang dit khun
Tiu dit t bo ung th
Sn xut
knh, gng
chng m
Mt s c trng c bn ca VL
Sn phm thu c c nh gi c trng bng
cc phng php ha l hin i:
- Nhiu x tia X (XRD).
- Hp ph ng nhit N
2
77K.
- Xc nh b mt ring theo l thuyt BET.
- Hnh thi ca sn phm c chng minh bng
hin vi in t qut (SEM) v hin vi in t truyn
qua (TEM).
Phng php tng hp
Phng php sol - gel
Quy trnh chung thc hin theo s sau y:
Phng php tng hp
Phng php kt ta ng th
S dng dung dch TiCl
4
lm tin cht iu ch
bt TiO
2
bng phng php kt ta ng th. Dung
dch TiCl
4
c lm lnh 0
o
C, sau thm tng
mu nh vo thc hin phn ng thu phn
to thnh dung dch mu vng nht TiOCl
2
. Thm
nc ct vo dung dch TiOCl
2
thu c dung
dch trong sut c nng Ti
4+
l 0.5M, dng cho
qu trnh kt ta ng th.
Phng php tng hp
Phng php thy nhit
Bt TiO
2
thng mi c phn tn trong dung
dch NaOH m c bng my khuy t trong 1h,
huyn ph ny sau c chuyn sang thit b
Autoclave vi lp lt bng Teflon. Qu trnh tng hp
thy nhit c tin hnh trong khong nhit
t130 180
o
C vi thi gian tng hp t 12 36h. T
l mol TiO
2
: NaOH l 1:20 1:30. Kt thc qu trnh
thy nhit, cht rn trong Autoclave c lc, ra
sch bng nc ct ri ngm trong dung dch axit
HCl long trong 1 gi. Sau , sn phm c ra
li bng nc ct cho n pH trung tnh => c sy
kh 100
o
C => nung trong khng kh ti nhit
500
o
C trong 2h.
Phng php tng hp
Phng php thy phn
Thy phn
TiCl
4
trong
dung dch
Na
2
SO
4
Phng php tng hp
Phng php thy phn
Thy phn
TiCl
4
trong
dung dch
H
2
SO
4
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