Professional Documents
Culture Documents
CR 314 Rottner
CR 314 Rottner
Combustible Dusts
Presented by Presented by
Bruce L. Rottner, CSP
Bruce L. Rottner, CSP
At At
AIHce 2006 in Chicago, Illinois
AIHce 2006 in Chicago, Illinois
First Documented Dust Explosion
First Documented Dust Explosion
Mr. Giacomelli
Mr. Giacomelli
s Bakery
s Bakery
Turin, Italy
Turin, Italy
December 14 1785
December 14 1785
Count Morozzo recounts his investigation as documented in the Count Morozzo recounts his investigation as documented in the
Memoirs of the Academy of Science of Turin Memoirs of the Academy of Science of Turin
On the 14 On the 14
TH TH
of December, 1785, about six o of December, 1785, about six o clock in the evening, there clock in the evening, there
took place in the house of Mr. Giacomelli, baker in the city, an took place in the house of Mr. Giacomelli, baker in the city, an
explosion which threw down the windows and window explosion which threw down the windows and window- -frames of his frames of his
shop which looked into the street; the noise was as loud as that shop which looked into the street; the noise was as loud as that of a of a
large cracker, and was heard at a considerable distance. At the large cracker, and was heard at a considerable distance. At the
moment of the explosion, a very bright flame, which lasted only moment of the explosion, a very bright flame, which lasted only a a
few seconds, was seen in the shop; and it was immediately few seconds, was seen in the shop; and it was immediately
observed, that the inflammation proceeded from the flour observed, that the inflammation proceeded from the flour - -
warehouse which was situated over the back shop where a boy was warehouse which was situated over the back shop where a boy was
employed in stirring some flour by the light of a lamp. employed in stirring some flour by the light of a lamp.
Data from 1898 until 1942
Data from 1898 until 1942
519 fatalities
519 fatalities
1206 injured
1206 injured
Losses in dollars
Losses in dollars
55,728,940
55,728,940
Case History
Case History
West
West
Pharmaceutical Services 1/29/2003
Pharmaceutical Services 1/29/2003
6 fatalities 6 fatalities
38 injuries 38 injuries
The explosion could be The explosion could be
heard 25 miles from the heard 25 miles from the
plant plant
Shattering glass injured a Shattering glass injured a
student at a school 0.5 student at a school 0.5
mile away. mile away.
Flaming debris set woods Flaming debris set woods
on fire as far as two miles on fire as far as two miles
away. away.
West Pharmaceutical (cont.)
West Pharmaceutical (cont.)
to
to
Electrical fault
Electrical fault
Agricultural
Agricultural
Chemical
Chemical
Pharmaceuticals
Pharmaceuticals
Wood
Wood
Plastics
Plastics
Food
Food
Coal
Coal
Combustion Principles
Combustion Principles
Fire is a rapid oxidation Fire is a rapid oxidation
process with the evolution of process with the evolution of
light and heat in varying light and heat in varying
intensities. intensities.
2C + O 2C + O
2 2
2CO 2CO
Deflagration is a combustion Deflagration is a combustion
reaction in which the velocity reaction in which the velocity
of the reaction front through of the reaction front through
the unreacted fuel medium is the unreacted fuel medium is
less than the speed of sound. less than the speed of sound.
One Explosion or Two
One Explosion or Two
Factors Impacting a Dust Explosion
Factors Impacting a Dust Explosion
Particle size
Particle size
Moisture content
Moisture content
Cloud dispersion
Cloud dispersion
Process Equipment at Risk
Process Equipment at Risk
DUST COLLECTORS
DUST COLLECTORS
Storage Enclosures (e.g., silos, bins, hoppers,
Storage Enclosures (e.g., silos, bins, hoppers,
etc.)
etc.)
Pneumatic Conveying Systems
Pneumatic Conveying Systems
Air
Air
-
-
Material Separators
Material Separators
Size Reduction (e.g., hammermills, granulators,
Size Reduction (e.g., hammermills, granulators,
grinders, etc.)
grinders, etc.)
Material Feeding Devices (bucket elevators)
Material Feeding Devices (bucket elevators)
Heating Equipment
Heating Equipment
Importance of Maintenance (and
Importance of Maintenance (and
Inspection) of Equipment
Inspection) of Equipment
dust
dust
Combustible Dust
Combustible Dust
Mechanical sparks
Mechanical sparks
Static electricity
Static electricity
Electrical sources
Electrical sources
Heat sources
Heat sources
Open flames
Open flames
General Parameters
General Parameters
Average minimum concentration of a
Average minimum concentration of a
combustible dust is approximately 0.05 ozs / ft
combustible dust is approximately 0.05 ozs / ft
3 3
or 50 g / m
or 50 g / m
3 3
Materials that ignite above 0.50 joules are not
Materials that ignite above 0.50 joules are not
considered sensitive to ignition by electrostatic
considered sensitive to ignition by electrostatic
discharge.
discharge.
Draft System +,
Draft System +,
-
-
, and ?
, and ?
Min. Ignition Temp. of a Cloud < 400
Min. Ignition Temp. of a Cloud < 400
C
C
Min. Ignition Temp. of a Layer 5mm < 300
Min. Ignition Temp. of a Layer 5mm < 300
C
C
Min. Ignition Energy of a Cloud < 15 mJ
Min. Ignition Energy of a Cloud < 15 mJ
Laboratory Tests
Laboratory Tests
Variation of apparatus *
Variation of apparatus *
Particle Size
Particle Size
Moisture Content
Moisture Content
Minimum Explosive Concentration
Minimum Explosive Concentration
Conducted in a Godbert
Conducted in a Godbert
-
-
Greenwald
Greenwald
Furnace
Furnace
Increments of 5
Increments of 5
C.
C.
Hartmann Apparatus
Hartmann Apparatus
20
20
-
-
Liter Sphere
Liter Sphere
K
K
ST
ST
K
K
ST ST
is an index used to classify the explosion
is an index used to classify the explosion
severity of a combustible dust.
severity of a combustible dust.
It is based on the maximum rate of pressure
It is based on the maximum rate of pressure
rise, (dP/dt)
rise, (dP/dt)
MAX MAX
and the units are
and the units are
bar/second.
bar/second.
K
K
ST ST
= (dP/dt)
= (dP/dt)
MAX MAX
* V
* V
1/3 1/3
(V is the vessel
(V is the vessel
volume ~ m
volume ~ m
3 3
)
)
K
K
ST
ST
Index
Index
> 300
> 300
St
St
-
-
3
3
201
201
-
-
300
300
St
St
-
-
2
2
Up to 200
Up to 200
St
St
-
-
1
1
K
K
ST ST
(bar
(bar
-
-
m/ s)
m/ s)
Dust Class
Dust Class
Explosion Severity Index
Explosion Severity Index
(US Bureau of Mines)
(US Bureau of Mines)
>10
>10
>2.0
>2.0
>5.0
>5.0
Severe
Severe
1.0
1.0
-
-
10
10
1.0
1.0
2.0
2.0
1.0
1.0
5.0
5.0
Strong
Strong
0.1
0.1
1.0
1.0
0.5
0.5
1.0
1.0
0.2
0.2
1.0
1.0
Moderate
Moderate
<0.1
<0.1
<0.5
<0.5
<0.2
<0.2
Weak
Weak
Index of Index of
explosibility explosibility
Explosion Explosion
Severity Severity
Ignition Ignition
sensitivity sensitivity
Relative Relative
explosion explosion
hazard rating hazard rating
Ignition Sensitivity
Ignition Sensitivity
Minimum Ignition Temperature X Minimum Ignition Energy Minimum Ignition Temperature X Minimum Ignition Energy
X Minimum Explosible Concentration) Pittsburgh Coal X Minimum Explosible Concentration) Pittsburgh Coal
dust dust
Minimum Ignition Temperature X Minimum Ignition Energy Minimum Ignition Temperature X Minimum Ignition Energy
X Minimum Explosible Concentration) Sample dust X Minimum Explosible Concentration) Sample dust
Explosion Severity
Explosion Severity
(Maximum Explosion Pressure X Maximum Rate of
(Maximum Explosion Pressure X Maximum Rate of
Pressure Rise) Sample dust
Pressure Rise) Sample dust
(Maximum Explosion Pressure X Maximum Rate of
(Maximum Explosion Pressure X Maximum Rate of
Pressure Rise) Pittsburgh Coal dust
Pressure Rise) Pittsburgh Coal dust
Index of Explosibility
Index of Explosibility
Ignition Sensitivity X Explosion Severity
Ignition Sensitivity X Explosion Severity
Protection Methods
Protection Methods
Deflagration Pressure Containment
Deflagration Pressure Containment
Deflagration Venting
Deflagration Venting
Suppression
Suppression
Oxygen Reduction
Oxygen Reduction
Deflagration venting through a listed dust
Deflagration venting through a listed dust
retention and flame
retention and flame
-
-
arresting device
arresting device
Isolation (prevent propagation)
Isolation (prevent propagation)
chokes, rotary
chokes, rotary
valves, flame front diverters, fast acting valves
valves, flame front diverters, fast acting valves
NEC Classifications
NEC Classifications
Article 500
Article 500
Class II, Division 1 and 2 locations where fire or explosion Class II, Division 1 and 2 locations where fire or explosion
hazards may exist due to combustible dust. hazards may exist due to combustible dust.
Division 1 Division 1
Combustible dust in air under normal operating conditions in Combustible dust in air under normal operating conditions in
quantities sufficient to produce an explosive or ignitible quantities sufficient to produce an explosive or ignitible
mixture. mixture.
Division 2 Division 2
Combustible dust due to abnormal conditions in quantities, Combustible dust due to abnormal conditions in quantities,
Dust accumulation on, in, or in the vicinity of the electrical Dust accumulation on, in, or in the vicinity of the electrical
equipment could be sufficient to interfere with the safe equipment could be sufficient to interfere with the safe
dissipation of heat from electrical equipment, or could be dissipation of heat from electrical equipment, or could be
ignitible by abnormal operation or failure of electrical ignitible by abnormal operation or failure of electrical
equipment equipment. .
Group E
Group E
Group E
Group E
Forklifts
Forklifts
Vacuum Cleaners
Vacuum Cleaners
Power Tools
Power Tools
Fire Brigades and Emergency
Fire Brigades and Emergency
Response
Response
Pre
Pre
-
-
Explosion
Explosion
Dust Explosion
Dust Explosion
Post
Post
-
-
Explosion
Explosion
Determining the Cause
Determining the Cause