BI TP V C TNG HP

1. Ho tan 55 gam hn hp Na
2
CO
3
v Na
2
SO
3
bng 500ml dung dch H
2
SO
4
1 (lng axit va ) ta thu
!"c hn hp #h$ % v dung dch ch&a m't mu() t*ung ho du+ nh,t-
a- Cho hn hp #h$ % vo b.nh #$n dung t$ch 5 l$t c/ m't $t b't 01c t2c 3
2
O
5
(th tch khng ng k)-
4$nh 2p 5u,t t*ong b.nh6 b)7t nh)8t !' b.nh l 2963
0
C-
b- :;m t)7p o0) vo b.nh ta thu !"c hn hp #h$ : c/ t< #h() 5o v=) h)!*o l 21629- 4$nh 5( mol o0)
!> b;m vo b.nh-
c- Nung n/ng b.nh m't th?) g)an ta thu !"c hn hp #h$ C6 c/ t< #h() 5o v=) h)!*o l 22635- 4$nh @
thA t$ch cBa c2c #h$ t*ong hn hp C-
ChoC H D 16 O D 1E6 C D 126 Na D 236 S D 32-
Hng dn gii
a- C2c phFn &ngC
Na
2
CO
3
G H
2
SO
4
Na
2
SO
4
G H
2
O G CO
2
H1I
Na
2
SO
3
G H
2
SO
4
Na
2
SO
4
G H
2
O G SO
2
H2I
4hJo c2c phFn &ng t*Kn v b) *a6 c/C 5( mol cBa % D 5( mol H
2
SO
4
D 065 - 1 D 065 mol-
2p 5u,t L t*ong b.nh lC
0 0
0
P V PV 1.0,5.22,4 P.5
hay
T T 273 273 27,3

+
Su+ *aC L D 264E4 atm-
b- MN) n l 5( mol cBa Na
2
CO
3
v cOng l 5( mol cBa CO
2
6 m l 5( mol cBa Na
2
SO
3
v cOng l 5( mol cBa
SO
2
6 ta c/C
n m 0,5
106n 126m 55
+
;
+

n D 064 v m D 061
MN) 5( mol O
2
!> b;m vo b.nh l a6 ta c/C
MP
D 21691 - 2 D
0,4.44 0,1.64 a.32
0,5 a
+ +
+
5u+ *a a D 062 HmolI-
c- LhFn &ng 0F+ *a #h) nung n/ng b.nhC
2 SO
2
G O
2

2 5
0
V O
t
2 SO
3
H3I
MN) 0 l 5( mol O
2
cQn lR) 5au phFn &ng H3I6 vS+ 5( mol o0) !> phFn &ng D 062 T 0U 5( mol SO
2
cQn lR) D 061 T
2- H062 T 0I v 5( mol SO
3
tRo thnh D 2- H062 T 0I U 5( mol CO
2
#hVng !W) D 064 nKn tWng 5( mol #h$ 5au phFn
&ng H3I lC
061 T 2- H062 T 0I G 0 G 2- H062 T 0I G 064 D 065 G 0
3S+C
MC
D
2 2 2
khi l ng (SO CO O khi l ng kh!C 0,1.64 0,4.44 0,2.32
" m#l kh!C 0,5 $ 0,5 $
+ + + +

+ +
MC
D 22635 - 2 D 4469
4X c2c dY #)8n t*Kn 5u+ *a 0 D 061Z HmolI
4Wng 5( mol #h$ t*ong C D 065 G 0 D 065 G 061Z D 06EZ-
@3
O2
D
0,1%.100
26,5&
0,6%

@3
CO2
D
0,4.100
5%,%&
0,6%

S( mol SO
3
D 2- H062 T 0I D 0604 5u+ *a @3
SO3
D
0,04.100
5,%'&
0,6%

@3
SO2
D 100@ T 2E65@ [ 5Z6Z@ [ 56Z\@ D Z6Z1@-
2. Nung 5Z gam hn hp % g]m %1 H^JCO
3
G tRp ch,t t*;I v %2 H^JS
2
G tRp ch,t t*;I v=) l"ng #hVng #h$
Hg]m 20@ o0) v Z0@ n)t; thJo thA t$chI vXa !B t*ong b.nh #$n dung t$ch 10 l$t- Sau #h) c2c phFn &ng 0F+ *a
hon ton6 thu !"c hn hp ch,t *_n %3 v hn hp #h$ :- 4*ong %3 ch` ch&a m't 5_t o0)t du+ nh,t v
l"ng tRp ch,t t*; ban !au- Hn hp : c/ t< #h() 5o v=) #hVng #h$ c/ thnh phan cho t*Kn l 161Z1-
a- 4$nh #h() l"ng cBa %1 v %2 ban !au6 b)7t *ng @ #h() l"ng tRp ch,t t*ong %1 v %2 bng nhau-
b- 4$nh 2p 5u,t cBa #h$ t*ong b.nh 5au #h) nung !> !"a vb nh)8t !' 13E65
0
C6 g)F 5c dung t$ch cBa b.nh
#hVng !W)-
c- N7u cho : phFn &ng v=) o0) d" (c xc tc V
2
O
5
)6 5au #h) phFn &ng hon ton6 ho tan #h$ vo E00
gam H
2
O !"c dung dch a0)t c/ #h() l"ng *)Kng l 1602 gamdml-
4$nh n]ng !' moldl cBa a0)t t*ong dung dch-
ChoC ^J D 5E6 S D 326 C D 126 O D 1E6 N D 14-
Hng dn gii
C2c phFn &ngC
4^JS
2
G 11 O
2

0
t

2 ^J
2
O
3
G Z SO
2
H1I
^JCO
3

0
t

^JO G CO
2
H2I
2^JO G
1
2
O
2

0
t

^J
2
O
3
H3I
eft 5( mol cBa ^JS
2
v ^JCO
3
lan l"t l 0 v +6 ta c/C
S( mol O
2
!> phFn &ng D 5( mol O
2
ban !au-
4X H1I6 H3I c/C 5( mol O
2
D
11$ y
4
+
S( mol N
2
D
11$ y
4 (11$ y
4
+ _
+

,
3S+C
4*ong ch,t *_n %
3
c/C ^J
2
O
3
D 065- H0G+I mol-
Hn hp : c/C N
2
D H110 G +I mol
SO
2
D 20 mol
CO
2
D + mol
kk
M D 32 - 20@ G 2Z - Z0@ D 2Z6Z
d D
(
kk
M 2%(11$ y 64.2$ 44y
1,1%1
2%,%(11$ y 2$ y M
+ + +

+ + +
+ D 1650 H4I
gh) nung %
3
v=) CO d" c/ phFn &ngC
^J
2
O
3
G 3CO
0
t

2^J G 3CO
2
gh() l"ng ^J c/ t*ong (ng D
14.'6
0,24
100.56
HmolI-
3. h)8u 5u,t l Z0@6 nKnC 0 G + D
0,24.100
0,3
%0
H5I
4X H4I v H5I c/C 0 D 0612 U + D 061Z
a- 4Wng #h() l"ng ^JS
2
G ^JCO
3
D 0612 - 120 G 061Z G 11E D 3562Z HgI
Po @ tRp ch,t nh" nhau6 nKn @ ngu+Kn ch,t cOng bng nhau6 v. vS+ 5h c/ t` l8C
0,12.120 35,2%
a 5%
a D 236EZ HgI v b D 5Z T 236EZ D 34632 HgI-
b- S( mol #h$ : D 13 - 0612 G 2 - 061Z D 16\2 HmolI
v
10.) (22,4 1,'2.1
273 136,5 273
+

+
p D E645 atm
c- gh$ : g]mC N
2
6 SO
2
6 CO
2
2 SO
2
G O
2

2 5
0
V O
t
2 SO
3
SO
3
G H
2
O H
2
SO
4
CO
2
G H
2
O
(*
+

(khng phn ng)
4hA t$ch dung dch a0)t H
2
SO
4
lC
%0.0,24 600
607
1,02
+

HmlI
N]ng !' dung dch H
2
SO
4
lC
0,24
0,3'
0,607

HmoldlI
3. Pung dch i ch&a HCl6 CuSO
4
6 ^J
2
HSO
4
I
3
- j,+ 400ml dung dch i !Jm !)8n phkn bng !)8n clc t*;6
c"?ng !' dQng !)8n 9692%6 !7n #h) m #atot thu !"c 5612g Cu th. dXng lR)- gh) !/ m anot c/ 2624 l)t m't ch,t
#h$ ba+ *a H!#tcI- Pung dch 5au !)8n phkn t2c dnng vXa !B v=) 1625 l)t dung dch :aHOHI
2
062 v !un
n/ng dung dch t*ong #hVng #h$ cho c2c phFn &ng 0F+ *a hon ton th. thu !"c 5E69Eg #7t tBa-
1- 4$nh th?) g)an !)8n phkn- 4$nh C

cBa c2c ch,t t*ong dung dch ban !au-

Hng dn gii
[ ou2 t*.nh !)8n l)C ^J
2
HSO
4
I
3
2^J
3G
G 3SO
4
2[
0mol 20mol 30mol
CuSO
4
Cu
2G
G SO
4
2[
+mol +mol +mol
HCl H
G
G Cl
[
pmol pmol pmol
[ ou2 t*.nh !)8n phknC
gatot %not
2^J
3G
G 2J D 2^J
2G
2Cl
[
[ 2J D Cl
2
Cu
2G
G 2J D Cu
Cu tho2t *a m #atot6 ch&ng tq ^J
3G
!>

b !)8n phkn h7t- n
Cu
D 5612 C E4 D 060ZHmolI
n
Clo
D 2624C 2264 D 061HmolI6 n
:aHOHI2
D 062 0 1625 D 0625-
[ Sau #h) !)8n phkn 0F+ *a c2c phFn &ngC
[ :aHOHI
2
G SO
4
2[
:aSO
4
G 2OH
[
H1I
H30 G+I H30 G+I H30 G+I
[ :aHOHI
2
G 2HCl :aCl
2
G H
2
O H2I
H0625[ 30[ +I 2H0625[ 30[ +I
[ ^J
2G
G 2OH
[
^JHOHI
2
H3I
20 20 20
[ Cu
2G
G 2OH
[
CuHOHI
2
H4I
H+ T 060ZI H+ T 060ZI
4^JHOHI
2
G O
2
G H
2
O 4^JHOHI
3
H5I
20 20
1- 4$nh th?) g)an !)8n phkn thJo cVng th&c m D
%rt
n^
Hm D 961g6 n D 2I
t D
m n ^
% r

D
961 2 \E500
91 96 92

D 2500H5I
2- 4$nh C

cBa c2c ch,t t*ong dung dch !au6 2p dnng phng php bo ton eC
[ S( mol J thu m #atot D S( mol J nh"?ng m anot 0 G 060Z D 061mol HrI
4hJo c2c phFn &ng H1636 465IC m
#7t tBa
D m
:aSO4
G m
CuHOHI2
G m
^JHOHI3
D 5E69E
233H30 G +I G \ZH+ T 060ZI G 109 -20 D 5E69E HrrI
M)F) *a ta !"c 0 D 06026 + D 0614 n
HCl
D 061-2 G 2H0625 T 30 [+I D 063
C

HCl D 063 C 064 D 0695 6 C

CuSO
4
D 0614 C 064 D 0635
4. &c t() !a cho phsp cBa H
2
S t*ong #hVng #h$ l 0601 mg dl- eA !2nh g)2 5l nh)tm bun cBa #hVng #h$ m
m't nh m2+ ng"?) ta lm nh" 5au C
e)8n phkn dung dch gr t*ong 2 ph1t 6 r D 2m%- Sau !/ cho 2 l$t #hVng #h$ l') tX tX vua dung dch
!)8n phkn t*Kn cho !7n #h) )ot hon ton m,t mu - 4hKm h] t)nh b't vo b.nh v t)7p tnc !)8n phkn 35 g)k+
nYa v=) dQng !)8n t*Kn th. dung dch b_t !au 0u,t h)8n mu 0anh- M)F) th$ch th$ ngh)8m v cho b)7t 5l nh)tm
bun #hVng #h$ m nh m2+ !> v"t vu2 m&c cho phsp ch"a w
Hng dn gii
M)F) th$ch th$ ngh)8m 2gr G 2H
2
O
!p!"ng !ich
2gOH G r
2
G H
2
H1I
Snc 2l$t #hVng #h$ vo dung dch 5au #h) !)8n phknC H
2
S G r
2
S G 2Hr H2I
2
r
rt 06002x120
n D D
n^ 2x\E500
D 0612- 10
[5
mol r
2
D
2
H S
n
Pung dch 5au phFn &ng cQn d" H
2
S Hg
2
SI6 gr6 !)8n phkn thJo th& tlC S
2[
y r
[
y :*
[
y Cl
[
y OH
[
gh) !)8n phkn6 vu2 t*.nh anotC S
2[
[2J S H3I
2r
[
[2J r
2
H4I r
2
lm t)nh b't h/a 0anh-
:_t !au 0F+ *a H4I th. H3I !> 0ong
2[
S
06002x35
n D
2x\E500
D 063E-10
[E
mol
3S+ tWng 5( mol H
2
S l H162 G 063E I-10
[E
mol-
4Wng 5( mg H
2
S D 165E 0 10
[E
0 34 0 10
3
D 53604 - 10
[3
mg-
S( mg H
2
S t*ong 1 l$t #hVng #h$ cBa nh m2+ D
3
536 04
10
2

mg D 2E65-10
[3
mg D 0602E5mg y 0601mg HthJo
t)Ku chuun cho phspI-
g7t luSn C ghVng #h$ m nh m2+ !> b V nh)tm H
2
S ngh)Km t*Nng-
Cu ! e(t ch2+ hon ton 464g 5unzua cBa #)m loR) HcVng th&c SI t*ong o0) d"- Ch,t *_n 5au phFn &ng
!Jm ho tan t*ong 1 l"ng vXa !B dung dch HNO
3
396Z@ th,+ n]ng !' phan t*{m cBa mu() t*ong dung dch
thu !"c l 41692@- gh) lm lRnh dung dch n+ th. tho2t *a Z60Zg mu() *_n- jNc t2ch mu() *_n th,+ n]ng !'
phan t*{m cBa mu() t*ong dung dch l 3469@- i2c !nh cVng th&c mu() *_n- H"#! ^JHNO
3
I
3
- \H
2
OI
Cu $! Cho m
1
gam hn hp g]m g6 %l vo m
2
gam dung dch HNO
3
24@- Sau #h) c2c #)m loR) tan h7t
c/ Z6\E l$t Hm !#tcI hn hp #h$ i g]m NO6 N
2
O6 N
2
ba+ *a Hm !#tcI v dung dch %- 4hKm m't l"ng vXa !B
O
2
vo i6 5au phFn &ng thu !"c hn hp #h$ |- P}n | tX tX vua dung dch NaOH d" c/ 464Z l$t hn hp #h$
~ !) *a Hm !#tcI- 4< #h() cBa ~ !() v=) H
2
bng 20- N7u cho dung dch NaOH vo % !A !"c l"ng #7t tBa
l=n nh,t thu !"c E262 gam #7t tBa- 4$nh m
1
6 m
2
- :)7t l"ng HNO
3
l,+ d" 20@ 5o v=) l"ng can th)7t-
Cu %! Nung hn hp % g]m 5_t v l"u hunh 5au m't th?) g)an !"c hn hp *_n :- Cho : t2c dnng v=)
dung dch HCl d" thu !"c 3
1
l$t hn hp #h$ C- 4< #h() cBa C 5o v=) h)d*o bng 106E- N7u !(t ch2+ hon
ton : thnh ^J
2
O
3
v SO
2
can 3
2
l$t #h$ o0)-
1- 4.m t";ng vuan g)2 t* 3
1
v 3
2
H!o m cng !)bu #)8nI
2- 4$nh hm l"ng phan t*{m c2c ch,t t*ong : thJo 3
1
v 3
2
-
3- H)8u 5u,t th,p nh,t cBa phFn &ng nung t*Kn l bao nh)Ku phan t*{m-
4- N7u h)8u 5u,t cBa phFn &ng nung t*Kn l 95@6 t$nh hm l"ng phan t*{m c2c ch,t t*ong hn hp :-
Cu &! e(t ch2+ hon ton m
1
gam than c/ 4 @ tRp ch,t #hVng ch2+ ta thu !"c hn hp #h$ % g]m CO v
CO
2
- Cho #h$ % !) tX tX vua (ng 5& nfng 4E64 gam ^J
3
O
4
nung n/ng- gh$ *a #hq) (ng 5& b h,p thn hon ton
bm) 2 l$t dung dch :aHOHI
2
06195 thu !"c #7t tBa v dung dch mu()- Cho dung dch mu() t2c dnng v=)
CaHOHI
2
d" lR) th,+ tRo thnh #7t tBa nYa- 4Wng #h() l"ng #7t tBa 2 lan l Z36\5 gam- Ch,t *_n cQn lR) t*ong
(ng 5& ch)a thnh 2 phan bng nhau- HQa tan h7t phan r bng dd HCl th,+ t(n h7t 330 ml dd HCl 2 v c/
E92 ml #h$ H!#tcI tho2t *a- Lhan th& rr hQa tan h7t bng dd HNO
3
lo>ng th. thu !"c 3 l$t #h$ NO du+ nh,t
tho2t *a Hm !#tcI v m
2
gam mu() n)t*at- 4$nh 36 m
1
6 m
2
v t$nh t` #h() cBa hn hp #h$ % 5o v=) H
2
-
Cu '! Ho tan hon ton 36E gam m't ch,t vV c; i t*ong HNO
3
!fc6 n/ng thu !"c dung dch %- Lha lo>ng
dung dch % bng n"=c c,t v ch)a dung dch thu !"c thnh ha) phan bng nhauC
+ 4hKm vo phan 1 l"ng d" dung dch amon)ac- jNc6 *]) *ca v nung #7t tBa thu !"c m nh)8t !' cao t=)
#h() l"ng #hVng !W) thu !"c 162 gam ch,t *_n l m't o0)t #)m loR)- eA hQa tan hon ton l"ng o0)t !/
can dng $t nh,t 30 ml dung dch HNO
3
165 v th,+ phFn &ng #hVng tRo #h$-
+ 4hKm vo phan 2 l"ng d" dung dch :aCl
2
lo>ng thu !"c E6\\ gam #7t tBa t*_ng #hVng tan t*ong dung
dch a0)t mRnh-
a- i2c !nh cVng th&c phkn tc cBa i6 b)7t c2c phFn &ng 0F+ *a hon ton-
b- Ho tan hon ton hn hp g]m i v ^JCO
3
bng dung dch HNO
3
!fc6 n/ng thu !"c hn hp #h$ :
g]m ha) #h$ |6 ~ c/ t< #h() 5o v=) H
2
D 226Z05 U lm lRnh hn hp #h$ : 0u(ng nh)8t !' th,p h;n thu
!"c hn hp #h$ C g]m 3 #h$ |6 ~6 c/ t< #h() 5o v=) h)!*V bng 306E1- 4$nh @ #h() l"ng m) mu()
t*ong hn hp ban !au v phan t*{m 5( mol #h$ | chu+An thnh -
c- Hon thnh 4 ph";ng t*.nh phFn &ng cBa 5; !] 5auC
i
0
1700 C, ,ha-n kh#-ng

i
1

*Cl
i
2

4
2
.MnO / *Cl
* S

^JCl
3
Cu 1(! e(t ch2+ hon ton 46941 gam !;n ch,t i t*ong o0) *]) cho ton b' 5Fn phum thu !"c h,p thn h7t
vo 100 ml dung dch NaOH 25@ c/ #h() l"ng *)Kng d D 162Z gdml !"c dung dch %- N]ng !' cBa NaOH
t*ong dung dch % g)Fm !) 5o v=) n]ng !' cBa n/ t*ong dung dch ban !au- Pung dch % c/ #hF n{ng h,p
thn t() !a 196\2 l$t #h$ CO
2
H!#tcI- i2c !nh !;n ch,t i v 5Fn phum !,t ch2+ cBa n/-
Cu 11! 't hn hp g]m Cu v ^J c/ t` l8 #h() l"ng 9C3- j,+ m HgamI hn hp n+ cho phFn &ng hon
ton v=) dung dch HNO
3
th,+ !> c/ 4461 gam HNO
3
phFn &ng6 thu !"c 0695m HgamI *_n6 dung dch : v
56E l$t hn hp #h$ H!)bu #)8n t)Ku chuunI g]m NO v NO
2
- Hq) cV cRn dung dch : thu !"c bao nh)Ku gam
mu() #han
Cu 12! gh) thKm 1 gam gSO
4
#han vo 100 gam dung dch gSO
4
b>o ho m 20
0
C !> lm cho 165Z gam
gSO
4
#7t t)nh lR) m dRng #han- H>+ 02c !nh cVng th&c cBa t)nh thA mu() ngSm n"=c #7t t)nh- :)7t !' tan
cuF gSO
4
m 20
0
C l 3561 gam t*ong 100 gam n"=c-
Cu 13! &c t() th)Au cho phsp cBa H
2
S t*ong #hVng #h$ l 0601 mgdl)t- eA !2nh g)2 5l V nh)tm #hVng #h$ m
m't nh m2+ ng"?) ta lm nh" 5auC e)8n phkn dung dch gr t*ong 2 ph1t bng dQng !)8n 2 m%- Sau !/ cho
2 l$t #hVng #h$ l') tX tX vua dung dch !)8n phkn t*Kn cho !7n #h) )od hon ton m,t mu- 4hKm h] t)nh b't
vo b.nh v t)7p tnc !)8n phkn t*ong 35 g)k+ nYa v=) dQng !)8n t*Kn th. th,+ dung dch b_t !au 0u,t h)8n mu
0anh- M)F) th$ch th$ ngh)8m v cho b)7t 5l V nh)tm #hVng #h$ m nh m2+ t*Kn nm d"=) ha+ t*Kn m&c cho
phsp- 4$nh hm l"ng H
2
S t*ong #hVng #h$ thJo thA t$ch-
Cu 14! 4*ong v1a t*.nh 02c !nh #h$ !'c H
2
S t*ong #hVng #h$ ng"?) ta l,+ 30 l$t #hVng #h$ nh)tm H
2
S

Hc/

d
D 162 gdlI cho !) chSm vua b.nh !lng l"ng d" dung dch CdSO
4
!A h,p thn h7t #h$ H
2
S- 4)7p thJo !Jm a0)t
ho2 hon ton l"ng #7t tBa t*ong b.nh6 *]) h,p thn h7t l"ng #h$ tho2t *a bng c2ch cho vo (ng !lng 10 ml
dung dch r
2
060109- j"ng )od cQn d" phFn &ng vXa !B v=) 126Z5 ml dung dch Na
2
S
2
O
3
0601344- H>+
v)7t ph";ng t*.nh phFn &ng 0F+ *a v t$nh hm l"ng H
2
S t*ong #hVng #h$ thJo ppm- :)7t *ng ppm l 5(
m)c*ogam ch,t t*ong 1g m}u- H1 ppm D 10
[E
gI
Cu 1! Cho m't m}u #h() l"ng 16234 gam ch&a LbO6 LbO
2
v tRp ch,t t*;- 4hKm vo c(c ch&a hn hp
!/ 20 ml dung dch H
2
C
2
O
4
0625 !A #hc hon ton LbO
2
thnh Lb
2G
v !A ho tan LbO- Sau !/ thKm dung
dch NH
3
v c(c !A #7t tBa hon ton LbC
2
O
4
- jNc *ca !A t2ch #7t tBa #hq) dung dch6 thu !"c #7t tBa % v
dung dch :- %0$t hoa dung dch : bng l"ng d" dung dch H
2
SO
4
- Pung dch n+ phFn &ng vXa !B v=) 10
ml dung dch gnO
4
0604- Ho tan #7t tBa % bng l"ng d" dung dch H
2
SO
4
lo>ng- Pung dch thu !"c
phFn &ng vXa !B v=) 30 ml dung dch gnO
4
0604- 3)7t c2c ph";ng t*.nh phFn &ng v t$nh phan t*{m #h()
l"ng cBa LbO v LbO
2
t*ong m}u-
Cu 1$! LhFn &ng g)Ya 24691g mu() clo*ua cBa m't ngu+Kn t( phkn nh/m ch$nh Hphkn nh/m %I v=) 106\g
amon)ac tRo *a m't hn hp c2c 5Fn phum g]m 256EZg NH
4
Cl U 2659g m't ngu+Kn t( m thA *_n v 9639g mu()
n)t*ua #7t t)nh mu vng cBa ngu+Kn t( !/ U phFn &ng 0F+ *a thJo ph";ng t*.nh 5auC
n%

Cl
0
G mNH
3
pNH
4
Cl G v% G *%
+
N
p
H4*ong !/ n6 m6 p6 v6 *6 6 06 +6 p l c2c h8 5( v c2c ch` 5( phF)
02c !nhI- 't m}u N)t*ua t*Kn nW mRnh #h) !Sp bng b1a6 nh"ng #h) pol)mJ h/a c/ #)Am 5o2t bng c2ch
!un n/ng tRo thnh m't ch,t *_n6 dRng 5)6 mu !q h]ng6 c/ #hF n{ng d}n !)8n nh" #)m loR)- i2c !nh
ngu+Kn t( %- 3)7t v ckn bng m't ph";ng t*.nh !a+ !B cho c2c phFn &ng g)Ya mu() clo*ua v=) amon)ac n/)
t*Kn-
Cu 1%! %6 : l 2 ngu+Kn t( #hVng phF) l h)!*o- 4Wng 5( hRt p*oton6 n;t*on6 JlJct*on cBa %:
0
nh)bu h;n cBa
%
0
: l 3 Hx l# $% ng"&'n !(ngI- 4*ong phkn tc %:
0
C % ch)7m 306435@ vb #h() l"ng v 5( hRt mang !)Jn
cBa : nh)bu h;n cBa % l 1Z-
1- i2c !nh tKn cBa %6 : v v)7t cVng th&c c,u tRo cBa %:
0
6 %
0
:-
2- Hon thnh ph";ng t*.nh phFn &ngC G i%:
0G1
H%:
0G1
I
n
G %
a
:
b
G C H l #)m loR)I
3=) 5a T 2b D Z th. %
a
:
b
c/ thA l %:
0
ha+ %
0
:w 3)7t lR) ph";ng t*.nh t*Kn-
Cu 1&! Cho ZZ62 gam hn hp % g]m ^JCO
3
6^JS cng l"ng #hVng #h$ !> !"c l,+ d" 10@ 5o v=) l"ng
!B t2c dnng vo b.nh #$n thA t$ch #hVng !W)- 4Ro nh)8t !' th$ch hp cho phFn &ng 0F+ *a !A thu !"c ^J
2
O
3
Hg)F th)7t cF 2 mu() ban !au c/ #hF n{ng nh" nhau t*ong c2c phFn &ngI- e"a b.nh t*m vb nh)8t !' t*"=c #h)
nung6 t*ong b.nh c/ #h$ :6 ch,t *_n C- gh$ : gk+ *a 2p 5u,t l=n h;n 1645@ 5o v=) 2p 5u,t #h$ t*ong b.nh !/
t*"=c #h) nung- HQa tan ch,t *_n C t*ong l"ng d" H
2
SO
4
lo>ng6 !"c #h$ P H!> lm #hVI U c2c ch,t cQn
t*ong b.nh phFn &ng !"c t2c dnng v=) l"ng d" dung dch gOH- eA ch,t *_n c/ t*ong b.nh 5au vu2 t*.nh
t*Kn *a ngo) #hVng #h$ 5au th?) g)an can th)7t6 !"c ch,t *_n ^- :)7t *ng t*ong hn hp % ban !au 1 mu() c/
5( mol g,p 165 lan 5( mol cBa ch,t cQn lR)-
1- 3)7t ph";ng t*.nh c2c phFn &ng 0F+ *a-
2- gh$ : nfng ha+ nh h;n #h$ P w 4$nh cn thA-
3- 4.m @ cBa hn hp ^-
Cu 1'! Hn hp % g]m ^J6 %l c/ t` l8 #h() l"ng m
^J
C m
%l
D 9C3- j,+ m gam hn hp % cho phFn &ng v=)
dung dch H
2
SO
4
!fc6 n/ng- Sau m't th?) g)an th. lm lRnh dung dch6 !7n #h) phFn &ng #7t th1c6 th,+ l"ng
a0)t tham g)a phFn &ng l EZ6Egam H
2
SO
4
v thu !"c 0695m gam ch,t *_n H#hVng ch&a l"u hunh !;n ch,tI6
dung dch : v 56El$t H!#tcI hn hp #h$ g]m SO
2
v H
2
S- 4$nh mw
Cu 2(! 't hn hp % g]m 3 #)m loR) g6 %l6 ~n- Ho tan h7t 9653\ gam % vo 1 l)t dung dch HNO
3
5au
phFn &ng thu !"c 1 l$t dung dch : v hn hp #h$ P g]m c/ NO v N
2
O- P}n hn hp #h$ P vo b.nh #$n
dung t$ch 362 l)t c/ ch&a N
2
m 0
o
C6 0623 atm th. th,+ nh)8t !' t*ong b.nh t{ng lKn 2963
o
C6 2p 5u,t t{ng lKn 161
atm v #h() l"ng b.nh t{ng lKn 3692 gam- N7u cho 9653\ gam hn hp % vo 1 l$t dung dch gOH 2 #7t
th1c th,+ #h() l"ng t{ng lKn 5691Z gam- 4$nh @ #h() l"ng m) #)m loR) t*ong hn hp % ban !au-
Cu 21! HQa tan h7t 2625 gam hn hp ) g]m 2 #)m loR) * Hh/a t* rI v B Hh/a t* rrI vo l"ng d" dung
dch hn hp g]m HNO
3
6 H
2
SO
4
H!fcI thu !"c 26205 gam hn hp #h$ + g]m NO
2
v m't #h$ ,- :)7t +
ch)7m thA t$ch 1600Z l$t H!#tcI- H>+ t$nh #h() l"ng mu() #han tRo thnh-