4231 Witherow Road Winston-Salem, NC 2710-2!4" #33$ 72"-4"4! MSDS %& 'ffe(ti)e Date& C*02 May 1", 2011 SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE +rod,(t& *mmonia, -0 M #-0 N$ sol,tion NFPA CHEMTREC HMIS* Chemi(al Synonyms& *mmoni,m hydro.ide, -0 M sol,tion !""# 424$%&"" He'(th) 2 /orm,la& Mi.t,re- See Se(tion 00- Fi*e) " 1nit Si2e& ,3 to 1-000 liter Re'cti+it,) - C*S %& Mi.t,re- See Se(tion 00- H'.'*/ R'tin0 Minim'( " S(i0ht - Mo/e*'te 2 Se*io1s & Se+e*e 4 SECTION II INGRE2IENTS OF MI3TURES P*inci4'( Com4onents# Pe*cent'0e H'.'*/o1s5 TL6 Units *mmonia, N43 #C*S %& 133-21-$ 5126 as N43 7es 2" 33m in air as N43 Water, 428 #C*S %& 7732-19-"$ 5996 No None esta:lished 2ANGER7 CORROSI6E7 CAUSES SE6ERE 8URNS9 MAY 8E FATAL IF S:ALLO:E2 OR INHALE29 6APOR E3TREMELY IRRITATING9 SECTION III PHYSICAL 2ATA Meltin; +oint #</$& 0 <C #32 </$ S3e(ifi( =ra)ity #428 > 1$& 51-0 ?oilin; 3oint #</$& 5 100 <C #212 </$ +er(ent @olatile :y @ol,me #6$& 1006 @a3or +ress,re #mm of 4;$& 14 mm #water$ ')a3oration Rate #Water > 1$& A 1 @a3or Density #*ir > 1$& 0-7 #water$ Sol,:ility in Water& Com3lete *33earan(e B 8dor& Clear, (olorless liC,idD 3,n;ent, :itin; ammonia odor SECTION I6 FIRE AN2 E3PLOSION HA;AR2 2ATA /lash +oint #Method 1sed$ NE* /lamma:le Fimits in *ir 6 :y @ol,me N43 ;as Fower 133er 1 2" '.tin;,isher Media 1se any media for e.tin;,ishin; the s,33ortin; fire- SPECIAL FIREFIGHTING PROCE2URES Wear f,ll 3rote(ti)e (lothin; with res3irator masG with ammonia (annister, or N08S4EMS4*-a33ro)ed self-(ontained :reathin; a33arat,s- #2004 'M'R='NC7 R'S+8NS' =10D'?88H, RS+* + "900-!, =10D' +*=' N8- 1"4$ UNUSUAL FIRE AN2 E3PLOSION HA;AR2S @a3ors formed from this 3rod,(t are hea)ier than air and may tra)el alon; the ;ro,nd to a distant so,r(e of i;nition- /ire may 3rod,(e irritatin;, (orrosi)e, andEor to.i( f,mes- *,to- i;nition tem3erat,re "1 <C #1204 </$ 29O9T9 Ammoni' so(1tions, !, UN2<=2, PG III, Lt/ >t, ? @ Lt9 *33ro)ed :y 1-S- De3artment of Fa:or Iessentially similarJ to form 8S4*-20 SECTION 6 HEALTH HA;AR2 2ATA CA"2 THRESHHOL2 LIMITE2 6ALUE *s ammonia ;as KW*& 2" 33mD SK'F& 3" 33m #*C=04 2001$- Ko.i(ity data& oral-rat FD"0& 3"0 m;EG;- EFFECTS OF O6ERE3POSURE Material is e.tremely destr,(ti)e to tiss,e of the m,(o,s mem:ranes, ,33er res3iratory, ;astrointestinal and di;est tra(t, eyes, and sGin- 0nhalation may :e fatal as a res,lt of s3asm, inflammation, and edema of the laryn. and :ron(hi, (hemi(al 3ne,monitis, and 3,lmonary edema- Sym3toms of o)ere.3os,re may in(l,de :,rnin; sensation, shortness of :reath, heada(he, na,sea, )omitin;, (on),lsions, and sho(G- Kar;et or;ans& 'yes, sGin, and m,(o,s mem:ranes- EMERGENCY AN2 FIRST AI2 PROCE2URES INGESTION& Call 3hysi(ian or +oison Control Center immediately- 0nd,(e )omitin; only if ad)ised :y a33ro3riate medi(al 3ersonnel- Ne)er ;i)e anythin; :y mo,th to an ,n(ons(io,s 3erson- EYES& Che(G for and remo)e (onta(t lenses- /l,sh thoro,;hly with water for at least 1" min,tes, liftin; ,33er and lower eyelids o((asionally- =et immediate medi(al attention- SAIN& Remo)e (ontaminated (lothin;- /l,sh thoro,;hly with mild soa3 and water- 0f irritation o((,rs, ;et medi(al attention- INHALATION& Remo)e to fresh air- 0f not :reathin;, ;i)e artifi(ial res3iration- 0f :reathin; is diffi(,lt, ;i)e o.y;en- =et medi(al attention- SECTION 6I REACTI6ITY 2ATA St'Bi(it, Unst'B(e Con/itions to A+oi/ '.(essi)e tem3erat,re St'B(e L Incom4'tiBi(it, M'te*i'(s to A+oi/# *(ids, stron; o.idi2in; a;ents, halo;ens, hea)y metals- H'.'*/o1s 2ecom4osition P*o/1cts De(om3oses to ammonia ;as, and a:o)e 4"0 <C #942 </$ to hydro;en ;as and nitro;en o.ides- H'.'*/o1s Po(,me*i.'tion Con/itions to A+oi/ Not a33li(a:le- M', Occ1* :i(( Not Occ1* 3 SECTION 6II SPILL OR LEAA PROCE2URES Ste4s to Be t'Cen in c'se m'te*i'( is *e(e'se/ o* s4i((e/ Wearin; 3rote(ti)e eC,i3ment, ne,trali2e with a weaG a(id s,(h as sodi,m :is,lfate- *:sor: with inert dry material and 3la(e in s,ita:le (ontainer for 3ro3er dis3osal- :'ste 2is4os'( Metho/ Dis(har;e, treatment, or dis3osal may :e s,:Me(t to /ederal, State, or Fo(al laws- Khese dis3osal ;,idelines are intended for the dis3osal of (atalo;-si2e C,antities only- Dis3ose of in a((ordan(e with all a33li(a:le federal, state, and lo(al laws and re;,lations- SECTION 6III SPECIAL PROTECTION INFORMATION Res4i*'tion P*otection S4eciD, T,4e# WorG in a f,me hood or wear a N08S4EMS4*-a33ro)ed res3irator with ammonia (annister if ne(essary- 6enti('tion Loc'( EEh'1st Re(ommended S4eci'( No Mech'nic'( Gene*'(# Re(ommended Othe* No P*otecti+e G(o+es R,::er E,e P*otection Chemi(al safety ;o;;les Othe* P*otecti+e EF1i4ment =o;;les and fa(eshield, eye wash station, 3ro3er ;lo)es, )entilation hood, la: (oat, a3ron- SECTION I3 SPECIAL PRECAUTIONS P*ec'1tions to Be T'Cen in H'n/(in0 G Sto*in0 Store in a well-)entilated area away from heat, s3arGs, and o3en flame at room tem3erat,re- 0solate from in(om3ati:le s,:stan(es- Wash thoro,;hly after handlin;- Othe* P*ec'1tions Read la:el on (ontainer :efore ,sin;- Do not wear (onta(t lenses when worGin; with (hemi(als- /or la:oratory ,se only- Not for dr,;, food, (osmeti(, or ho,sehold ,se- Hee3 o,t of rea(h of (hildren- *)oid (onta(t with eyes, sGin, and m,(o,s mem:ranes- *)oid :reathin; )a3or and ,se adeC,ate )entilation- Remo)e and wash (ontaminated (lothin;- Re)ision %& 1 Date& May 1", 2011 *33ro)ed& Ro:ert ?r,(e Khom3son Chemi(al Safety Coordinator& R?K Khe information (ontained herein is f,rnished witho,t warranty of any Gind- 'm3loyers sho,ld ,se this information only as a s,33lement to other information ;athered :y them and m,st maGe inde3endent determinations of s,ita:ility and (om3leteness of information from all so,r(es to ass,re 3ro3er ,se of these materials and the safety and health of em3loyees- N 4a2ardo,s Materials 0nd,strial Standards