Diesel Fuel Effect of aromatics and cetane number Combustion in CI Engine In a CI engine the fuel is sprayed directly into the cylinder and the fuel-air mixture ignites spontaneously. These photos are taken in a RCM under CI engine conditions with swirl air flow 0.4 ms after ignition 3.2 ms after ignition 3.2 ms after ignition Late in combustion process 1
c m Combustion Characteristic Combustion occurs throughout the chamber over a range of equivalence ratios dictated by the fuel-air mixing before and during the combustion phase. In general most of the combustion occurs under very rich conditions within the head of the jet, this produces a considerable amount of solid carbon (soot). Compression ratio limitations in CI engine The higher the combustion pressure, the higher the sealing pressure. The higher the sealing pressure, the higher the friction loss. The higher the compression ratio, the higher the combustion pressure, sealing pressure, and friction loss. Advantages and disadvantages of diesel engines Advantages Fuel Economy Durability Low HC Low CO High torque Reliability Low fuel cost Low maintenance cost Disadvantages Noise Weight High NOx High PM Low speed Low air utilization High engine cost Low exhaust temperature Diesel Combustion Process Diesel Ignition Flame Front Propagation Spontaneous combustion (auto ignition) due to temperature increase of reactants. Ignition triggered by compression heating of fuel-air mixture. Ignition initiated at random point in combustion chamber Fast combustion process Less complete combustion process The Four stroke Diesel Operation DI and IDI Combustion chamber designs Important Combustion Bowl dimensions Straight-sided Mexican hat Bowl Features of Combustion Bowl Designs CI combustion cycle P-crank angle and P-volume diagram Valve timing events In Cylinder Measurements This graph shows the fuel injection flow rate, net heat release rate and cylinder pressure for a direct injection CI engine. Start of injection Start of combustion End of injection Heat release diagram of CI combustion Combustion in CI Engine The combustion process proceeds by the following stages: Ignition delay (ab) - fuel is injected directly into the cylinder towards the end of the compression stroke. The liquid fuel atomizes into small drops and penetrates into the combustion chamber. The fuel vaporizes and mixes with the high-temperature high-pressure air. Premixed combustion phase (bc) combustion of the fuel which has mixed with the air to within the flammability limits (air at high-temperature and high- pressure) during the ignition delay period occurs rapidly in a few crank angles. Mixing controlled combustion phase (cd) after premixed gas consumed, the burning rate is controlled by the rate at which mixture becomes available for burning. The rate of burning is controlled in this phase primarily by the fuel-air mixing process. Late combustion phase (de) heat release may proceed at a lower rate well into the expansion stroke (no additional fuel injected during this phase). Combustion of any unburned liquid fuel and soot is responsible for this. Four Stages of Combustion in CI Engines Start of injection End of injecction -10 TC -20 10 20 30 Combustion steps in DI diesel engine Ignition Delay Ignition delay is defined as the time (or crank angle interval) from when the fuel injection starts to the onset of combustion. Both physical and chemical processes must take place before a significant fraction of the chemical energy of the injected liquid is released. Physical processes are fuel spray atomization, evaporation and mixing of fuel vapour with cylinder air. Good atomization requires high fuel-injection pressure, small injector hole diam., optimum fuel viscosity, high cylinder pressure (large divergence angle). Rate of vaporization of the fuel droplets depends on droplet diameter, velocity, fuel volatility, pressure and temperature of the air. Chemical processes similar to that described for autoignition phenomenon in premixed fuel-air, only more complex since heterogeneous reactions (reactions occurring on the liquid fuel drop surface) also occur. Fuel Ignition Quality The ignition characteristics of the fuel affect the ignition delay. The ignition quality of a fuel is defined by its cetane number CN. For low cetane fuels the ignition delay is long and most of the fuel is injected before autoignition and rapidly burns, under extreme cases this produces an audible knocking sound referred to as diesel knock. For high cetane fuels the ignition delay is short and very little fuel is injected before autoignition, the heat release rate is controlled by the rate of fuel injection and fuel-air mixing smoother engine operation. Cetane Number The method used to determine the ignition quality in terms of CN is analogous to that used for determining the antiknock quality using the ON. The cetane number scale is defined by blends of two pure hydrocarbon reference fuels. By definition, isocetane (heptamethylnonane, HMN) has a cetane number of 15 and cetane (n-hexadecane, C 16 H 34 ) has a value of 100. In the original procedures -methylnaphtalene (C 11 H 10 ) with a cetane number of zero represented the bottom of the scale. This has since been replaced by HMN which is a more stable compound. The higher the CN the better the ignition quality, i.e., shorter ignition delay. The cetane number is given by: CN = (%hexadecane) + 0.15 (% HMN) The method developed to measure CN uses a standardized single-cylinder engine with variable compression ratio The operating condition is: Inlet temperature ( o C) 65.6 Speed (rpm) 900 Spark advance ( o BTC) 13 Coolant temperature ( o C) 100 Injection pressure (MPa) 10.3 With the engine running at these conditions on the test fuel, the compression ratio is varied until combustion starts at TC, ignition delay period of 13 o . The above procedure is repeated using blends of cetane and HMN. The blend that gives a 13 o ignition delay with the same compression ratio is used to calculate the test fuel cetane number. Cetane Number Measurement Cetane vs Octane Number The octane number and cetane number of a fuel are inversely correlated. Gasoline is a poor diesel fuel and vice versa. Cetane number C e t a n e m o t o r
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n u m b e r Factors Affecting Ignition Delay Injection timing At normal engine conditions the minimum delay occurs with the start of injection at about 10-15 BTC. The increase in the delay time with earlier or later injection timing occurs because of the air temperature and pressure during the delay period. Injection quantity For a CI engine the air is not throttled so the load is varied by changing the amount of fuel injected. Increasing the load (bmep) increases the residual gas and wall temperature which results in a higher charge temperature at injection which translates to a decrease in the ignition delay. Intake air temperature and pressure an increase in ether will result in a decrease in the ignition delay, an increase in the compression ratio has the same effect. (gauge) Factors Affecting Ignition Delay CI Engine Types Two basic categories of CI engines: i) Direct-injection have a single open combustion chamber into which fuel is injected directly ii) Indirect-injection chamber is divided into two regions and the fuel is injected into the prechamber which is connected to the main chamber via a nozzle, or one or more orifices. For very-large engines (stationary power generation) which operate at low engine speeds the time available for mixing is long so a direct injection quiescent chamber type is used (open or shallow bowl in piston). As engine size decreases and engine speed increases, increasing amounts of swirl are used to achieve fuel-air mixing (deep bowl in piston) For small high-speed engines used in automobiles chamber swirl is not sufficient, indirect injection is used where high swirl or turbulence is generated in the pre-chamber during compression and products/fuel blowdown and mix with main chamber air. Types of CI Engines Direct injection: quiescent chamber Direct injection: swirl in chamber Indirect injection: turbulent and swirl pre-chamber Orifice -plate Glow plug DI and IDI Combustion chamber designs Important Combustion Bowl dimensions Straight-sided Mexican hat Bowl Features of Combustion Bowl Designs Direct Injection quiescent chamber Direct Injection multi-hole nozzle swirl in chamber Direct Injection single-hole nozzle swirl in chamber Indirect injection swirl pre-chamber General characteristics of DI and IDI Engines Combustion Characteristics differences Combustion Characteristics differences Higher Higher Harsher Higher Higher Lower Higher Higher Heavier Lower Lower Higher Lower Peak combustion pressure Peak Combustion temp Combustion severity Rate of pressure rise Noise harshness Heat rejection Fuel economy Fuel system pressure Engine structure EMISSIONS HC CO NOx PM Lower Lower Harsh Lower Lower Higher Lower Lower Lighter Higher Higher Lower Higher DI Characteristics IDI Other Types of CI Engines Two vs. Four stroke Turbocharged Vs. Naturally Aspirated Low speed Vs. High Speed Mechanically Vs. Electronically Control SOHC Vs. DOHC Off Highway Vs. On Highway Direct Vs. Indirect injection Interesting points about CI Combustion Combustion delay lead to diesel knock Fuel properties - improve performance, cetane number is measured High cetane number low octane Fuel concentrated no minimum fuel limit Fuel quantity can control engine Higher injection lead to higher engine output no throttle thus higher part-load efficiency than SI engine Poorer mixing require excess oxygen Minimum practical air to fuel ratio is 18:1 to 25:1 Improving with combustion chamber design Lower CO than SI Less power than equivalent SI Functions of the fuel injection system Main Functions Injection timing control Injection quality control Proper Atomization and Penetration Additional Functions Pilot injection Rate shaping Post Injection Effects on Injection Controls Show effects of Injection timing Effects on Injection Controls Show effects of Pilot Injection and injection rate shaping. Effects on Injection Controls Show effects of Injection timing Injection rate control (IRC) Injection Pressure Effects on Injection Controls Show effects of Injection timing Injection rate control (IRC) Injection Pressure Injection Pressure Vs. time Characteristics of Injection pressure Types of Injection Systems Pump-Line-Nozzle (P-L-N) Types of Injection Systems Unit Injector (UI) Types of Injection Systems Common Rail (CR) Regulater Emissions from CI Engines Un Regulater Emissions from CI Engines Sources of HC Sources of CO Sources of NOx NOx Reduction Technologies Injection Timing Retard Intake Charge cooling NOx Reduction Technologies Injection Timing Retard caused lower peak combustion pressure thus lower maximum combustion temperature that results in lower NOx. Effects of colder intake charge air on peak combustion pressure. NOx Reduction Technologies NOx Reduction Technologies Injection Pressure Improved Fuel economy NOx Reduction Technologies Injection Rate Shaping Effects of Injection rate shaping on rate of pressure rise NOx Reduction Technologies Injection Rate Shaping Effects of Injection rate shaping on combustion pressure. NOx Reduction Technologies Injection Rate Shaping Effects of Injection rate shaping and pilot quantity on emissions. Effects of pilot injection on combustion noise NOx Reduction Technologies Injection Rate Shaping Effects of injection pilot quantity prior to ignition on emissions. NOx Reduction Technologies Exhaust gas recirculation Effects of various diluent in intake mixture. Effects of EGR on intake manifold temperature. Effects of EGR on NOx formation. NOx Reduction Technologies Effects of Injection Timing Retard Vs. Exhaust gas recirculation on Fuel consumption NOx Reduction Technologies Effects of Injection Timing Retard Vs. Exhaust gas recirculation on Particulate emissions and composition. This method may affect PM emissions as shown below: NOx Reduction Technologies Effects of water emulsion on NOx emissions at various injection timing and compression ratio. Diesel with water Emulsion may be used to control NOx. Definition of Particulate Matter Composition of particulate emission Sources of PM Effects of Fuel Sulfur on PM distribution Effects of EGR on Particle size distribution Comparison of Nanoparticle concentration between different combustion systems Particulate Reduction Technologies Improved Air management turbocharger for low speed high load conditions Increased ait through turbocharger Increased air by increasing density through air cooling Particulate Reduction Technologies Improved combustion system Improved PM oxidation. Improved mixture preparation through intake port design (swirl port) Improved combustion system design Particulate Reduction Technologies Improved combustion system Improved PM oxidation. Improved mixture preparation through intake port design (swirl port) Improved combustion system design Particulate Reduction Technologies Improved oil control Through cylinder bore honing (cross-hatch) Through piston ring design Particulate Reduction Technologies Improved injection system Increased injection pressure Optimized injector hole size Reduced nozzle sac volume Electronic injection control Particulate Reduction Technologies Rated speed optimization Effects of Sharp cut-off for end of injection Particulate Reduction Technologies Reduction of sulfur in diesel Technology options